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Big Bang Nucleosynthesis (BBN), together with the analyses of the Cosmic Microwave Background (CMB) anisotropies, confirm what our day to day experience of life attests : antimatter is far less present than matter in the Universe. In addition, these observables also permit to evaluate that there exists about one proton for every 10^{10} photons present in the Universe. This is in contradiction with expectations coming from the standard hot big bang, where no distinction between matter and antimatter is made, and where subsequent annihilations would lead to equal matter and antimatter contents, at a level 10^{−10} smaller than the observed one. The Standard Model of fundamental interactions fails to explain this result, leading us to search for ‘Beyond the Standard Model’ physics. Among the possible mechanism which could be responsible for the creation of such a matter asymmetry, leptogenesis is particularly attractive because it only relies on the same ingredients previously introduced to generate neutrino masses. Unfortunatelly, this elegant proposal suffers from a major difficulty : it resists to any tentative of being probed by our low energy observables. In this thesis, we tackle the problem the other way around and propose a way to falsify this mechanism. Considering the type-I leptogenesis mechanism, i.e. a mechanism based on the asymmetric decay of right-handed neutrinos, in a left-right symmetric framework, we show that the observation of a right-handed gauge boson W_R at future colliders would rule out any possibility for such mechanism to be responsible of the matter asymmetry present in our Universe. Another intriguing question that analyses of the anisotropies of the CMB confirmed is the presence of a non-baryonic component of matter in our Universe, i.e. the dark matter. As hinted by observations of galactic rotation curves, it should copiously be present in our galactic halo, but is notoriously difficult to detect directly. We can take advantage on the fact that antimatter almost disappeared from our surroundings to detect the contamination of cosmic rays from standard sources the annihilation products of dark matter would produce. The second subject tackled in this work is the study of the imprints the Inert Doublet Modem (IDM) could leave in (charged) cosmic rays, namely positrons, antprotons and antideuterons. This model, first proposed to allow the Bout-Englert-Higgs particle to evade the Electroweak Precision Test (EWPT) measurements, introduces an additional scalar doublet which is inert in the sense that it does not couple directly to fermions. This latter property brings an additional virtue to this additional doublet : since it interacts weakly with particles, it can play the role of dark matter. This study will be done in the light of the data recently released by the PAMELA, ATIC and Fermi-GLAST collaborations, which reported e^± excesses in two different energy ranges.

The generation of nanostructured assemblies with complex (three-dimensional, 3D) self-assembled morphologies and with complex (multicomponent) tailorable inorganic compositions is of considerable technological and scientific interest. This research demonstrates self-assembled 3D organic templates of biogenic origin can be converted into replicas comprised of numerous other functional nanocrystalline inorganic materials. Nature provides a spectacular variety of biologically-assembled 3D organic structures with intricate, hierarchical (macro-to-micro-to-nanoscale) morphologies. Morphology-preserving chemical conversion of such readily available, structurally complex templates will provide a framework for chemical conversion of synthetic organic templates and, potentially, production of organic/inorganic composites. Four research thrusts are detailed in this dissertation. First, chemical conversion of a nanostructured bioorganic template into a multicomponent oxide compound (tetragonal BaTiO₃ via layer-by-layer surface sol-gel coating and subsequent morphology-preserving microwave hydrothermal processing was demonstrated. Second, photoluminescence was imparted to bioorganic template structures through morphology-preserving chemical conversion to exhibit both the dramatic change in properties such processing can provide, and the potential utility of chemically transformed templates in anti-counterfeiting / authentication applications. Third, the reaction mechanism(s) for morphology-preserving microwave hydrothermal conversion of TiO₂ to BaTiO₃, were studied with the aid of Au inert markers on single crystal rutile TiO₂. Finally, constructive coating techniques (SSG) and moderate temperature (< 500C) heat treatments were utilized to modify and replicate structural color and were coupled with deconstructive focused ion beam microsurgery to prepare samples for microscale structure/property interrogation. Specifically, the effects of coating thickness and coating composition on reflection spectra of structurally colored templates were examined. Also, the effects of the replacement of natural material with higher index of refraction inorganic materials on optical properties were studied. The three processing research thrusts constituting chapters 1, 2 and 4 take advantage of moderate temperature processing to ensure nanocrystalline materials, either for shape preservation or to prevent scattering in optical applications. The research thrust presented in chapter 3 examines hydrothermal conversion of TiO₂ to BaTiO₃, not only to identify the reaction mechanism(s) involved in hydrothermal conversion under morphology-preserving conditions, but also to introduce inert marker experiments to the field of microwave hydrothermal processing.

