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Thermal co-processing of coal and biomass has been increasingly focused for its environmental and economic benefits. In the present work, the experimental and kinetic study on co-pyrolysis and co-gasification of Rhenish brown coal (HKN) and wheat straw (WS) was made. The pyrolysis behavior, especially for co-pyrolysis, was investigated in a thermogravimetric analyzer (TGA) and a small fixed bed reactor (LPA). In TGA, the mass loss and reaction rate of single and blend samples were studied under various experimental conditions, and their effects on synergy effects. The synergy effects on products yield and properties of chars were studied in LPA. The kinetics of pyrolysis was obtained based on data from TGA by using the Coats-Redfern method. For gasification with CO2, a small fixed bed reactor (quartz glass reactor), equipped with an online GC to monitor the gas composition, was used. The effects of processing conditions on gasification behavior and synergy effects for mixed chars and co-pyrolysis chars were investigated. The volume reaction model (VRM), shrinking core model (SCM) and random pore model (RPM), were applied to fit the experimental data. The model best fitting the experiments was used to calculate the kinetic parameters. The reaction orders of gasification reactions with single chars are also investigated. The pyrolysis study showed that a small amount of wheat straw added to the brown coal promoted the decomposition better and showed more significant synergy effects. The synergy effects varied with increasing heating rates and pressures, especially at 40 bar. The kinetic parameters were inconsistent with experimental behavior during co-pyrolysis, since the reaction was also affected by heat transfer, contact time, particles distribution and so on. The gasification study on single chars showed that Rhenish brown coal chars had higher reactivity; chars pyrolyzed at higher temperatures showed lower reactivity; and higher gasification temperatures and CO2 partial pressures led to higher reactivity. For co-gasification process, there was no significant synergy effect for mixed chars. However, negative synergy effects (reactivity decreased compared to the calculated values based on rule of mixing) were observed for co-pyrolysis chars, caused by properties change by co-pyrolysis process. For kinetics, the reaction orders of chars ranged from 0.3 to 0.7. Only random pore model fitted most experiments at low and high temperatures. Synergy effects were also observed in kinetic parameters. The values of activation energy E and pre-exponential factor A for mixed chars and co-pyrolysis chars were lower than expected. The negative synergy effects showed the pre-exponential factor A had more effects. However, the higher reactivity of mixed chars than co-pyrolysis chars showed that the reaction was affected more by activation energy E. Therefore, only investigating E or A value was not enough. In addition, a marked compensation effect between activation energies and pre-exponential factors was found in the present study. The isokinetic temperature for the present study was 856 °C. This was close to the temperature at which the gasification reaction transforms from the chemical controlled zone to the diffusion controlled zone for most chars.

The present study mainly focus on two parts: one was the optimization of FactSage calculation, compared with HT-XRD measurements on mineral matter behaviors during the heating of coal and blend ashes from 500 °C to 1000 °C in reducing atmosphere. The aim was to obtain the optimized input parameters and options for FactSage calculation, and the outputs should be as close as possible to HT-XRD results. The other was the application of FactSage on ash melting behaviors. Since the maximum temperature of HT-XRD measurement in laboratory was 1000 °C in reducing atmosphere, the optimized FactSage was applied to investigate the ash melting behaviors in temperature range between 600 °C and 1600 °C for coal, biomass and their blends. The FactSage calculation was optimized by investigations of several input parameters and options including the mass ratio of reactant gas amount to ash sample, solution species and compound solid species. The results obtained from the optimized calculation were much better to fit the mineral transformations measured by HT-XRD. However, there were still some differences between the results from optimized FactSage calculations and HT-XRD measurements. This is mainly due to the amorphous substances which occurred as solid phases and liquid slag in FactSage outputs but cannot be detected by HT-XRD. Besides, several factors, such as the diffusion, particle size distribution and so on, affect the actual measurements greatly but been neglected in thermodynamic calculations, which enhance the distinctions. In addition, the effects of atmosphere were investigated and the differences of mineral matter behaviors were mainly embodied in sulphur-rich minerals, iron-rich minerals and amorphous substance. For application of FactSage on ash melting behaviors, AFTs tests for coal, biomass and their blends were adopted, and the results were well investigated by ash chemical components analyzed by XRF and also equilibrium phases calculated by FactSage. Hemispheric temperature and flowing temperature were mainly dependent on the high melting point substances at high temperature, such as free CaO in HKN and SWC, SiO2 in WS and KOL. The sintering temperature was largely affected by alkali oxides, which could combine with other oxides to form low melting point substances. For blended ashes, AFTs of the blended ash of HKN and WS shown a V shape with WS addition mass ratio rising, and the minimum values of AFTs appeared at 50 wt.% WS addition. AFTs of KOL changed in a small scale when mixed with WS, due to their similar ash composition (high in SiO2). As the SWC ash contents is much less than HKN and KOL, it did not affect the AFTs much when blended with coals. Moreover, the biomass addition affection on the blended ashes AFTs were also well illustrated by the liquid phases mass fraction and also the mineral matter transformations calculated by FactSage.

