Journal articles are the formal medium for the communication of results among scientists, and often contain valuable data. However, manually collecting article data from a large field like lithium-ion battery chemistry is tedious and time consuming, which is an obstacle when searching for statistical trends and correlations to inform research decisions. To address this a platform for the automatic retrieval and analysis of large numbers of articles is created and applied to the field of lithium-ion battery chemistry. Example data produced by the platform is presented and evaluated and sources of error limiting this type of platform are identified, with problems related to text extraction and pattern matching being especially significant. Some solutions to these problems are presented and potential future improvements are proposed.

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The global energy system is under transformation. The energy transition from a centralized, fossil fuel based energy system to a more decentralized, renewable energy based system will challenge the balancing of electricity supply and demand. This stresses the importance of grid flexibility. In this challenge, energy storage will play a valuable role as it can provide flexibility and support the renewable energy integration. More specifically, lithium-ion battery energy storage systems (Li-ion BESS) demonstrate technological advantages and valuable application possibilities in the electricity grid. This thesis examines opportunities and barriers for deployment of grid-scale Li-ion BESS in the Swedish electricity market, and provides an overview of different perspectives of possibilities with BESS from several market actors. The purpose of the exploratory study is to gain an understanding of prospects for grid-scale BESS in Sweden. Through a comprehensive literature study and an empirical study, based on fourteen interviews with various actors in the electricity market, data was collected and analyzed. The analysis of the empirical findings resulted in two tables summarizing opportunities and barriers for implementation of BESS in Sweden. The opportunities and barriers are categorized into three hierarchical levels; contextual level, power system level and BESS level, referring to where in the system the benefits or hinders are localized. Also, key discussion points related to BESS (such as storage time perspective, ownership, grid services, cost, price signals and knowledge gap) are explored and evaluated. Furthermore, to understand the possibilities for grid-scale BESS in Sweden, a potential business setup for BESS is assessed and analyzed to identify preconditions for BESS to be attractive on the Swedish electricity market. The findings of the thesis indicate that grid flexibility is most likely going to be a considerable issue within 10-20 years. By the time of the potential nuclear phase out in Sweden, there will be major instabilities in the electricity grid if solutions are not in place. Therefore, keys to grid flexibility need to be evaluated and planned for well in advance, and the findings indicate that BESS could be a possible part of the solution. Until now, the regulatory framework has been perceived as rather unclear when it comes to energy storage, which has led to uncertainties among the market actors. These unclarities are about to be clarified with new laws and regulations, which will enable potential businesses for BESS. With the changes in the regulatory framework in place, we see an opportunity with new actors on the market. Our analysis shows that the BESS owner will most likely be a commercial actor, to enable utilization of a BESS for combined applications. An important factor, affecting the possibilities of implementing BESS on the Swedish electricity market, is the cost of BESS. We consider the cost aspect as vital for the likelihood of deploying BESS in Sweden. Based on our main findings, we conclude several preconditions for the deployment of BESS in Sweden. These are; decreased costs of BESS, acceptance from market actors, increased knowledge, a trading platform for grid services provided by a BESS, coordination between markets and electricity load forecasts. We believe that if these preconditions are fulfilled, Li-ion BESS has a chance to affect and have an impact on the Swedish electricity market. / Dagens energisystem är under förändring. Det sker en omvandling där energisystemet går från att vara centraliserat och fossilbaserat till att bli mer decentraliserat och baserat på förnybar energi. Detta kommer att utmana balanseringen av elproduktion och elkonsumtion, vilket betonar vikten av flexibilitet i elnätet. I den stundande utmaningen kommer energilagring att spela en viktig roll eftersom det kan bidra med flexibilitet och samtidigt stödja integrationen av mer förnybar elproduktion. Mer specifikt har energilagersystem med litiumjon-batterier flertalet tekniska fördelar och värdefulla användningsområden i elnätet. Det här examensarbetet utforskar möjligheter och hinder för en framtida implementering av nätanslutna litiumjonbatterilager på den svenska elmarknaden och ger en överblick över perspektiv på utsikter för batterilager från flertalet marknadsaktörer. Syftet