New processes for the production of polymeric dispersions with high solids content and low viscosity were developed, investigated and characterized. The specifications required for the desired application of paper coating, which constitutes one of the major innovative aspects of this thesis, requires in average particle sizes smaller than 200 nm. This particle size is significantly smaller than obtained in previous work in this area. The main objective of this project was to increase the solids content of existing products from ~50 to ~60 wt% while keeping the viscosity at low levels (< 1200 mPa•s at 20 s-1). In order to produce high solids content latexes with low viscosity, bimodal particle size distributions were resorted to. To obtain highest packing fraction, the small particle size population should be about 7 times smaller than the large particles, bringing the size of the small particles to less than 30 nm. Modified (micro)emulsion processes were developed in order to produce small particle size latex with reduced surfactant concentration and increased solids content. The large particle population was developed using a semi-batch emulsion polymerization process, simulating a product that is commercially available (~52 wt% solids content and viscosity of ~500 mPa•s at 20 s-1). To increase the solids content of this product up to 60 wt%, a second population of small particles was created using two approaches. In the first approach, the small particles were generated in situ using the modified (micro)emulsion approaches developed previously. This process resulted in latexes of ~ 60% solids content and viscosities lower than 500 mPa•s at 20 s-1. In the second approach, the second population of particles was created by the addition of seeds by using small cross-linked particles as pseudo inert-fillers. This process resulted in products with ~58% solids and viscosities lower than 1400 mPa•s at 20 s-1. The slightly decreased solids content and increased viscosity relative to the previous approaches is due to the difficulty in producing cross-linked seeds with particle sizes smaller than 30 nm at an acceptable concentration, causing deviations from ideal conditions. / Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2011-05-03 13:58:44.22

Orientador: Edevar Luvizotto Junior / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Civil, Arquitetura e Urbanismo / Made available in DSpace on 2018-08-07T09:53:33Z (GMT). No. of bitstreams: 1 ArandaSaldana_EdwinAntonio_M.pdf: 1687985 bytes, checksum: 0c5e968a32c41fdf3cc83eca866e6ea6 (MD5) Previous issue date: 2006 / Resumo: O presente trabalho apresenta as bases para a elaboração de um modelo hidráulico computacional baseado na filosofia de programação orientada por objetos (POO) para o tratamento de problemas de escoamento de fluidos em condutos forçados em regime permanente e transitório. Na modelação hidráulica foi empregado um modelo dinâmico inercial elástico com solução através do Método das Características (MOC). Os estudos de casos apresentados mostram o potencial da ferramenta proposta para a análise de escoamentos de instalações hidráulicas em condutos forçados / Abstract: The present work shows the basis for the elaboration of a computational hydraulic model based on the object oriented programming (POO) philosophy for the management of flow problems such as flow rate in pipe systems in steady and unsteady states. The hydraulic modeling is based on the inertial dynamic model with solved through the Method of Characteristics (MOC). The different cases of studies presented in this dissertation show the potential of this tool proposal for the analysis of pipe flow installations in hydraulic systems / Mestrado / Recursos Hidricos / Mestre em Engenharia Civil

In der vorliegenden Arbeit wird ein Maschinenkonzept präsentiert, welches für die Additive Fertigung von großvolumigen Titanbauteilen speziell entwickelt wurdet. Hierbei wird mit den Direct-Energy_Deposition Verfahren das Bauteil in einer separaten Inertgasatmosphäre erzeugt. Zur Führung der Prozesstechnik soll erstmals ein Roboter verwendet werden, der ebenfalls in dieser Atmosphäre verbaut ist. Dieser ist allerdings schwierigen Bedingungen ausgesetzt, da die Spannungsfestigkeit sowie die Isolationsschwelle in Argon im Vergleich zu Luft drastisch reduziert sind.

