xvi, 145 p. : ill. (some col.) / The structures of several compounds in the [(PbSe)0.99]m[WSe2]n, [(PbSe)1.00]1[MoSe2]1, and [(SnSe)1.03]1[MoSe2]1 systems were determined using x-ray data. The structural determination using Rietveld methods was complicated by the strong preferred orientation of the samples, which resulted in x-ray diffraction scans with either 00l or hk0 reflections depending on the orientation of the sample in the diffractometer. Rietveld refinements of the [(PbSe)0.99]1[WSe2]1, [(PbSe)1.00]1[MoSe2]1, and [(SnSe)1.03]1[MoSe2]1 samples were compared to single crystal sample refinement results for [(MX)1+d]1[TX2]1, where M is a metal, T is a transition, X is a chalcogen, and d is the misfit parameter. The structural refinement yielded rock salt layer puckering values of 25 pm, 23 pm, and 36 pm for [(PbSe)0.99]1[WSe2]1, [(PbSe)1.00]1[MoSe2]1, and [(SnSe)1.03]1[MoSe2]1, respectively, which are all within the established literature range of 20 pm to 60 pm. The refinement of the hk0 reflections confirmed that the in plane structures were consistent with the dichalcogenide (P63mmc) and rock salt (Fm3m) structure types. Structures for the [(PbSe)0.99]m[WSe2]m isomer series where m = 1 to 5 were determined, and a systematic trend in structure as a function of the thickness of the constituent layers was discovered. The structure of the rock salt constituent was found to distort into pairs, forming alternating long and short distances along the c axis. This distortion decreases as the number of rock salt planes increases from 4 to 6 to 8 and is either absent or nearly so in compounds with a larger number of rock salt planes. The puckering distortion at the interface between the rock salt and the dichalcogenide is also observed in the inner rock salt layers but decreases in magnitude moving away from the rock salt – dichalcogenide interface. Structures of [(PbSe)0.99]m[WSe2]n where m = 1 or 2 and n = 1 or 2 were also determined. The degree of structural distortion is a function of the ratio of rock salt to dichalcogenide layers. This dissertation includes unpublished co-authored material. / Committee in charge: Dr. Thomas R. Dyke, Ph.D., Chairperson; Dr. David C. Johnson, Ph.D., Advisor; Dr. Catherine J. Page, Ph.D., Member; Dr. Andrew H. Marcus, Ph.D., Member; Dr. John L. Hardwick, Ph.D., Member; Dr. Richard Taylor, Ph.D., Outside Member

Polyelektrolytmikrokapseln (PEMC) stellen ein neuartiges System künstlicher Zellen dar. Durch Einbringen von z.B. Hämoglobin in solche PEMC können sie als  künstliche Erythrozyten den Gastransport im Organismus unterstützen bzw. übernehmen. Es muss jedoch berücksichtigt werden, dass jede Zelle des Säugtierorganismus zur Aufrechterhaltung ihrer Funktion Enzyme benötigt, die ihre Stoffwechselfunktionen katalysieren. Um sich der Lösung dieses Problems bei der Entwicklung eines künstlichen Erythrozyten schrittweise zu nähern, wurde als Modellenzym Trypsin ausgewählt. Es wurden Polyelektrolytmikrokapseln (PEMC) auf der Basis von Erythrozyten durch Selbstassemblierung von Polynatriumstyrensuphonat (PSS) und Polyallylamino-hydrochlorid (PAH) hergestellt ((PSS/PAH)2PSS), und anschliessend nach der Layer-by-Layer Methode (LbL) alternierend mit Trypsin und den Polyelektrolyten (PE) PSS, Alginat oder Dextransulphat weiterbeschichtet. Der Schichtenaufbau wurde durch Zellelektrophorese, konfokale Laserscanning-mikroskopie (CLSM), Durchflusszytometrie (FACS) und photometrische Proteinbestimmung charakterisiert und quantifiziert. Die Aktivität des an der PEMC-Membran immobilisierten Enzyms wurde untersucht und mit der Aktivität freien Trypsins verglichen. Weiterhin wurden pH-Profile von freiem Enzym mit denen des immobilisierten Trypsins verglichen. Der Schichtaufbau aus Trypsin und den unterschiedlichen Polyelektrolyten wurde anhand der Änderung der