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The risk for climate change is a growing concern for theglobal society. According to what is known as the Kyoto Protocol,developed countries have committed themselves to reduce theirgreenhouse gas (GHG) emissions. The purpose of this thesis hasbeen to analyse opportunities for CO2 reductions in Swedish pulpand paper mills. The pulp and paper industry accounts forsignificant shares of the Swedish utilisationof both electricityand, in particular, biomass fuels. In this thesis, it has been agoal to focus not only on the technical potential of alternativesfor CO2 reductions in the energy systems of pulp and paper mills,but also on analysing the costeffectiveness of the studiedmeasures. Moreover, the analysis has covered questions concerningthe capacity and willingness among the actors involved with thepulp and paper mills’energy systems to realise CO2reduction potentials. A broad techno-economical evaluation of available technologiesfor increased power production as well as more efficient energyutilisation is carried out. Furthermore, a more indepth analysisof pulp mill-based biomass energy with CO2 removal and permanentsequestration (BECS) is presented. An evaluation is made of thepotential for pulp and paper production with a negative CO2balance through the implementation of BECS. In recent yearsoutside suppliers, mainly energy service companies (ESCOs), havebegun to operate energy facilities in some Swedish pulp and papermills. Based on interviews with managers from pulp and papercompanies and ESCOs, the main driving forces behind theincreasing co-operation as well as the opportunities and riskswith energy related co-operation are presented. Furthermore, the technical possibility of carbon-negativitythrough the implementation of BECS is discussed in relation tocarbon management on both corporate and global levels. The extentto which CO2-reducing measures in pulp and paper mills arerealised will have an impact on Sweden’s capacity to reachCO2 reduction targets. Whether or not technologies for CO2capture and sequestration are developed and implemented inSwedish pulp mills has a very large impact on the size ofSweden’s long-term CO2 reduction potential. Moreover, thedevelopment of business and competence focus in pulp and papercompanies and ESCOs suggests that cooperation will become ofincreasing importance for future sustainable industrial energymanagement. <b>Keywords:</b>CO2 reduction, pulp and paper industry, energysystem, biomass, CO2 capture and sequestration, black liquor,gasification, power production, outsourcing, sustainable energymanagement

The increased concentration of greenhouse gases in theatmosphere, in particular CO2, is changing the Earth’s climate. Accordingto the Kyoto protocol, where the international community agreedon binding emission targets, developed countries are committedto reduce their greenhouse gas emissions. The increased use ofbiomass in energy systems is an important strategy to reduce CO2emissions. The purpose of this thesis has been toanalyse the opportunities for Sweden to further reduce CO2emissions in the energy system, by rationallyutilising woody biomass energy. The characteristics of currentcommercially operating biofuel-based CHP plants in Sweden aresurveyed and systematically presented. A consistent andtransparent comprehensive reference base for system comparisonsis given. Furthermore, the fuel effectiveness and contributionto CO2reduction is calculated. The governmentalsubsidies of the CHP plants’investment, expressed as costof specific CO2reduction, appears to be low. The competitiveness of biomass-fuelled energy production inrelation to fossil-based production with carbon capture isanalysed, showing that the biomass-fuelled systems provide acompetitive option, in terms of cost of electricity andefficiencies. The remaining Swedish woody biofuel potential ofat least 100 PJ/yr is principally available in regions with abiomass surplus. Transportation is therefore required to enableits utilisation in a further national and international market.Refining the biofuel feedstock to pellets, or even furtherrefining to motor fuels (DME, methanol or ethanol) or power,could facilitate this transport. Different options for fuelrefining are studied and compared. The entire fuel chain, fromfuel feedstock to end users, is considered and CO2emissions are quantified. Substituting fuelpellets for coal appears to be the most costeffectivealternative and shows the largest CO2reduction per energy unit biofuel. Motor fuelsappear more costly and give about half the CO2reduction. Transportation of the upgraded biofuelpellets is highly feasible from CO2emissions point of view and does not constitute ahindrance for further utilisation, i.e. the pellets can betransported over long distances efficiently with only limitedemissions of CO2. Bioenergy utilisation has additional features forenvironmental improvement, apart from the CO2aspect. Waste heat from biofuel-based CHP can becost-effectively used in conjunction with sewage treatment. Theincoming sewage water to the nitrification process can bepreheated with the waste heat, and thereby substantiallyenhance the nitrification and the reduction of ammoniumnitrogen during the winter season. <b>Keywords:</b>CO2reduction, energy system, biofuel, CHP, refining,fuel pellets, ethanol, methanol, DME, fuel substitution, sewagewater, nitrification.

