Made available in DSpace on 2017-07-21T20:42:28Z (GMT). No. of bitstreams: 1 Eduardo Prestes.pdf: 9360031 bytes, checksum: cf81ac633030e28b561a09650cf7105a (MD5) Previous issue date: 2007-12-14 / The recycled lead obtained mainly from the recovery of lead from lead-acid batteries is named secondary lead. The process of lead scrap smelting and reduction is carried out in short rotary furnaces and the standard refractory lining is the burned magnesia-chromite bricks. The employment of refractory castables is not found in the literature for this type of application. Therefore, this research provides an evaluation by slag attack of commercial castable refractories selected for short rotary furnace application of secondary lead smelting in confrontation with commercial burned magnesia-chromite bricks. After the scorification tests, statics and dynamics, the wear and slag penetration area in each sample was measured using the analysis image software “Image- Pro Plus 5.1”. For the best performance products was realized the corrosion study by analysis of the refractory-slag interface by Scanning Electronic Microscopy (SEM), Energy Dispersive Scanning (EDS) and X-Ray Diffractometry. Sintered magnesia-chrome spinel bricks showed the best slag attack resistance and the evaluated castable refractories showed inferior performance than the standards refractory bricks. Nevertheless, a low cement alumina-chrome castable based on white fused alumina was similar to performance of the direct bonded magnesia-chromite bricks. This result shows that the employment of castable refractory in short rotary furnace of secondary lead smelting is very promising. The analysis of the refractory products after the static and dynamic slag attack showed that the FeO is the main corrosive agent of the slag, due to its reaction with components of refractory and formation of low melting compounds. / O chumbo reciclado produzido principalmente a partir da recuperação do chumbo de sucatas de baterias automotivas é denominado chumbo secundário. O processo de fusão e redução da sucata metálica de chumbo é realizado em pequenos fornos rotativos e o revestimento refratário normalmente empregado é composto por produtos formados a base de magnésia-cromo. O emprego de concretos refratários para este tipo de aplicação praticamente não é encontrado na literatura. Por isso, este trabalho apresenta uma avaliação, pelo ataque por escória, de concretos refratários comerciais selecionados para aplicação em fornos rotativos d e redução de chumbo secundário em comparação com os refratários formados de magnésiacromo. Após os testes de escorificação, estáticos e dinâmicos, os produtos refratários foram avaliados pela área do perfil de desgaste e de infiltração dos corpos de prova. A área foi obtida pelo emprego do software de análise de imagem “Image-Pro Plus 5.1”. Para os produtos de melhor desempenho nos ensaios de escorificação foi realizado o estudo da corrosão pela análise da interface refratário-escória, utilizando as técnicas de microscopia eletrônica de varredura (MEV), espectroscopia por dispersão de energia (EDS) e difratometria de raios X. Os refratários formados de magnésia-cromo apresentaram melhor resistência ao ataque por escória em relação aos concretos refratários avaliados. No entanto, um concreto refratário de aluminacromo de baixo teor de cimento, a base coríndon branco, apresentou desempenho próximo dos produtos formados de magnésia-cromo. Este resultado mostra que o emprego de concretos refratários em fornos rotativos de redução de chumbo secundário é muito promissor. A análise dos produtos refratários após o ataque por escória estático e dinâmico mostrou que o FeO é o principal agente corrosivo da escória, devido a sua reação com os componentes do refratário e formação de compostos de baixo ponto de fusão.

