京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第22774号 / 工博第4773号 / 新制||工||1746(附属図書館) / 京都大学大学院工学研究科材料工学専攻 / (主査)教授 中村 裕之, 教授 田中 功, 教授 吉村 一良 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

Den industriella revolutionen kom med behovet av att bygga byggnader och broar, till en början förstod man inte vikten av armering och förstärkning av konstruktion. Men med tiden behövde man komma på någon strategi att göra konstruktionen starkare och mer hållbar, och det var då man började använda sig av förstärkning. I dagens moderna samhälle är det vanligare att bygga med betong, betong är det viktigaste byggmaterialet i världen. Det har flera egenskaper som garanterar en lång livslängd för konstruktionen; dess hållbarhet och styvhet är av störst intresse för att designa betongkonstruktioner. Andra egenskaper såsom täthet och bearbetbarhet är också viktiga. För att utnyttja betongegenskaperna korrekt måste nästan alla strukturer förstärkas på ett eller annat sätt. Därför har man under en lång period gjort stora forskningar på hur man kan göra betong starkt i draghållfasthet och inte bara i tryck. Moderna komplicerade konstruktionsformer kräver nya förstärkningsmetoder, komplexiteten i den nya strukturen både när det gäller höjd och bredd har nödvändiggjort behovet av nya metoder för betongarmering. En metod är användningen av järn-baserade minneslegeringar (Fe-SMA), genom forskning har det visat sig vara en effektiv metod för armering av stål. SMAs har unika egenskaper och det mest speciella är att det återgår till sin ursprungliga form även när det har deformerats. Som ett resultat av detta möjliggör det förstärkning av betong av vilken form och storlek som helst, de goda limegenskaperna hos betong och järn gör installationen komplett. Detta examensarbete resulterade att SMA har väldigt unika egenskaper som kommer att göra stora skillnader i byggbranschen. Detta gäller främst hos broar och är en väldigt aktuell metod som har förmågan att anpassa sig till den omgivande miljön. Utöver det kan den även justera sig själv för att säkerställa optimal och säker drift under normala och svåra belastnings villkor och det minimala kravet för underhåll.

Direction of the master's thesis is design and construct electronic device for testing available accumulators. Than there are in detail subscribe some metods of charging cells and their right usage to select type of cells. Also eventually problems that can become if the choice is false. Next part contains description of principles as several type accumulator works and their loading characteristic witch are important know for choose the best testing way. The most important knowledge is detection of stop point charging when accumulators are charged and following charging can be dangerous. Because there are more methods to detect this point so in thesis are overwrite. The most important part is design of tester. That is mapped to more segments witch communicating together. Controller part of intelligent tester contains ATmega128 microcontroller so there is present a passage of program code. Last section of master's thesis describe a physical consruction and explain division for smaller parts and hole process of tester function.

Philosophiae Doctor - PhD / The commercial need to improve the performance of low-cost organic solar cells has led to the idea for this research. The study discusses the synthesis of one dimensional TiO2 and ZnO nanowire arrays synthesised using a hydrothermal autoclave method and their application in bulk heterojunction inverted organic solar cells. Previous literature has shown that the precise manipulation, positioning and assembly of 1D nanostructures remain one of the greatest challenges in the field of nanotechnology, with much of the difficulty arising primarily from the lack of size and scale of the materials as well as the inability to visualise the nanostructures. In particular, one dimensional metal-oxides such as TiO2, ZnO and Fe2O3 have emerged as attractive alternatives to traditional semiconductor structures such as Si and GaAs as they are simple and inexpensive to manufacture, with research showing that application of ZnO nano-cones yield efficiencies of 8.4%, which is very attractive given the scope that exists in optimising the metal-oxide architecture. Much is still to be learned from the precise structural features of these materials and their influence on device performance. In this regard, this work largely focuses on this aspect of metal-oxide nanowires prior their application in organic solar cells.

