Approximately 6.6 million years ago in the Eastern Equatorial Pacific a large increase in biogenic mass accumulation rates (MAR’s) occurred. This increased level of biogenic mass accumulation persisted until about 4.4 Ma at which time levels returned to those similar to before the transition at 6.6 Ma. The exact nature of the change that facilitated this transition in biogenic MAR’s, however, was not understood. Here we present the results of a study which characterizes the diatom assemblage spanning the depositional transition at 6.6 Ma from sediments taken from ODP Hole 850B. A close inspection of lithology reveals a clear change in lithology from a diatom nannofossil ooze to a nannofossil diatom ooze at 6.6 Ma. This transition is immediately followed by the occurrence of laminated diatom ooze (LDO). Diatom absolute abundance data reveals three levels of productivity associated with pre-transitional, post-transitional, and LDO formational sediments. An increase in the absolute abundance of Thalassionema nitzschioides was the major contributor to the formation of post-transitional, and LDO sediments. The known ecological preferences of this species indicate an overall increase in nutrient availability followed by sporadic changes in nutrient availability. These changes in nutrient availability could be associated with the establishment, or increase in strength, of an upwelling cell and/or the increase in nutrients made available via upwelling due to a shoaling of the thermocline.

Five line transect surveys for marine mammals were conducted offshore of mainland Ecuador and the Galápagos Islands from 2008-2011. These data were used in conjunction with MODIS (Moderate Resolution Imaging Spectroradiometer) observations of ocean color and sea surface temperature (SST) to assess spatial and temporal relationships between surface oceanographic features and cetacean distribution within the Eastern Equatorial Pacific (EEP). Results from this study indicated that oceanographic processes affected cetacean distribution on inter-annual, seasonal, and weekly to monthly time scales. The spatial scales on which these processes affect cetacean distribution are small, the smallest associations being found at 4 km2 bin sizes, as well as 9 km2 and 36 km2 bin sizes. By utilizing ocean color and SST data from the MODIS instrument and analyzing variability of these parameters in addition to average concentration, cetacean distribution within the region was related to the locations of frontal boundaries. Cetaceans were grouped into two categories based on the trophic level and relative depths at which they forage. Cetaceans feeding nearer the ocean surface and lower on the trophic scale were generally found in cooler waters of higher average chlorophyll concentration and elevated variability. Those cetaceans feeding higher on the trophic scale and lower in the water column (mesopelagic and bathypelagic depths) were sighted within relatively warmer waters of reduced temperature variability near areas of high chlorophyll variability (though less variable and lower in average chlorophyll than surface feeding cetaceans), with little spatial and temporal lag between peak surface chlorophyll concentration and cetacean presence. The EEP is a biologically productive region with many competing economic and environmental interests. Ecuador is home to one of the largest artisenal fishing fleets in South America, and entanglement of various cetacean species has been a known issue for several decades (Félix and Haase, 2006; Castro and Rosero, 2010). Seismic exploration, shipping, and tourism are also found on the busy waterways surrounding both mainland Ecuador and the archipelago. The results of this study provide additional insight into the mesoscale processes affecting the distribution and habitat use of cetaceans within the EEP and South American waters and to support ongoing ecosystem management efforts.

Approximately 6.6 million years ago in the Eastern Equatorial Pacific a large increase in biogenic mass accumulation rates (MAR’s) occurred. This increased level of biogenic mass accumulation persisted until about 4.4 Ma at which time levels returned to those similar to before the transition at 6.6 Ma. The exact nature of the change that facilitated this transition in biogenic MAR’s, however, was not understood. Here we present the results of a study which characterizes the diatom assemblage spanning the depositional transition at 6.6 Ma from sediments taken from ODP Hole 850B. A close inspection of lithology reveals a clear change in lithology from a diatom nannofossil ooze to a nannofossil diatom ooze at 6.6 Ma. This transition is immediately followed by the occurrence of laminated diatom ooze (LDO). Diatom absolute abundance data reveals three levels of productivity associated with pre-transitional, post-transitional, and LDO formational sediments. An increase in the absolute abundance of Thalassionema nitzschioides was the major contributor to the formation of post-transitional, and LDO sediments. The known ecological preferences of this species indicate an overall increase in nutrient availability followed by sporadic changes in nutrient availability. These changes in nutrient availability could be associated with the establishment, or increase in strength, of an upwelling cell and/or the increase in nutrients made available via upwelling due to a shoaling of the thermocline.

