Cannabis is the only plant which contains cannabinoids and thanks to these compounds it has enormous potential. This thesis deals with the analysis of technical hemp. Effects of cannabinoids and methods used for cannabis analysis are discussed in the theoretical part. The experimental part includes spectrophotometric characterization of cannabis, it´s antimicrobial effects and thin layer chromatography analysis. Three sorts of Cannabis sativa L. were analyzed, namely Finola, Fedora and Kompolti. Firstly, the content of polyphenols, flavonoids and antioxidant activity in prepared tinctures were determined. Moreover, antimicrobial test were performed using disk test and turbidity determination. Gram-positive and Gram-negative bacteria and yeast organism were tested. It was found that cannabis tinctures possess good antimicrobial effects. Some of them are comparable with synthetic antibiotics. Finally, thin layer chromatography enabled visualization of cannabinoids in prepared tinctures.

Risk, and how one proceeds with uncertainty, are key indicators of behavior. In particular, in observing farmers, risk perception is found to influence the decision to innovate and adopt new crops (Ghadim et al., 2005). Farmers who are more risk-averse tend to be later adopters of new crops, while risk-loving farmers tend to be first adopters (Barham et al., 2014). As such, the recent legal shifts in hemp production laws have prompted many growers eager to test out the crop to do so. A vast majority of current licensees planted less than 50 acres to start, despite being mostly corn and soy producers—implying large acreage access. The American ‘hemp rush’ provides us with a real-time display of adoption behavior and its gendered implications.

<p>  </p> <p>Environmental conditions, like light quality and herbivory, can induce changes in plant physiology. Light quality can be manipulated using LEDs (light emitting diodes) to improve crop quality and yield in horticultural production. The manipulation of light quality has also been utilized in the management of agricultural insect pests. Previous research has provided evidence that changes in light quality can have effects on the growth and chemistry of cannabis crops (<em>Cannabis spp.</em>). Varieties of cannabis are grown for the production of the valued cannabinoids CBD and THC. Pest of cannabis include herbivorous arthropods that reduce hemp yield and quality. Arthropod herbivory can induce chemical and physical changes in plants. This thesis further investigates the role of light quality on both cannabis biology and the crop-pest interaction between cannabis and the cannabis aphid (<em>Phorodon cannabis</em>). In the experiments described herein, the effects of light quality and <em>P. cannabis </em>herbivory on cannabis were assessed by measuring impact on biomass accumulation, yield, and the production of CBD and THC. The effects of light quality on the life history traits of <em>P. cannabis </em>were also measured. Cannabis grown under red-blue light quality saw a reduction in vegetative growth but no reduction in yield. Light treatments had no measured effect on the concentrations of CBD and THC in the cannabis buds. Aphid herbivory decreased bud yield but increased vegetative growth. Aphid herbivory reduced the concentration of both CBD and THC in cannabis bud tissue. Under blue-rich light quality, <em>P. cannabis </em>experienced higher reproductive rates when compared to red-blue and full-spectrum lighting. </p>