Submitted by JOSIANE SANTOS DE OLIVEIRA (josianeso) on 2018-11-08T13:01:52Z No. of bitstreams: 1 João Eduardo Sampaio_.pdf: 5481805 bytes, checksum: ff4fd651d904071e9a30223e3222c4dc (MD5) / Made available in DSpace on 2018-11-08T13:01:52Z (GMT). No. of bitstreams: 1 João Eduardo Sampaio_.pdf: 5481805 bytes, checksum: ff4fd651d904071e9a30223e3222c4dc (MD5) Previous issue date: 2018-08-23 / Nenhuma / O Brasil precisa de um setor siderúrgico eficiente e competitivo para enfrentar a concorrência externa. A siderurgia é um ramo da metalurgia responsável pela fabricação do aço, e dentre os processos produtivos do setor, destaca-se o processo de laminação do aço, que utiliza fornos de reaquecimento. Esta pesquisa emprega a modelagem com as técnicas do Pensamento Sistêmico e da Dinâmica de Sistemas na formulação de um modelo computacional no contexto dos fornos de reaquecimento. A partir da validação do modelo, são utilizadas a Análise Envoltória de dados, para avaliar a eficiência técnica, e a regressão Tobit, para identificar variáveis estatisticamente significantes. Essas variáveis são usadas para definição dos cenários simulados. Posteriormente, as eficiências dos cenários são avaliadas por meio de estatística descritiva. Também são avaliados alvos e folgas e é testada a hipótese de igualdade da média com o teste de Welch e Post-Hoc Kruskal-Wallis. Finalmente, é realizada a análise explicativa e, com a aplicação da técnica computacional da Rede Neural Artificial, são identificadas as variáveis prevalentes da eficiência técnica do forno de reaquecimento. Tal estudo possibilita e estimula o planejamento, a gestão e a tomada de decisão a partir da análise das melhores opções. Permite, ainda, a tomada de ações com base no conhecimento prévio, contribuindo para iniciativas pontuais e focadas na competitividade. / Brazil needs an efficient and competitive steel sector to face external competition. The siderurgy is a branch of metallurgy responsible for steelmaking, and among the productive processes in the industry the steelmaking process that uses the reheating furnaces can be highlighted. This research employs the modeling with the techniques of Systemic Thinking and Systems Dynamics in the formulation of a computational model in the context of reheating furnaces. Then, using the validated model, Data Envelopment Analysis was used, evaluating the technical efficiency and the use of the Tobit regression of statistically significant variables. These variables are used to define the simulated scenarios. Subsequently, the scenarios efficiencies were evaluated by means of descriptive statistics, evaluated targets and backlash and tested the hypothesis of equality of the average with the test of Welch and Post-Hoc Kruskal-Wallis. Finally, the explanatory analysis and identified with the application of the computational technique of the Artificial Neural Network are the prevalent variables of the technical efficiency of the reheating furnace. This study enables and stimulates planning, management and decision making based on the analysis of the best options and allows the taking of actions based on previous knowledge, and thus contributes to specific initiatives focused on competitiveness.

Dans l'industrie sidérurgique, les fours de réchauffage sont les plus grands consommateurs d'énergie après les hauts fourneaux. Réduire leur consommation énergétique est donc la préoccupation majeure de la commande des fours. Dans un four de réchauffage, des brames d'acier sont chauffées en traversant successivement plusieurs zones, de la température ambiante à un profil de température homogène de 1250 °C en sortie du four, avant d’être laminées dans les laminoirs à chaud. La température de brames est contrôlée par une structure de commande hiérarchisée à deux niveaux (niveau 1 et 2).L'objectif de ces travaux est d'améliorer la performance du chauffage et donc de réduire la consommation énergétique du four via une stratégie de commande prédictive distribuée hiérarchisée sur les deux niveaux de commande. Une approche de commande prédictive distribuée est tout d’abord développée pour le niveau 1 afin de suivre les consignes de température de zone, prenant en compte les couplages entre les zones et induisant une moindre complexité d’implantation par rapport à une approche centralisée. L’implantation