Abstract The occurrence of ripples on the workpiece surface after solidification in electron-beam weld or melting is experimentally and analytically investigated. The maximum accelerating voltage and welding current of electron-beam welder are 60kV and 50mA, respectively, while the workpieces are four different materials containing different quantities of sulfur. Using a scale analysis to account for heat transfer and fluid flow induced by different quantities of surface active element in the molten pool. The result predicted results show good agreement with experimental data.

Increase in consumption of fresh produce over the past decade has resulted in a rise in incidents of foodborne outbreaks due to pathogens. Chemical sanitizers have been extensively used in the industry for decontamination of fresh produce. However, they are ineffective in certain commodities and under certain processing conditions, necessitating the evaluation of alternative technologies. Electron beam irradiated sliced cantaloupe were tested for 21 days of storage for total aerobic bacterial counts, texture, color and sensory parameters as a function of irradiation doses 0, 0.7 and 1.4 kGy and the wash treatments, water and 200 mg/L chlorine applied to the melons before cutting. Melons washed only with water prior to cutting had total aerobic bacterial counts of 4.0, 2.0 and 0.8 log cfu/g on day 0 at irradiation doses of 0, 0.7 and 1.4 kGy respectively. On day 0, melons washed with chlorine prior to cutting had total aerobic bacterial counts of 2.7, and 0.7 log cfu/g at irradiation doses of 0 and 0.7 kGy and below detection limit at 1.4 kGy. Texture measured as compression force was lower only for cantaloupe irradiated at 1.4 kGy. Irradiation did not affect objective color and descriptive attribute flavor and texture sensory attributes of cantaloupe. Irradiation reduced Salmonella Poona by 1.1 log cfu/g at 0.7 kGy and 3.6 log cfu/g at 1.5 kGy. The D-value of S. Poona on irradiated sliced cantaloupe was found to be 0.211 kGy. Among the spoilage organisms, lactic acid bacteria and mold were reduced effectively by irradiation but there was no significant effect on reduction of yeasts. Our results show that electron beam irradiation in combination with chemical sanitizers is effective in decontamination of fresh-cut produce. Electron microscopy images provided valuable information on attachment sites of S. Poona on cantaloupe rind. The ineffectiveness of chemical sanitizers due to possible inaccessibility to pathogens in these attachment sites provides the basis for application of irradiation in decontamination of fresh produce.

A chemical solution composed of paraffin wax, chloroform, and methyl yellow biological indicator was shaped into a solid 3-D apple phantom to determine absorbed dose from e-beams and X-rays. The purpose of this research was to determine the most uniform irradiation treatment on apple-phantoms (a complex shaped target) and GAFCHROMIC® HD-810 films using electron beams from (1) a 2 MeV Van de Graaff (VDG) accelerator, (2) a 10 MeV Linear Accelerator (LINAC), and (3) X-rays from a 5 MeV LINAC. Irradiation with the VDG accelerator confirmed that tilting the apple-phantom yaxis towards the e-beam source by 90 degrees, 45, and 22.5 degrees resulted in more uniform treatment in both the methyl yellow apple phantom and HD-810 film. The phantoms were over-exposed at the top and bottom regions when their y-axis was oriented exactly parallel to the e-beam at 22.5-degrees. The 45-degree orientation ensured uniformity throughout the whole apple surface without overexposing it at the top and bottom. In contrast, the 90-degree orientation resulted in the least effective treatment with the bottom and top region not receiving any radiation. A 10 MeV dual e-beam showed uniform penetration from top to bottom in the HD-810 film and apple phantoms. The HD-810 film responded linearly with doses up to 1.5 kGy while the methyl yellow response was non-linear up to 0.5 kGy maximum. The X-ray irradiation completely penetrated the apple phantoms from top to bottom showing excellent lateral uniformity at different penetration depths.

<p>This thesis describes the development, characterization andoptimization of compact, high-brightness, liquid-jet-targetx-ray sources. Two different source types have been developedfor different wavelength regions and applications.</p><p>A laser-plasma source for generating soft x-ray andextreme-ultraviolet radiation has been further developed forsoft x-ray microscopy and extreme-ultraviolet lithography. Thiswork focused on improved target stability, increased conversionefficiency and decreased debris production. For x-raymicroscopy applications using carbon-containingliquid-jetdroplet targets, the droplet stability has beeninvestigated and a method for source stabilization introduced.This source has also been optimized in terms of flux per debriswith respect to target material and size. Forextreme-ultraviolet lithography applications, aliquid-xenon-jet-target laser-plasma source system has beengreatly improved, especially in terms of stability andconversion efficiency. This source has also been characterizedin terms of, e.g., source size, angular distribution, andrepetition-rate capability. For extremeultraviolet lithography,the possible use of tin as a target material has also beenstudied and conversion efficiency and debris measurementsperformed.</p><p>A new anode concept for electron-impact hard x-ray sourcesbased on high-speed liquidmetal jets has been introduced.Initial calculations show that this new target concept couldpotentially allow more than a hundred-fold increase in sourcebrightness compared to existing state-of-the-art technology. Alow-power, proof-of-principle, experiment has been performed,verifying the basic source concept. Scaling tohigh-poweroperation is discussed and appears plausible. A main obstaclefor high-power operation, the generation of a microscopichigh-speed jet in vacuum, is investigated usingdynamic-similarity experiments and shown to be feasible.Finally, initial medium-power experiments, approaching currentstate-of-the-art sources in terms of brightness, have beenperformed.</p>