Most of mining operations in Indonesia use open pit mine methods, with truck and shovel system and a large amount of manpower. The mining industry plays an important role contributed to the national economy and development in Indonesia, otherwise the mine accidents become as sensitive issue or problem. The main cause of mine accidents is still dominant of the low safety awarenesses and accountabilities, and also improperly cost spent on the occupational health and safety (OSH) programs. This thesis describes the concept behind the return on prevention and workers‟ perception descriptive analyses of the occupational health and safety in relation to improve safety performances. The proactive action plan related to accidents prevention is as an essential step of the risk management processes. Participation and intervention for all employees are important and urgent, especially for the frontline workers, which are crucial in achieving good safety performances with financial support properly. The main objective of this study evaluates of the workers‟ perception and cost spent on the occupational health and safety program at the companies in relation to accident prevention efforts. In general, the several objectives are described to evaluate of the mine accident rates, the validity and reliability tests of the questionnaires, workers relationships and suggestions, interviews, observations, and the OSH cost effectiveness. The methods of this study are assessed by the descriptive statistical analysis approaches of the return on prevention with the microeconomic model of the net present value, internal rate of return, and cost benefit analysis to justify the benefits return and the break even point and interventions directly according to the workers‟ perception through questionnaire, interview, and observation. The methodology is assessed by the gathering data obtained from the companies through the surveys of the questionnaire, interview, observation, and the money expenses in the occupational health and safety for the workers. The valuation methods are used by the degree of significance of 95%, margin of error 5%, with total number of respondents are 1,600 persons as sampling which representation of the four surface coal mine companies in Indonesia. The seven elements are a basic assessment approached of the training and education, personal protective equipment, preventive medical check up, employment injury insurance, improvement existing technology, signalization, and organization. The result shows the advantages using these analyses which described the importance of the money invested on OSH and effectiveness of interventions by worker‟s perception in order to prevent accidents at workplace. The effectiveness of interventions to the environment working conditions and workers mindsets directly. The OSH cost invested for workers, in general, will triggers the work performances to be better, and then the occupational health and safety in a strong position to achieve the goals of the company. Improvement safety awareness and accountability of workers shall reduce or prevent accidents at work, and the company should be invested money in the OSH program with the minimum amount is US $ 207.17 per employee or US $ 0.12 per ton of coal produced. The investment of the people and money properly shall give significant impacts in preventing accidents to achieve zero accident vision in order to protect people, property, process and profit of the company for short or long term benefits, and will also give a good images for sustainable in mining business.

