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Emissions of air pollutants from non-conventional sources have been on the rise in the North Texas area over the past decade. These include primary pollutants such as volatile organic compound (VOC) and oxides of nitrogen (NOx) which also act as precursors in the formation of ozone. Most of these have been attributed to a significant increase in oil and gas production activities since 2000 within the Barnett Shale region adjacent to the Dallas-Fort Worth metroplex region. In this study, air quality concentrations measured at the Denton Airport and Dallas Hinton monitoring sites operated by the Texas Commission on Environmental Quality (TCEQ) were evaluated. VOC concentration data from canister-based sampling along with continuous measurement of oxides of nitrogen (NOx), ozone (O3), particulate matter (PM2.5), and meteorological conditions at these two sites spanning from 2000 through 2014 were employed in this study. The Dallas site is located within the urban core of one of the fastest growing cities in the United States, while the Denton site is an exurban site with rural characteristics to it. The Denton Airport site was influenced by natural gas pads surrounding it while there are very few natural gas production facilities within close proximity to the Dallas Hinton site. As of 2013, there were 1362 gas pads within a 10 mile radius to the Denton Airport site but there were only 2 within a 10 mile radius to Dallas Hinton site. The Dallas site displayed higher concentrations of NOx and much lower concentrations of VOC than the Denton site. Extremely high levels of VOC measured at the Denton site corresponded with the increase in oil and gas production activities in close proximity to the monitoring site. Ethane and propane are two major contributors to the measured VOC concentration, suggesting the influence of fugitive emissions of natural gas. In Dallas, the mean and maximum values of ozone had decreased since 2000 by about 2% and 25%, respectively. Similarly NOx decreased by 50% and 18% in the mean and maximum values. However, the mean VOC value showed a 21% decrease while the maximum value increased by about 46%. In Denton, the change in percentage of ozone and NOx were similar to Dallas but the mean VOC concentration increased by about 620% while the max value increased 1960%. Source apportionment analysis confirmed the findings by identifying the production of natural gas to be the primary source of VOC emissions in Denton, while traffic sources were more influential near the Dallas site. In light of the recent proposal by EPA to revise the ozone standard, the influence of these new unconventional sources should be further evaluated.

Gas obtained from previously unexploited shale rock strata has emerged as an economically viable way of sourcing additional fossil fuel energy resources after the so-called ‘shale gas revolution’ in the United States. In the United Kingdom, the incumbent government has committed to the development of its own shale gas resources. A highly polarised public debate has erupted on the risks and rewards of extracting the shale gas deposits that presently lie underneath large swathes of the country using the controversial method of hydraulic fracturing, or ‘fracking’. This thesis examines how different groups in North West England – the major frontier of fracking in the UK – are contesting, resisting and negotiating the current government’s decision to sanction and push ahead towards the development a domestic shale gas industry. Employing a theoretical framework drawn from political ecology as its core mode of examination, this thesis utilises qualitative methods including in-depth interviews and participant observation techniques. It documents a range of social groupings that are contesting shale gas in the UK in a number of ways, and argues that landscapes and risk are fundamental hinges in this ongoing environmental conflict.

