As part of the SUNRISE project (Semiconductors Using Nanostructures for Record Increases in Solar-cell Efficiency), high efficiency, III-V semiconductor, quantum-dot-enhanced, triple-junction solar cells designed and manufactured by Cyrium Technologies Inc. were integrated into OPEL Solar, MK-I, Fresnel-lens-based, 550x concentrating modules carried on a dual axis tracker. Over its first year of operation 1.8 MWh of AC electrical energy was exported to the grid. Measurements of the direct and indirect components of the insolation, as well as the spectral irradiance of light incident on the demonstrator in Ottawa, Canada are presented. The system efficiency is measured and compared to that predicted by a system model to identify loss mechanisms so that they can be minimized in future deployments.

Inkjet printing promises to be an invaluable technique for processing organic solar cells with key advantages such as low material consumption, freedom of design and compatibility with different types of flexible substrates making it suitable for large-area production. However, one concern about inkjet printed organic solar cells is the common use of chlorinated solvents during the ink formulation process. While chlorinated solvents suit the inkjet printing process due to their high boiling points, suitable viscosity, and excellent solubility of organic donor and acceptor compounds, they still pose some risks for both human health and the environment, excluding them from being the ultimate choice for large-area production. As a step towards commercialization of OPV, we demonstrated the possibility to close the laboratory to fabrication gap, through the engineering of environmentally friendly inks, using a blend of non-halogenated benzene derivatives solvents optimized to meet the viscosity and surface tension requirements for the inkjet printing process. Starting from using the non-fullerene acceptor O-IDTBR combined with the commercially available donor polymer P3HT we obtained solar cell device with efficiency up to 4.73% - the best efficiency achieved by the P3HT:O-IDTBR system processed with all non-halogenated solvents via inkjet printing. We also delivered highly transparent active layer with device power conversion efficiency of up to 10% with a highly efficient blend of polymer donor PTB7-Th in combination with the ultranarrow band gap NFA IEICO-4F, using hydrocarbons solvent. Lastly, we demonstrated both high efficiency, transparency, and stability by presenting a novel approach based on NFAs consisting of lowering the donor:acceptor ratio in the photoactive layer ink formulations, resulting in more stable devices with comparable power conversion efficiencies to those achieved by lab methods. This breakthrough in ink engineering paves the way in closing the lab-to-fab gap in organic photovoltaic using the low-cost, high throughput inkjet printing technology while considering both environmental and health-conscious mass production and device stability of organic photovoltaics.

<p> Silicon solar cells were produced using inexpensive techniques for obtaining high efficiencies. Large area cells were made with efficiencies greater than 10% (AM1) which were subsequently mounted on a Solar panel for future evaluation. </p> / Thesis / Master of Engineering (MEngr)

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No description available.

Over the past several years, energy efficiency and power density have become the top concerns for power conversion. Rising energy intensity leads to a higher cost of delivering power. Meanwhile, the demand for compact power supplies grows significantly. It requires power supplies with high efficiency, low profile and high power density. Dc-dc power conversion has been widely applied for industry, medial, military and airspace applications. Conventional PWM dc-dc converters have relatively low power transfer efficiency and low power density. In contrast, resonant dc-dc converters have numerous advantages for dc-dc power conversions. In this work, topologies and system optimization of resonant converters are investigated to meet challenges of high efficiency, high power density, low EMI, easy startup and over current protection. LLC resonant converters can achieve zero-voltage-switching (ZVS) for primary side devices and zero-current-switching (ZCS) for the secondary side rectifiers. The switching loss is minimized. LLC is very attractive to overcome the issues of conventional circuits. However, challenges still remain. First of all, for low-voltage high-current applications, the synchronous rectifier (SR) with lower conduction loss is a must for high efficiency. To solve the driving issues of SRs, a novel synchronous driving scheme is proposed. Experimental results demonstrate the considerable loss reduction with utilization of the proposed driving scheme. Secondly, dc-dc converters are required to meet EMI standard. This work proposes an EMI mode. Based on the proposed model, EMI analysis and noise attenuation techniques are proposed and verified by experiments. Thirdly, startup and over-load protection are another issues of LLC resonant converters. With proposed multi-element resonant converters, the current limit issues can be resolved. In addition, the proposed multi-element resonant converters can utilize higher-order harmonics to enhance power transfer. Fourthly, for high-current applications, the secondary side structure becomes very critical. An improved secondary side construction is proposed to alleviate ac termination losses and SR paralleling issues. Novel winding structures are proposed to reduce the winding loss. The magnetic integration technique is proposed and analyzed, and an optimal integrated transformer design is proposed, which has low loss and compact size. / Ph. D.

Since future microprocessors will have higher current in accordance with Moore's law, there are still challenges for voltage regulators (VRs). Firstly, high efficiency is required not only for easy thermal management, but also for saving on electricity costs for data centers, or battery life extension for laptop computers. At the same time, high power density is required due to the increased power of the microprocessors. This is especially true for data centers, since more microprocessors are required within a given space (per rack). High power density is also required for laptop computers to reduce the size and the weight. To improve power density, a high frequency is required to shrink the size of the output inductors and output capacitors of the multi-phase buck VR. It has been demonstrated that the output bulk capacitors can be eliminated by raising the VR control bandwidth to around 350kHz. Assuming the bandwidth is one-third of the switching frequency, a VR should run at 1MHz to ensure a small size. However, the efficiency of a 12V VR is very poor at 1MHz due to high switching losses. As a result, a 12V VR can only run at 300kHz to 600kHz, and the power density is very low. To attain high efficiency and high power density at the same time, two-stage power architecture was proposed. The concept is "Divide and Conquer". A single-stage VR is split into two stages to get better performance. The second stage has about 5V-6V input voltage; thus the duty cycle can be extended and the switching losses are greatly reduced compared with a single-stage VR. Moreover, a sub-20V MOSFET can be used to further improve the efficiency at high frequencies. The first stage of the proposed two-stage architecture is converting 12V to 5-6V. High efficiency is required for the first stage since it is in series with the second stage. Previous first stage which is a buck converter has good efficiency but bulky size due to low frequency operation. Another problem with using a buck converter is that light-load efficiency of the first stage is poor. To solve these problems, switched-capacitor voltage dividers are proposed. Since the first stage does not require voltage regulation, the sweet point for the voltage divider can be determined and high efficiency can be achieved. At the same time, since there are no magnetic components for the switched-capacitor voltage divider, high power density can be achieved. By very careful design, a power density of more than 2000W/in3 with more than 97% efficiency can be achieved for the proposed voltage divider. The light-load efficiency of the voltage divider can be as high as 99% by reducing the switching frequency at light load. As for the second stage, different low-voltage devices are evaluated, and the best device combinations are found for high-frequency operation. It has been demonstrated that 91% efficiency can be achieved with 600kHz frequency, and 89% efficiency can be achieved with a 1MHz frequency for the second stage. Moreover, adaptive on-time control method and a non-linear inductor structure are proposed to improve CCM and DCM efficiency for the second stage respectively. Previously the two-stage VR was only used as a CPU VR. The two-stage concept can also be applied to other systems. In this dissertation, the two-stage power architecture is applied to two different applications: laptop computers and high-end server microprocessors. The common characteristics of the two applications are their thermal design power (TDP) requirement. Thus the first stage can be designed with much lower power than the maximum system power. It has been demonstrated that the two-stage power architecture can achieve either higher efficiency or higher power density and a lower cost when compared with the single-stage VR. To get higher efficiency, a parallel two-stage power architecture, named sigma architecture, is proposed for VR applications. The proposed sigma VR takes advantage of the high-efficiency, fast-transient unregulated converter (DCX) and relies on this converter to deliver most of the output power, while using a low-power buck converter to achieve voltage regulation. Both the DCX converter and the buck converter can achieve around 90% efficiency when used in the sigma VR, which ensures 90% efficiency for the sigma VR. The small-signal model of the sigma VR is studied to achieve adaptive voltage positioning (AVP). The sigma power architecture can also be applied to low-power point of load (POL) applications to reduce the magnetic component size and improve the efficiency. Finally, the two-stage VR and the sigma VR are briefly compared. / Ph. D.

Master of Science / Department of Architectural Engineering and Construction Science / Julia A. Keen / Nanofibers are classified as fibers less than 1 micrometer in diameter. These fibers can be layered to form nanofibrous membranes, and these membranes offer great potential in the filtration industry. The membranes' smaller fiber diameters and pore sizes permit such filters to filter out more and smaller particulate. Additionally, antimicrobial agents can be incorporated into the membrane to inhibit fungal and bacterial growth on the membrane’s surface. This report evaluates nanofibrous membranes with antimicrobial agents and their potential in two specific locations: cleanrooms and protective environment rooms, where bacterial and fungal growth would have a detrimental effect on the process or occupant of the space.

A new dual fuel Controlled Auto-Ignition (CAI) combustion concept was proposed and researched for lower exhaust emissions and better fuel economy. The concept takes the advantage of the complementary physical and chemical properties of high octane number gasoline and high cetane number Di-Methyl Ether (DME) to organize the combustion process. Homogeneous gasoline/air mixture is utilized as the main combustible charge, which is realised by a low-cost Port Fuel Injection (PFI) system. Pressurised DME is directly injected into cylinder via a commercial Gasoline Direct Injection (GDI) injector. Flexible DME injection strategies are employed to realise the controlled auto ignition of the premixed charge. The engine is operated at Wide Open Throttle (WOT) in the entire operating region in order to minimize the intake pumping loss. Engine load is controlled by varing the amount of internal Exhaust Gas Recirculation (iEGR) which is achieved and adjusted by Positive Valve Overlap (PVO) and/or exhaust back pressure, and exhaust rebreathing method. The premixed mixture can be of either stoichiometric air/fuel ratio or fuel lean mixture and is heated and diluted by recycled exhaust gases. The use of internal EGR is considered as a very effective method to initiate CAI combustion due to its heating effect and moderation of the heat release rate by its dilution effect. In addition, the new combustion concept is compared to conventional SI combustion. The results indicate that the new combustion concept has potential for high efficiency, low emissions, enlargement of the engine operational region and flexible control of CAI combustion.

In 2013, the worldwide production of renewable electricity accounted for 22.1% of the total energy production with 0.9% coming from solar photovoltaics (PVs). Recently, there has been a growing interest for Cu2ZnSnS4 (CZTS) quaternary semiconductor due to the abundance and low cost of its precursors. Moreover, this chalcopyrite material has an ideal direct band gap around 1.5 eV, high absorption coefficient (α >104 cm-1) and high conductivity, making it suitable for nanostructured and dye-sensitized solar cell (DSSC) applications. Here, CZTS nanoparticles have been synthesized by pulsed laser deposition (PLD) and simultaneously deposited in the interstitial space of ZnO nanowire arrays to form bulk heterojunction 3D nanostructured solar cells. Secondly, vertically oriented CZTS nanoplates have been synthesized by PLD and used as counter electrode in platinum-free dye-sensitized solar cells. These CZTS nanostructures proved to be suitable in achieving workable solar cells, which could significantly cut down the cell cost and provide environmentally friendly photovoltaic devices. Alternately, hybrid organic–inorganic perovskite solar cells have become one of the most attractive photovoltaic technologies with easy solution fabrication and high conversion efficiencies. However, the devices remain unstable under certain processing and environmental conditions. Herein, formamidinium lead tri-halide perovskite (FAPbI3) planar heterojunction solar cells have been fabricated under a controlled environment. The fabrication parameters (precursor concentration, annealing, etc) and the effect of humidity on the structural, optical, and electrical properties of FAPbI3 thin films and devices have been investigated and proved to be critical in the processing of efficient devices. Solar cells with conversion efficiency of 16.6% have been obtained. Furthermore, in-situ techniques such as in-situ (scanning) transmission electron microscopy and in-situ XRD were performed to understand the crystallization and degradation mechanisms of FAPbI3 thin films.The in-situ data were correlated with planar heterojunction FAPbI3 devices efficiency data in order to improve the device fabrication process.