Die immer komplexer werdenden geologischen Verhältnisse aktueller Lagerstätten, sowie die Umsetzung einer hoch-selektiven Rohstoffgewinnung, machen eine Modellierung auf Basis von geostatistischen Simulationsverfahren in einem modernen Lagerstättenmanagement notwendig, da diese Verfahren die in-situ Variabilität der struktur- und qualitätsbeschreibenden Lagerstättenparameter realistisch vorhersagen und damit auch realitätsnahe betriebswirtschaftliche Risikoabschätzungen zu den Auswirkungen der Unsicherheiten in der Vorhersage, aufgrund eines unvollständigen Kenntnisstandes, ermöglichen. Die Arbeit beschreibt die Weiterentwicklung und Anwendung von Verfahren der geostatistischen Simulation für die Modellierung komplexer, sedimentartig ausgebildeter Lagerstätten in einem praxisrelevanten Umfang und unter Berücksichtigung der besonderen Anforderungen, welche aus der Charakteristik der Lagerstätte und der Zielsetzung einer selektiven Rohstoffgewinnung abgeleitet wurden. Zunächst wird ein geeigneter Ansatz identifiziert, welcher die Grundlage für eine methodische Erweiterung und effiziente Implementierung, hinsichtlich der zu erfüllenden Anforderungen, bildet. Danach wird die komplette Prozesskette für eine zuverlässige Lagerstättenmodellierung untersucht und praktikable Modellierungsstrategien werden vorgestellt. Ein komplexes Anwendungsbeispiel aus dem Braunkohlenbergbau dient der Evaluierung der vorgestellten Modellierungsverfahren. / The more and more complex geological conditions of current deposits, as well as the implementation of a highly selective extraction of raw materials, require new approaches for the reservoir management. The use of geostatistical simulation methods for modelling the shape and quality of deposits is necessary, because these methods taking into account the natural variability of the deposit attributes and the resulting geological uncertainties. Furthermore this methods allow faithfully and realistic economic risk assessments on the impact of uncertainties in the prediction, due to an incomplete state of knowledge. This work describes the further development and application of geostatistical simulation algorithms for the modelling of complex sediment-like formed deposits in a practically scope, taking into account the special requirements, which are derived from the characteristics of such deposits and the objective of the selective extraction of raw material. First an appropriate simulation approach is identified, which then forms the basis for a methodical expansion and efficient implementation, in terms of fulfilling requirements. In addition, the complete process chain for reliable reservoir modelling is studied and a viable modelling strategy is presented. A complex application example from the lignite mining is used for evaluation of the presented modelling methods.

The primary purpose of this thesis is to find out the mechanism of cracking formation during filtration as well as improve the dewatering efficiency of Limestone and Vietnam coal. They are both fine materials, which negatively affect the filtration process. Experiments are executed by changing parameters like solid volume fraction of initial suspension, the height of filter cake and the applied pressure difference using the conventional pressure filtration. Permeability ratio is used as the relevance output parameter to quantify the degree of cracking. Otherwise, saturation and residual moisture content on filter cake are also calculated to evaluate the extent of dewatering. Almost the mechanism of cracking is assumpted and proved. Countermeasures are suggested to prevent the probability and degree of cracking on filter cake. Otherwise, steam pressure filtration is applied as a new method allow improve the dewatering efficiency and reduce the cracking.:Contents Abstract iii Acknowledgment v Contents vi List of Figure viii List of Tables xvi List of Symbols xvii Abbreviation xix 1. Background 1 1.1. The Filtration process 1 1.2. Conventional pressure filtration and steam pressure filtration 3 1.3. Filtration theory 6 1.4. Cake deliquoring - immiscible fluid displacement in porous media 16 1.5. Tensile stress between particles 20 1.6. Coal processing/ washing 24 2. Literature review 34 2.1. Cracking on filter cake and the dewatering process with and without cracking 34 2.2. Summary and focus of research 47 3. Material, methods and the result of capillary pressure curve and tensile stress versus saturation 51 3.1. Material used 51 3.1.1. Limestone 51 3.1.2. Vietnam Coal 52 3.2. Conventional filtration rig and steam pressure filtration rig 55 3.2.1. Conventional filtration rig 55 3.2.2. Steam pressure filtration rig 57 3.3. Filtration experimental 58 3.4. Relevant parameter 59 3.5. Analyze technique 65 3.6. Tensile stresses depend on saturation during deliquoring 66 4. The influence of operating parameters on cracks formation in case of limestone 69 4.1. Capillary pressure curve and tensile stress during the filtration in the case of limestone 69 