Le cadre général de la thèse concerne la valorisation sous forme de production d'énergie électrique de la chaleur présente à quelques kilomètres de profondeur (3 à 5 km), en général dans des milieux peu perméables et fracturés. Notre objectif principal est d'étudier le phénomène des microséismes induits relativement au refroidissement, en nous basant sur une expérience de terrain de longue durée, menée sur le site de Rosemanowes (Cornwall, UK). Pour cela nous avons procédé à la mise en place d'un outil de calcul, FRACAS, capable de simuler ce phénomène en introduisant une approche à double milieu thermique pour mieux simuler le refroidissement du réservoir dû à l'injection de fluide à long terme, responsable des nouveaux mécanismes de ruptures dus à la traction de la roche. Dans ce contexte nous avons introduit un nouvel algorithme pour prendre en compte les manifestations d'instabilités, un mécanisme de « stick-slip » avec prise en compte d'une friction statique et d'une friction dynamique. La possibilité d'induire des microséismes est ensuite étudiée à partir des données issues d'un site particulier, avec deux modèles 3D proposant des approches géométriques différentes, un modèle déterministe et un modèle stochastique, dont les propriétés géométriques et physiques ont été tirées des observations et travaux antérieurs effectués sur ce site de Rosemanowes. La simulation thermo-hydro-mécanique (THM) du modèle déterministe nous a permis de modéliser les échanges thermiques en régime transitoire dans le réservoir formé par le système de forages RH12/RH15 et d'estimer un ordre de grandeur des tractions d'origine thermique. Pour mieux étudier l'effet induit par la contraction des blocs de roche dans le temps nous utilisons le modèle 3D stochastique dont l'objectif principal est de simuler de façon plus réaliste la progression dans l'espace les ruptures en cisaillement. Avec ce modèle nous avons constaté l'apparition différée d'une activité et l'effet d'un cycle de pulses de pression, ce qui suggère un moyen d'atténuer les fortes magnitudes potentielles des ruptures en cisaillement dues au refroidissement. / The general framework of our research deals with the development of geothermal energy for electricity production using the heat stored in geological formations at depths ranging in 3 to 5 km, Generally the environment is poorly permeable and fractured. Our main objective is to study the phenomenon of induced micro-earthquakes in relation to the cooling of the rock. The work is based on field experiences including long duration tests, conducted on the Rosemanowes site (Cornwall, UK). For this, we proceeded to the development of a calculation tool, FRACAS, able to simulate this phenomenon by introducing a dual thermal approach to better simulate the cooling of the reservoir due to long term fluid injections, which might be responsible for new failure mechanisms due to the induced tractions. In this context, we introduced a new algorithm to describe shear in stabilities, a mechanism of "stick-slip" type with the consideration of static/dynamic friction coefficients. The possibility of inducing micro-seismicity is then studied using the in situ data base, with two 3D models offering different geometric approaches, a deterministic model and a stochastic model whose geometrical and physical properties were obtained from observations and previous work on this Rosemanowes site. The Thermo-Hydro-Mechanical (THM) simulation using the deterministic model has allowed us to calibrate the transient heat transfer in the reservoir formed by the drilling system RH12/RH15 and to give an estimate of tensile stress of thermal origin. To better study the effect induced by the contraction of the rock during time, we use the stochastic 3D model whose main objective is to simulate a more realistic spatial migration of shear ruptures. With this model we found a delayed onset of shear activity and discuss the effect of pressure step tests. The results suggest a way to mitigate the potential impact of shear ruptures due to cooling.

Using ethnographic research methods, I collaborated with the organization Earthworks to conduct a community assessment on the health issues related to the air quality in Karnes County, Texas, an oil and gas community. The research consisted of in-depth interviews with residents on their experiences and knowledge on the health issues associated to air quality. This research is going to be used to inform the community and develop strategies to empower community members in improving their environmental conditions.

Den technologischen Hintergrund für diese Arbeit liefert die bei der Erschließung tiefer Lagerstätten (Erdgas, Erdöl, Erdwärme) eingesetzte Stimulationstechnik des Hydraulic Fracturing. Bei dieser Technik werden mittels hydraulischem Druck Risse im Lagerstättengestein erzeugt, die durch Einspülen von Feststoffkörnern (Proppants) offengehalten werden sollen. Der inhaltliche Schwerpunkt liegt auf der theoretischen und experimentellen Untersuchung der Einbettung von Proppants in das Lagerstättengestein unter besonderer Berücksichtigung des Einflusses auf die hydraulische Leitfähigkeit eines durch Proppants gestützten Risses. Thematisch teilt sich die Arbeit in die beiden Schwerpunkte: (1) Berechnung der Proppant-Einbettung auf der Grundlage kontaktmechanischer Ansätze und (2) experimentelle Untersuchungen an realen Proppant-Schüttungen. Zur mathematischen Formulierung der Proppant-Einbettung wurde die in der Werkstofftechnik entwickelte Theorie des mechanischen Verhaltens rauer Oberflächen unter Lasteintrag (Kontaktmechanik) mit der ebenfalls aus der Werkstofftechnik bekannten Messung und Interpretation der Oberflächenhärte nach Meyer gekoppelt. Diese neuartige Formulierung ermöglicht es, die Einbettung von Proppants in Abhängigkeit der Materialeigenschaften der Formation, des Spannungszustandes, der Korngrößenverteilung und der Proppants-Konzentration zu berechnen. Zur Prognose des Erfolges einer Stimulation wurde ein 2D-numerischer Algorithmus (MATLAB®) entwickelt, der den Gesamtprozess der Einbettung, der Durchlässigkeitsentwicklung und deren Folgen für die Produktivität der Sonden widerspiegelt. Zur Verifizierung des Berechnungsalgorithmus wurde die Einbettung realer Proppant-Schüttungen in Lagerstättengesteinen (Tonschiefer, Shale) untersucht. Hierfür wurde in einer dafür konzipierten Flutzelle ein durch Proppants gestützter Riss nachgebildet, belastet und durchströmt. Ziel der Versuche war dabei zu messen, welchen Einfluss ein Spannungsanstieg auf die Einbettung und damit auf die hydraulische Leitfähigkeit hat. Diese Versuche wurden an zwei verschiedenen Shale-Gesteinen mit zwei verschiedenen Proppant-Konzentrationen durchgeführt. Zusätzlich zu den hydraulischen Experimenten wurden mechanische Untersuchungen (Härtemessungen) ausgeführt und nach der Meyer-Analyse der Werkstofftechnik interpretiert. Ein besonderer Vorteil dieser Auswertungsmethode liegt in ihrer durch Dimensionsanalyse erzielten Übertragbarkeit der Ergebnisse von Werkstoffen auf Gesteine. Der Vergleich von gemessenen und berechneten Einbettungen und hydraulischen Leitfähigkeiten ergab eine zufriedenstellende Übereinstimmung und erlaubt es festzustellen, dass mit der neuen Formulierung die planerische Voraussage von Frac-Stimulation möglich ist, wobei alleine die relativ einfachen laborativen Messverfahren zur Härtemessung (Gestein) und zur Korngrößenanalyse (Proppant) erforderlich sind.

