The Giant Mine near Yellowknife, NWT generated 237 000 tonnes of arsenic-trioxide (As₂O₃)-rich dust as a by-product of gold mining during its years of operation (1948 - 2004). Arsenic trioxide is a relatively soluble form of arsenic (As) and is currently stored in the mine, posing a threat of contamination to the adjacent Great Slave Lake. This research investigates the potential for permanent remediation of the As₂O₃ using sulfidation to transform it to arsenic trisulfide (As₂S₃). Knowing that aqueous As₂O₃ readily reacts with sulfide (Ostermeyer, 2021), it was determined that the most practical and effective method to achieve sulfidation of the Giant Mine dust is to first dissolve the As₂O₃ and then conduct the reaction with sulfide. The optimal conditions at which to dissolve As₂O₃ were investigated. The solubility and dissolution rate in water were shown to increase with temperature, with solubility increasing from 185.7 g As₂O₃/kg water at 140 °C to 250.6 g As₂O₃/kg water at 180 °C. Qualitative demonstrations of the rate of dissolution show that ≥ 90 % of the As₂O₃ dissolved within 5 minutes at 140 °C, and 4 minutes at 180 °C; previous research indicates that time to equilibrium is > 24 hours at 60 °C (CANMET, 2000). Reaction of Giant-Mine material in water at elevated temperatures (140 °C - 200 °C) for 10 to 30 minutes consistently resulted in dissolution of approximately 80 wt. % of the initial solid-phase As concentrations, representing almost all the As₂O₃, yielding undissolved residues (≈ 40 wt. % of initial mass). The persistence of As in these residues is likely due to it being hosted in As₂O₃ - Sb₂O₃ solid solutions and low-solubility Fe-oxide phases in the initial sample (CANMET, 2000; Poirier, 2004).

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The United States has become dependent on nonrenewable resources such as nuclear, coal, and crude oil as major sources of energy and fuel. Ethanol has been identified as a renewable fuel source that may help alleviate this dependence. Recent technological advances have developed a method to produce ethanol from lignocellulosic biomass. The purpose of this study is to determine production and transportation costs of switchgrass, eastern gammagrass, and giant miscanthus using Mississippi and Oklahoma data. This study also estimated the returns above the cost of feedstock for a biorefinery and the incentive package needed to pay for feedstock and construction cost. Results indicate cost difference across species, method of harvest, and location. The biorefinery returns and the incentive package explain the amount of capital needed for a biorefinery to compensate for the cost of feedstock and construction.

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<p>&#65279;<p></p><p>Giant multipole resonances are a fundamental property of nuclei and</p><p>arise from the collective motion of the nucleons inside</p><p>the nucleus. Careful studies of these resonances and their properties provides</p><p>insight into the nature of nuclear matter and constraints</p><p>which can be used to test our theories. </p><p></p></p><p><p></p><p>An investigation of the Isovector Giant Quadrupole Resonance (IVGQR)</p><p>in ²⁰⁹Bi has been preformed using the High Intensity &gamma;-ray</p><p>Source (HI&gamma;S) facility. Intense nearly monochromatic</p><p>polarized &gamma;-rays were incident upon a ²⁰⁹Bi target producing</p><p>nuclear Compton scattered &gamma;-rays that were detected using the HI&gamma;S</p><p>NaI(Tl) Detector Array (HINDA). The HINDA array consists of six</p><p>large (10''x10'') NaI(Tl) core crystals, each surrounded by an</p><p>optically segmented 3'' thick NaI(Tl) annulus. The scattered &gamma;-rays</p><p>both parallel and perpendicular to the plane of polarization were</p><p>detected at scattering angles of 55&deg; and 125&deg; with</p><p>respect to the beam axis. This was motivated by the realization that</p><p>the term representing the interference between the electric dipole</p><p>(E1) and electric quadrupole (E2) amplitudes, which appears in the</p><p>theoretical expression for the ratio of the polarized cross sections,</p><p>has a sign difference between the forward and backward angles and also</p><p>changes sign as the incident &gamma;-ray energy is scanned over the E2</p><p>resonance energy. The ratio of cross sections perpendicular and</p><p>parallel to the plane of polarization of the incident &gamma;-ray were</p><p>measured for thirteen different incident &gamma;-ray energies between 15 and</p><p>26 MeV at these two angles and used to extract the parameters of the</p><p>IVGQR in ²⁰⁹Bi.