Laminated glass (LG) consists of two or more glass layers bonded by an elasto-polymeric layer, the most commonly used being PVB (Polyvinyl Butyral). LG has improved safety properties compared with single layer glass because the interlayer prevents large sharp pieces from spreading when the glass is broken by impact. Even if one of the layers breaks, the other layer(s) still contribute in carrying the load. Through proper understanding of the interaction between the interlayer and the glass LG could be used in engineering as a load bearing material to a larger extent. This study aims at gaining a deeper knowledge of the behaviour of laminated glass by experimental investigations and by numerical model simulation. To pursue the proposed study, three point bending test with simple support conditions were performed for single layer glass and laminated glass units with three different types of interlayer materials. Corresponding finite element numerical models were created in the software ABAQUS to fit the model with experiment to obtain the bending stiffness and shear stiffness of the interlayer material. The PVB tested showed viscos-elastic material properties, whereas other two interlayer materials, Solutia DG 41 and Sentry Glass, showed linear elastic properties. PVB is the least stiff interlayer material among the three types. Solutia DG 41 and Sentry Glass have similar stiffness, about 13 to 15 times stiffer than the PVB. The behaviour of laminated glass lies in general between the two limits of a layered glass unit with no interaction and a monolithic unit of the same total thickness, depending on the stiffness of the interlayer material. Failure tests of the specimens were also carried out. The obtained strength of glass from four specimens is 80 MPa to 92 MPa with a variation of about 15%. The number of more performed experiments would have better outcome for strength of glass. The bending stiffness of the laminated glass as estimated with the numerical model fitted well with the experimental results with an error of about 2%. Hence the experimentally and numerically obtained results show a good correlation and are thought be possible to use in future larger scale modelling.

This thesis project consists of 19 sculptures. The medium is hot blown glass. The work interprets and extends the visual and metaphorical qualities of bagpipes. The utilization of the German dudelsack references the playful improvisational nature of these international and culturally diverse forms.

Orientador: Agda Eunice de Souza Albas / Resumo: Neste trabalho, vidro e material vitrocerâmico foram obtidos a partir de uma composição baseada no diagrama ternário SiO2-Al2O3-CaO, utilizando escória de ferro fundido, provenientes de empresas de fundição, e, cal hidratada (comercial). A escória foi caracterizada através de: espectrometria de fluorescência de raios X (FRX), para determinar sua composição química; difratometria de raios X (DRX), para a identificação das fases cristalinas e análise térmica (TG), para evidenciar as reações térmicas associadas à desidratação e decomposição dos compostos presente no material. O vidro foi obtido através do processo de fusão/resfriamento (melt-quenching), fundido na temperatura de 1450°C. Foram caracterizados através de: calorimetria exploratória diferencial (DSC), para determinar as temperaturas de transição vítrea e de cristalização e difratometria de raios X (DRX), para identificar a sua estrutura amorfa. O estudo da cinética de cristalização do vidro foi realizado através de métodos cinéticos não isotérmicos baseados na descrição teórica formulada por Johnson-Mehl-Avrami (JMA). Estes métodos descrevem os processos de nucleação e cristalização utilizando dados provenientes da curva de DSC. O estudo cinético teve início com a obtenção do material vitrocerâmico tratado termicamente à 900ºC por 1,5h e identificação das fases cristalinas formadas, utilizando DRX. Considerando a formação de três fases cristalinas, os parâmetros cinéticos foram determinados a partir dos ajustes dos d... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: In this work, glass and glass-ceramic materials were obtained from a composition based on the ternary diagram SiO2-Al2O3-CaO using cast iron slag from foundry companies and hydrated lime (commercial). The slag was characterized by: X-ray fluorescence (XRF) to determine its chemical composition; X-ray diffractometry (XRD), to the crystalline phases identification and thermal analysis (TG), to show the thermal reactions associated with dehydration and decomposition of the compounds present in the material. The glass was obtained by melt quenching at 1450°C. They were characterized by differential scanning calorimetry (DSC) to determine glass transition and crystallization temperatures and X-ray diffraction (XRD) to identify their amorphous structure. The study of crystallization kinetics was performed by non-isothermal kinetic methods based on the theoretical description formulated by Johnson-Mehl-Avrami (JMA). These methods describe the nucleation and crystallization processes using data from the DSC data. The kinetic study began by obtaining heat-treated glass-ceramic material, at 900ºC for 1.5h, and identifying the crystalline phases formed using XRD. Considering three crystalline phases formation, the kinetic parameters were determined from the DSC data adjustments by the Kissinger, Augis-Bennett, and Matusita and Sakka methods. The best fit resulted in three crystallization peaks. The activation energy (Ea) of the crystallization process was obtained using the Kissinger an... (Complete abstract click electronic access below) / Mestre

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第20386号 / 工博第4323号 / 新制||工||1670(附属図書館) / 京都大学大学院工学研究科材料化学専攻 / (主査)教授 田中 勝久, 教授 平尾 一之, 教授 三浦 清貴 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