Världens fokus på hållbar utveckling är större än någonsin tidigare, och konstruktionssektorn ansvarar för upp emot 25 till 40 procent av de globala koldioxid emissionerna. Ett av nyckelmaterialen för att öka en byggnads energieffektivitet är isoleringsmaterialen. Syftet med detta kandidatexamensarbete är att utvärdera GWP:n av hampafiberisolering jämfört med de två marknadsledande isoleringsmaterialen, mineralull och cellplast.  GWP:n av de tre isoleringsmaterialen beräknas efter att vardera isoleringsmaterial har blivit placerat i ett envåningshus med storleken 30 m2. Livscykelanalysen för byggnader används sedan som bakgrund för att beräkna GWP:n av de tre byggnaderna. De beräknade kategorierna för GWP:n av byggnaderna är: råmaterial, transport, produktion, konstruktion samt energianvändningen. Byggnaderna antas ha en inomhustemperatur på 20°C och har blivit konstruerade i Stockholm, Sverige.  Utan överraskning var hampafibern det isoleringsmaterial som hade lägst GWP i kategorierna; råmaterial, produktion och konstruktion. Däremot på grund av hampafiberns mindre optimala termiska konduktivitet jämfört med de andra isoleringsmaterialen var byggnaden med hampafiberisolering den minst energieffektiva.  Trots den lägre energieffektiviteten visade sig byggnaden med hampafiberisolering vara den med lägst GWP under en 30 årsperiod, förutsatt att förnyelsebara energikällor användes. Överraskande nog, var däremot källan från vart elektriciteten kom mycket viktig för att avgöra byggnadernas GWP. När den svenska elmixen från Boverkets klimatdatabas användes var skillnaden i GWP mellan de olika byggnaderna marginell. Användes istället förnyelsebara energikällor i form av vindkraft, var hampafiberisoleringen det mest fördelaktiga isoleringsmaterialet ur ett miljöperspektiv. / The world's focus on global warming has grown larger than ever before, and the construction sectorisresponsibleforupwardsof 25to40percentoftheglobalcarbonemissions.Oneof the key materials to increase the energy efficiency of buildings are insulation materials. The purpose of the thesis is to evaluate the global warming potential of insulation made out of hemp compared with the two leading insulation materials on the global market, Mineral wool insulation &amp; EPS.  The global warming potential of the three insulation materials are calculated whilst each is placed in a 30 m2 one-story house. The life cycle assessment (LCA) of buildings is used as background to calculate the global warming potential of each of the three buildings. The calculated categories for the global warming potential are: raw materials, transportation, production, the construction phase, and energy usage in the building. The buildings are assumed to have an inside temperature of 20°C and have been constructed in Stockholm, Sweden.  To no surprise the hemp fibre insulation material had the lowest global warming potential out of the three materials during the raw material, production and construction phase. However due to the less optimal value of thermal conductivity for the hemp fiber insulation compared to the other materials, the energy efficiency in the building using hemp fibre insulation was comparatively the worst.  However, the building using hemp fibre insulation could be concluded as the one with the least global warming potential during a 30 year usage if the correct energy sources were used. Surprisingly enough it turned out that the source of electricity was vital for the global warming potential. When using the Swedish electricity mix found in Boverkets Climate database the difference between the buildings was marginal. If renewable sources in the form of wind power were used instead of the national mix for electricity the differences were more noticable and the building using hemp fiber as insulation was less impactful the lower the global warming potential of the energy source was per kWh.

Cette recherche porte sur les fils multifilamentaires de verre utilisés pour renforcer les matériaux à base de ciment. Elle est focalisée sur les interactions mécaniques de ce type de fils, constitués d'un assemblage de milliers de filaments micrométriques, avec un micro-béton et sur le rôle spécifique de l'imprégnation du fil par cette matrice cimentaire. Trois pré-conditionnements des fils ont été employés lors de la fabrication des éprouvettes afin de moduler les conditions d'imprégnation par la matrice cimentaire. L'imprégnation de 5 fils multi-filamentaires par la matrice cimentaire a été caractérisée et les paramètres d'imprégnation ont été définis en s'appuyant sur des observations MEB, ainsi que des essais de porosimétrie au mercure et des essais spécifiques d'écoulement le long du fil enrobé. Des essais classiques d'arrachement de type pull-out ont été utilisés pour la caractérisation mécanique. L'analyse des liens entre les propriétés mécaniques et les paramètres d'imprégnation ont permis de mieux comprendre les micro-mécanismes d'interaction filaments / matrice cimentaire et d'expliquer le comportement macroscopique à l'arrachement. / This research deals with multi-filaments glass yarns used as reinforcement of cement based materials. It focuses on the mechanical interactions of these yarns, made of thousands of micrometric filaments, with a micro-concrete and on the specific part of the impregnation of the yarn by the cementitious matrix. Modulated impregnation conditions of the yarns were obtained by using three different manufacturing processes for the samples preparation. The impregnation of 5 multi-filament yarns by the cementitious matrix has been characterized and physical parameters of impregnation were determined using SEM investigations, mercury intrusion porosity measurements and specific tests of flow all along the embedded yarn. Classical pull-out tests have been used for the mechanical characterisation. The study of the links between the mechanical properties and the physical parameters of impregnation allowed accessing a better understanding of the filaments / cementitious matrix interaction micro-mechanisms, and explaining the macroscopic pull-out behaviour.

