Frequently, deep foundations extend through potentially liquefiable soils. When liquefaction occurs in cohesionless soils surrounding a deep foundation, the skin-friction in the liquefied layer is compromised. After cyclical forces suspend and pore pressures dissipate, effective stress rebuilds and the liquefied soil consolidates. When the settlement of the soil exceeds the downward movement of the foundation, downdrag develops. To investigate the loss and redevelopment of skin-friction, strain was measured on an instrumented micropile during a blast-induced liquefaction test in Mirabello, Italy. The soil profile where the micropile was installed consisted of clay to a depth of 6m underlain by a medium to dense sand. The 25cm diameter steel reinforced concrete micropile was bored to a depth of 17m. Pore pressure transducers were placed around the pile at various depths to observe excess pore pressure generation and dissipation. Soil strain was monitored with profilometers in a linear arrangement from the center of the 10m diameter ring of buried explosives out to a 12m radius. Immediately following the blast, liquefaction developed between 6m and 12m below ground. The liquefied layer settled 14cm (~2.4% volumetric strain) while the pile toe settled 1.24cm under elastic displacement. The static neutral plane in the pile occurred at a depth of 12m. From 6m to 12m below ground, the incremental skin-friction was 50% compared to pre-liquefaction measurements. The decrease in residual skin-friction is consistent with measurements observed by Dr. Kyle Rollins from previous full-scale tests in Vancouver, BC, Canada, Christchurch, New Zealand, and Turrel, Arkansas.

Stricter requirements from the European Union and the German government regarding the utilization of renewable and sustainable fuels for transportation, power, and heat production are currently in effect. This has led to that heavy transportation companies are looking for a more sustainable alternative to liquefied natural gas, such as liquefied biomethane. The monetary costs for the release of greenhouse gas are also increasing due to the carbon certificates that are being traded are decreasing in numbers each year. Carbon certificates grant companies an allowance of releasing a certain amount of emissions without being fined. Carbon dioxide and biomethane liquefaction can be a good investment for producers of biomethane to find new markets by for example trading in carbon certificates, selling liquid carbon dioxide, and producing liquefied biomethane as an alternative transportation fuel. The sale price of biomethane is heavily dependant on the emission factor for the biomethane and as such, capturing the carbon dioxide from the biomethane plant and off-setting fossil carbon dioxide would increase the sale price of the biomethane. The methods used are theoretical and quantitative, Numerical data was collected to be able to perform the economical and environmental calculations. The investment cost for the liquefaction technologies was scaled down to correspond to a plant with a production capacity of 350 Nm3/h. Also included in this thesis is a review of biomethane production, together with theory for the economical and environmental calculations.  By performing a technical, economical and environmental assessment of the technologies for the liquefaction of carbon dioxide and biomethane. This thesis shows that liquefaction of biomethane is not an economical viable option at the moment for plants equal or below this production capacity, due to a negative net present value, negative return on investment, sensitivity to fluctuating costs, and a high payback time. However, it could help in achieving the sustainability goals set forth by the European Union and the German government. With regards to the liquefaction of carbon dioxide it is deemed a viable investment option with an investment cost of approximately 1 million Euro and a payback time of approximately 3 years. Liquefaction of carbon dioxide could bring an extra income to the biomethane plant. This due to an added revenue in the sales of liquid carbon dioxide and an increase in the sale price of biomethane due to a reduction of the emission factor from 17 gCO2-eq /MJ to -23 gCO2-eq /MJ. The investment could also help achieving the sustainability goals by decreasing the dependence on fossil carbon dioxide for various sectors.