The turbine technology improvements from 1980 onwards have considerably increased mechanical and thermal stresses on turbine oils which, cause oil oxidation and thereby turbine oil degradation (Livingstone et al., 2007; Sasaki &amp; Uchiyama, 2002). If the oil degradation problem is ignored, this might result in serious turbine system erratic trips and start-up operational problems (Overgaag et al., 2009). Oil oxidation by-products, in other words, sludge and varnish contaminants, lead stated turbine operation-tribological problems. Hence, sludge and varnish presence in turbine oil become a major reason for declining turbine reliability and availability. In the power generation industry, heavy-duty gas turbines as well as steam turbines have been lubricated with mineral based turbine oils for many decades (Okazaki &amp; Badal, 2005). First, generally Group I oils (mineral base oils produced by solvent extraction, dewaxing) were used. Nevertheless, this group of oils has lower oxidation resistance. Therefore, modern gas turbines demand oils which have better oil oxidation resistance, and lower sludge and varnish contaminants tendency (Hannon, 2009). Today, there are many turbine lubricants available on the market. Besides Group I oils, more and more Group II oils (mineral base oils produced by hydro cracking and hydro treating) are selected in service, and having increased oil oxidation resistance. However field inspections demonstrate that Group II oils also experience sludge and varnish problems as well as Group I oils. Primary reason for these phenomena is the antioxidant additive packages that are used in Group II oils (Overgaag et al., 2009). In any case with recent oil formulations, oil degradation products still exist in current turbine oils, and will continue to do so in natural process. These sludge and varnish contaminants are less than 1 micron in size. Thus, they can pass turbine oil system standard mechanical filters without obstruction. With regard to keep the turbine systems in best operational conditions, external turbine oil cleaning practices became crucial to remove these less than 1 micron size oil degradation products from turbine oils. Current effective method for removing the sludge and varnish is to use electrostatic oil cleaners (Moehle &amp; Gatto et al., 2007). Since the majority of turbine user and operator population have been shifted to use Group II based oils to counter the increased sludge and varnish problems, traditional oil cleaners became insufficient to remove sludge and varnish from Group II. (Due to Group II oils have different oil characteristics such as oil oxidation stability and solvency capability). With this awareness, thesis project is looking for ways to introduce and develop an Advanced Electrostatic Oil Cleaner to increase the availability and reliability figures of heavy-duty gas turbines against the rising amount of oil degradation products in modern formulated turbine oils. ECC (Electrostatic Cooled Cleaner) is an electrostatic oil cleaner device to clean and cool mineral based turbine oils for heavy-duty gas turbine applications by removing the sludge and varnish - oil contaminants from turbine oils. The basic principle of the ECC is based on the electrostatic force produced by parallel positioned electrodes which are charged with a high D.C. voltage. Oil contaminants- sludge and varnish have polar nature. Therefore, they are attracted by electrostatic forces whose intensity is proportional to the voltage applied. With the oil flowing in parallel to these electrodes, the polar particles in the oil (which is only neutral /no polar) are caught by filter media positioned between these electrodes. Small investments on advanced oil cleaner result in big savings on turbine system performance. Increased turbine availability and reliability predominantly reduce maintenance costs and risks besides, and thus maximizing revenue by extending heavy-duty gas turbine operational life. An introduced prototype of the ECC-D4 model was tested using two Group II and one Group I oils. The amounts of 200 liter (each) test oils were circulated approximately 300 times through the ECC-D4. In each 3 oil cleaning test sessions, it is proved that the oil insolubles content decreased approximately 40% in tested turbine oils within about 240 ECC-D4 operating hours. With taken base of heavy-duty gas turbine characteristics such as 400 MW power production capacity, annually 8000 operating hours, and 15000 liter oil reservoir volume; it is estimated that the ECC-D4 can extend the oil service-life from 24000 to 48000 operating hours (which is approximately the oil service end-life). In addition to that, assuming the ECC-D4 investment cost as 30k€, about 15k€ savings per year through the new turbine oil and component replacement costs, besides turbine operation profit losses. Moreover, the ECC-D4 returns on investment with a rate of 39 % for defined heavy-duty gas turbine. In general perspective of ECC-D4, it makes heavy-duty gas turbine infrastructure innovative, fully integrated and committed to fulfilling the need for clean, efficient, reliable power production practices in an environmental manner.