elektrophoretischen Mobilität beim Aufbringen jeder Schicht, sowie durch die Zunahme der photometrisch bestimmten Proteinmenge pro PEMC charakterisiert. Außerdem wurde Trypsin mit Fluoreszeinisothiozyanat (FITC) markiert und in den Beschichtungsserien die Zunahme der flowzytometrisch bestimmten Fluoreszenz-Intensität mit jeder aufgebrachten FITC-Trypsin Schicht beobachtet. Die Aktivität des an den PEMC immobilisierten Trypsins beträgt etwa 30% der Aktivität freien Trypsins gleicher Konzentration. Es konnte gezeigt werden, dass sich Trypsin im Rahmen eines Schichtaufbaus nach der LbL-Technologie in die Membran der verwendeten PEMC einbringen lässt. Dabei behält das Enzym einen Teil seiner Funktion. / Artificial cells are not only used to study the biological processes of living cells, they also serve as micro reactors to provide certain functions in the organism. Polyelectrolyte microcapsules (PEMC) represent a new approach to artificial cell studies. When filled with hemoglobin, PEMC are able to perform the erythrocyte gas exchange. This work shows the general possibility of integrating enzymes into the PEMC membrane. PEMC were composed using the layer-by-layer (l-b-l) technique. Glutaraldehyde stabilized human red blood cells (RBC) served as templates and were coated with five layers poly(styrene sulfonate) (PSS) and poly(allylaminehydrochloride) (PAH). After decomposition of the RBC by sodium hypochlorite, the PEMC were coated with ten layer pairs of trypsin and either PSS or alginate. The trypsin layer growth was followed performing measurements by cell electrophoresis, confocal laser scanning microscopy (CLSM), flow cytometry (FACS) and protein determination according to Lowry after each adsorption step. Results showed a continuous layer buildup for both polyelectrolytes and no desorption of trypsin. The amount of immobilized enzyme was larger for the coating series with trypsin/PSS compared to that with trypsin/alginat. This was concluded as a result of PSS/trypsin complex formation. Normalizing the enzym activity to the amount of adsorbed trypsin no significant differences between the activity of PSS-PEMC and alginate-PEMC were found. Further experiments prove that PSS inhibits the enzyme activity and alginat does not.

本論文將詳述對湍流熱對流系統改變邊界條件的三組實驗。 / 第一組實驗中，在寬高比等於1 的圓柱形對流槽中，通過平滑板和由金字塔狀規則排列的粗糙表面的板的組合，我們對五個對流槽進行測量。对實驗測量得到Nu 和Ra 的关系式，进行两个指数函数关系式的叠加--分别是由GL 模型提出的主体主导的（1/2）指数和边界层主导的(1/4)指数关系式。两个关系式的系数之比表明，粗糙板可以提高主体的贡献，而且将系统从边界层主导转变到主体主导。而對各個板上的測量顯示，改變平板的條件，比如恒定熱量或者恒定溫度條件，以及同一個對流槽中另外一塊板是否粗糙板，該平板的傳熱沒有發生變化。而對於粗糙版，讓它處於恒定熱量或者恒定溫度條件，得到不同的結果；同一個槽中另外一塊板是平板或者粗糙板，該粗糙板的傳熱也會受影響。 / 第二組實驗中，在平滑板组成的对流槽，和两块粗糙板组成的对流槽中，我们添加高分子聚合物，进一步研究添加的效果。对于平滑板的对流槽，研究观察到热传递效率Nusselt 数在添加聚合物之后降低。而且，添加的聚合物越多，Nu 降低越多，在聚合物浓度大约120ppm 的时候，Nu 降低了接近12%，而且保持不变。而对于粗糙板组成的对流槽，当聚合物浓度大于120ppm 的时候，Nu 提高了大约4%。 / 第三組實驗，在两块平滑板组成的圆柱形对流槽中，我们也对底板边界层内的速度场进行了实验测量。结果表明，在倾斜角度小于1°的时候，速度边界层的厚度δ[subscript v]与雷诺数的指数关系，与理论给的平流边界层的结果接近。当倾斜角度比较大的时候，边界层厚度与雷诺数的指数随着角度减小。 在不同瑞利数下，同一个倾斜角度时，测量得到的水平速度剖面通过标准化后，得到的形状是一致不变的。而对于不同的角度，标准化的形状之间，是有区别的。 / In this thesis three sets of experiments of turbulent Rayleigh-Bénard convection with modified boundary conditions are presented. / The first set of measurements were made in cylindrical cells with aspect ratio one and with various combinations of smooth and rough plates in the form of regularly-arrayed pyramids. The experimental results suggest that the Nu - Ra relationship can be represented by the combination of two power laws, corresponding to the bulk dominant regime (exponent=1/2) and boundary layer dominant one (exponent=1/4) of the Grossmann-Lohse model. The behaviors of the coefficients of the two power laws suggest that the roughness of the plate can enhance the contribution of bulk and push the system to change from the boundary dominant state to bulk dominant state. A further examination of the individual plates