</p><p></p></p><p><p></p><p>The polarization ratio was calculated at 55&deg; and</p><p>125&deg; using a model consisting of E1 and E2 giant resonances as</p><p>well as a modified Thomson scattering amplitude. The parameters of the E1 giant</p><p>resonance came from previous measurements of the Giant Dipole</p><p>Resonance (GDR) </p><p>in ²⁰⁹Bi. The finite size of the nucleus was</p><p>accounted for by introducing a charge form factor in the (modified)</p><p>Thomson amplitude. This form factor was obtained from</p><p>measurements of the charge density in inelastic electron scattering</p><p>experiments. </p><p></p></p><p><p></p><p>The resulting curves were fit to the data by varying the</p><p>E2 parameters until a minimum value of the &chi;² was found.</p><p>The resulting parameters from the fit yield an IVGQR in ²⁰⁹Bi</p><p>located at E_res=23.0&plusmn;0.13(stat)&plusmn;0.25(sys) MeV</p><p>with a width of &Gamma;=3.9&plusmn;0.7(stat)&plusmn;1.3(sys) MeV and a</p><p>strength of 0.56&plusmn;0.04(stat)&plusmn;0.10(sys) Isovector Giant</p><p>Quadrupole Energy Weighted Sum Rules (IVQEWSRs).</p><p></p></p><p><p></p><p>The ability to make precise measurements of the parameters of the</p><p>IVGQR demonstrated by this work opens up new challenges to both</p><p>experimental and theoretical work in nuclear structure. A detailed</p><p>search for the missing sum rule strength in the case of ²⁰⁹Bi should</p><p>be performed. In addition, a systematic study of a number of nuclei</p><p>should be studied with this technique in order to carefully examine</p><p>the A dependence of the energy, width and sum rule strength of the</p><p>IVGQR as a function of the mass number A. The unique properties of</p><p>the HI&gamma;S facility makes it the ideal laboratory at which to perform</p><p>these studies.</p><p></p></p><p><p></p><p>Such a data base will provide more stringent tests of nuclear</p><p>theory. The effective parameters of collective models can be fine</p><p>tuned to account for such precision data. This should lead to new</p><p>insights into the underlying interactions responsible for the nature</p><p>of the IVGQR. Furthermore, with the recent advances in computational</p><p>power and techniques, microscopic shell model based calculations</p><p>should be possible and could lead to new insights into the underlying</p><p>properties of nuclear matter which are responsible for the collective</p><p>behavior evidenced by the existence and properties of the IVGQR.</p><p></p></p> / Dissertation

Giant pandas in captivity are typically fed discrete amounts of highly concentrated food on a fixed time schedule, in addition to limited amounts of fresh bamboo throughout the day. In response to informal observations that these animals engage in a number of undesirable behaviors just prior to the predictable feeding of concentrated meals, we examined the existing feeding regime at the Research Base of Giant Panda Breeding in Chengdu, Peoples Republic of China. We sought to determine whether undesirable behaviors were occurring more frequently before the delivery of meals than at other times of day and whether modified feeding regimes would result in a more species-appropriate activity budget overall. As predicted, female giant pandas spent significantly more time engaged in door-directed/human-oriented behavior, stereotypic behavior, and non-stereotypic locomotion in the 30-minute periods prior to the feeding of concentrated meals. When placed on a modified feeding schedule in which frequency of bamboo provisioning was increased (total amount was held constant), significant differences were not found between study phases for the above-mentioned behaviors of interest, though a visual trend towards a decline in stereotypic behavior during the experimental phase was noted. Male pandas, when placed on a less predictable feeding schedule, did not exhibit significant behavioral differences in behaviors of interest between experimental phases or observation periods. These findings may be attributable in part to the low power inherent in the small sample size. However, visual trends that may be indicative of feeding anticipatory activity (FAA) were apparent. It appears that giant pandas, like many other animal species cited in the literature, are sensitive to periodic feeding regimes, though it is less clear as to which regime modifications will prove most beneficial.