industrielle a permis une amélioration significative de la précision du suivi de température et une réduction de la consommation d'énergie de 3%. Une deuxième étape propose l’élaboration de la commande prédictive hiérarchisée du niveau 2 afin, à partir de la consigne de température de brame, de déterminer les consignes de température optimales des zones en se fondant sur un modèle de transfert thermique du four. Les résultats de simulation, comparés aux données industrielles, montrent une réduction de la consommation énergétique de 5% et une meilleure qualité de chauffage des brames. L’approche précédente est enfin étendue pour prendre en compte et optimiser le cadencement des brames afin d’augmenter la productivité du four. La simulation montre une augmentation potentielle de productivité du four de 15 tonnes par heure tout en améliorant la qualité de chauffage des brames. / In steel industry, reheating furnaces are the biggest energy consumers after blast furnaces. As a result, reduction of energy consumption is the major concern of furnace control. In a walking-beam slab reheating furnace, steel slabs are heated by moving through successive zones from ambient temperature to a homogenous temperature profile of 1250°C at the furnace exit, to be rolled subsequently in the hot rolling mills. Temperature of slabs is controlled mainly by a two-level hierarchical structure, so called level 1 and level 2.The aim of this thesis is to improve the heating performance and consequently to reduce the energy consumption of the furnace by using hierarchical distributed model predictive control (MPC) strategy for both levels. In a first step, distributed model predictive controllers are developed for the level 1 in order to track zone temperature set-points. The distributed feature of the control law enables to consider coupling effects between zones while reducing the computation complexity compared to a complete centralized approach. The industrial results showed significant improvement on temperature tracking accuracy and an energy consumption reduction of 3%. In a second step, the hierarchical MPC is constructed for the level 2 in order to determine the optimal zones temperature setpoint from the slab temperature setpoint, based on a numerical heat transfer model of the furnace. The simulation results obtained with this strategy compared against industrial data show an energy consumption reduction of 5% and a better heating quality. The previous structure is finally extended to take into account and optimize the scheduling of the slabs within the MPC level 2 in order to increase productivity of the considered furnace. The simulation shows a potential increase of productivity of the furnace of 15 tons per hour while improving the slab heating quality.

O pó de forno elétrico a arco (FEA) é gerado durante a fusão de sucata ferrosa nos fornos elétricos a arco e coletado predominantemente através de filtros de mangas. Esta substância é listada como resíduo sólido perigoso de fonte específica, K061, conforme a Norma ABNT NBR 10004:2004. As maiores empresas siderúrgicas semi-integradas do mundo têm adotado para o tratamento de pó de FEA, fundamentalmente três rotas: a recuperação de zinco e chumbo, através de dois processos complementares, um piro-metalúrgico, o Wäelz kiln e outro hidro-metalúrgico, o processo de dupla lixiviação Óxido de Wäelz; a inertização através da blendagem com a cal, aditivos e água, de forma a alcançar o pH da mistura >11, o que garante que metais pesados como o chumbo, cádmio e o zinco, presentes no pó de forno elétrico, não possam se tornar solúveis, evitando consequentemente, a sua lixiviação e a disposição em aterros industriais de resíduos sólidos perigosos. Sob a perspectiva da sustentabilidade, deve ser considerada a rota da recuperação de zinco e chumbo, que para ser viável necessita reunir a geração de pó de FEA de varias plantas, o que para um país com dimensões continentais pode ser um fator de insucesso. Esse trabalho trata da reciclagem do pó de FEA através do processo de sinterização de um compósito constituído de pó de FEA aglomerado com coque, carepa e fluorita cerâmica em pelotas, aplicável a uma planta unitária. Como resultado deste processo foram obtidos dois coprodutos, o aglomerado pré-fundido, APF, com teor de óxido de ferro superior a 70%, objeto