Made available in DSpace on 2016-04-28T14:16:30Z (GMT). No. of bitstreams: 1 Izabel Cristina Alves.pdf: 377405 bytes, checksum: 2e61fb86f7e92f75ea8bbae58f831cdd (MD5) Previous issue date: 2007-10-17 / Secretaria da Educação do Estado de São Paulo / The dissertation goal is to point out and analyze Portugal actions for agricultural incentive on Brazil, most specifically the culture of plants that would turn into threads that could substitute linen hemp on late 17th and early 18th Centuries. These actions were based in a new way to understand nature, deeply marked by whole restoration plans that aimed Portugal's economic development. Shall be shown relevant authors which dedicated studies about such plants whose ideas contributed in a new position and manners to observe Nature through a scientific agriculture turned into a new methodology of observation and experimentation, yet these changes had not been enough for complete agricultural technique and culture developments. Still on context will be presented difficulties faced by settlers observed through research on original documents / O objetivo desta dissertação é apontar e analisar as ações de Portugal de incentivo à agricultura no Brasil, mais especificamente sobre a cultura das plantas que se poderiam fabricar fios e que poderiam substituir o linho cânhamo, em finais do século XVIII e início do XIX. Essas ações estavam baseadas em uma nova forma de se compreender a natureza, e eram marcadas profundamente pelo conjunto de reformas que visavam o desenvolvimento econômico de Portugal. Serão apresentados autores, que se dedicaram aos estudos dessas plantas, cujas idéias contribuíram na formação de novas posturas e modos de se olhar a natureza através de uma agricultura científica, voltada para uma nova metodologia de observação e experimentação, ainda que essas mudanças não tenham sido suficientes para o total desenvolvimento dessas culturas e de técnicas agrícolas. Ainda neste contexto apresentaremos as dificuldades enfrentadas pelos colonos que foram observadas através da pesquisa em documentos originais