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Diamond is widely known for its extraordinary properties, such as high hardness, thermal conductivity, electron mobility, energy bandgap and durability making it a very attractive material for many applications. Synthetic diamonds retain most of the attractive properties of natural diamond. Among the types of synthetic diamonds, nanocrystalline diamond (NCD) is being developed for electrical, tribological, optical, and biomedical applications. In this research work, NCD films were grown by the pulsed electron beam ablation (PEBA) method at different process conditions such as accelerating voltage, pulse repetition rate, substrate material and temperature. PEBA is a relatively novel deposition technique, which has been developed to provide researchers with a new means of producing films of equal or better quality than more conventional methods such as Pulsed Laser Deposition, Sputtering, and Cathodic Vacuum Arc. The deposition process parameters have been defined by estimating the temperature and pressure of the plasma particles upon impact with the substrates, and comparing the data with the carbon phase diagram. Film thickness was measured by visible reflectance spectroscopy technique and was in the range of 40 – 230 nm. The nature of chemical bonding, namely, the ratio (sp3/sp3+sp2) and nanocrystallinity percentage were estimated using visible Raman spectroscopy technique. The films prepared from the ablation of a highly ordered pyrolytic graphite (HOPG) target on different substrates consisted mainly of nanocrystalline diamond material in association with a diamond-like carbon phase. The micro-structural properties and surface morphology of the films were studied by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The mechanical properties of the NCD films were evaluated by nano-indentation.

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No description available.

Noble metal nanoparticles are of great interest due to their tunable optical and radiative properties. The specific wavelength of light at which the localized surface plasmon resonance occurs is dependent upon the shape, size and composition of the particle as well as the dielectric constant of the host medium. Thus, the optical properties of noble metal nanoparticles can be systematically tuned by altering these specific parameters. The purpose of this thesis is to investigate some of these properties related to metallic nanoparticles. The first several chapters focus on theoretical modeling to predict and explain various plasmonic properties of gold and silver nanoparticles while the later chapters focus on more accurately combining experimental and theoretical methods to explain the plasmonic properties of hollow gold nanoparticles of various shapes. The appendix contains a detailed description of the theoretical methods used throughout the thesis. It is intended to serve as a guide such that a user could carry out the various types of calculations discussed in this thesis simply by reading this appendix.

Mushrooms are one of the protein rich foods, however they have a short pro-harvest life (2 to 3 days) compared to most vegetables. The aim of this study was to evaluate whether applying an anti-browning solution using vacuum impregnation and then electron beam irradiation can be used to extend the shelf life of fresh-cut mushrooms (Agaricus bisporus). Solutions made with (a) 2% ascorbic acid + 1% calcium lactate, (b) 2% citric acid + 1% calcium lactate, (c) 1% chitosan + 1% calcium lactate, and (d) 1% calcium lactate were used to impregnate mushroom slices at different vacuum pressures, vacuum pressure times, and atmospheric restoration times. Mushrooms were also irradiated at a dose of 1 kGy using a 1.35 MeV e-beam accelerator and their quality was evaluated in terms of color, texture, and microbial growth during 15 days storage at 4 degrees C. The best vacuum impregnation treatment was the 2% ascorbic acid and 1% calcium lactate solution using a vacuum pressure of 50 mmHg for 5 minutes and an atmospheric restoration time of 5 minutes. The control (not treated) and impregnated samples lost their structure (softening) during storage. The irradiated samples lost their firmness by day 4 of storage. The addition of calcium lactate to the samples during the treatment helped to keep the product’s texture during the 15 days storage time. Color of the mushrooms changed during storage for all the control and impregnated samples and only the irradiated samples showed an acceptable color by the end of day 15. Aerobics and psychrotrophics counts were significantly reduced by irradiation; while yeast and molds population increased by day 9 and were not completely inactivated with a dose of 1 kGy. Sensory panelists preferred the treated samples over the controls. The best treatment was the combination of vacuum impregnation with irradiation according to the consumer studies.