Don't Frack With Denton chronicles the ground-breaking movement to ban hydraulic fracturing in the city of Denton, Texas by combining observational location shooting with extensive sit-down interviews and carefully negotiated subject-filmmaker relationships to create a safe and comfortable space for thoughtful reflection and criticism of a complex social movement who's activities span several years and many individuals. The result is a long-form documentary that is unapologetically in solidarity with this movement's goals while simultaneously maintaining enough editorial independence and critical distance to allow the activists themselves to honestly evaluate their decision-making, tactics and interpersonal relationships in ways that will provide insight and instruction to similar movements around the country and the world.

No description available.

The effect of shale gas activities on ground-level ozone pollution in the Dallas-Fort Worth area is studied in detail here. Ozone is a highly reactive species with harmful effects on human and environment. Shale gas development, or fracking, involves activities such as hydraulic fracturing, drilling, fluid mixing, and trucks idling that are sources of nitrogen oxides (NOX) and volatile organic compounds (VOC), two of the most important precursors of ozone. In this study two independent approaches have been applied in evaluating the influences on ozone concentrations. In the first approach, the influence of meteorology were removed from ozone time series through the application of Kolmogorov-Zurbenko low-pass filter, logarithmic transformation, and subsequent multi-linear regression. Ozone measurement data were acquired from Texas Commission on Environmental Quality (TCEQ) monitoring stations for 14 years. The comparison between ozone trends in non-shale gas region and shale gas region shows increasing ozone trends at the monitoring stations in close proximity to the Barnett Shale activities. In the second approach, the CAMx photochemical model was used to assess the sensitivity of ozone to the NOX and VOC sources associated with shale oil and gas activities. Brute force method was applied on Barnett Shale and Haynesville Shale emission sources to generate four hypothetical scenarios. Ozone sensitivity analysis was performed for a future year of 2018 and it was based on the photochemical simulation that TCEQ had developed for demonstrating ozone attainment under the State Implementation Plan (SIP). Results showed various level of ozone impact at different locations within the DFW region attributed to area and point sources of emissions in the shale region. Maximum ozone impact due to shale gas activities is expected to be in the order of several parts per billion, while lower impacts on design values were predicted. The results from the photochemical modeling can be used for health impact assessment and air quality management purposes. Both studies in this research show that the impact of shale gas development on local and regional level of ozone is significant, and therefore, it should be considered in the implementation of effective air quality strategies.

The environmental problems associated with the boom in hydraulic fracturing or "fracking," such as anthropogenic earthquakes and groundwater contamination, have motivated some citizens living in affected areas such as Denton, Texas to form movements with the goal of imposing greater regulation on the industry. As responses to an environmental threat that is localized and yet mobile, these anti-fracking movements must construct rhetorical appeals with complicated relationships to place. In this thesis, I examine the anti-fracking movement in Denton, Texas in a series of three rhetorical analyses. In the first, I compared fracking bans used by Frack Free Denton and State College, Pennsylvania to distinguish the argumentative claims that are dependent on the politics of place, and affect strategies localities must use in resisting natural gas extraction. In the second, I compare campaign strategies that use local identity as a way of invoking legitimacy, which reinforces narrative frameworks of environmental risk. In the third, I conduct and analyze interviews with anti-fracking leaders who described the narrative of their movement, which highlighted tensions in the rhetorical construction of a movement as local. Altogether, this thesis traces the rhetorical conception of place across the rhetoric of the anti-fracking movement in Denton, Texas, while seeking to demonstrate the value of combining rhetorical criticism with rhetorical field methods.