do processo de sinterização e o concentrado de zinco, com teor de óxido de zinco maior que 50%, resultante da volatilização deste metal durante o processo de sinterização e coletado através de filtro de mangas. Complementarmente foi extraído aproximadamente 90% dos óxidos de chumbo e cádmio contidos no pó de FEA inicial. A produção do APF ocorreu em escala experimental dividida em três fases, a primeira fase foi efetuada com oito formulações distintas e comprovou através de análises químicas de espectrometria por fluorescência de raios X e difratometria de raios X, a viabilidade técnica da utilização somente de resíduos sólidos industriais para fabricação do APF. A segunda fase, também com oito formulações, definidas conforme planejamento de experimentos com delineamento fatorial, teve como objetivo identificar os principais efeitos das interações entre os componentes do APF, para obtenção da mistura com formulação ótima. A terceira fase testou a intensidade das variáveis, coque e fluorita cerâmica, para a extração do zinco. As duas primeiras fases dos testes de produção em escala experimental foram realizadas em uma planta piloto de sinterização de fluxo descendente e a terceira fase em uma planta piloto de fluxo ascendente, ambas instaladas na usina ArcelorMittal Piracicaba. O APF, com a formulação ótima, foi produzido em escala industrial na planta de sinterização Metalflexi, também instalada na usina ArcelorMittal Piracicaba, e testado em alto-forno de pequeno porte. O concentrado de zinco foi caracterizado quimicamente para se avaliar o uso em segmentos industriais que utilizem este elemento. / The electric arc furnace (EAF) dust is generated during melting of steel scrap in electric arc furnaces and collected mainly through bag filters. The EAF dust is listed as hazardous waste from specific source, K061, according to ABNT 10004:2004. The major semi-integrated steel companies in the world have adopted for the treatment of EAF dust, basically three routes: the recovery of zinc and lead, through two complementary processes, a pyro-metallurgy, Waelz kiln and other hydro-metallurgical the leaching process of double oxide Waelz; the blanketing by blending with lime, water and additives in order to achieve the pH of the mixture>11, which ensures that heavy metals like lead, cadmium and zinc, present in furnace residue, can not become soluble, thereby avoiding the leaching and disposal in landfills of hazardous waste. This work suggests recycling of the EAF dust by sintering of a composite consisting of EAF dust agglomerate to coke particles (carbon source), mill scale (iron source) and ceramic fluorite (adictive agent used like fluxant) into pellets, a process known as sintering. As a result of the process is expected to obtain two by-products, the pre-cast agglomerated, PCA, with iron oxide content exceeding 70%, object of the process of sintering and zinc dust, containing more than 50% zinc oxide resulting from volatilization of this metal during the sintering process and collected by bag filter. Addition is expected to extract approximately 90% of lead and cadmium oxide contained in the initial EAF dust. The production of the PCA occurred in experimental scale divided into three stages, the first stage was performed with eight different formulations and checked by chemical analysis by X-ray fluorescence spectrometer and X-ray diffraction, the technical viability of using only solid waste industrial manufacturing PCA. The second phase, also with eight formulations, defined as planning experiments with factorial design, was tested the main effects and the double and triple interactions between the components of the PCA, to obtain the optimal formulation. The third phase was checked the intensity of the variables, coke fluorite ceramics, for removing zinc of PCA. The first two stages of the production tests were carried out on a pilot scale in a pilot plant sintering downstream and the third phase in a pilot plant xii upstream, both installed in the plant ArcelorMittal Piracicaba. The PCA, with the optimal formulation was produced on an industrial scale in the sinter plant Metalflexi also installed at the plant ArcelorMittal Piracicaba, and tested in small blast furnace. The zinc dust was characterized chemically for application in industries that use this element.