Background Running is a popular form of exercise that more than 55 million Americans actively participate. Endurance running like marathon and half- marathon is getting increasingly popular among active runners. Although the effect of running is considered beneficial to bone health, the direct relationship between strains and strain gradients occurred during long distance running and bone changes is still not clear. Especially, given a high rate of injury associated with the first-time marathon, understanding the direct effect of strain stimuli on bone health is an important issue. Based on the previous studies, we hypothesized that the higher values of strain will induce bone adaptation more effectively and will lead to higher bone osteogenic changes. Since osteocytes sense shear stress caused by the interstitial fluid flow, which is created by the deformations, and regulate activities of osteoblasts and osteoclast that govern bone adaptation, we also hypothesized that the local strain gradient will create pressure differences within the interstitial fluid network and will increase fluid flow. Furthermore, due to that increased fluid flow, the regions with the higher strain gradient will experience a higher amount of bone adaptation. Thus, in this study, our purpose was to define the effect of the strains and strain gradients on bone changes within distal tibia, which is the most prone anatomical site to low risk stress fracture, during training for first-time marathon. Methods High-resolution and low-resolution computed tomographic (CT) images of the distal tibia were obtained before and after a self-selected training from runners who were actively training to participate in their first-time marathon in the next calendar year. The low resolution scan covered a 69.864 mm length of the distal end of the tibia while the high resolution CT scan covered a 9.02 mm region of the distal tibia. Using low resolution CT image based subject specific finite element (FE) models, the strains and strain gradients of the distal tibia at the instance of the peak ground reaction force (GRF) were calculated. The baseline and follow-up high resolution CT scans were used in high resolution peripheral quantitative CT (HRpQCT) analysis and the estimation of bone changes over the training period. Finally, the effect of strains and strain gradients on the distal tibia bone changes was estimated based on the FE model driven strain values and HRpQCT analysis driven bone changes. We used a linear mixed model to define the relationship between strain values and bone changes in the distal tibia. Results The strain values that occurred during marathon training had significant effects on bone changes in the distal tibia. Particularly, the strain gradients showed a higher effect than the strains. In the cortical compartment, the strain gradients, which were calculated as a strain difference of a node from the surrounding nodes (Strain Gradient-1), affected the bone mineral density (BMD) negatively, and per 1000 µε increase resulted in 2.123% decrease in the cortical BMD. The strain gradients, which were calculated as a strain difference of a node from the surrounding nodes normalized to distance to surrounding nodes (Strain Gradient-2), presented a positive effect on the cortical bone volume with a slope of 4.335% / 1000 µε. In the trabecular compartment, the strain gradient-1 showed negative effects on the percent change in BMD and bone mineral density (BMC), whereas the strain gradient-2 showed positive effects on the percent change in BMD and BMC. Conclusion The linear mixed model analysis revealed a statistically significant (p < 0.05) relationship between strain gradients that occurred during running and distal tibia bone changes. The strains, biometrics, and initial parameters of bone did not show any significant effect on the bone changes. The connection between local strain environment and bone changes in the distal tibia investigated in this study is an important step to understand the mechanism of mechanically induced bone adaptation.

This thesis work focus on evaluating the metallurgical bonding between the TiB2 andiron grains in the Fe-TiB2 composite. The starting materials were commercial materialsin form of Ferro-boron and Ferro-titanium that together with pure TiB2 powder formeda material with the composition seen below:FeB + FeTi + TiB2  52.3TiB2 + 45.7Fe + 2TiDuring sintering an iron liquid phase is formed where the boron from the FeB diffuse tothe titanium in FeTi which enables the formation of TiB2. The temperature used in theliquid phase sintering was chosen just above the three phase region, Fe-TiB2-liquid inthe phase diagram, to get an adequate densification of the samples. However, thetemperature could not be too high because of the internal stress and deformation thesamples would have been exposed to.After sintering the material properties and microstructure were examined throughPalmqvist indentations, Fargo and Transverse-Rupture-Strength tests and SEM studiesincluding EBSD.Through these tests the hardness was measured to 1323 HV and the microstructureconsidered to be fine with well distributed phases. The EBSD also showed that thebrittle Fe2B phase is present close to the TiB2 grains and that the porosity givesunreliable results for the Fargo and TRS-tests. The composite was impregnated withcopper to show that it may be possible to achieve wetting of the TiB2 phase by castingand to perform new tests on the material with less porosity.

In this thesis six different models of IPE240 have been created in order to study their behavior undershear, bending and torsion. These models simulate IPE240 but differ in the boundary conditions, inthe loading and the length of the beam and in some connections which connect certain elements. Inthis study the modeling and simulation of the steel member is executed in ABAQUS Finite ElementAnalysis software with the creation of input files. When developing a model for the finite elementanalysis a typical analysis process is followed. All the parameters that are required to perform theanalysis are defined initially to geometry which is half the beam due to symmetry, and the materialproperties of each model are defined too. Then a mesh is generated for each model, the loads of eachmodel are applied which are expressed as initial displacement. Subsequently, the boundary conditionsfor each model are defined and finally the model is submitted to the solver when the kind of analysishas been defined. Namely, the analysis which is performed in this thesis is static stress analysis.When the ABAQUS has run the models, the contour plots for the von Mises stresses for each modelare studied. In these contour plots, a large concentration of stresses and problems which arise in eachone of the models are notified. As it has been observed in all models, the beam yields at the flangesof the mid-span and collapses at the mid-span. Therefore, the failure at the mid-span is more criticalthan the failure at the support. Moreover, the beams are weak in bending due to the fact that theytwist almost 60-90 degrees under a large initial displacement at the control node. Additionally, much localized failure and buckling occurred at the mid-span, and local concentrated stresses also occurredat the bottom flange at the support due to the boundary conditions details.Thereafter, a verification of the results of the ABAQUS through the simple analytical handcalculations is performed. It is concluded that the error appearing in most selected points is small.However, in some points in the web of the mid-span the error is greater. Additionally, whilecomparing the load-displacement curves of the two different plastic behaviors, it is observed that themodel with an elastic-plastic with a yielding plateau slope behavior has smaller maximum loadresistance than the model with a true stress-strain curve with strain hardening behavior.Finally, some errors and warning messages have occurred during the creation of the input files of themodels and a way of solving them is suggested.