<p>The risk for climate change is a growing concern for theglobal society. According to what is known as the Kyoto Protocol,developed countries have committed themselves to reduce theirgreenhouse gas (GHG) emissions. The purpose of this thesis hasbeen to analyse opportunities for CO2 reductions in Swedish pulpand paper mills. The pulp and paper industry accounts forsignificant shares of the Swedish utilisationof both electricityand, in particular, biomass fuels. In this thesis, it has been agoal to focus not only on the technical potential of alternativesfor CO2 reductions in the energy systems of pulp and paper mills,but also on analysing the costeffectiveness of the studiedmeasures. Moreover, the analysis has covered questions concerningthe capacity and willingness among the actors involved with thepulp and paper mills’energy systems to realise CO2reduction potentials.</p><p>A broad techno-economical evaluation of available technologiesfor increased power production as well as more efficient energyutilisation is carried out. Furthermore, a more indepth analysisof pulp mill-based biomass energy with CO2 removal and permanentsequestration (BECS) is presented. An evaluation is made of thepotential for pulp and paper production with a negative CO2balance through the implementation of BECS. In recent yearsoutside suppliers, mainly energy service companies (ESCOs), havebegun to operate energy facilities in some Swedish pulp and papermills. Based on interviews with managers from pulp and papercompanies and ESCOs, the main driving forces behind theincreasing co-operation as well as the opportunities and riskswith energy related co-operation are presented.</p><p>Furthermore, the technical possibility of carbon-negativitythrough the implementation of BECS is discussed in relation tocarbon management on both corporate and global levels. The extentto which CO2-reducing measures in pulp and paper mills arerealised will have an impact on Sweden’s capacity to reachCO2 reduction targets. Whether or not technologies for CO2capture and sequestration are developed and implemented inSwedish pulp mills has a very large impact on the size ofSweden’s long-term CO2 reduction potential. Moreover, thedevelopment of business and competence focus in pulp and papercompanies and ESCOs suggests that cooperation will become ofincreasing importance for future sustainable industrial energymanagement.</p><p><b>Keywords:</b>CO2 reduction, pulp and paper industry, energysystem, biomass, CO2 capture and sequestration, black liquor,gasification, power production, outsourcing, sustainable energymanagement</p>

<p>The increased concentration of greenhouse gases in theatmosphere, in particular CO₂, is changing the Earth’s climate. Accordingto the Kyoto protocol, where the international community agreedon binding emission targets, developed countries are committedto reduce their greenhouse gas emissions. The increased use ofbiomass in energy systems is an important strategy to reduce CO₂emissions. The purpose of this thesis has been toanalyse the opportunities for Sweden to further reduce CO₂emissions in the energy system, by rationallyutilising woody biomass energy. The characteristics of currentcommercially operating biofuel-based CHP plants in Sweden aresurveyed and systematically presented. A consistent andtransparent comprehensive reference base for system comparisonsis given. Furthermore, the fuel effectiveness and contributionto CO₂reduction is calculated. The governmentalsubsidies of the CHP plants’investment, expressed as costof specific CO₂reduction, appears to be low.</p><p>The competitiveness of biomass-fuelled energy production inrelation to fossil-based production with carbon capture isanalysed, showing that the biomass-fuelled systems provide acompetitive option, in terms of cost of electricity andefficiencies. The remaining Swedish woody biofuel potential ofat least 100 PJ/yr is principally available in regions with abiomass surplus. Transportation is therefore required to enableits utilisation in a further national and international market.Refining the biofuel feedstock to pellets, or even furtherrefining to motor fuels (DME, methanol or ethanol) or power,could facilitate this transport. Different options for fuelrefining are studied and compared. The entire fuel chain, fromfuel feedstock to end users, is considered and CO₂emissions are quantified. Substituting fuelpellets for coal appears to be the most costeffectivealternative and shows the largest CO₂reduction per energy unit biofuel. Motor fuelsappear more costly and give about half the CO₂reduction. Transportation of the upgraded biofuelpellets is highly feasible from CO₂emissions point of view and does not constitute ahindrance for further utilisation, i.e. the pellets can betransported over long distances efficiently with only limitedemissions of CO₂.</p><p>Bioenergy utilisation has additional features forenvironmental improvement, apart from the CO₂aspect. Waste heat from biofuel-based CHP can becost-effectively used in conjunction with sewage treatment. Theincoming sewage water to the nitrification process can bepreheated with the waste heat, and thereby substantiallyenhance the nitrification and the reduction of ammoniumnitrogen during the winter season.</p><p><b>Keywords:</b>CO₂reduction, energy system, biofuel, CHP, refining,fuel pellets, ethanol, methanol, DME, fuel substitution, sewagewater, nitrification.</p>