Doctor of Philosophy / Department of Grain Science and Industry / Sajid Alavi / Sorghum grain (Sorghum bicolor) is safe for consumption by individuals afflicted with celiac disease, and its proteins can be used as a supplement in gluten-free foods. However, utilization of sorghum in human foods is limited by the poor digestibility and lack of functionality of its proteins, which result from their entrapment in protein bodies, tight association with starch, and high degree of cross-linking induced by cooking. The first part of this study presents an extensive review of current methods for concentration and isolation of sorghum proteins, which are laboratory-scale techniques used for protein characterization and have no potential for commercial scale-up. Furthermore, these methods typically use non-food grade reagents and do not improve protein digestibility and functionality. In the second part, a novel extrusion-enzyme liquefaction (EEL) process was used to produce sorghum protein concentrates to overcome the aforementioned limitations. EEL involves extrusion pre-treatment of sorghum flour and starch liquefaction with a thermostable α-amylase, followed by enzyme inactivation, protein separation and drying. To demonstrate the concept, a laboratory-scale EEL process was used to produce concentrates with higher protein content (PC; 80% db) and digestibility (D; 74%) than those made by batch liquefaction. The optimum conditions for producing concentrates with both high PC and D were 32% wb in-barrel moisture content and 2.5% α-amylase added after extrusion. Using these conditions, EEL was scaled-up to a pilot-scale process to produce sorghum protein concentrates with 72-80% db PC and 62-74% D, while the batch liquefied control had only 70% db PC and 57% D. Dynamic oscillatory measurements of dough (55% moisture) and batter (65% moisture) containing sorghum protein concentrates (5 and 10%) and potato starch were performed to evaluate protein functionality. At lower moisture, pure potato starch and dough containing 10% sorghum protein concentrate had similar elastic and viscous moduli. At higher moisture, potato starch was more stable and exhibited significantly higher moduli than the batters with protein concentrates. Sorghum protein concentrates can improve the quality of some gluten-free foods. EEL shows promise for commercial production of sorghum protein concentrates because of its high throughput and potential for delivering high protein content and digestibility.

Call number: LD2668 .T4 1978 H77 / Master of Science

The suitability of water hyacinth (Eichornia crassipes) as a viable feedstock for renewable energy production was investigated in this project. Water hyacinth used in this study was harvested from the Vaal River near Parys in the northwest region of the Free State province, South Africa (26°54′S 27°27′E). The wet plants were processed in the laboratory at the North-West University by separating the roots from the leaves and the stems, thus obtaining two separate water hyacinth feedstock. Characterisation of the feedstock showed that the stems and leaves are more suitable for bio-energy production than roots, due to the higher cellulose and hemicellulose content and very low lignin content of the stems and leaves. Water hyacinth was evaluated as feedstock for the production of bio-ethanol gel, bio-ethanol, bio-oil and bio-char. The recovery of water from the wet plants for use in bio-refining or for use as drip-irrigation in agriculture was also investigated. Cellulose was extracted from water hyacinth feedstock to be used as a gelling agent for the production of ethanol-gel fuel. A yield of 200 g cellulose/kg dry feedstock was obtained. The extracted cellulose was used to produce ethanol-gel with varying water content. The gel with properties closest to the SANS 448 standard contained 90 vol% ethanol and 10 vol% water, with 38 wt% cellulose. This gel was found to ignite readily and burn steadily, without flaring, sudden deflagrations, sparking, splitting, popping, dripping or exploding from ignition until it had burned to extinction, as required by SANS 448. The only specifications that could not be met were the viscosity (23,548 cP) and the high waste residue (32 wt%) left after burning. The other major concern is the extremely high costs involved with the manufacturing of ethanol-gel from water hyacinth cellulose. It can be concluded that ethanol-gel cannot be economically produced using water hyacinth as feedstock. Chemical and enzymatic extraction of water from the feedstock, which is stems and leaves or roots, showed that the highest yield of water was obtained using a combination of Celluclast 1.5 L, Pectinex Ultra SP-L and additional de-ionised water. A yield of 0.89 ± 0.01 gwater/gwater in biomass was realised. This is, however, only 0.86 wt% higher than the highest yield obtained (0.87 ± 0.01 gwater/gwater in biomass) using only Pectinex Ultra SP-L and de-ionised water. It is recommended to use only Pectinex Ultra SP-L and de-ionised water at a pH of 3.5 and a temperature of 40°C. Using one enzyme instead of two reduces operating costs and simplifies the chemical extraction process. The extracted water, both filtered and unfiltered, was not found to be suitable for domestic