In recent years, due to growing environmental awareness, considerable attention has been given to the development and production of natural fibre reinforced polymer (both thermoset and thermoplastic) composites. The main objective of this study was to reinforce epoxy and polylactic acid (PLA) with hemp fibre to produce improved composites by optimising the fibre treatment methods, composite processing methods, and fibre/matrix interfacial bonding. An investigation was conducted to obtain a suitable fibre alkali treatment method to: (i) remove non-cellulosic fibre components such as lignin (sensitive to ultra violet (UV) radiation) and hemicelluloses (sensitive to moisture) to improve long term composites stability (ii) roughen fibre surface to obtain mechanical interlocking with matrices (iii)expose cellulose hydroxyl groups to obtain hydrogen and covalent bonding with matrices (iv) separate the fibres from their fibre bundles to make the fibre surface available for bonding with matrices (v) retain tensile strength by keeping fibre damage to a minimum level and (vi) increase crystalline cellulose by better packing of cellulose chains to enhance the thermal stability of the fibres. An empirical model was developed for fibre tensile strength (TS) obtained with different treatment conditions (different sodium hydroxide (NaOH) and sodium sulphite (Na2SO3) concentrations, treatment temperatures, and digestion times) by a partial factorial design. Upon analysis of the alkali fibre treatments by single fibre tensile testing (SFTT), scanning electron microscopy (SEM), zeta potential measurements, differential thermal analysis/thermogravimetric analysis (DTA/TGA), wide angle X-ray diffraction (WAXRD), lignin analysis and Fourier transform infrared (FTIR) spectroscopy, a treatment consisting of 5 wt% NaOH and 2 wt% Na2SO3 concentrations, with a treatment temperature of 120oC and a digestion time of 60 minutes, was found to give the best combination of the required properties. This alkali treatment produced fibres with an average TS and Young's modulus (YM) of 463 MPa and 33 GPa respectively. The fibres obtained with the optimised alkali treatment were further treated with acetic anhydride and phenyltrimethoxy silane. However, acetylated and silane treated fibres were not found to give overall performance improvement. Cure kinetics of the neat epoxy (NE) and 40 wt% untreated fibre/epoxy (UTFE) composites were studied and it was found that the addition of fibres into epoxy resin increased the reaction rate and decreased the curing time. An increase in the nucleophilic activity of the amine groups in the presence of fibres is believed to have increased the reaction rate of the fibre/epoxy resin system and hence reduced the activation energies compared to NE. The highest interfacial shear strength (IFSS) value for alkali treated fibre/epoxy (ATFE) samples was 5.2 MPa which was larger than the highest value of 2.7 MPa for UTFE samples supporting that there was a stronger interface between alkali treated fibre and epoxy resin. The best fibre/epoxy bonding was found for an epoxy to curing agent ratio of 1:1 (E1C1) followed by epoxy to curing agent ratios of 1:1.2 (E1C1.2), 1: 0.8 (E1C0.8), and finally for 1:0.6 (E1C0.6). Long and short fibre reinforced epoxy composites were produced with various processing conditions using vacuum bag and compression moulding. A 65 wt% untreated long fibre/epoxy (UTLFE) composite produced by compression moulding at 70oC with a TS of 165 MPa, YM of 17 GPa, flexural strength of 180 MPa, flexural modulus of 10.1 GPa, impact energy (IE) of 14.5 kJ/m2, and fracture toughness (KIc) of 5 MPa.m1/2 was found to be the best in contrast to the trend of increased IFSS for ATFE samples. This is considered to be due to stress concentration as a result of increased fibre/fibre contact with the increased fibre content in the ATFE composites compared to the UTFE composites. Hygrothermal ageing of 65 wt% untreated and alkali treated long and short fibre/epoxy composites (produced by curing at 70oC) showed that long fibre/epoxy composites were more resistant than short fibre/epoxy composites and ATFE composites were more resistant than UTFE composites towards hygrothermal ageing environments as revealed from diffusion coefficients and tensile, flexural, impact, fracture toughness, SEM, TGA, and WAXRD test results. Accelerated ageing of 65 wt% UTLFE and alkali treated long fibre/epoxy (ATLFE) composites (produced by curing at 70oC) showed that ATLFE composites were more resistant than UTLFE composites towards hygrothermal ageing environments as revealed from tensile, flexural, impact, KIc, SEM, TGA, WAXRD, FTIR test results. IFSS obtained with untreated fibre/PLA (UFPLA) and alkali treated fibre/PLA (ATPLA) samples showed that ATPLA samples had greater IFSS than that of UFPLA samples. The increase in the formation of hydrogen bonding and mechanical interlocking of the alkali treated fibres with PLA could be responsible for the increased IFSS for ATPLA system compared to UFPLA system. Long and short fibre reinforced PLA composites were also produced with various processing conditions using compression moulding. A 32 wt% alkali treated long fibre PLA composite produced by film stacking with a TS of 83 MPa, YM of 11 GPa, flexural strength of 143 MPa, flexural modulus of 6.5 GPa, IE of 9 kJ/m2, and KIc of 3 MPa.m1/2 was found to be the best. This could be due to the better bonding of the alkali treated fibres with PLA. The mechanical properties of this composite have been found to be the best compared to the available literature. Hygrothermal and accelerated ageing of 32 wt% untreated and alkali treated long fibre/PLA composites ATPLA composites were more resistant than UFPLA composites towards hygrothermal and accelerated ageing environments as revealed from diffusion coefficients and tensile, flexural, impact, KIc, SEM, differential scanning calorimetry (DSC), WAXRD, and FTIR results. Increased potential hydrogen bond formation and mechanical interlocking of the alkali treated fibres with PLA could be responsible for the increased resistance of the ATPLA composites. Based on the present study, it can be said that the performance of natural fibre composites largely depend on fibre properties (e.g. length and orientation), matrix properties (e.g. cure kinetics and crystallinity), fibre treatment and processing methods, and composite processing methods.