<p>Disertacija je posvećena problemima<br />o&scaron;tećenja cevi pirolitičkih peći u fabrici etilena,<br />kao i metodima procene preostalog ţivotnog<br />veka cevi peći, uop&scaron;tava teorijska i praktična<br />istraţivanja koja su sprovedena za vreme<br />trajanja doktorskih studija.<br />Peć za pirolizu benzina je uzeta kao tipičan<br />primer za proučavanje preostalog ţivotnog veka<br />na osnovu prikupljenih podataka o cevima peći,<br />kao &scaron;to su: redukcija debljine zida, povećanje<br />spoljnjeg prečnika, tvrdoća i metalografska<br />istraţivanja, itd., a eksperimentalni rezultati su<br />dobiveni iz pripremljenih isečaka cevi peći.<br />Razmatra se veliki kompleks pitanja povezan<br />sa problemom tačnosti procene ţivotnog veka.<br />Iako otkaz cevi peći nije veliki bezbednosni<br />problem, procena preostalog ţivotnog veka cevi<br />je značajna zbog u&scaron;tede tro&scaron;kova koji proizilaze<br />iz optimizacije procesnih parametara ili<br />redukcije frekvence ispitivanja i prevazilaţenja<br />neplaniranih zastoja.</p> / <p>The dissertation is devoted to<br />problems of pyrolysis furnace tubes<br />damage in ethylene plant, and methods of<br />assessment of the furnace tube remaining<br />life, generalizes the theoretical and<br />practical research that is conducted during<br />the doctoral studies.<br />Furnace for the gasoline pyrolysisis<br />taken as a typical example for the study of<br />the remaining life based on data collected<br />on the furnace tube, such as the reduction<br />of wall thickness, increasing the outer<br />diameter, hardness and metallographic<br />testing, etc.., and experimental results<br />were obtained from prepared furnace tube<br />slices.<br />Discusses the major issues associated<br />with the complex problem of the accuracy<br />of life expectancy. Although furnace tube<br />failure isn&rsquo;t a major security problem, the<br />tube remaining life estimation is important<br />because of cost savings resulting from the<br />optimization of process parameters or<br />reducing the frequency of tests and<br />overcome unplanned downtime.</p>

O objetivo desta tese foi o estudo da influência do aditivo redutor de retração (SRA) e o aditivo compensador de retração (SCA) em argamassas e pastas de cimento de escória ativada com silicato de sódio. A metodologia foi centrada na análise da retração por secagem e autógena, com o estudo de outras características que influenciam no fenômeno da retração, como as propriedades mecânicas. Para o avanço no conhecimento do efeito dos aditivos no comportamento do cimento de escória, foi caracterizada a microestrutura com a determinação da análise por termogravimetria, porosimetria e difração de raios X. Neste estudo foram empregados os seguintes teores de aditivo, porcentagem relativa à massa de aglomerante: 0,5%, 1%, 1,5% e 2% do aditivo SRA e 5%, 10% e 15% do aditivo SCA. Para a análise da influência da relação a/agl foram empregadas três teores: 0,40, 0,48 e 0,56. No estudo das amostras de referência, sem a utilização de aditivo, observou-se que o aumento da relação a/agl causa o aumento da retração por secagem e da retração autógena do cimento de escória ativada. A diminuição da resistência mecânica com o aumento da relação a/agl, o que torna o esqueleto sólido mais susceptível à deformações, e o aumento das tensões capilares, em razão do aumento da quantidade de água livre para ser evaporada, são os principais fatores para o aumento da retração por secagem. No caso da retração autógena, seu aumento é atribuído ao aumento da auto-secagem com o aumento do volume de poros com diâmetro na faixa de mesoporos, além da diminuição da resistência mecânica. O aditivo redutor de retração (SRA) conseguiu reduzir a retração por secagem em percentuais de 40% até 74% aos 28 dias, no entanto, este tipo de aditivo não obteve êxito no combate a retração autógena. Com relação à resistência mecânica, o aditivo SRA causou a redução de até 40%, efeito atribuído à diminuição do grau de hidratação e retardo do refinamento da porosidade. O aditivo compensador de retração (SCA) amenizou a retração por secagem e a retração autógena, reduzindo em até 64% e 70%, respectivamente, porém reduziu em até 60% a resistência mecânica do cimento de escória ativada. Com relação à microestrutura, o aditivo SCA diminuiu o grau de hidratação e aumentou a porosidade total, com o aumento da proporção do volume de macroporos. / The aim of this research was the study of the influence of shrinkage reducing admixture (SRA) and shrinkage compensating admixture (SCA) in mortars and pastes of blast furnace slag activated with sodium silicate. The method was centered in the analysis of free drying and autogenous shrinkage, with other characteristics that affect the shrinkage, as the mechanical properties. The microstructure behavior was accomplished with thermogravimetry (TG), mercury intrusion porosimetry (MIP) and X-ray diffraction (XRD). The