reveal that the heat transport properties of smooth plates are insensitive to the surface and boundary conditions of the other plate of the same cell, whether smooth or rough, or whether under constant flux or constant temperature. The heat transport properties of the rough plates, on the other hand, appear to depend on surface and boundary conditions of the other plate of the same cell. / In the second set of experiments we study the effect of polymer additives in two Rayleigh-Bńard convection cells, one with smooth top and bottom plates and the other with rough top and bottom plates. For the cell with smooth plates, a reduction of the measured Nusselt number (Nu) was observed. Furthermore, the amount of Nu reduction increases with increasing polymer concentration (c), reaching ~12% for c = 120 ppm and an apparent level-off thereafter. For the cell with rough plates, however, an enhancement (~4%) of Nu was observed when the polymer concentration is greater than 120 ppm. / The third set of experiments investigates the properties of the velocity boundary layer in turbulent Rayleigh-Bénard convection in a cylindrical cell when it is tilted with respect to gravity. It is found that at small tilt angles (θ ≤ 1°), the measured viscous boundary layer thickness δ[subscript v] scales with the Reynolds number Re with an exponent close to that for a Prandtl-Blasius laminar boundary layer. For larger tilt angles, the scaling exponent of δ[subscript v] with Re decreases with θ. The normalized mean horizontal velocity profiles measured at the same tilt angle but with different Ra are found to have an invariant shape. But for different tilt angles, the shape of the normalized profiles is different. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Wei, Ping = 改變邊界條件下的熱湍流對流系統 : 傳熱性質及邊界層的實驗研究 / 韋萍. / "November 2012." / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references (leaves 148-158). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstracts also in Chinese. / Wei, Ping = Gai bian bian jie tiao jian xia de re tuan liu dui liu xi tong : chuan re xing zhi ji bian jie ceng de shi yan yan jiu / Wei Ping. / Table of Contents --- p.vii / List of Figures --- p.xxii / List of Tables --- p.xxiv / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Background of Turbulence --- p.1 / Chapter 1.2 --- Rayleigh-Bénard convection system --- p.4 / Chapter 1.2.1 --- Physical picture --- p.4 / Chapter 1.2.2 --- Structure of Rayleigh-Bénard convection --- p.8 / Chapter 1.2.3 --- Previous investigation about Rayleigh-Bérnard Convection --- p.11 / Chapter 1.3 --- Motivation of the thesis --- p.15 / Chapter 1.4 --- Organization of this thesis --- p.17 / Chapter 2 --- Experimental apparatus and method --- p.18 / Chapter 2.1 --- Experimental apparatus --- p.18 / Chapter 2.1.1 --- The convection cell with smooth conducting plate --- p.18 / Chapter 2.1.2 --- The rough conducting plate --- p.20 / Chapter 2.2 --- Experimental techniques --- p.21 / Chapter 2.2.1 --- Temperature measurements --- p.21 / Chapter 2.2.2 --- Particle Image Velocimetry (PIV) --- p.23 / Chapter 2.3 --- Correction of heat flux measurment --- p.25 / Chapter 3 --- Convective Heat Transfer in Bulk- and Boundary-Dominated Regimes in Turbulent Thermal Convection --- p.28 / Chapter 3.1 --- Introduction --- p.29 / Chapter 3.2 --- Apparatus and experimental method --- p.31 / Chapter 3.3 --- Results and discussion --- p.34 / Chapter 3.3.1 --- Homogenity of temperature measurement over plate --- p.34 / Chapter 3.3.2 --- The heat transport measurement Nu --- p.40 / Chapter 3.3.3 --- Different heat transport behaviors over smooth and rough plates --- p.41 / Chapter 3.3.4 --- Fluctuations of local temperature --- p.47 / Chapter 3.3.5 --- Velocity and Reynolds number measurement --- p.48 / Chapter 3.3.6 --- Comparison with theoretical model and