A thesis submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science in Engineering. Johannesburg, May 2016 / In this study, hybrid multiscale epoxy composites were developed from woven glass fabrics and PAN nanofibers embedded with short ECNFs (diameters of ~200nm) produced via electrospinning. Unlike VGCNFs or CNTs which are prepared through bottom-up methods, ECNFs were produced through a top-down approach; hence, ECNFs are much more cost-effective than VGCNFs or CNTs. Impact absorption energy, tensile strength, and flexural strength of the hybrid multiscale reinforced GFRP composites were investigated. The control sample was the conventional GFRP composite prepared from the neat epoxy resin. With the increase of ECNFs fiber volume fraction up to 1.0%, the impact absorption energy, tensile strength, and flexural strength increased. The incorporation of ECNFs embedded in the PAN nanofibers resulted in improvements on impact absorption energy, tensile strength, and flexural properties (strength and modulus) of the GFPC. Compared to the PAN reinforced GRPC, the incorporation of 1.0% ECNFs resulted in the improvements of impact absorption energy by roughly 9%, tensile strength by 37% and flexural strength by 29%, respectively. Interfacial debonding of matrix from the fiber was shown to be the dominant mechanism for shear failure of composites without ECNFs. PAN/ECNFs networks acted as microcrack arresters enhancing the composites toughness through the bridging mechanism in matrix rich zones. More energy absorption of the laminate specimens subjected to shear failure was attributed to the fracture and fiber pull out of more ECNFs from the epoxy matrix. This study suggests that, the developed hybrid multiscale ECNF/PAN epoxy composite could replace conventional GRPC as low-cost and high-performance structural composites with improved out of plane as well as in plane mechanical properties. The strengthening/ toughening strategy formulated in this study indicates the feasibility of using the nano-scale reinforcements to further improve the mechanical properties of currently structured high-performance composites in the coming years. In addition, the present study will significantly stimulate the long-term development of high-strength high-toughness bulk structural nanocomposites for broad applications. / MT2016

Indiana University-Purdue University Indianapolis (IUPUI) / MICROTENSILE BOND STRENGTH OF NEW PASTE/PASTE RESIN-MODIFIED GLASS IONOMER CEMENT SYSTEMS: THE EFFECT OF DENTIN PRETREATMENT by Yasser Fawaz Al-fawaz Indiana University School of Dentistry Indianapolis, Indiana Background: In order to improve the clinical performance of RMGIC 3M ESPE and GC America introduced paste/paste resin-modified glass ionomer cements, Ketac™ Nano and Fuji Filling™ LC, respectively. Both companies developed non-rinse substrate conditioners (i.e., Ketac Nano Primer-3M ESPE and GC Self-Conditioner-GC America) that should be used with these new materials instead of the conventional polyacrylic acid. It has been also advised by both manufacturer’s to use this novel substrate conditioner with the previously marketed RMGICs. Objective: to investigate whether the use of novel non-rinse conditioners (i.e., Ketac Nano Primer 3M ESPE and GC Self Conditioner GC America) as substrate pre-treatment and the new paste/paste resin-modified glass-ionomer cement, RMGIC (Ketac™ Nano 3M ESPE and Fuji Filling™ LC GC America) would affect the microtensile dentin bond strength (µTBS) of the material when compared to the traditional RMGIC with polyacrylic acid as a surface substrate pre-treatment. Materials and Methods: 96 extracted non-restored human molar were sectioned to expose occlusal dentin. Dentin surface was finished with SiC paper to standardize the smear layer. Bonding protocols of the different materials to dentin were performed following the use of two dentin conditioners. Eight groups (n=12) were tested: G1: Ketac Nano Primer + Ketac Nano, G2: Ketac Conditioner + Ketac Nano, G3: Ketac Nano Primer + Photac Fil, G4: Ketac Conditioner + Photac Fil, G5: GC Self Conditioner + Fuji Filling LC, G6: GC Cavity Conditioner + Fuji Filling LC, G7: GC Self Conditioner + Fuji II LC and G8: GC Cavity Conditioner + Fuji II LC. The specimens were stored in 37°C for 24h in 100% humidity before cutting non-trimmed beams for the µTBS with cross-sectional areas of approximately 0.8 × 0.8 mm2. Nine beams were used from each specimen. Test was done using universal testing machine at a cross-head speed of 1mm/min. Debonded specimens were examined under a stereomicroscope at 45× magnification to evaluate the failure mode. Eight randomly chosen representative debonded beams were imaged under a scanning electron microscope (SEM). Results: µTBS in MPa (mean ± SE) were: G1: 9.5±1.0, G2: 11.0±1.0, G3:20.0±1.0, G4:16.8±0.9, G5: 15.1±1.0, G6: pre-test failure, G7: 20.0±1.0, G8:14.1±0.9. Weibull-distribution survival analysis was used to compare the differences in microtensile peak stress among the groups. Group5 has cohesive predominant faultier mod while the other groups have adhesive predominant failure. Conclusion: Within the limitations of this study, the use of the novel non-rinse conditioners did not improve the microtensile bond strength of new paste/paste RMGIC to dentin. In fact, the use of the novel non-rinse conditioners enhanced the bond strength of the traditional RMGIC to dentin.

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Chalcogenide glasses are well known to have good transparency into the infrared spectrum. These glasses though tend to have low thresholds as compared to oxide glasses for photo-induced changes and thermally-induced changes. Material modification such as photo-induced darkening, bleaching, refractive index change, densification or expansion, ablation of crystallization have been demonstrated, and are typically induced by a thermal furnace-based heat treatment, an optical source such as a laser, or a combination of photo-thermal interactions. Solely employing laser-based heating has an advantage over a furnace, since one has the potential to be able to spatially modify the materials properties with much greater precision by moving either the beam or the sample. The main properties of ChG glasses investigated in this study were the light-induced and thermally-induced modification of the glass through visible microscopy, white light interferometry, and Raman spectroscopy. Additionally computational models were developed in order to aid in determining what temperature rise should be occurring under the conditions used in experiments. It was seen that ablation, photo-expansion, crystallization, and melting could occur for some of the irradiation conditions that were used. The above bandgap energy simulations appeared to overestimate the maximum temperature that should have been reached in the sample, while the below bandgap energy simulations appeared to underestimate the maximum temperature that should have been reached in the sample. Ultimately, this work produces the ground work to be able to predict and control dose, and therefore heating, to induce localized crystallization and phase change.

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