The ocean reanalysis Simple Ocean Data Assimilation (SODA) 2.2.4 is used to explore the changes in upwelling from normal conditions to either El Nino or La Nina conditions. Physical and thermodynamic variables from the reanalysis are used to explore the structure and behavior of El Nino Southern Oscillation (ENSO) events. The results of this analysis show that sea surface temperature (SST), entrainment velocity, wind stress, mixed layer depth, wind curl, and heat content anomalies are in general agreement with ENSO theory. Interestingly, the distribution of upwelling based on the entrainment velocity is very patchy, which led us to explore zonal and meridional sections of vertical velocity. We used three methods to compute changes in upwelling during ENSO events. The first method computes upwelling within the areas of SST anomalies during ENSO events. During El Nino events upwelling shows prominent decadal variability, while during La Nina the decadal variability is weaker. A new upwelling index is used for the second method, and upwelling is computed in the areas of strong upwelling anomalies. The variability of upwelling is higher in periods of reduced upwelling than in periods of strong upwelling. Despite the fact that the new index is computed independently, it agrees in the timing of the index used to define ENSO events for this research. The first and second methods show that the amplitude of SST anomalies and upwelling anomalies do not have a direct relationship, suggesting that upwelling does not explain all of the variance in SST. The last method used is to compute changes in upwelling in the Nino 1+2 region during ENSO events. In the east Pacific there is almost no correlation between upwelling and SST anomalies during ENSO, but this might be attributed to the fact that the Nino 1+2 region is a relatively small region compared to the Nino 3.4 region that is used to define ENSO events. In general, the time series of SST and upwelling anomalies agree well just in the cases when ENSO events are prominently in the eastern Pacific. A comparison between yearly fisheries data from Ecuador and Peru and monthly data of SST anomalies during ENSO years is presented showing that during El Nino events the fish catch decreases and during La Nina events the fish catch increases. We infer that the increase or decrease in fish catch is associated to changes in fish populations, and that these changes are mainly due to availability of nutrients and changes in temperature during ENSO events.

Indiana University-Purdue University Indianapolis (IUPUI) / Paleoproductivity records during the late Pleistocene are sparse. The equatorial Pacific and the Southern Ocean are collectively responsible for the majority of the new production in the oceans. The nutrient and carbon mass balances of these regions must be constrained in order to fully understand net global biological productivity on glacial timescales. The geochemistry of two east-central equatorial Pacific Ocean cores (02° 33.48 N; 117° 55.06 W) and (00° 15.42 S; 113° 00.57 W) are used to examine changes in biological productivity due to nutrient upwelling on glacial timescales during the Pleistocene. The cores were recovered in March 2006 on the AMAT03 cruise, a site survey cruise for IODP Proposal 626. The total concentrations of Ca, Ti, Fe, Al, P, Ba, S, Mg, Sr, Zn and Mn were determined by a total sediment digestion followed by analysis by inductively coupled plasma-atomic emission spectrometry (ICP). Original solid forms of P for 34 evenly spaced samples throughout one core were determined using the P Sequential Extraction technique. This study is attempting to compare upwelling and productivity records by determining temporal records of nutrient proxies, using Latimer and Filippelli (2006) which focused on the Southern Ocean. Equatorial upwelling and Southern Ocean upwelling both appear to exhibit strong glacial timescale variability. The P geochemistry results indicate that the P signal is largely biological. The equatorial Pacific evidence, in accordance with Southern Ocean patterns, supports a nutrient budget-driven productivity signal over time. Gabriel M. Filippelli, Ph. D, Committee Chair

No description available.