understanding . --- p.50 / Chapter 3.4 --- Summary --- p.52 / Chapter 4 --- Enhanced and Reduced Heat Transport in Turbulent Thermal Convection with Polymer Additives --- p.54 / Chapter 4.1 --- Introduction --- p.55 / Chapter 4.2 --- Experimental setup and methods --- p.58 / Chapter 4.2.1 --- The convection cell and experimental parameters --- p.58 / Chapter 4.2.2 --- Characterization of Polymer --- p.59 / Chapter 4.2.3 --- Measurement of the polymer solution viscosity --- p.62 / Chapter 4.3 --- Results --- p.65 / Chapter 4.3.1 --- The Nusselt number measurement --- p.65 / Chapter 4.3.2 --- Fluctuations of Nu and the local temperature --- p.72 / Chapter 4.3.3 --- Velocity and Reynolds number behavior --- p.83 / Chapter 4.4 --- Discussions --- p.90 / Chapter 4.5 --- Summary --- p.94 / Chapter 5 --- Viscous boundary layer properties in turbulent thermal convection in a cylindrical cell: the effect of cell tilting --- p.97 / Chapter 5.1 --- Introduction --- p.98 / Chapter 5.1.1 --- Boundary layer measurements in turbulent thermal convection --- p.98 / Chapter 5.1.2 --- Organization of the chapter --- p.102 / Chapter 5.2 --- Experimental apparatus --- p.103 / Chapter 5.2.1 --- Convection cell --- p.103 / Chapter 5.2.2 --- PIV measurement --- p.104 / Chapter 5.3 --- Results and discussion --- p.104 / Chapter 5.3.1 --- Temperature profile and fluid properties --- p.106 / Chapter 5.3.2 --- Velocity profiles and the Reynolds number scaling --- p.106 / Chapter 5.3.3 --- The viscous boundary layer and its scaling with Ra and Re --- p.114 / Chapter 5.3.4 --- Fluctuations and statistical properties of the velocity field in the boundary layer --- p.121 / Chapter 5.3.5 --- Properties of shear stresses and near-wall quantities --- p.125 / Chapter 5.3.6 --- Dynamical scaling and the shape of velocity profiles in the boundary layer --- p.130 / Chapter 5.4 --- Summary --- p.138 / Chapter 6 --- Conclusion --- p.141 / Chapter 6.1 --- Conclusion of our work --- p.141 / Chapter 6.1.1 --- Comparison of the thermal convection with modified plates --- p.142 / Chapter 6.1.2 --- The effect of polymer additives in smooth and rough cells --- p.143 / Chapter 6.1.3 --- Velocity field with tilting angles --- p.144 / Chapter 6.2 --- Perspectives for further investigation --- p.146 / Bibliography --- p.148

Properties of cast aluminum components can be improved by strategically placing ferrous inserts to locally improve properties such as wear resistance and stiffness. A cost-effective production method is to cast-in the insert using the solidification of the molten aluminum as a joining method. Metallurgically bonding between the metals could potentially improve both load and heat transfer across the interface. The metallurgical bond between the steel and the aluminum has to be strong enough to withstand stresses related to solidification, residual stresses, thermal expansion stresses, and all other stresses coupled with the use of the component. Formation of a continuous defect free bond is inhibited by the wetting behavior of aluminum and is governed by a diffusion process which requires both energy and time. Due to the diffusional nature of the bond growth in combination with post manufacturing heat treatments defects such as Kirkendall voids can form. The effect of aluminum alloying elements during liquid-solid bond formation in regards to microstructural changes and growth kinetics has been described. A timeframe for defect formation during heat treatments as well as microstructural changes has been established. The effect of low melting point coatings (zinc and tin) on the nucleation of the metallurgical bond has been studied as well the use of a titanium coating for microstructural modification. A set of guidelines for successful metallurgical bonding during multi- material metal casting has also been constructed.