In this thesis we study the interaction of helium, neon, argon and gallium ions with graphene. The graphene structure is contaminated with gallium ions during the graphene processing by focused gallium beam (FIB). The graphene properties are affected, e.g. reducing the electrical conductivity. The aim of this thesis is to verify the effect of selected ion beams on the graphene structure and select suitable ion beam for sputtering. Furthermore, the modification of standard heating stage used in LEIS instrument (Qtac 100) was designed and implemented. The LEIS instrument is connected to the complex UHV system for deposition and analysis of nanostructures – SPECS. This modification allows analysis of selected nanoparticles on suitable substrate at the elevated temperature.

This diploma thesis deals with the development of multifunction welding machine for manual metal arc welding MMA and metal inert/active gas welding MIG/MAG. The goal of this work was to design compactly shaped welding inverter considering ergonomics and technological aspects. The thesis is divided into two parts. First part contains historical progress of arc welding, basic principles of chosen methods and view on contemporary market with welding machines. The second part deals with the development of the design, analysis and options of the final proposal.

The dissertation thesis is focused on the investigation of the influence of inert gases on characteristic parameters of the combustion process. Inert gases are usually standard components of alternative gaseous fuels such as the producer gas, coal gas or biogas. For a long period some of the fuels were considered as waste gases and their potential was not sufficiently utilised. Compared with noble fuels such as natural gas, alternative fuels have different physical-chemical properties. For example, their lower heating value (LHV) can be lower even than 10 MJ/mN3. The composition of the alternative gaseous fuels can be various during their production process. Lower LHV is a result of the occurrence of inert gases that does not take a part in the combustion reactions. Inert gases have the ability to accumulate the heat. Under certain conditions it is possible to combust alternative fuels on conventional burners, but due to their different properties, problems can occur during the combustion. E.g. to achieve the same heat output as with the noble fuel, it is necessary to burn bigger volume of the alternative fuel. However, the limiting factor could be the burner's head geometry. Theoretical introduction of the thesis summarizes research results in the field of low calorific gaseous fuels combustion and the addition of inert gases into the noble fuels. The thesis also describes the mechanisms of the NOx formation and summarizes techniques which can be used to reduce NOx formation. Furthermore, fuels from alternative sources are categorized and described, including their composition and characteristics. Their physical-chemical properties were obtained by means of the combustion simulation carried out in the simulation software. Two devices had to be designed and manufactured to fulfil goals of the dissertation thesis. The first is a gas mixing station capable of mixing 4 different components. The second device is a burner utilized for the combustion of low calorific fuels. The key section of this thesis is a chapter describing the experimental plan, the performance and the evaluation of the experiments. The goal of the experiments was to dilute the natural gas by two inert gases, namely carbon dioxide and nitrogen. The lowest LHV value achieved during the experiment was 10,7 MJ/mN3. The influence of the inert gases on the NOx emissions, the flame stability and characteristics, the flue gas temperature, the in-flame temperatures, the heat flux and the thermal efficiency was investigated and evaluated. Each parameter was measured and evaluated for three different burners: the burner with the staged gas, the burner with the staged air and the burner for low calorific fuels. Generally, after the addition of the inert gas into the noble fuel, the in-flame temperatures decreased. As a consequence, the NOx emissions decreased as well. The effects of carbon dioxide on the investigated combustion parameters were more substantial than the effects of nitrogen. Each measured parameter is strongly dependent on the burner geometry. The experiments revealed that in most cases the addition of the inert gas into the fuel influenced the flame length (flame shortened) and also more heat was transfered into the chamber's walls closer to the burner tile.