samples were prepared with 0,5%, 1%, 1,5% and 2% of SRA admixture and 5%, 10% and 15% of SCA admixture, by binder mass. The effect of water/binder ratio was accomplished in three contents: 0,40, 0,48 and 0,56. In the reference mixtures, without admixtures, it was observed that an increase of water/binder ratio incurs in an increase of drying and autogenous shrinkage of alkali activated slag. The explanations for drying shrinkage behavior are the decrease of mechanical strength as consequence of water/binder increase, that turns the porous structure more susceptible to deformations, and the increase of the capillary tensions, attributed to the increase of free water to be evaporated. The increase of autogenous shrinkage with water/binder ratio is attributed to the increase of pore volume with diameter in the mesopores range, besides the decrease of the mechanical strength. The shrinkage reducing admixture (SRA) diminish drying shrinkage of 40% up to 74% at 28 days, however, this type of admixture was not capable to combat the autogenous shrinkage. About mechanical strength, the SRA admixture incurs in a decrease up to 40% of compression strength that it was attributed to the decrease of the hydration degree and retard of pore size refinement. The shrinkage compensating admixture (SCA) softened drying and autogenous shrinkage, reducing in up to 64% and 70%, respectively. However, the SCA admixture decreases in up to 60% mechanical strength of alkali activated slag. About microstructure, SCA admixture reduced the hydration degree and it increased the total porosity, with the increase of macropores volume.

At the institute of technology of building materials and components at the fakulty of civil engineering in Brno was initiated research deal with study of the effect of limestone on the progress of decarbonization. This work is an introductory study into this problems. It focuses on describing the genesis and diagenesis of limestones, their crystallography, texture and requirements for burning. Further describes the extraction and treatment of limestones before burning. In very burning is focused on its mechanism and the used furnace systems. In the experimental part is focused on the analysis of samples of limestones of various world sites in terms of petrology, geological origin, chemical composition, the content of insoluble residues, density and porosity, and analysis of formed limes, burned at 900 °C in terms of density, CO2 content and crystal size.

In well cementing, the cement slurry is exposed to the conditions far different than those of ordinary Portland cement (PC) used in construction. After placement, hardened cement paste should preserve integrity and provide zonal isolation through the life of the well. American Petroleum Institute (API) Class G cement is the most common cement type used in various well conditions. Class G cement has a high degree of sulfate resistance which makes it more stable than PC when subjected to the compulsive well conditions. Ground granulated blast furnace slag (GGBFS) blended cement has a long history of use in the construction industry, but is not extensively used in well cementing applications. This study presents an experimental program to investigate the applicability of CEM I and GGBFS blended cement pastes in the well cementing industry. Class G cement and blends of CEM I and GGBFS with the proportions (80:20), (60:40), (40:60) and (20:80) are prepared with same water/cement ratio (0.44) as restricted for Class G cement in API Specification 10A to be tested. The cement pastes are cured for ages of 1 day, 7 days and 28 days at 80

Oxygen-diluted Combustion (OdC) technology has evolved from the concept of Excess Enthalpy Combustion and is characterized by reactants of low oxygen concentration and high temperature. Recent advances in this technology have demonstrated significant energy savings, high and uniform thermal field, low pollution, and the possibility for downsizing the equipment for a range of furnace applications. Moreover, the technology has shown promise for wider applications in various processes and power industries. The objectives of this thesis are to analyze the thermodynamic aspects of this novel combustion technology and to quantify the enhancement in efficiency and heat transfer inside a furnace in order to explore the potentials for reduced thermodynamic irreversibility of a combustion process and reduced energy consumption in an industrial furnace. Therefore, theoretical and experimental investigations were carried out. The 2nd law of thermodynamics analyses of OdC systems have been carried out for cases in which the oxidizer is either oxygen (Flameless-oxy-fuel) or air (High Temperature Air Combustion, HiTAC). The analyses demonstrate the possibilities of reducing thermodynamic irreversibility of combustion by considering an oxygen-diluted combustion process that utilizes both gas- and/or heat-recirculation. Furthermore, the