Nickel-based super alloys are widely employed in the aerospace industry due to their high- temperature strength and high corrosion resistance. Because of the special application, the superficial residual stress of the super alloy is mandatory to 100% compressive stress according to the Federal Aviation Administration (FAA) regulations. In manufacturing of nickel-based super alloy components, grinding processes are necessarily applied as the final material removal step for achieving the stringent tolerance and surface finish requirements. During the traditional grinding process of Nickel based alloy, due to the thermal effect, tensile residual stress might be generated on the surface of the alloy. It's critical to transfer the tensile residual stress to compressive one which benefits on the fatigue life of alloy. In the thesis, a novel technology is developed to generate the superficial compressive residual stress with the method of embed a subsurface heating layer inside the workpiece to regulate the distribution of temperature field very before mechanical process. The residual stress might be reduced much, even transfer to compressive stress after combining the thermal effect. The numerical model will be built in the thesis including the induction model, heat transfer model, grinding heat model. Effects of different parameters on final subsurface heating layer will be studied including the coil parameters, concentrator parameters, coolant parameters, feed rate and also electromagnetic field properties such as the skin effect, proximity effect and slot effect. The thesis creates a system combining induction heating and cooling processes to regulate the temperature distribution in subsurface area that will be used for further stress analysis.

Made available in DSpace on 2017-07-24T19:37:59Z (GMT). No. of bitstreams: 1 ClicianeGuadalupeJesus.pdf: 2429700 bytes, checksum: c3ac935bcc2b97480f80dc8cf9ff472d (MD5) Previous issue date: 2009-02-27 / Nanostructured films composed by a 3-n-propylpyridinum silsesquioxane polymer (designated as SiPy+Cl-) and copper (II) tetrasulphophthalocyanine (CuTsPc) were produced using the Layer-by-Layer technique (LbL). The deposition of the bilayers was monitored by UV-Vis spectroscopy accompanying the absorbance of Q-band at 617 nm. It was observed that the absorbance linearly increased with the number of SiPy+Cl-/CuTsPc or CuTsPc/SiPy+Cl- bilayers, indicating that the same amount of material was deposited at each step of film formation. FTIR spectra showed that there is a specific interaction by the SO3 - groups of CuTsPc and the pyridinium groups of the polycation, SiPy+Cl-. Morphological studies of films surfaces showed that their roughness and thickness increase with the number of bilayers. The films were employed to detect dopamine (DA) and ascorbic acid (AA) using cyclic voltammetry. It was observed that the number and the sequence of bilayers deposition directly influenced on the electrochemical response in presence of the analytes. LbL films with lower number of bilayers (1 to 5 bilayers) presented higher current values in presence of the analytes, which is attributed to the higher facility of diffusion of target species to the electrode surface and enhancement of the efficiency of the electron transfer process. Considering the sequence of bilayers deposition, it was observed that the CuTsPc/SiPy+Cl- film did not show any redox peaks in the potential range -0.2 V to 1.6 V vs Ag/AgCl in presence of DA and AA. In contrast, the SiPy+Cl-/CuTsPc LbL film, presented a defined oxidation redox peak at approximately 1.2 V for DA and 0.8 V for AA, which linearly increased with DA concentration in HCl 1.0x10-3 molL-1 electrolyte solution (pH 3). Studies in different scan rates for the SiPy+Cl-/CuTsPc LbL film in presence of these analytes showed that the anodic peak current (Ipa) linearly increased with the square root of the scan rate (n1/2 ) which is a typical behavior for systems governed by a diffusion controlled mechanism. The relationship Ipa/ n1/2 vs n resulted in an exponential profile, confirming the existence of an electrocatalytical process for both AA and DA provided by CuTsPc in the LbL film. Using differential pulse technique, films comprising SiPy+/CuTsPc were able to distinguish between DA