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Successful captive-breeding and re-introduction programs must have the ability to breed a surplus of genetically suitable animals for release into the wild. Unfortunately, many individuals in captive breeding programs often do not reproduce even when they are apparently healthy and presented with genetically appropriate mates. Mate choice can affect multiple parameters of reproductive sperformance, including mating success, offspring production, survival, and fecundity. We investigated the role of mate preference and personality on the reproductive performance of male and female giant pandas (Ailuropoda melanoleuca) as measured by intromission success and litter production. We conducted these studies on giant pandas at the China Conservation and Research Center for the Giant Panda (Bifengxia, Sichuan, China.) from February-May 2011, 2012, and 2013. In Chapter 2, we compared reproductive performance between individuals mated with preferred and nonpreferred males of the focal female (female preference), the focal male (male preference), and mutual mate choice perspective. There were four types of reproductive pairings in our mutual mate choice analyses: females and males that preferred each other (P-P), females that preferred the male but the male did not prefer the female (P-NP), females that did not prefer the male but the male preferred the female (NP-P), and females and males that did not prefer each other (NP-NP). Pairing giant pandas with a preferred partner increased the probability of intromission success and producing a cub. Of the 25 females mated to a preferred partner, 72% had successful intromission, 64% produced cubs, and 52% reared their own cubs versus 31%, 12%, 12% for females mated to their nonpreferred partner (N = 16). Male giant panda mate preference showed similar results. Of the 24 males that were mated with their preferred females, 75% had successful intromission, 77.8% produced cubs, and 92.9% produced cubs that were maternally reared versus 31%, 60%, 66.7% for males mated with their nonpreferred females (N = 16). There was a statistically significant difference in intromission success and cub production for P-P pairings versus NP-NP pairings. Of the twelve P-P mate dyads 83% had successful intromission, 90% produced cubs, and 88.9% had mothers rear their cubs. Of the four P-NP mate dyads 50% had successful intromission, 50% produced cubs, and 100% had the mother rear their cub. Of the seven NP-P mate dyads 57% had successful intromission, 50% produced cubs, and 100% had the mothers rear their cubs. Of the three NP-NP mate dyads 0% had successful intromission resulting in 0% producing cubs and having mother-rear cubs. In addition, we took into account various life and breeding history factors that may have affected reproductive performance such as birth location, rearing, previous sexual history with the opposite sex and familiarity status directly prior to breeding. Mate pairings that were familiar with each other as measured by successfully producing a cub in the past, had increased intromission success. Females mated to heavier males had more intromissions and produced more cubs than females mated to smaller males. In Chapter 3 and 4, we investigated the effect of personality on reproductive performance measurements. Recently, personality of individual animals has been implicated in the failure or success of captive management and breeding of threatened and endangered species. Measurements of personality included novel object tests (where behaviors of individual giant pandas were scored toward a novel object for one hour) and keeper surveys (where the primary keeper rated giant pandas on 23 adjectives describing personality); both measures significantly correlated with variation in long-term and specific mating dyad reproductive performance. In Chapter 3 we evaluated the effect of personality on long-term reproductive performance. Our results show that for both male and female giant pandas, `fearful' individuals had lower natural mating success and cub production. In addition, `aggressive' female giant pandas had increased natural mating success but decreased cub production. Males did not show these relationships between `aggressive' personality types and reproductive performance. Female giant pandas that were labeled as `aggressive' had higher frequencies of positive mating behaviors but `fearful of conspecifics' females had lower frequencies. Males labeled `fearful of conspecifics' and with high `playful-clever' component scores had a lower frequency of positive mating behaviors. In Chapter 4 we further investigated the effects of personality within a specific mating dyad. Recent studies suggest that mate compatibility within personality types can improve reproductive performance measurements such as mating success, offspring survivorship, and offspring quality. We investigated the effect of personality compatibility on reproductive performance through analyzing mate dyad similarity in personality (similar versus dissimilar), specific personality combinations, and relative personality scores (male scores higher or lower than female scores). The specific personality combinations were: females and males that were both low on the personality component (L_L), females were low but males were high (L_H), females were high but males were low (H_L), and females and males were both high (H_H). Our results suggest that giant pandas appear to be assortatively mating based on aggressive, fearful, and stereotypical-excitable personality traits. Mate dyads that were dissimilar on the stereotypical-excitable component score were more likely to have successful intromission than pairs that were similar. L_H mate dyads on the aggressive and stereotypical-excitable personality traits had increased intromission success and cub production than all other possible personality combinations. L_L on fearfulness had higher intromission success but not higher cub production than all other possible personality combinations. Mate dyads composed of males ranked high on the aggressive component relative to the female resulted in higher reproductive performance and cub production. In captive breeding programs, mates are traditionally selected solely on the basis of genetic parameters to minimize loss of genetic diversity and inbreeding coefficients. Our results suggest that integrating genetic with behavioral measures of preference, breeding history factors, and personality would increase the reproductive output of the giant panda captive-breeding program. We stress the importance of considering husbandry practices to accommodate personality traits and ultimately increase reproductive performance in the captive population while simultaneously maintaining both genetic and behavioral diversity.