Biomass-fuelled proton exchange membrane fuel cells (PEMFCs) offer asolution for replacing fossil fuel for hydrogen production. Through using thebiomass-derived hydrogen as fuel, PEMFCs may become an efficient andsustainable energy system for small and medium-sized enterprises. The aim ofthis thesis is to evaluate the performance and potential applications of biomassfuelledPEMFC systems which are designed to convert biomass to electricity andheat. Biomass-fuelled PEMFC systems are simulated by Aspen plus based ondata collected from experiments and literature.The impact of the quality of the hydrogen-rich gas, anode stoichiometry, CH4content in the biogas and CH4 conversion rate on the performance of the PEMFCis investigated. Also, pinch technology is used to optimize the heat exchangernetwork to improve the power generation and thermal efficiency.For liquid and solid biomass, anaerobic digestion (AD) and gasification (GF),respectively, are relatively viable and developed conversion technologies. ForAD-PEMFC, a steam reformer is also needed to convert biogas to hydrogen-richgas. For 100 kWe generation, the GF-PEMFC system yields a good technicalperformance with 20 % electrical efficiency and 57 % thermal efficiency,whereas the AD-PEMFC system only has 9 % electrical efficiency and 13 %thermal efficiency. This low efficiency is due to the low efficiency of theanaerobic digester (AD) and the high internal heat consumption of the AD andthe steam reformer (SR). For the environmental aspects, the GF-PEMFC systemhas a high CO2 emissions offset factor and the AD-PEMFC system has anefficient land-use.The applications of the biomass-fuelled PEMFC systems are investigated on adairy farm and an olive oil plant. For the dairy farm, manure is used as feedstockto generate biogas through anaerobic digestion. A PEMFC qualified for 40 %electrical efficiency may generate 360 MWh electricity and 680 MWh heat peryear to make a dairy farm with 300 milked cows self-sufficient in a sustainableway. A PEMFC-CHP system designed for an olive oil plant generating annual 50000 m3 solid olive mill waste (SOMW) and 9 000 m3 olive mill waste water(OMW) is simulated based on experimental data from the Biogas2PEM-FCproject1. After the optimization of the heat exchanger network, the PEMFC-CHP  system can generate 194 kW electricity which corresponds to 62 % of the totalelectricity demand of the olive oil plant.The economic performance of the PEMFC and biogas-fuelled PEMFC areassessed roughly including capital, operation &amp; maintenance (O&amp;M) costs of thebiogas plant and the PEMFC-CHP, the cost of heat and electricity, and the valueof the digestate as fertilizer. / <p>QC 20151109</p>

This thesis puts forth the means of a strategic approach to address a persistent problem in the energy system and in this way, to transition the built environment to a future state that is more exergy-aware to curb CO2 emissions. Such a vision is made possible by the six-fold contributions of the research work: I) An analytical model is developed, which for the first time, formulates the CO2 emissions that are compounded in the energy system as a function of the systematic failures to match the supply and demand of exergy. This model is namely the Rational Exergy Management Model or REMM. II) REMM is then applied to analyze the pathways in which it is possible to lead the built environment into addressing structural overshoots in its exergy supply to curb CO2 emissions. The cases that embody these pathways are also analyzed over a base case, including cases for sustainable heating and cooling. III) New tools are designed to augment decision-making and exemplify a paradigm shift in the more rational usage of exergy to curb CO2 emissions. These include a scenario-based analysis tool, new options for CO2 wedges, and a multi-fold solution space for CO2 mitigation strategies based on REMM. IV) The concept of a net-zero exergy building (NZEXB) is developed and related to REMM strategies as the building block of an exergy-aware energy system. The target of a NZEXB is further supported by key design principles, which address shortcomings in state-of-the-art net-zero design. V) A premier building that deployed the key design principles to integrate building technology in an innovative, exergy-aware design and received LEED Platinum is analyzed on the basis of the NZEXB target. The results validate that this building boosts net self-sufficiency and