Det finns en oro kring konsekvenserna av ökade växthusgasutsläpp. Därför har bland annat EU:s medlemsländer tecknat avtal om att minska utsläppen. I Sverige har det lett till krav att från och med 2022 redovisa byggmaterials miljöpåverkan genom klimatdeklarationer. Byggsektorn har potential att minska klimatpåverkan. Byggnadsmaterial ger olika utsläpp av växthusgaser och valet av material är viktigt. Isoleringsmaterial med naturlig härkomst anses orsaka mindre utsläpp än konventionell isolering. Hampa är ett exempel på ett naturligt material som kan användas i småhusbebyggelse. Hampan kan bli en kolsänka då biomaterial binder kol. Tyvärr finns det idag mycket begränsad forskning på just hampfiberisolering i svenskt klimat.  Syftet med studien är att bidra med ökad kunskap inför valet av isoleringsmaterial i ett småhus, av modellen Eneryda av Rörvikshus, placerat i Växjö. I arbetet jämförs klimatpåverkan och kostnader för isoleringsmaterialen hamp-, cellulosa- och glasullsisolering genom en livscykelanalys (LCA) och en livscykelkostnad (LCC) i en vald husmodell. I studien undersöks skedena A-D, d.v.s. från vagga till grav. Resultatet visar att byggnaden isolerad med hampfiber orsakar det lägsta nettoutsläppet på 124 följt av cellulosa 132 och glasull 139 CO₂e/m². Kostnaden för byggnaden med isolering av hampfiber är 5467, cellulosa 4830 och glasull 4861 SEK/m²BOA. Genom att välja hampfiberisolering istället för glasull kan utsläppen för husmodellen Eneryda minskas med 12 % samtidigt som kostnaden ökar med 20 %. Att välja cellulosaisolering i stället för glasullsisolering ger en minskning av nettoutsläppen med 5 % och kostnaderna förblir detsamma.  Studiens känslighetsanalyser visar effekten av indata. Om råvaran till cellulosa byts ut från oanvänt papper till återvunnen råvara orsakar det att nettoutsläppen för byggnaden Eneryda minskar med 13 %. Det innebär att småhuset Eneryda isolerad med cellulosa från återvunnen produkt orsakar 15 % lägre utsläpp än glasullshuset - utan att påverka priset. Största påverkan på nettoutsläppen hade Enerydas värmesystem. Att använda bergvärme istället för Veab:s fjärrvärme ökade nettoutsläppen med 56 – 63 %. Slutligen ledde resultatet av studien till en diskussion om avsaknaden av en entydig definition och metod för användandet av biogent kol i klimatdeklarationer. Att exkludera biogent kol leder till att hampfiberisoleringen bidrar med högst utsläpp tätt följt av cellulosan och sist glasullsisoleringen som släpper ut minst. Studiens resultat påvisar vikten av vaksamhet och att Boverket borde blir tydligare kring det biogena kolet i klimatberäkningar. Enheten bör utvecklas mer av institut för standarder. Av resultaten framgår också vikten av att ta tidsaspekten av biomaterialets förnyelsetid i beaktande vid beräkningarna för att material som hampfiber binder kol snabbare än exempelvis trä. / The concern of climate change has influenced the building sector in Sweden to become more climate neutral. The choice of building materials affect the emissions of carbon dioxide equivalents [CO₂e]. The purpose of the study is to provide more basis for the choice of insulation material looking into the climate- and cost implication of hemp fibre, cellulose and stone wool insulation.  The study includes an accounting-LCA from cradle to grave (A – D) and an LCC. The study looks at the climate shell of a one-story single-family house, model Eneryda from Rörvikshus, in Växjö over the lifetime 50 years.  The result shows that Eneryda net emissions for hemp fiber insulation is 124 CO₂e/m²BOA and the cost is 5467 SEK/m2 BOA. The result of emissions for the hempfiber-model is 12% less and the cost is 20% higher than the glass wool-model. Cellulose insulation results in net emissions of 132 CO₂e/m² and a cost of 4830 SEK/m2 BOA. Cellulose results in 5% less emissions and nearly the same cost as the glass wool building.

This master‘s thesis studies problems of chosen active substances in cosmetic emulsions and gels. There is their main characteristics – distribution and properties of cosmetic emulsions and gels, preparation of the active substances, effects on the skin and conditions, which could them influence. In experimental part, preparation of gels and emulsions bases was described which were than enriched by active substances - evening primrose oil, hemp oil, Salvia officinalis extract, Symphytum officinale extract and sea salt. Properties of these cosmetic gels and emulsions bases with the addition of active substances depend on temperature and method of storage, amount of light exposure, method of preparation and another conditions. Action of these factors can cause changes of the stability, thereby the cosmetics effects on the skin can be lost. On the bases of performed rheology measurements (oscillation and flow measurements), pH measurements and sensory analysis were determined, if the properties of examined samples were changed. The measurement was performed in the certain time intervals and the properties were evaluated like at laboratory temperature 23±2 °C, so after exposure to temperature regime 37 °C in thermoregulator. On the basis of performed measurements, there was determined, that gel base with addition of Symphytum officinale extract had the most stability properties.

The thesis discusses possibilities of use new thermal insulation materials based on natural renewable resources (primary technical hemp) in development of the new thermal insulation materials. The main task (in the work) is to find modifications of the thermal insulation mats based on natural fibres by chemicals substances to improve the moisture properties, thermal properties and fire resistance.