use without further purification to reduce the total dissolved solids (TDS), potassium and manganese levels. Both the unfiltered and filtered water were, however, found to be suitable for industrial and agricultural purposes, except for the high TDS levels. If the TDS and suspended particle level can be reduced, the extracted water would be suitable for domestic, industrial and agricultural use. The potential fermentation of the sugars derived from the water hyacinth, using ultrasonic pretreatment, was investigated. Indirect ultrasonic treatment (ultrasonic bath) proved to be a better pretreatment method than direct sonication (ultrasonic probe). The optimum sugar yield for the ultrasonic bath pretreatment with 5% NaOH was found to be 0.15 g sugar/g biomass (0.47 g sugar/g available sugar) using an indirect sonication energy input of 27 kJ/g biomass. The optimum sugar yield is lower than those reported in other studies using different pretreatment methods. Theoretically a maximum of 0.24 g ethanol can be obtained per g available sugar. This relates to an ethanol yield of 0.08 g ethanol/kg wet biomass. The low yield implies that ethanol production from water hyacinth is not economically feasible. The production of bio-oil and bio-char from water hyacinth through thermochemical liquefaction of wet hyacinth feedstock was investigated. An optimum bio-char yield of 0.55 g bio-char/g biomass was achieved using an inert atmosphere (nitrogen) at 260°C and the stems and leaves as feedstock. With the roots as feedstock a slightly lower optimum yield of 0.45 g bio-char/g biomass was found using a non-reducing atmosphere (carbon monoxide) at 280°C. The bio-oil yield was too low to accurately quantify. As water is required during thermochemical liquefaction, it was found unnecessary to dry the biomass to the same extent as was the case with the pretreatment and fermentation of the water hyacinth, making this a more feasible route for biofuel production. Bio-char produced through liquefaction of roots as the feedstock and leaves and stems as the other feedstock had a higher heating value (HHV) of 10.89 ± 0.45 MJ/kg and 23.31 ± 0.45 MJ/kg respectively. Liquefaction of water hyacinth biomass increased the HHV of the feedstock to a value comparable to that of low grade coal. This implies a possible use of water hyacinth for co-gasification. The most effective route for bio-energy production in the case of water hyacinth was found to be thermochemical liquefaction (12.8 MJ/kg wet biomass). Due to the high production costs involved, it is recommended to only use water hyacinth as a feedstock for biofuel production if no alternative feedstock are available. / MIng (Chemical Engineering), North-West University, Potchefstroom Campus, 2014

The suitability of water hyacinth (Eichornia crassipes) as a viable feedstock for renewable energy production was investigated in this project. Water hyacinth used in this study was harvested from the Vaal River near Parys in the northwest region of the Free State province, South Africa (26°54′S 27°27′E). The wet plants were processed in the laboratory at the North-West University by separating the roots from the leaves and the stems, thus obtaining two separate water hyacinth feedstock. Characterisation of the feedstock showed that the stems and leaves are more suitable for bio-energy production than roots, due to the higher cellulose and hemicellulose content and very low lignin content of the stems and leaves. Water hyacinth was evaluated as feedstock for the production of bio-ethanol gel, bio-ethanol, bio-oil and bio-char. The recovery of water from the wet plants for use in bio-refining or for use as drip-irrigation in agriculture was also investigated. Cellulose was extracted from water hyacinth feedstock to be used as a gelling agent for the production of ethanol-gel fuel. A yield of 200 g cellulose/kg dry feedstock was obtained. The extracted cellulose was used to produce ethanol-gel with varying water content. The gel with properties closest to the SANS 448 standard contained 90 vol% ethanol and 10 vol% water, with 38 wt% cellulose. This gel was found to ignite readily and burn steadily, without flaring, sudden deflagrations, sparking, splitting, popping, dripping or exploding from ignition until it had burned to extinction, as required by SANS 448. The only specifications that could not be met were the viscosity (23,548 cP) and the high waste residue (32 wt%) left after burning. The other major concern is the extremely high costs involved with the manufacturing of ethanol-gel from water hyacinth cellulose. It can be concluded that ethanol-gel cannot be economically produced using water hyacinth as feedstock. Chemical and enzymatic extraction of water from the feedstock, which is stems and leaves or roots, showed that the highest yield of water was obtained using a combination of Celluclast 1.5 L, Pectinex Ultra SP-L and additional de-ionised water. A yield of 0.89 ± 0.01 gwater/gwater in biomass was realised. This is, however, only 0.86 wt% higher than the highest yield obtained (0.87 ± 0.01 gwater/gwater in biomass) using only Pectinex Ultra SP-L and de-ionised water. It is recommended to use only Pectinex Ultra SP-L and de-ionised water at a pH of 3.5 and a temperature of 