The climate response of the equatorial Pacific to increased greenhouse gases is investigated using numerical experiments from five climate models participating in the Intergovernmental Panel on Climate Change Fourth Assessment Report. Changes in the heat budget of the surface layer in response to CO2 doubling (2xCO2) are analyzed in experiments with full-coupled ocean dynamics; and compared to experiments with uncoupled ocean dynamics. In full-coupled experiments, weaker ocean zonal currents driven by a slowing down of the Walker circulation reduce the ocean heat flux divergence throughout the equatorial Pacific. The resulting ocean dynamical heating enhances the surface warming due to increased clear-sky surface radiation in response to 2xCO2. The total radiative plus ocean dynamical heating are stabilized by evaporation and cloud feedbacks over the warm pool and by increased ocean vertical heat transport over the cold tongue. Increased near-surface thermal stratification enhances vertical heat transport in the cold tongue despite a reduction in vertical velocity. This ocean dynamical cooling is the dominant negative term in the heat budget changes over the eastern Pacific; and represents a strengthening of the processes leading to the annual cycle of the cold tongue, which increases by 0.4 K as a result. The stratification response is found to be a permanent feature of the equilibrium climate potentially linked to both thermodynamical and dynamical changes within the equatorial Pacific. To conclude, the relationship between the heat budget changes and the SST response is discussed along with implications for detecting these signals in the modern observational record.

Les coups de vent d’ouest (WWEs) issu de la variabilité synoptique atmosphérique jouent un rôle crucial dans les irrégularités d’ENSO en contribuant au déclenchement et au développement de sa phase chaude, El Niño. Les WWEs sont des événements haute fréquence peu prévisibles et dont les origines atmosphériques restent encore débattues. Dans le but d’affiner la prévisibilité d’ENSO, cette thèse caractérise la part stochastique de la part prévisible des WWEs ainsi que de leur réponse océanique et couplée. Dans une première partie, j’ai relié l’occurrence et les caractéristiques des coups de vent à des phénomènes de grande échelle comme l'oscillation de Madden-Julian, les ondes de Rossby atmosphériques et ENSO, à partir d’analyse d’observations. Ensuite, la forte sensibilité de la réponse océanique des WWEs à l’état de l’océan a été mise en évidence grâce à une série de simulations océaniques forcées. Finalement, une simulation d’ensemble réalisée avec un modèle couplé océan-atmosphère a permis d'explorer le rôle des WWEs dans l’évolution contrastée des années 1997,2014 et 2015 qui présentaient des conditions similaires et favorables au déclenchement d'El Niño. Les résultats de ce travail montrent que la stochasticité des WWEs aboutit à une limitation intrinsèque de la prévisibilité des caractéristiques d’El Niño. / Equatorial Pacific Westerly Wind Events (WWEs) impact ENSO evolution through their oceanic response and strongly contribute to its irregularities. WWEs are characterized by episodes of anomalous, short-lived, strong westerlies developing over the western Pacific warm pool. This thesis characterize the atmospheric origins and the oceanic and coupled impacts of these events in order to improve ENSO prediction. First, we show that, at intraseasonnal timescale, the Madden-Julian oscillation and the convectively coupled Rossby waves provide favourable conditions for the occurence of WWEs and confirm their modulation by ENSO at interannual timescale. Oceanic simulation with idealized forcing further allow characterizing and understanding the modulation of the SST response to WWE by the oceanic background state. Finally, The role of WWEs in the contrasted evolution of El Niño in 1997,2014 and 2015, which exhibited favourable conditions for El Niño to develop, is explored in ensemble simulations using a coupled ocean-atmosphere model. It is shown that the stochasticity of the WWEs acts as a strong limitation for ENSO predictability.