4.2. Test were conducted using conventional pressure filtration 76 4.2.1. Particle size distribution effect 76 4.2.2. The solid volume fraction of suspension effect 82 4.2.3. Height of filter cake (filter cake deep/ filter cake thickness) effect 92 4.2.4. Pressure difference effect 101 4.3. The difference in the crack formation by using steam pressure filtration 111 4.4. General conclusion 116 5. The influence of operating parameters on cracks formation in the case of Vietnam coal 118 5.1. Capillary pressure curve and tensile stress during filtration in case of Vietnam coal 118 5.2. Test were conducted using conventional pressure filtration 122 5.2.1. The influence of the solid volume fraction on crack formation and saturation 122 5.2.2. The influence of the height of filter cake on crack formation and saturation 127 5.2.3. The influence of pressure difference on crack formation and saturation 134 5.3. Estimate the efficiency dewatering as well as the crack formation using steam pressure filtration 139 5.4. General conclusion 146 6. Overall conclusion and recommendation 148 6.1. Overall conclusion 148 6.2. Recommendation 150 References 152 Appendices 156 Appendix A: Data from CCWP. 156 Appendix B: Data from the crack formation with various operation parameters using conventional pressure filtration (CPF). 159 Appendix C: Data from steam pressure filtration. 167 Appendix D: Miscellaneous Information. 177

Most of mining operations in Indonesia use open pit mine methods, with truck and shovel system and a large amount of manpower. The mining industry plays an important role contributed to the national economy and development in Indonesia, otherwise the mine accidents become as sensitive issue or problem. The main cause of mine accidents is still dominant of the low safety awarenesses and accountabilities, and also improperly cost spent on the occupational health and safety (OSH) programs. This thesis describes the concept behind the return on prevention and workers‟ perception descriptive analyses of the occupational health and safety in relation to improve safety performances. The proactive action plan related to accidents prevention is as an essential step of the risk management processes. Participation and intervention for all employees are important and urgent, especially for the frontline workers, which are crucial in achieving good safety performances with financial support properly. The main objective of this study evaluates of the workers‟ perception and cost spent on the occupational health and safety program at the companies in relation to accident prevention efforts. In general, the several objectives are described to evaluate of the mine accident rates, the validity and reliability tests of the questionnaires, workers relationships and suggestions, interviews, observations, and the OSH cost effectiveness. The methods of this study are assessed by the descriptive statistical analysis approaches of the return on prevention with the microeconomic model of the net present value, internal rate of return, and cost benefit analysis to justify the benefits return and the break even point and interventions directly according to the workers‟ perception through questionnaire, interview, and observation. The methodology is assessed by the gathering data obtained from the companies through the surveys of the questionnaire, interview, observation, and the money expenses in the occupational health and safety for the workers. The valuation methods are used by the degree of significance of 95%, margin of error 5%, with total number of respondents are 1,600 persons as sampling which representation of the four surface coal mine companies in Indonesia. The seven elements are a basic assessment approached of the training and education, personal protective equipment, preventive medical check up, employment injury insurance, improvement existing technology, signalization, and organization. The result shows the advantages using these analyses which described the importance of the money invested on OSH and effectiveness of interventions by worker‟s perception in order to prevent accidents at workplace. The effectiveness of interventions to the environment working conditions and workers mindsets directly. The OSH cost invested for workers, in general, will triggers the work performances to be better, and then the occupational health and safety in a strong position to achieve the goals of the company. Improvement safety awareness and accountability of workers shall reduce or prevent accidents at work, and the company should be invested money in the OSH program with the minimum amount is US $ 207.17 per employee or US $ 0.12 per ton of coal produced. The investment of the people and money properly shall give significant impacts in preventing accidents to achieve zero accident vision in order to protect people, property, process and profit of the company for short or long term benefits, and will also give a good images for sustainable in mining business.

Die immer komplexer werdenden geologischen Verhältnisse aktueller Lagerstätten, sowie die Umsetzung einer hoch-selektiven Rohstoffgewinnung, machen eine Modellierung auf Basis von geostatistischen Simulationsverfahren in einem modernen Lagerstättenmanagement notwendig, da diese Verfahren die in-situ Variabilität der struktur- und qualitätsbeschreibenden Lagerstättenparameter realistisch vorhersagen und damit auch realitätsnahe betriebswirtschaftliche Risikoabschätzungen zu den Auswirkungen der Unsicherheiten in der Vorhersage, aufgrund eines unvollständigen Kenntnisstandes, ermöglichen. Die Arbeit beschreibt die Weiterentwicklung und Anwendung von Verfahren der geostatistischen Simulation für die Modellierung komplexer, sedimentartig ausgebildeter Lagerstätten in einem praxisrelevanten Umfang und unter Berücksichtigung der besonderen Anforderungen, welche aus der Charakteristik der Lagerstätte und der Zielsetzung einer selektiven Rohstoffgewinnung abgeleitet wurden. Zunächst wird ein geeigneter Ansatz identifiziert, welcher die Grundlage für eine methodische Erweiterung und effiziente Implementierung, hinsichtlich der zu erfüllenden Anforderungen, bildet. Danach wird die komplette Prozesskette für eine zuverlässige Lagerstättenmodellierung untersucht und praktikable Modellierungsstrategien werden vorgestellt. Ein komplexes Anwendungsbeispiel aus dem Braunkohlenbergbau dient der Evaluierung der vorgestellten Modellierungsverfahren. / The more and more complex geological conditions of current deposits, as well as the implementation of a highly selective extraction of raw materials, require new approaches for the reservoir management. The use of geostatistical simulation methods for modelling the shape and quality of deposits is necessary, because these methods taking into account the natural variability of the deposit attributes and the resulting geological uncertainties. Furthermore this methods allow faithfully and realistic economic risk assessments on the impact of uncertainties in the prediction, due to an incomplete state of knowledge. This work describes the further development and application of geostatistical simulation algorithms for the modelling of complex sediment-like formed deposits in a practically scope, taking into account the special requirements, which are derived from the characteristics of such deposits and the objective of the selective extraction of raw material. First an appropriate simulation approach is identified, which then forms the basis for a methodical expansion and efficient implementation, in terms of fulfilling requirements. In addition, the complete process chain for reliable reservoir modelling is studied and a viable modelling strategy is presented. A complex application example from the lignite mining is used for evaluation of the presented modelling methods.

By analyzing process samples full and pilot scale gasifiers, the main influences affecting their slag are identified. Based on this knowledge as well as the current literature, the effect of crystallization was identified as crucial for understanding slag behavior and is analyzed during cooldown. Finally, the emerging interest in sewage sludge upcycling via gasification necessitated an investigation on the influence of adding P2O5 as slag constituent. All conclusions concerning the full scale gasifier slags were based on XRF, XRD, and SEM-EDX analyses coupled with thermodynamic equilibrium calculations via FactSage. The subsequently presented research on crystallization and the effect of P2O5 was centered on conducting slag viscosity measurements, recreating the conditions of said measurement in a quench oven, and analyzing the resulting quench samples via the mentioned analysis methods. Special focus was put on the phase evolution, its governing factors, and the effect on slag viscosity.:1. INTRODUCTION 1 2. FUNDAMENTALS IN SLAG BEHAVIOR CHARACTERIZATION 3 2.1. BASE TO ACID RATIO AS KEY FIGURE FOR SLAG CHARACTERIZATION 7 2.2. VISCOSITY ALTERING SECONDARY PHASES IN SLAGS 9 2.2.1. The effect of crystallization on slag flow 10 2.2.2. Modelling and measuring crystallization in slags 11 2.3. CRITICAL VISCOSITY 13 2.4. PHOSPHOROUS OXIDE IN SLAGS 15 2.4.1. Behavior of P2O5 within slags 16 2.4.2. Phase separation in melts containing P2O5 17 2.4.3. Effect on slag viscosity 22 3. ANALYTICAL METHODS 26 3.1. SAMPLE PRETREATMENT 26 3.2. ASH FUSION TEMPERATURE 28 3.3. X-RAY FLUORESCENCE MEASUREMENT (XRF) 30 3.4. X-RAY DIFFRACTION 31 3.5. VISCOSITY MEASUREMENT 32 3.6. DIFFERENTIAL THERMAL ANALYSIS (DTA) 36 3.7. QUENCH APPARATUS 37 3.8. SEM-EDX 39 3.9. THERMODYNAMIC EQUILIBRIUM CALCULATIONS 40 4. CHARACTERIZATION OF SLAGS FROM FULL OR PILOT SCALE GASIFIERS 42 4.1. SLAG FROM GENERAL ELECTRICS GASIFIER IN TAMPA 43 4.1.1. Analysis of the suspending main phase 45 4.1.2. Analysis of the silica phase 50 4.1.3. Analysis of the metal enclosures 51 4.1.4. Analysis of the vanadium-rich particles 53 4.1.5. Summary of the analysis of the General Electrics gasifier slag 55 4.2. SLAG FROM GSP GASIFIER 57 4.2.1. NCPP slag 57 4.2.2. Huainan Anhui slag 64 4.2.3. Genesee slag 70 4.2.4. Hambach-Garzweiler 50:50 slag 75 4.2.5. Summary of the analysis of the GSP slags 86 4.3. SLAG FROM BRITISH GAS/LURGI (BGL) GASIFIER 88 4.3.1. Summary and conclusions of the analysis of the BGL slag 99 5. CHARACTERIZING CRYSTALLIZATION DURING SLAG VISCOSITY MEASUREMENTS 102 5.1. EXPERIMENTAL PROCEDURE 103 5.1.1. Sample preparation 107 5.1.2. Viscosity measurement 108 5.1.3. Differential thermal analysis (DTA) 108 5.1.4. Quench oven 108 5.1.5. XRD, XRF, SEM-EDX, and FactSage calculations 109 5.2. RESULTS AND DISCUSSION 109 5.2.1. Slag 1 (CO/CO2 atmosphere) 110 5.2.2. Slag 2 (CO/CO2 atmosphere) 112 5.2.3. Slag 3 (air atmosphere) 116 5.2.4. Slag 3 (CO/CO2 atmosphere) 119 5.3. CONCLUSION AND SUMMARY OF THE STUDY OF CRYSTALLIZATION IN SLAGS DURING COOLDOWN 122 6. THE EFFECT OF PHOSPHOROUS OXIDE ON SLAGS 125 6.1. PRELIMINARY SEWAGE SLUDGE SLAG INVESTIGATION 126 6.1.1. Conclusion and summary sewage slag investigation 136 6.2. EXPERIMENTAL PROCEDURE FOR PARAMETRIC STUDY 139 6.3. PARAMETRIC STUDY 141 6.3.1. HKN with 15% sand (HKNS) 142 6.3.2. HKNS with low P2O5 addition (HKNS5P) 147 6.3.3. HKNS with medium low P2O5 addition (HKNS10P) 153 6.3.4. HKNS with medium high P2O5 addition (HKNS15P) 158 6.3.5. HKNS with high P2O5 addition (HKNS20P) 163 6.3.6. P2O5 distribution 169 6.3.7. Effect of P2O5 on viscosity 174 6.4. SUMMARY ON THE INVESTIGATION OF P2O5 IN SLAGS 179 7. CONCLUSION AND OUTLOOK 185 8. REFERENCES 190 9. APPENDIX A: DIFFERENCE IN PREDICTION OF SEWAGE SLUDGE ELEMENTAL DISTRIBUTION 213 10. APPENDIX B COMPARISON OF XRF ANALYSES OF HKNS-P2O5 MIXTURES 215 11. APPENDIX C EDX MAPS OF THE QUENCH SAMPLES IN THE PARAMETRIC PHOSPHORUS ADDITION STUDY 218 12. APPENDIX D SUMMARY OF PHASE COMPOSITION OF THE EDX MAPS 239 13. APPENDIX E ENRICHMENT FACTORS FOR THE QUENCH SAMPLES IN THE PARAMETRIC PHOSPHORUS ADDITION STUDY 242

Kernthema der Dissertation ist die Weiterentwicklung von Kohle-Online-Messtechniken zur kontinuierlichen Bestimmung, das Brennstoffverhalten in Kraftwerkskesseln beeinflussender anorganischer Kohleinhaltsstoffe im Rheinischen Braunkohlerevier, die geologisch bedingt, natürlichen Schwankungen unterliegen. Im Rahmen dieses Vorhabens wurden die Gammastrahlenabsorptionsverfahren zur Aschegehaltsbestimmung und die Prompte-Gamma-Neutronen-Aktivierungs-Analyse (PGNAA) zur Multielement-Analyse als innovative Messmethoden zur Analyse des gesamten Kohlestroms auf Förderbandanlagen identifiziert, deren Eignung im Rahmen von Voruntersuchungen bestätigt, betrieblich eingeführt und unter Praxisbedingungen optimiert. Dabei wurde die Wechselwirkung zwischen Gamma- und Neutronenstrahlung unterschiedlicher Energien mit Braunkohlen und Fördergurten unterschiedlicher Eigenschaften sowie Einflüsse variierender homogener und inhomogener Elementzusammensetzungen bei verschiedenen Messsystemanordnungen und Förderleistungen auf die Messergebnisse systematisch erfasst und für die Versuchsanlagen in der betrieblichen Praxis umgesetzt. Die Gamma-Absorptionsmethode ist im betrieblichen Einsatz, die Erprobung der PGNAA-Prototypanlage steht bevor.