40°C. Using one enzyme instead of two reduces operating costs and simplifies the chemical extraction process. The extracted water, both filtered and unfiltered, was not found to be suitable for domestic use without further purification to reduce the total dissolved solids (TDS), potassium and manganese levels. Both the unfiltered and filtered water were, however, found to be suitable for industrial and agricultural purposes, except for the high TDS levels. If the TDS and suspended particle level can be reduced, the extracted water would be suitable for domestic, industrial and agricultural use. The potential fermentation of the sugars derived from the water hyacinth, using ultrasonic pretreatment, was investigated. Indirect ultrasonic treatment (ultrasonic bath) proved to be a better pretreatment method than direct sonication (ultrasonic probe). The optimum sugar yield for the ultrasonic bath pretreatment with 5% NaOH was found to be 0.15 g sugar/g biomass (0.47 g sugar/g available sugar) using an indirect sonication energy input of 27 kJ/g biomass. The optimum sugar yield is lower than those reported in other studies using different pretreatment methods. Theoretically a maximum of 0.24 g ethanol can be obtained per g available sugar. This relates to an ethanol yield of 0.08 g ethanol/kg wet biomass. The low yield implies that ethanol production from water hyacinth is not economically feasible. The production of bio-oil and bio-char from water hyacinth through thermochemical liquefaction of wet hyacinth feedstock was investigated. An optimum bio-char yield of 0.55 g bio-char/g biomass was achieved using an inert atmosphere (nitrogen) at 260°C and the stems and leaves as feedstock. With the roots as feedstock a slightly lower optimum yield of 0.45 g bio-char/g biomass was found using a non-reducing atmosphere (carbon monoxide) at 280°C. The bio-oil yield was too low to accurately quantify. As water is required during thermochemical liquefaction, it was found unnecessary to dry the biomass to the same extent as was the case with the pretreatment and fermentation of the water hyacinth, making this a more feasible route for biofuel production. Bio-char produced through liquefaction of roots as the feedstock and leaves and stems as the other feedstock had a higher heating value (HHV) of 10.89 ± 0.45 MJ/kg and 23.31 ± 0.45 MJ/kg respectively. Liquefaction of water hyacinth biomass increased the HHV of the feedstock to a value comparable to that of low grade coal. This implies a possible use of water hyacinth for co-gasification. The most effective route for bio-energy production in the case of water hyacinth was found to be thermochemical liquefaction (12.8 MJ/kg wet biomass). Due to the high production costs involved, it is recommended to only use water hyacinth as a feedstock for biofuel production if no alternative feedstock are available. / MIng (Chemical Engineering), North-West University, Potchefstroom Campus, 2014

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Earthquake-induced soil liquefaction that occurs within the built environment is responsible for billions of dollars of damage to infrastructure and loss of economic productivity. There is an acute need to accurately predict the risk of soil liquefaction as well as to quantify the effectiveness of soil improvement techniques that are meant to decrease the risk of soil liquefaction. Current methods indirectly measure the risk of soil liquefaction by empirically correlating certain soil characteristics to known instances of surficial evidence of soil liquefaction, but these methods tend to overpredict the risk in sands with silts, to poorly predict instances of soil liquefaction without surface manifestations, and fail to adequately quantify the effectiveness of soil improvement techniques. Direct in-situ evaluation of liquefaction susceptibility was performed at a single site at the Wildlife Liquefaction Array (WLA) in Imperial Valley, California, in March 2012. The project included a CPT sounding, crosshole testing, and liquefaction testing. The liquefaction testing involved the measurement of water pressure and ground particle motion under earthquake-simulating cyclic loading conditions. The objective of this testing technique is to observe the relationship between shear strain in the soil and the resulting generation of excess pore water pressure. This fundamental relationship dictates whether or not a soil will liquefy during an earthquake event. The direct in-situ evaluation of liquefaction susceptibility approach provides a more accurate and comprehensive analysis of the risks of soil liquefaction. It also has the ability to test large-scale soil improvements in-situ, providing researchers an accurate representation of how the improved soil will perform during a real earthquake event. The most important results in this thesis include the identification of the cyclic threshold strain around 0.02% for the WLA sand, which is very similar to results achieved by other researchers (Vucetic and Dobry, 1986, and Cox, 2006) and is a characteristic of liquefiable soils. Another key characteristic is the 440 to 480 ft/sec (134 to 146 m/s) shear wave velocity of the soil, which are well below the upper limit 656 ft/sec (200 m/s) and an indication that the soil is loose enough for soil liquefaction to occur. The third significant point is that the compression wave velocity of the sand is greater than 4,500 ft/sec (1,370 m/s), indicating that it is at least 99.9% saturated and capable of generating large pore water pressure due to cyclic loading. These three conditions (cyclic threshold strain, shear wave velocity, and compression wave velocity) are among the most important parameters for characterizing a soil liquefaction risk and must all be met in order for soil liquefaction to occur. / text