results showed that an oxygen-diluted combustion system that utilizes oxygen as an oxidizer, in place of air, results in higher 1st and 2nd law efficiencies. Mathematical models for heat regenerators were developed to be designing tools for maximized heat recovery. These models were verified by heat performance experiments carried out on various heat regenerators. Furthermore, experiments were performed in a semi-industrial test furnace. It was equipped with various regenerative burning systems to establish combustion and heat transfer conditions prevailing in an industrial furnace operating based on HiTAC. The tests were carried out at seven firing configurations, two conventional and five HiTAC configurations, for direct and indirect heating systems. Measurements of energy balance were performed on the test furnace at various configurations in order to obtain the 1st law efficiency. Moreover, local measurements of temperature, gas composition, and heat fluxes in the semi-industrial test furnace were performed to find out the main characteristics of HiTAC flame and the effects of these characteristics on the heating potential, i.e., useful heating in the furnace. In the case of HiTAC, these measurements showed uniformities of chemistry, temperature, temperature fluctuation, and heat fluxes profiles. The values of fluctuations in temperature were small. The high speed jets of the fuel and air penetrated deep into the furnace. The fuel gradually disappeared while intermediate species gradually appeared in relatively high concentrations and at broader regions inside the furnace. These findings indicate: a large reaction zone, low specific combustion intensity in the flame, low specific fuel energy release, and high heat release from this large flame. In addition to the thermodynamic limitations to the maximum temperature of the Oxygen-diluted Combustion, the low specific energy release of the fuel and the high heat release from the flame to its surroundings cause this uniform and relatively moderate temperature profile in a HiTAC flame, consequently suppressing thermal-NO formation. Heat flux and energy balance measurements showed that heating potential is significantly increased in the case of HiTAC compared to that in the conventional case, implying much more energy savings than the apparent heat recovery from the heat regenerators, and consequently much less pollutants emissions. Therefore, it is certain that this large HiTAC flame emits more thermal radiation to its surroundings than the conventional flame does, in spite of the moderate-uniform temperature profile of the flame. This intense heat flux was more uniform in all HiTAC configurations, including the indirect heating configuration, than that of the conventional-air combustion configuration. / QC 20101011

Slurry walls have been widely used for more than 25 years to control the migration of contaminants in the subsurface. In the USA, vertical barriers are mostly constructed of soil-bentonite using the slurry trench method of construction. In this method, sodium bentonite is mixed with water to form a viscous slurry that is pumped into a trench during excavation to maintain the trench stability. The stable trench is then backfilled with a mixture of soil and slurry having a consistency of high slump concrete. These barriers have been designed primarily for low permeability, generally less than 10&minus / 9 m/s. Some investigations have pointed toward improved performance using admixtures that would provide low permeability. In this study, Soma thermal power plant fly ash, granulated blast furnace slag, lime, and steel slag are used as admixture to improve the performance of slurry walls. Permeability, compressive strength, slump, compressibility properties of the mixtures were found and checked for the minimum requirements. According to the findings of this study, granulated blast furnace slag (GGBS), fly ash and steel slag can be used at certain percentages and curing periods as additive in cement-bentonite barrier wall construction. Permeability of specimens having fly ash decreases by increasing fly ash content. Mixtures having 50 % of GGBS type I with 5 % of lime and 9% bentonite content gave acceptable results in 28 days of curing time. Specimens including 50 % of GGBS type II with 5 % of lime and 9% bentonite content gave the higher permeability value in 28 days of curing time with respect to GGBS type I. In addition, most of the mixtures prepared by steel slag gave the acceptable permeability values in 28 days of curing period. Unconfined compressive strength of all mixtures increase by increasing curing time. Cc, Cr, Cv, kcon values were found from consolidation test results. Permeability values found from consolidation tests are 10 times to 100 times higher than flexible wall k results for the same effective stress of 150 kPa. Generally, mv values are decreasing with increasing curing time. As mv decreases, D increases.