This study aims to unravel the ecological and evolutionary dynamics within the calcareous nannofossil communities at the Eocene/Oligocene (E/O) transition and during the Oligocene time when Cenozoic 'icehouse' conditions were established. The main question this study aims to answer is whether the changes in the nannofossil assemblages were controlled by intrinsic evolutionary trends or if the changes were controlled by environmental factors such as changes in temperature and nutrient availability in the surface water. These questions are addressed with detailed analyses of the taxonomy, biostratigraphy and fluctuations in abundance and diversity of calcareous nannofossil assemblages from a continuous latest Eocene through Oligocene sediment section from the ODP Site 1218 (8°53.38´N, 135°22.00´W), paleo-equatorial Pacific Ocean. An improved nannofossil taxonomy and biostratigraphy has been established. At the E/O transition, changes in the nannofossil preservation mimics changes in calcium carbonate content. A detailed investigation of late Eocene and Oligocene sediments yields age estimates for ten nannofossil bioevents. Morphometric studies of the Reticulofenestra umbilicus-R. hillae show that these cannot be subdivided into two different morphospecies. Based on different morphometry and stratigraphic ranges, the Oligocene Sphenolithus lineage appears to be the result of a combined anagenetic and cladogenetic evolution. A new nannolith species is described: Triquetrorhabdulus longus. High-resolution nannofossil data indicate changes in the composition, abundance and diversity of the mid-Oligocene assemblages. Intervals of high diversity index coincide with Oi-glaciation events. However, visual examination of the variations in abundance of nannofossil taxa do not appear to correlate with changes in either oxygen or carbon isotopes. This presumably indicates that a dynamic equilibrium did not exist between these Oligocene nannoplankton assemblages and changes in surface water temperature or productivity conditions. / Doctoral Thesis in Marine Geoscience at Stockholm University, Sweden 2009