Recent experiences from the Darfield and Canterbury, New Zealand earthquakes have shown that the soft soil condition of saturated liquefiable sand has a profound effect on seismic response of buildings, bridges and other lifeline infrastructure. For detailed evaluation of seismic response three dimensional integrated analysis comprising structure, foundation and soil is required; such an integrated analysis is referred to as Soil Foundation Structure Interaction (SFSI) in literatures. SFSI is a three-dimensional problem because of three primary reasons: first, foundation systems are three-dimensional in form and geometry; second, ground motions are three-dimensional, producing complex multiaxial stresses in soils, foundations and structure; and third, soils in particular are sensitive to complex stress because of heterogeneity of soils leading to a highly anisotropic constitutive behaviour. In literatures the majority of seismic response analyses are limited to plane strain configuration because of lack of adequate constitutive models both for soils and structures, and computational limitation. Such two-dimensional analyses do not represent a complete view of the problem for the three reasons noted above. In this context, the present research aims to develop a three-dimensional mathematical formulation of an existing plane-strain elasto-plastic constitutive model of sand developed by Cubrinovski and Ishihara (1998b). This model has been specially formulated to simulate liquefaction behaviour of sand under ground motion induced earthquake loading, and has been well-validated and widely implemented in verifcation of shake table and centrifuge tests, as well as conventional ground response analysis and evaluation of case histories. The approach adopted herein is based entirely on the mathematical theory of plasticity and utilises some unique features of the bounding surface plasticity formalised by Dafalias (1986). The principal constitutive parameters, equations, assumptions and empiricism of the existing plane-strain model are adopted in their exact form in the three-dimensional version. Therefore, the original two-dimensional model can be considered as a true subset of the three-dimensional form; the original model can be retrieved when the tensorial quantities of the three dimensional version are reduced to that of the plane-strain configuration. Anisotropic Drucker-Prager type failure surface has been adopted for the three-dimensional version to accommodate triaxial stress path. Accordingly, a new mixed hardening rule based on Mroz’s approach of homogeneous surfaces (Mroz, 1967) has been introduced for the virgin loading surface. The three-dimensional version is validated against experimental data for cyclic torsional and triaxial stress paths.

The characterization of silty soils is usually designated by the percentage of silt contained within the soil matrix, along with the soil’s void ratio, which is used to describe the soil’s current state. The use of these parameters to assess a soil’s strength and undrained behavior is limited when finer material is contained within the soil. Therefore, additional parameters must be considered in order to correctly assess the strength and liquefaction potential of silty soils. These additional parameters include the skeleton void ratio, equivalent void ratio and granulometric factors. The current research investigates the influence of granulometric parameters, specifically the Median Grain Size Ratio (D50/d50), denoted as μDR (or MDR within graphs and charts), on the strength and liquefaction potential of loose silty sands. A series of undrained monotonic triaxial compression tests (σ3’= 69, 83, and 103 kPa) are performed on reconstituted soil samples, using three different base sand samples and a constant silt material. As a result, three distinct median grain size ratios (μDR = 4.2, 6.75, and 9) were tested with fines content ranging from 0-30% for each μDR. The undrained shear strength at all confining pressures tends to increase with in μDR; beyond 10% fines content there was no noticeable influence of μDR. At any μDR the excess PWP is higher than that of clean sand, when fines content is larger than 5% fines content. The slope of the instability line and phase transformation line are directly affected by the μDR and fines content, with an increase in the instability line and decrease in the phase transformation line with a growing μDR. The results indicate loose granular fills can be designed to be stronger and more resilient under extreme conditions by careful choice of materials in which the μDR>6.75 and the fines content does not exceed 10%. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection