Structural energetic materials (SEM) are a class of multicomponent materials which may react under various conditions to release energy. Fragmentation and impact induced reaction are not well characterized phenomena in SEMs. The structural energetic systems under consideration here combine aluminum with one or more of the following: nickel, tantalum, tungsten, and/or zirconium. These metal+Al systems were formulated with powders and consolidated using explosive compaction or the gas dynamic cold spray process. Fragment size distributions of the indicated metal+Al systems were explored; mean fragment sizes were found to be smaller than those from homogeneous ductile metals at comparable strain rates, posing a reduced risk to innocent bystanders if used in munitions. Extensive interface failure was observed which suggested that the interface density of these systems was an important parameter in their fragmentation. Existing fragmentation models for ductile materials did not adequately capture the fragmentation behavior of the structural energetic materials in question. A correction was suggested to modify an existing fragmentation model to expand its applicability to structural energetic materials. Fragment data demonstrated that the structural energetic materials in question provided a significant mass of combustible fragments. The potential combustion enthalpy of these fragments was shown to be significant. Impact experiments were utilized to study impact induced reaction in the indicated metal+Al SEM systems. Mesoscale parametric simulations of these experiments indicated that the topology of the microstructure constituents, particularly the stronger phase(s), played a significant role in regulating impact induced reactions. Materials in which the hard phase was topologically connected were more likely to react at a lower impact velocity due to plastic deformation induced temperature increases. When a compliant matrix surrounded stronger, simply connected particles, the compliant matrix accommodated nearly all of the deformation, which limited plastic deformation induced temperature increases in the stronger particles and reduced reactivity. Decreased difference between the strength of the constituents in the material also increased reactivity. The results presented here demonstrate that the fragmentation and reaction of metal+Al structural energetic materials are influenced by composition, microstructure topology, interface density, and constituent mechanical properties.

Les joints adhésifs sont de plus en plus utilisés dans des structures industrielles critiques. Ils sont donc susceptibles de subir des chargements dynamiques complexes. Les méthodes de caractérisation dynamiques existantes ne caractérisent pas seulement le joint adhésif, mais l'assemblage collé tout entier. Cette thèse propose une méthode innovante pour caractériser un joint adhésif sous sollicitations dynamiques multiaxiales. La méthode expérimentale repose sur trois éléments principaux: i) un système de barres d'Hopkinson conventionnel (SHPB), ii) une nouvelle géométrie d'éprouvette, nommée DODECA, qui permet d'appliquer trois chargements multiaxiaux différents et iii) des mesures locales de déformation et de contrainte par corrélation d'images. La contrainte et la déformation dans le joint adhésif sont estimées directement à partir des données expérimentales pendant le chargement jusqu'au point de rupture. Une autre approche basée sur la méthode FEMU (Finite Element Model Updating) a été utilisée pour compléter le modèle du joint adhésif. Une méthode inverse numérique a été développée pour obtenir les paramètres élastiques, plastiques et de rupture du joint adhésif. De plus, des outils qualitatifs ont été proposés pour estimer les incertitudes sur les paramètres identifiés. Ce travail a prouvé l'intérêt de l'imagerie rapide locale pour caractériser les joints adhésifs.Cette méthode innovante a été validée sur une autre éprouvette nommée BIADH45. Cette dernière étude a aussi mis l'accent sur de nouveaux domaines de recherche : en particulier, le rôle des interfaces dans la rupture du joint adhésif et l'intérêt des substrats en CMO dans la caractérisation dynamique des joints adhésifs. / Adhesive joints are increasingly employed for bonding critical parts of industrial structures. Therefore, they are subject to complex dynamic loadings. Existing dynamic characterization techniques do not characterize only the adhesive joint, but the complete assembly. This thesis proposes an innovative experimental technique for the characterization of adhesive joints under dynamic multiaxial loadings. The experimental method relies on three main components: i) a conventional split Hopkinson pressure bar (SHPB) apparatus, ii) a novel specimen, denoted as DODECA, which enables testing of three distinct multiaxial loadings using the same method and iii) local strain and stress measurements performed by digital image correlation (DIC). The stress and strain in the adhesive joint are estimated directly from the experimental data both during loading and at the failure point. Another approach based on the Finite Element Model Updating method (FEMU) has been used to complete the adhesive joint model. A numerical inverse method has been developed to obtain elastic, plastic and fracture parameters. Besides, qualitative tools have been proposed to estimate uncertainties on identified parameters. This work has proven the value of local high-speed imaging to characterize adhesive joints.This innovative method has been validated on another specimen denoted as BIADH45. This last study has also emphasized new research interests : in particular, the role of the interfaces in the adhesive joint failure and the benefit of substrates in CMO in dynamic characterization of adhesive joints.

Mitigation of the blast risk associated with terrorist attacks and accidental explosions threatening critical infrastructure has become a topic of great interest in the civil engineering community, both in Canada and abroad. One method of mitigating blast risk is to retrofit vulnerable structures to resist the impulsive effects of blast loading. A comprehensive re-search program has been undertaken to develop fibre reinforced polymer (FRP) retrofit methodologies for structural and non-structural elements, specifically reinforced concrete slabs and walls, subjected to blast loading. The results of this investigation are equally valid for flexure dominant reinforced concrete beams subject to blast effects. The objective of the research program was to generate a large volume of research data for the development of blast-resistant design guidelines for externally bonded FRP retrofit systems. A combined experimental and analytical investigation was performed to achieve the objectives of the program. The experimental program involved the construction and simulated blast testing of a total of thirteen reinforced concrete wall and slab specimens divided into five companion sets. These specimens were subjected to a total of sixty simulated explosions generated at the University of Ottawa Shock Tube Testing Facility. Companion sets were designed to study one- and two-way bending, as well as the performance of specimens with simply-supported and fully-fixed boundary conditions. The majority of the specimens were retrofitted with externally bonded carbon fibre reinforced polymer (CFRP) sheets to improve overall load-deformation characteristics. Specimens within each companion set were subjected to progressively increasing pressure-impulse combinations to study component behaviour from elastic response up to inelastic component failure. The blast performance of companion as-built and retrofitted specimens was quantified in terms of measured load-deformation characteristics, and observed member behaviour throughout all stages of response. The results show that externally bonded FRP retrofits are an effective retrofit technique to improve the blast resistance of reinforced concrete structures, provided that debonding of the composite from the concrete substrate is prevented. The test results also indicate that FRP retrofitted reinforced concrete structures may survive initial inbound displacements, only to failure by moment reversals during the negative displacement phase. The experimental test data was used to verify analytical techniques to model the behaviour of reinforced concrete walls and slabs subjected to blast loading. The force-deformation characteristics of one-way wall strips were established using inelastic sectional and member analyses. The force-deformation characteristics of two-way slab plates were established using commonly accepted design approximations. The response of all specimens was computed by explicit solution of the single degree of freedom dynamic equation of motion. An equivalent static force procedure was used to analyze the response of CFRP retrofitted specimens which remained elastic after testing. The predicted maximum displacements and time-to-maximum displacements were compared against experimental results. The analysis indicates that the modelling procedures accurately describe the response characteristics of both retrofitted and unretrofitted specimens observed during the experiment.

Mitigation of the blast risk associated with terrorist attacks and accidental explosions threatening critical infrastructure has become a topic of great interest in the civil engineering community, both in Canada and abroad. One method of mitigating blast risk is to retrofit vulnerable structures to resist the impulsive effects of blast loading. A comprehensive re-search program has been undertaken to develop fibre reinforced polymer (FRP) retrofit methodologies for structural and non-structural elements, specifically reinforced concrete slabs and walls, subjected to blast loading. The results of this investigation are equally valid for flexure dominant reinforced concrete beams subject to blast effects. The objective of the research program was to generate a large volume of research data for the development of blast-resistant design guidelines for externally bonded FRP retrofit systems. A combined experimental and analytical investigation was performed to achieve the objectives of the program. The experimental program involved the construction and simulated blast testing of a total of thirteen reinforced concrete wall and slab specimens divided into five companion sets. These specimens were subjected to a total of sixty simulated explosions generated at the University of Ottawa Shock Tube Testing Facility. Companion sets were designed to study one- and two-way bending, as well as the performance of specimens with simply-supported and fully-fixed boundary conditions. The majority of the specimens were retrofitted with externally bonded carbon fibre reinforced polymer (CFRP) sheets to improve overall load-deformation characteristics. Specimens within each companion set were subjected to progressively increasing pressure-impulse combinations to study component behaviour from elastic response up to inelastic component failure. The blast performance of companion as-built and retrofitted specimens was quantified in terms of measured load-deformation characteristics, and observed member behaviour throughout all stages of response. The results show that externally bonded FRP retrofits are an effective retrofit technique to improve the blast resistance of reinforced concrete structures, provided that debonding of the composite from the concrete substrate is prevented. The test results also indicate that FRP retrofitted reinforced concrete structures may survive initial inbound displacements, only to failure by moment reversals during the negative displacement phase. The experimental test data was used to verify analytical techniques to model the behaviour of reinforced concrete walls and slabs subjected to blast loading. The force-deformation characteristics of one-way wall strips were established using inelastic sectional and member analyses. The force-deformation characteristics of two-way slab plates were established using commonly accepted design approximations. The response of all specimens was computed by explicit solution of the single degree of freedom dynamic equation of motion. An equivalent static force procedure was used to analyze the response of CFRP retrofitted specimens which remained elastic after testing. The predicted maximum displacements and time-to-maximum displacements were compared against experimental results. The analysis indicates that the modelling procedures accurately describe the response characteristics of both retrofitted and unretrofitted specimens observed during the experiment.

Mitigation of the blast risk associated with terrorist attacks and accidental explosions threatening critical infrastructure has become a topic of great interest in the civil engineering community, both in Canada and abroad. One method of mitigating blast risk is to retrofit vulnerable structures to resist the impulsive effects of blast loading. A comprehensive re-search program has been undertaken to develop fibre reinforced polymer (FRP) retrofit methodologies for structural and non-structural elements, specifically reinforced concrete slabs and walls, subjected to blast loading. The results of this investigation are equally valid for flexure dominant reinforced concrete beams subject to blast effects. The objective of the research program was to generate a large volume of research data for the development of blast-resistant design guidelines for externally bonded FRP retrofit systems. A combined experimental and analytical investigation was performed to achieve the objectives of the program. The experimental program involved the construction and simulated blast testing of a total of thirteen reinforced concrete wall and slab specimens divided into five companion sets. These specimens were subjected to a total of sixty simulated explosions generated at the University of Ottawa Shock Tube Testing Facility. Companion sets were designed to study one- and two-way bending, as well as the performance of specimens with simply-supported and fully-fixed boundary conditions. The majority of the specimens were retrofitted with externally bonded carbon fibre reinforced polymer (CFRP) sheets to improve overall load-deformation characteristics. Specimens within each companion set were subjected to progressively increasing pressure-impulse combinations to study component behaviour from elastic response up to inelastic component failure. The blast performance of companion as-built and retrofitted specimens was quantified in terms of measured load-deformation characteristics, and observed member behaviour throughout all stages of response. The results show that externally bonded FRP retrofits are an effective retrofit technique to improve the blast resistance of reinforced concrete structures, provided that debonding of the composite from the concrete substrate is prevented. The test results also indicate that FRP retrofitted reinforced concrete structures may survive initial inbound displacements, only to failure by moment reversals during the negative displacement phase. The experimental test data was used to verify analytical techniques to model the behaviour of reinforced concrete walls and slabs subjected to blast loading. The force-deformation characteristics of one-way wall strips were established using inelastic sectional and member analyses. The force-deformation characteristics of two-way slab plates were established using commonly accepted design approximations. The response of all specimens was computed by explicit solution of the single degree of freedom dynamic equation of motion. An equivalent static force procedure was used to analyze the response of CFRP retrofitted specimens which remained elastic after testing. The predicted maximum displacements and time-to-maximum displacements were compared against experimental results. The analysis indicates that the modelling procedures accurately describe the response characteristics of both retrofitted and unretrofitted specimens observed during the experiment.

The aim of this thesis is to provide microstructural and mechanical characterisation of α-β titanium alloys exposed to a range of thermo-mechanical conditions, in particular under-going high rate deformation at elevated temperatures, representative of the Linear Friction Welding (LFW) manufacturing process. Three α-β titanium alloys provided by Rolls-Royce are studied: Ti-64 blade, disc and Ti-6246 disc. Ti-64 and Ti-6246 show complex deformation behaviour with strain, strain rate and temperature, especially near the transus temperature, where the low temperature α phase is transformed into the high temperature β phase. The microstructure and mechanical properties evolve in an interconnected fashion, and understanding this mutual influence is necessary to better predict the behaviour of these alloys. Characterisation of the mechanical properties was performed through uniaxial compression tests at strain rates from 0.001 to 3000 s^-1, using an Instron screw-driven machine at quasi-static rates, a servo-hydraulic machine at medium rates and a Split-Hopkinson Pressure Bar and a drop-weight tower at high strain rates. The tests were performed over a range of temperatures from room temperature to 1300 °C. The main focus was on high strain rate and high temperature tests, with the development of a gravity driven direct impact Hopkinson bar, referred as a drop-weight system, which is intended to evaluate the mechanical response of metals to high strain rate loading at temperatures up to c. 1300 °C. The design and principles of operation of the system are presented, along with calibration and validation data. Preliminary tests were performed on stock Ti-64, heated at two rates: 1 and 20 °C s^-1. The evolution of the mechanical properties was analysed, focussing on the strain rate, temperature and phases dependencies. Characterisation of the microstructure was realised by performing interrupted compression tests, first at room temperature, three plastic strains, 4%, 10% and 20%, and two different strain rates, 0.001 and 2000 s^-1; then at 4% plastic strain, a strain rate of 2000 s^-1 and three elevated temperatures, 700, 900 and 1100 °C. A better understanding of the microstructure evolution with strain, strain rates and temperature, including the macrotexture and microtexture of the specimens, was obtained using Electron Backscatter Diffraction (EBSD) to characterise the texture of the undeformed and deformed materials. The better understanding of the flow stress and microstructural evolution of both Ti-64 and its individual α and β phases with various strain rates and temperatures is intended to be used in the development of more accurate models representing the behaviour of these alloys. Predicting the microstructure evolution and then the mechanical properties of a material is essential to optimise the final mechanical properties of the alloys when welded by manufacturing processes such as the LFW process.

Above true strain rates of $10^4$ s$^{-1}$ FCC metals exhibit a rapid increase in strength. Understanding of the physical mechanisms behind this strength transition is hindered by the number and interdependence of candidate mechanisms. Broadly, contributions to strength can be split into `instantaneous' effects and the more permanent `structural' ones. In this thesis a series of experiments are presented which are designed to separate the two types of contribution. Chapter 2 outlines the basics of dislocation plasticity, based on the seminal works of Taylor and Orowan. It then progresses on to discuss recent experimental and theoretical work on the understanding of slip as avalanche behaviour. Chapter 3 summarises traditional modelling approaches for instantaneous strength contributions which are routinely applied below $10^4$ s$^{-1}$. It then continues on to outline a number of different approaches which have been adopted to attempt to explain and model the strength transition. Chapter 4 outlines the methods used in the earliest stages of the study: Instron and split Hopkinson pressure bar methods. Both methods are well established, and cover the majority of the range of rates under study. Emphasis is made on minimising experimental sources of error, and subsequently accounting for those which are unavoidable. Finally, the specimen material is introduced and is shown to be fit for purpose. Chapter 5 presents a set of mechanical tests of specimens at strain rates between $10^4-10^5$~s$^{-1}$. The softening of the specimens with increased temperature is observed to increase with strain rate, both in absolute terms and when normalised to the 300 K measurement for each strain rate. The observations are most easily explained if the strength transition is due to an increase in early stage work hardening, however, some anomalous behaviours remain. Chapter 6 introduces a new experimental technique; direct impact Hopkinson pressure bars, required to perform experiments shown to be necessary by the results of Chapter 5. Photon Doppler velocimetry is applied to the projectiles used in experiments, removing one of the most significant flaws of the technique, and creating a more confident basis with which to perform further experimental work. Chapter 7 presents a series of `jump tests' at ambient temperatures. Specimens are deformed at strain rates ranging from $10^{-2}$ to $10^5$~s$^{-1}$ to a fixed strain of 0.1, then reloaded to yield at a strain rate of $10^{-1}$. The yield point at reload is shown to have the same rapid upturn as seen when the specimens were deforming at high rates, providing strong evidence that the increase in strength is due to changes in the underlying dislocation structure, rather than a dynamic effect, as it remains even when the high strain rate is removed. Chapter 8 continues on from the conclusions of Chapter 7. Jump tests are expanded to a variety of temperatures and strains, to provide a more complete characterisation of metal behaviour. No dramatic change in the saturation of work hardening is observed to coincide with the increase in early stage work hardening. Chapter 9 discusses discrepancies between contemporary high rate models and recent developments in the understanding of plasticity being an avalanche process. Potential consequences of incorporating avalanche plasticity into high rate models are explored. Particular attention is paid to Brown's observation that based on quasi static observations of avalanche behaviour, the formation of dislocation avalanches will begin to fail at strain rates of approximately $10^4$ s$^{-1}$. Consequences of the progressive breakdown of avalanche behaviour are discussed with respect to the experimental observations presented in earlier chapters. In Chapter 10, we will discuss the key conclusions of the work. Finally, a number of avenues are proposed for building upon the current work both theoretically and experimentally.

Orientadores: Sergio Tonini Button, Mauro Moraes de Souza / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-11T13:19:22Z (GMT). No. of bitstreams: 1 SouzaFilho_Valterde_M.pdf: 4133313 bytes, checksum: a0db5181ce553fa4a0c17b20db4a876b (MD5) Previous issue date: 2008 / Resumo: A conformação a quente, especificamente em prensa horizontal, é um tema de pouco estudo no meio acadêmico, mas interessante pelo emprego da alta taxa de deformação que alcança 90s-1. A microestrutura resultante desse processo é influenciada por algumas variáveis como temperatura, taxa de deformação, tamanho de grão austenítico inicial e taxa de resfriamento. A proposta deste trabalho é prever o comportamento da microestrutura dos aços perante essa alta taxa de deformação com a utilização da simulação numérica. Para tanto, os materiais DIN 20NiCrMo8 MOD e DIN 16MnCr5 MOD foram ensaiados nessa taxa de deformação em um processo de conformação industrial. A comparação do tamanho de grão austenítico obtido da conformação industrial com o tamanho de grão austenítico obtido através da simulação numérica é demonstrada. A influência da taxa de resfriamento sobre a microestrutura para cada material também foi demonstrada. Concluiu-se que a previsão do tamanho de grão austenítico é adequada utilizando-se o software comercial MSC.Superform acrescido do cálculo para crescimento de grãos. A previsão do comportamento mecânico após o processo de conformação utilizando-se de equações da literatura foi insatisfatória, porém pode-se demonstrar a influência da variação da taxa de resfriamento na microestrutura das peças conformada a quente / Abstract: A conformação a quente, especificamente em prensa horizontal, é um tema de pouco estudo no meio acadêmico, mas interessante pelo emprego da alta taxa de deformação que alcança 90s-1. A microestrutura resultante desse processo é influenciada por algumas variáveis como temperatura, taxa de deformação, tamanho de grão austenítico inicial e taxa de resfriamento. A proposta deste trabalho é prever o comportamento da microestrutura dos aços perante essa alta taxa de deformação com a utilização da simulação numérica. Para tanto, os materiais DIN 20NiCrMo8 MOD e DIN 16MnCr5 MOD foram ensaiados nessa taxa de deformação em um processo de conformação industrial. A comparação do tamanho de grão austenítico obtido da conformação industrial com o tamanho de grão austenítico obtido através da simulação numérica é demonstrada. A influência da taxa de resfriamento sobre a microestrutura para cada material também foi demonstrada. Concluiu-se que a previsão do tamanho de grão austenítico é adequada utilizando-se o software comercial MSC.Superform acrescido do cálculo para crescimento de grãos. A previsão do comportamento mecânico após o processo de conformação utilizando-se de equações da literatura foi insatisfatória, porém pode-se demonstrar a influência da variação da taxa de resfriamento na microestrutura das peças conformada a quente / Mestrado / Materiais e Processos de Fabricação / Mestre em Engenharia Mecânica

This master’s thesis deals with the problem of measurement for thermomechanical parameters during metal forming under higher deformation rate. The first part works up general literary studies, comprising a summary of measurement methods for required parameters. There is described a principle of their function and usage. Further assessed the current situation and recommendation of appropriate methods for the dynamic processes of forming, especially their testing. The second part is devoted to the measurement for dynamic features of the material. This is a problem specified by Split Hopkinson preassure bar test. The test is described, including the mathematical evaluation process, in the theoretical part. In the practical part, there is a detailed description of the process and evaluation of the real test with aluminum alloy AlMg4, 5Mn ,07-EN AW 5083 performed within the framework of the junior project.

The high strain rate fiber direction tensile response of Ultra High Molecular Weight Polyethylene (UHMWPE) composites is of interest in applications where impact damage may occur. This response varies substantially with strain rate. However, physical testing of these composites is difficult at strain rates above 10^-1/s. A Monte Carlo simulation of composite tensile strength is constructed to estimate the tensile behavior of these composites. Load redistribution in the vicinity of fiber breaks varies according to fiber and matrix properties, which are in turn strain rate dependent. The distribution of fiber strengths is obtained from single fiber tests at strain rates ranging from 10^-4/s to 10^-1/s and shifted using the time-Temperature Superposition Principle (tTSP) to strain rates of 10^-4/s to 10^6/s. Other fiber properties are obtained from the same tests, but are assumed to be deterministic. Matrix properties are also assumed to be deterministic and are obtained from mechanical testing of neat matrix material samples. Simulation results are compared to experimental data for unidirectional lamina at strain rates up to 10^-1/s. Above 10^-1/s, simulation results are compared to experimental data shifted using tTSP. Similarly, through-thickness shear response of UHMWPE composites is of interest to support computational modeling of impact damage. In this study, punch shear testing of UHMWPE composites is conducted to determine shear properties. Two test fixtures, one allowing, and one preventing backplane curvature are used in conjunction with finite element modeling to investigate the stress state under punch shear loading and the resulting shear strength of the composite. / Ph. D.