The usage of linear 3D FEA is widespread within the bridge design community, and although this tool provides substantial benefits in the design process, there are certain practical issues related to the application of this analysis tool. A situation in which such an issue prevails is when linear 3D FEA is used to analyze restraint forces due to thermal shrinkage or expansion in concrete slab frame bridges. Effects related to restraint forces in concrete are difficult to model and predict as these forces differ significantly in nature from external loads, and dealing with them in practical design situations is complicated. In this thesis, cracking due to restraint forces in concrete slab frame bridges was investigated using 3D non-linear FE-analyses in the software package ATENA 3D. Using volumetric finite elements, attempts were made to realistically capture the load response and cracking behavior of concrete slab frame bridges subjected to restraint forces induced by temperature differences among members. The initial parts of this thesis aims to find appropriate modelling techniques and material models for the prediction of cracks due to restraint forces in base restrained walls using a previously reported experimental research project as reference. Comparative simulations were performed, using crack widths and crack patterns as comparate. Overall good correspondence was obtained with an exception of deviation in cracks formed at locations near the restrained corners where crack widths were overestimated in the simulations. The technique used to model the restrained boundary proved to be highly influential in the context of obtaining realistic results. Subsequent to the comparative study, a parametric study was performed where the correlation between crack widths and selected attributes was investigated. The parameter which exhibited the most distinct influential effect on the results was the length-to-height (L/H) ratio of the wall. The applicability of a crack control approach intended for crack width estimation in liquid retaining and containment structures made of concrete exposed to thermally induced restraint forces, given in EN 1992-3, was then evaluated for use in design of concrete frame bridges. This approach proved to return conservative results for walls with low L/H-ratios when compared to results produced in the numerical simulations. Finally, a NLFE (non-linear finite element) model of a concrete slab frame bridge designed by the consultancy company Tyréns AB was composed and tested. Different procedures of applying temperature differences between front wall and bridge deck were evaluated. This study indicated that the width of cracks induced by lateral restraint forces decreased when temperature was modelled applying a discrete thermal gradient to members in contact with back filling material compared to using a uniform temperature in these members when temperature differences between bridge deck and wall was simulated. The interacting effects of permanent external load effects and restraint forces were also investigated. Crack widths from NLFE simulations were then compared with corresponding results calculated using linear FEA results as input for design equations given in EN 1992-1-1. The latter resulted in estimated cracks more than 10 times wider than that obtained in the simulations, while crack widths predicted using the EN 1992-3 approach showed better correspondence to the NLFE results.

Understanding the true behaviour of impacted structures is the only way to assess their robustness under exceptional events such as vehicle collision. The primary objective of this master’s thesis was to perform a finite element parametric investigation on the influence that some parameters have in steel buildings subjected to vehicle impacts. The parameters chosen for the study, involved uncertainties in the material definition and in the load configuration of the bolts used in the impacted column end-connections. By using the Abaqus software, a finite element model of the structure has been created. The five storey steel building considered has been modelled in a simplified manner with the exception of the impacted area which, instead, has been defined in a more detailed fashion. During the simulations, different preload conditions have been used, comparing cases with and without the preload force. Regardless its variation, it has not been observed any increase in the structural resistance. On the other hand, the simulation provided interesting results for what concerns the material variations in the bolts. Although the changes have been small in magnitude, the effect on the structural response during the impact was remarkable. For all the cases considered, an increase of the material ductility, achieved by increasing the ultimate strain at failure, entailed higher resistance of the connections. Various failure modes have been observed when the material properties have been changed. Having clarified the influence of the assumptions made, the results provided helpful information in sight of future studies. Although the model still needs to be validated, the research clarified which of the parameters investigated are to be collected with more attention. Keywords: Vehicle collision, steel building, FE model, Abaqus/Explicit, parametric investigation, bolt preload, bolt material.

No description available.