and ascorbic acid (AA), with a potential difference of approximately with 400 mV, in the concentration range of 9.0x10-5 to 2.0x10-4 molL- 1(in pH 3.0) and detection limits in the order of 10-5 molL-1. / Filmes nanoestruturados formados entre o polímero 3-n-propilpiridínio silsesquioxano (designado como SiPy+Cl-) e ftalocianina tetrasulfonada de cobre (II) (CuTsPc) foram produzidos usando a técnica Layer-by-Layer (LbL). A formação dos filmes foi monitorada por espectroscopia na região do UV-Vis, acompanhando-se a absorbância da banda Q da ftalocianina em 617 nm. Observou-se que a absorbância aumentou linearmente com o número de bicamadas para os filmes SiPy+Cl-/CuTsPc ou CuTsPc/SiPy+Cl-, indicando que a mesma quantidade de material foi depositado a cada bicamada depositada. Espectros FTIR mostraram que há interação específica entre os grupos SO3 - da CuTsPc e o anel piridínio do policátion, SiPy+Cl-. Estudos da morfologia da superfície dos filmes mostraram que a rugosidade média e espessura dos filmes aumentam de acordo com o número de bicamadas. Os filmes foram empregados para detectar DA e AA, utilizando-se a técnica de voltametria cíclica. Observou-se que o número de bicamadas e a seqüência de deposição das mesmas influenciam diretamente sobre a resposta eletroquímica na presença dos analitos. Filmes LbL com menor número de bicamadas (1 a 5 bicamadas) apresentaram maiores valores de corrente, fato este atribuído a maior facilidade de difusão das espécies à superfície do eletrodo, aumentando a eficiência do processo de transferência de elétrons. Com relação à sequência de deposição das bicamadas constatou-se que o filme CuTsPc/SiPy+Cl- não mostrou picos redox na faixa de potencial de -0,2 V a 1,6 V vs Ag/AgCl na presença de DA e AA. Enquanto que o filme SiPy+Cl-/CuTsPc, apresentou um pico de oxidação bem definido em aproximadamente 1,2 V, para DA e em 0,8 V para AA, o qual aumentou linearmente com a concentração dos analitos utilizando HCl como eletrólito suporte. Estudos em diferentes velocidades de varredura do eletrodo SiPy+Cl-/CuTsPc na presença dos analitos mostraram que a corrente de pico anódica (Ipa) aumenta linearmente com a raiz quadrada da velocidade de varredura (n1/2), indicando que o processo de transferência de elétrons é controlado pela difusão das espécies à superfície do eletrodo. A relação entre Ipa/n1/2 vs n, resultou numa curva exponencial, confirmando a existência do processo eletrocatalítico resultante da oxidação da DA e AA proporcionada pela CuTsPc. Utilizando-se a técnica de voltametria de pulso diferencial, o eletrodo SiPy+Cl-/CuTsPc foi capaz de distinguir AA e DA quando presentes numa mesma solução, com um diferença de potencial de aproximadamente 400 mV, no intervalo de concentração de 9,0x10-5 a 2,0x10-4 molL-1(em pH 3) e limites de detecção (LOD) da ordem de 10-5 molL-1.

by Xin-liang Qiu. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1998. / Includes bibliographical references (p. 98-103). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web. / Abstracts in English and Chinese. / by Xin-liang Qiu.

長期以來，人們知道壁面受限湍流中的聚合物添加劑將顯著降低摩擦阻力，但是對聚合物在熱對流熱傳輸的影響還沒有太多研究。作為第一步，一項最近的工作[1]研究了在穩態邊界層流中熱量傳輸是怎樣被聚合物添加劑所影響的。在這項工作中[1]，聚合物是用Oldroyd-B模型來描述，這個模型允許聚合物無限伸展而沒有限制。 / 在這篇論文中，我們用一個更加真實的聚合物模型來研究聚合物在穩態邊界層流中對熱量傳輸的影響。我們採用FENE-P（有限擴展非線性彈性Peterlin）模型，在這個模型中，聚合物僅可以被伸展到一個最大的長度。聚合物的有限伸展性由參數L來衡量，它是聚合物最大長度與平衡長度的比例。基於該模型，我們發現，相對於與聚合物溶劑在底板處粘度相同的牛頓流體，熱量傳輸可以被提高或者被降低，這取決於聚合物不同的L值。而在不同的L值下，流場中底板的阻力始終加強。在早期的工作中，可以用一個隨位置改變的有效粘度來理解聚合物的效果。我們探討了聚合物的有效粘度和流速場是怎樣被聚合物改變的，以理解這個問題。我們也對熱量傳輸與不同參數的依賴關係進行了研究，這些參數包括威森博格數，普朗特數和聚合物對零剪切下溶劑粘度作出的貢獻的比例。 / It has long been known that friction drag will be reduced signicantly due to polymer additives in turbulent wall-bounded flows, but the effect of polymers on heat transport in thermal convection has not been studied much. As a rst step, a recent work [1] has studied how heat transport in a steady-state boundary layer flow might be influenced by the addition of polymers. In this work [1], polymers are modeled by the Oldroyd-B model, in which they can be extended innitely without a limit. / In this thesis, we study the effect of polymers on the heat transport in steady-state boundary layer flow using a more realistic model of polymers. We apply the FENE-P (nite extensible nonlinear elastic-Peterlin) model, in