Les alcénones constituent une classe de cétones insaturées à longue chaîne (C35 à C41)synthétisées par un nombre limité d’haptophytes. La proportion des alcènones en C37 di et triinsaturéesvarie en fonction de la température de croissance de l’haptophyte. A partir de cette caractéristique et de leur ubiquité dans l’environnement marin, un indice nommé '37U K =[C37 :2] / ([C37 :2 + C37 :3]) est utilisé depuis la fin des années 1980s comme paléomarqueur des températures des eaux de surface.Des processus de dégradation biotique et abiotique sélectifs, jusqu’alors partiellement ignorés,peuvent entraîner des biais significatifs (du fait de la perte préférentielle des alcénones les plus insaturées) dans les valeurs de paléotempératures estimées à partir de l’ '37U K . Ce travail a été entrepris dans le but d'étudier l'impact de ces processus diagénétiques sur les alcénones et d'évaluer leur importance dans l'environnement marin.Durant la première partie de ce travail, nous avons isolé et identifié diverses souches bactériennes à partir de cultures d’Emiliania huxleyi, que nous avons testées pour leur capacité à dégrader les alcénones. La souche Dietzia maris s'est révélée capable de dégrader sélectivement les alcénones. Cette dégradation sélective fait intervenir une époxydation initiale des doubles liaisons des alcénones, qui est vraisemblablement induite par une monoxygénase ayant une plus grande affinité pour la double liaison en position w29 et peut conduire à une augmentation des valeurs de l' '37U K de l’ordre de +0,10 (soit une surestimation des températures de +3°C).L'impact de ces processus de dégradation (biotique et abiotique) in situ s'est révélé plus oumoins significatif selon les zones géographiques considérées. En mer Méditerranée,l'augmentation des valeurs de l' '37U K (0,43 à 0,55) s'explique essentiellement par une forte autoxydation des alcénones lors de leur sédimentation. La détection d'alcénones stéréomutées à la surface du sédiment nous a permis d'estimer que les processus de stéréomutatio npouvaient entraîner un biais dans les valeurs de l' '37U K de +0,05 dans cette région. En Alaskaainsi que dans le Pacifique équatorial, les biais observés résultent essentiellement d’une dégradation bactérienne sélective des alcénones (+0,7 à +2,4°C et +2°C, respectivement).Lors de nos analyses de matériel particulaire provenant de l’océan Pacifique équatorial, nos observations ont mis en évidence une relation entre l’état de photo-oxydation des cellules phytoplanctoniques sénescentes et l’état physiologique des bactéries qui leur sont associées.Un transfert d’oxygène singulet (1O2) des phytodétritus aux bactéries entraînerait un déclin important de la croissance bactérienne et limiterait ainsi considérablement la biodégradation.Dans notre étude, ce transfert d’1O2 s’est révélé plus efficace dans les particules en suspension(forte photo-oxydation des bactéries) que dans les particules prélevées par trappes (forte biodégradation du phytodétritus). Cette différence s’expliquerait par l’abondance de particules riches en silice dans les particules prélevées par trappes (dominées par des agglomérats de diatomées) dont le caractère polaire réduirait la durée de vie de l’1O2.Nos résultats confirment que les processus de (i) dégradation bactérienne sélective, (ii)d'autoxydation et (iii) de stéréomutation peuvent introduire des bais significatifs dans les reconstructions de paléotempératures et des moyens de corriger les biais résultant de cette diagenèse ont été proposés afin d'améliorer les reconstructions de paléotempératures basées sur cet outil. / Alkenones constitute a class of long-chain unsaturated ketones (C35 to C41) synthesized by alimited number of haptophytes. The proportion of C37 di- and tri-unsaturated alkenones varies according to the growth temperature of the haptophytes. From this characteristic and theubiquity of alkenones in the marine environment, an index named '37U K = [C37: 2] / ([C37: 2 + C37:3]) is used since the late 1980s as paleomarker of sea surface temperatures. Selective biotic and abiotic degradation processes, previously ignored in the literature, canlead to significant biases (due to the preferential loss of the more unsaturated alkenones) in paleotemperature values estimated from the '37U K . This work was undertaken to estimate theimpact of diagenetic processes on alkenones in the marine environment.During the first part of this work, we isolated and identified various bacterial strains from cultures of Emiliania huxleyi, which were tested for their ability to degrade alkenones. Thestrain Dietzia maris sp. S1 appeared to be able to degrade selectively di- and tri-unsaturatedalkenones. This selective degradation involves an initial epoxidation of alkenone doublebonds, which is probably induced by a monooxygenase showing a greater affinity for the w29double bond and leads to increases of the '37U K values ranging from +0.05 to +0.10 units(corresponding to an overestimation of temperatures of 1.5 - 3°C).The impact of these biotic and abiotic degradation processes in situ was more or lesssignificant depending on the area considered. In Mediterranean Sea, increasing values of '37U Kwith depth (0.43 to 0.55) seemed to mainly result from an intense autoxidation of alkenones.The detection of stereomutated alkenones in surface sediments also attested to the importanceof these processes in this region (increased in '37U K values of +0.05 units). In contrast, in Alaska and Equatorial Pacific, the biases observed (+0.7 to +2.4°C and +2°C, respectively) appeared to be mainly induced by selective bacterial degradation of alkenones.Analyses of particulate matter from the Equatorial Pacific Ocean, revealed a relationshipbetween the state of photo-oxidation of senescent phytoplankton cells and the physiologicalstate of associated bacteria. A transfer of singlet oxygen (1O2) from phytodetritus to thebacteria may induce damages in bacteria and thus significantly limit biodegradation. This transfer of 1O2 appeared to be more effective in suspended particles (high photo-oxidation ofbacteria and preservation of phytodetritus) than in the sinking particles (weak photo-oxidationof bacteria and high biodegradation of phytodetritus). These differences were attributed to theabundance of particles rich in silica in sinking particles (dominated by agglomerates ofdiatoms), whose the polar character could reduce lifetime of 1O2.Our results confirm that the process of (i) selective bacterial degradation, (ii) autoxidation and(iii) stereomutation may introduce significant biases in the reconstruction ofpaleotemperatures. Some tools were proposed to correct some of these biases and thus toimprove the paleotemperature reconstructions based on alkenones