curbs compound CO2 emissions, which are then presented in a proposed scheme to benchmark and/or label future NZEXBs. VI) Based on the scalability of the best-practices of the NZEXB ready building, the means to realize a smarter energy system that has exergy-aware relations in each aspect of the value chain to curb CO2 emissions are discussed. This includes a target for such a network at the community level, namely a net-zero exergy community (NZEXC). As a whole, the results of the thesis indicate that the strategic approach as provided by REMM and the NZEXB target of the research work has the potential to steer the speed and direction of societal action to curb CO2 emissions. The thesis concludes with a roadmap that represents a cyclical series of actions that may be scaled-up at various levels of the built environment in a transition to be in better balance with the Planet. / QC 20111014

An eight-lot residential subdivision in central Wairarapa is being developed to demonstrate the principles of sustainable resource management. Local energy sources for low and high grade use, including electricity sourced from proposed grid-integrated, on-site, distributed generation will supplement imported network electricity. A unique component is an internal loop grid for lot connection that interfaces with the local network through a single connection point. A decision model was designed as a decision-support tool for the development based on the annual supply-demand electrical energy balance, site infrastructure covenants and a range of economic and technology criteria. Solar and wind resources were assessed for potential supply of electricity to the community energy system. Three demand profiles were developed using supplied and estimated electrical demand data; and included assumptions on thermal performance of the houses, the use of low-grade heat, user behaviour, and appliance use. Supply and demand were analysed as daily average profiles by hour for each month of the year. The decision model outputs were designed to give a graphic view of the system options. The accompanying output datasets also enabled a number of scenarios for connection configurations, load management, and economic sensitivity to be explored for their impact on the communal approach to managing energy. The viability of the community energy system is significantly influenced by managing demand level in conjunction with system size, capital cost management, and tariffs for electricity import and export. Energy requirements could be best met in the short term by installing a site-wide mixed generation system of sized capacity between 5 and 11kW, supported by metering and information technology to deliver management data to the residents. Future research opportunities exist to continue monitoring technical, economic and social outcomes from this unique community development. Incentivising private investment in userfocussed energy innovations is an option for New Zealand to consider in the current climate of market-driven large scale electricity developments.

Considerando que a duração do combate de judô pode variar entre poucos segundos até um período superior a 5 min, a caracterização da demanda fisiológica do combate na sua duração regulamentar e fracionada, assim como a relação dessas respostas com o nível de aptidão aeróbia e anaeróbia dos atletas é relevante para o aperfeiçoamento dos métodos de treinamento. Assim, o objetivo do presente estudo foi analisar a aptidão física, ações técnicas e respostas fisiológicas durante a luta de judô com diferentes durações. Para tanto, 12 atletas de judô foram submetidos a 10 sessões de avaliação. Nas duas primeiras sessões foram realizados quatro testes físicos para caracterização da aptidão aeróbia e anaeróbia dos membros superiores e inferiores. Nas demais sessões, os atletas foram submetidos a 15 combates simulados de judô (3 condições x 5 durações - 1, 2, 3, 4 e 5 min) com o mesmo oponente, em ordem aleatória e vendados quanto à duração do combate. Em uma das condições, os atletas simularam um combate real. Na segunda condição, os atletas lutaram usando um analisador de gases para mensurar o consumo de oxigênio, para a estimativa da contribuição dos sistemas de transferência de energia. Nessa condição foram impostas algumas adaptações de movimento. Para verificar se o uso do analisador de gases modificou as respostas obtidas, na terceira condição, os atletas lutaram com as mesmas adaptações, porém não usaram o equipamento. Em cada sessão foram conduzidos dois combates, intercalados por 60 min de recuperação. Foram quantificadas as respostas fisiológicas, perceptivas, de desempenho, de estrutura temporal e ações técnicas em todos combates. A comparação das variáveis dependentes foi realizada com uma análise de modelos mistos para medidas repetidas, seguida do post hoc de Bonferroni. As associações entre a aptidão aeróbia e anaeróbia com as variáveis do combate foram verificadas por meio da correlação de Pearson. Para todas as comparações pareadas significantes foi calculado o tamanho do efeito (d de Cohen). Em todas as análises foi adotado 5% como nível de significância. Os principais resultados demonstraram aumento da contribuição aeróbia com concomitante redução da contribuição dos sistemas anaeróbios com o transcorrer do combate, sendo a contribuição aeróbia superior à contribuição dos sistemas anaeróbios a partir do primeiro min de combate. O sistema anaeróbio lático contribuiu com a menor proporção do custo energético do combate de judô. As taxas de incremento das respostas fisiológicas e perceptivas por min de combate foram reduzidas com o transcorrer do combate, sendo as principais modificações observadas no início do combate, sugerindo que os atletas podem apresentar estratégia para modular seus esforços. Com o transcorrer do combate observou-se manutenção do tempo médio de esforço e ações aplicadas, porém houve aumento do tempo médio dos períodos de pausa. Após a realização do combate observou-se declínio da resistência muscular dinâmica dos membros superiores, manutenção da força isométrica máxima de preensão manual e melhora da potência muscular dos membros inferiores. As variáveis de aptidão aeróbia e anaeróbia relacionaram-se com menor queda do desempenho, maior taxa de golpes de perna e maior tempo médio de combate. Assim, observou-se predominância do sistema aeróbio para suprir a energia necessária para a realização do combate de judô. Além disso, maiores níveis de aptidão aeróbia e anaeróbia estão associados positivamente com o desempenho durante a luta / Considering that judo combat can last from a few seconds to up to more than 5 minutes, characterization of the physiological demands of combat in different time frames, and the relationship of these responses to an athlete\'s level of aerobic and anaerobic fitness is relevant to improving training methods. Thus, the objective of the present study was to describe the physiological demands of judo combat. Twelve judo athletes performed 10 experimental sessions. In the first and second sessions, four physical tests to characterize the aerobic and anaerobic fitness of the upper and lower limbs were performed. In the other sessions, the athletes performed 15 judo combat (involving 3 conditions x 5 durations of time: 1, 2, 3, 4 and 5 minutes) randomly determined, against the same opponent, on different days and blinded for time duration. In one condition, the athletes simulated actual combat. In the second condition, the athletes fought while using a gas analyzer to measure oxygen consumption in order to estimate the contribution of the energy systems. In this condition some motion adjustments were imposed. To verify if the use of the gas analyzer modified the responses obtained, in the third condition the athletes fought with the same adjustments, but did not use the equipment. These combat periods were divided into 8 sessions with two different conditions, separated by an interval of 60 minutes. The physiological, perceptual, performance, time-motion, and technical action responses were quantified in all matches. The comparison of the dependent variables was performed with an analysis of mixed models for repeated measures, followed by a post hoc Bonferroni. The associations between aerobic and anaerobic fitness to combat variables were verified using Pearson\'s correlation. For all significant pairwise comparisons the effect size (d Cohen) was calculated. A 5% level of significance was adopted for all analyses. The main results showed an increase in aerobic contribution with a concomitant reduction of the anaerobic contribution in the course of combat, given that the aerobic contribution was greater than the anaerobic contribution from the first minute of combat. The lactic anaerobic system contributed to the smaller proportion of energy cost in judo combat. The increment in rate of the physiological and perceptual responses per minute of combat decreased throughout the course of the combat, with the highest changes occurring at the beginning of combat, which suggest that judo athletes seem to modulate their effort. In the course of combat, maintenance of the average time of effort and actions occurred, but there was an increase in the average time of pause. After the combat, a decline in the dynamic strength endurance of the upper limbs was observed, while maximal isometric handgrip strength was maintained, and improvement of muscle power in the lower limbs was noted. The aerobic and anaerobic fitness variables were associated with lower fall performance, higher rate of leg attacks and a higher average time of standing combat. Thus, a predominance of the aerobic system in supplying the energy needed for the realization of judo combat was observed. In addition, higher levels of aerobic and anaerobic fitness are positively associated with performance during the combat