which the polymers can only be extended up to a maximum length. The nite extensibility of the polymers is measured by the parameter L, which is the ratio of the maximum length to the equilibrium one. Based on the model, we nd that compared to a Newtonian flow with the same viscosity as that of the polymer solution at the plate, heat transport can be enhanced or reduced depending on L. The fraction drag is always enhanced by the polymers for all different L. In the earlier work, the effect of the polymers has been understood to produce an effective viscosity that is position-dependent. We have explored the effective viscosity of the polymers and how the velocity eld is modied by the polymers to understand our results. We have also studied how the results depend on the different parameters, including Weissenberg number, Prandtl number and the ratio of polymer contribution to the total zero-shear viscosity. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Wang, Yiqu = 有限伸展的聚合物對邊界層流中熱量傳輸的改變 / 王異曲. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2012. / Includes bibliographical references (leaves 68-69). / Abstracts also in Chinese. / Wang, Yiqu = You xian shen zhan de ju he wu dui bian jie ceng liu zhong re liang chuan shu de gai bian / Wang Yiqu. / Chapter 1 --- Introduction --- p.1 / Chapter 2 --- Prandtl-Blasius boundary layer flow --- p.7 / Chapter 3 --- Earlier work with Oldroyd-B polymers --- p.13 / Chapter 4 --- Theoretical formulation of the problem with polymers of finite extensibility --- p.20 / Chapter 4.1 --- Equations of motion --- p.20 / Chapter 4.2 --- Quantities of interest --- p.30 / Chapter 5 --- Checking validity of fixed angle approximation --- p.34 / Chapter 6 --- Results and Discussion --- p.42 / Chapter 6.1 --- Calculations --- p.42 / Chapter 6.2 --- The effect on heat transport --- p.45 / Chapter 6.3 --- The effect on drag --- p.48 / Chapter 6.4 --- The velocity field due to polymers --- p.49 / Chapter 6.5 --- Effective viscosity --- p.55 / Chapter 6.6 --- Dependence on Weissenberg number --- p.58 / Chapter 6.7 --- Dependence on Prandtl number --- p.61 / Chapter 6.8 --- Dependence on the ratio of polymer contribution to the total zero-shear viscosity --- p.64 / Chapter 7 --- Conclusion --- p.66

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Des films multicouches à base de nanoparticules de TiO2 et d’Ag ont été construits sur des substrats modèles et des textiles via la technique du Layer-by-Layer (LbL). Les films à base de nanoparticules de TiO2 construits sur substrats modèles ont montré un comportement photocatalytique non conventionnel pour la minéralisation de l’acide formique en phase gaz sous irradiation UV-A, et une minéralisation très importante a été obtenue avec un film possédant une unique couche de nanoparticule de TiO2. Ces films ont également montré des propriétés biocides sous irradiation UV-A. La mise en œuvre d’une méthode one-pot, combinant la synthèse photo-induite des nanoparticules d’Ag et dépôt de la couche de TiO2 par LbL, a permis la synthèse de nanoparticules d’Ag directement au sein des films et une exaltation très importante des propriétés photocatalytiques des films. Les méthodes de constructions ont été transférées avec succès sur textiles. Les films restent photocatalytiquement actifs et biocides sous irradiation UV-A après plusieurs cycles de lavages. / TiO2 and Ag nanoparticle multilayered films were constructed on model substrates and textiles via Layer-by-Layer (LbL) assembly. The TiO2 nanoparticle based films constructed on model substrates showed a non-conventional photocatalytic behaviour for gas phase formic acid mineralisation upon UV-A irradiation, and a high mineralisation was obtained for a single layer TiO2 nanoparticle film. These films also showed biocidal properties upon UV-A irradiation. The elaboration of a one-pot method, combining the photo-induced synthesis of Ag nanoparticles and the LbL deposition of TiO2 nanoparticle layer, allowed the direct synthesis of Ag nanoparticles within the films and a high enhancement of the film photocatalytic properties. The construction methods were successfully transfered on textile surfaces. The films were photocatalytically active and biocidal under UV-A irradiation after several washing treatment cycles.