med den utforskande studien är att få en ökad förståelse för framtidsutsikterna för storskaliga batterilager i Sverige. Genom en omfattande litteraturstudie och en empirisk studie, baserad på fjorton intervjuer med olika aktörer på elmarknaden, samlades data in och analyserades. Analysen av de empiriska resultaten resulterade i två tabeller som sammanfattar möjligheter och hinder för implementering av batterilager i Sverige. Möjligheterna och hindren kategoriseras i tre hierarkiska nivåer; kontextuell nivå, kraftsystemnivå och batterilagersystemnivå, med hänvisning till var i systemet fördelarna eller barriärerna är lokaliserade. Dessutom utvärderas flera betydande diskussionsteman relaterade till batterilager (såsom lagringstid, ägande, nättjänster, kostnad, prissignaler och kunskapsluckor). För att förstå möjligheterna för att etablera batterilager i Sverige har en möjlig affärsuppställning utvärderats och analyserats. Detta för att identifiera förutsättningar för att batterilager ska vara attraktivt på den svenska elmarknaden. Examensarbetets resultat tyder på att nätflexibilitet sannolikt kommer att bli ett betydande problem inom 10-20 år. Den troliga avvecklingen av den svenska kärnkraften kommer att resultera i instabilitet i elnätet om inte lösningar finns på plats. Därför behöver lösningar för att uppnå flexibilitet i elnätet utvärderas och planeras i god tid och uppsatsens resultat visar på att batterilager kan vara en möjlig del av lösningen. Fram till nu har det funnits oklarheter i regelverket gällande energilagring, vilket har lett till osäkerheter hos marknadsaktörerna. Nya lagar och förordningar kommer att klargöra flertalet osäkerheter och möjliggöra potentiella affärer med batterilager. När det förändrade regelverket är på plats, ser vi potential för nya aktörer på marknaden. Vår analys visar på att batterilager med största sannolikhet kommer att ägas av kommersiella aktörer för att möjliggöra kombinerade användningsområden av batterilager. Möjligheterna till implementering av batterilager på den svenska elmarknaden påverkas i hög grad av kostnaden för batterilager. Vi anser att kostnadsaspekten är avgörande för sannolikheten att utnyttja batterilager i Sverige. Vår slutsats är att det finns flertalet förutsättningar för att batterilager ska bli attraktivt och lönsamt i Sverige. Dessa är; minskade kostnader för batterilager, acceptans från marknadsaktörer, ökad kunskap, en handelsplattform för nättjänster som tillhandahålls av batterilager, samordning mellan marknader samt lastprognoser. Om dessa förutsättningar uppnås anser vi att litiumjon-batterilager har en chans att påverka den svenska elmarknaden.

Over the last few decades, rechargeable lithium-ion batteries have been extensively used in portable instruments due to their high energy density and low self-discharge rate. Recently, lithium-ion batteries have emerged as the most promising candidate for electric vehicles and stationary energy storage. However, the maximum energy that lithium-ion batteries can store decreases as they are used because of various irreversible degradation mechanisms. Lithium-ion batteries are complex systems to understand, and various processes and their interactions are responsible for the degradation over time. The mechanical integrity and stability of the electrode layers inside the battery highly influence the battery performance, which makes it a necessity to characterize the mechanical behavior of electrode active layers for mesoscopic and macroscopic level modeling. In papers 1 and 2, the macroscopic mechanical behavior of active layers in the electrodes is investigated using U-shape bending tests. The active layers are porous and a different tensile and compressive behavior is captured by performing tests on single side coated dry specimens. The experiments reveal that the active layer is stiffer in compression as compared to tension. The compressive stiffness increases with bending strain whereas the tensile stiffness is almost independent of the bending strain. A very low value of modulus of the active layer (1-5 GPa) is measured in comparison to the metal foils (70-110 GPa) and the active particles (50-200 GPa) which shows that the electrode properties are governed majorly by the binders present in the active layers.  The time-dependent and hysteresis effects are also captured by the method which circumvents the flaws of many other test methods presented in the literature.   In paper 3, we present a multiscale homogenization method that couples mechanics and electrochemistry at the particle, electrode, and battery scales. The active materials of lithium-ion battery electrodes exhibit volume change during lithium intercalation or deintercalation. A lithium concentration gradient develops inside particles, as well as inside the active layer. The developed stress due to deformations further affects solid diffusion.  We utilized models that have already been developed to couple particle and electrode layer levels. The mechanical coupling between the electrode and the battery level is achieved by homogenization of the layered battery using three-dimensional laminate theory.  By application of the model, we demonstrate that the stresses on all considered scales can be predicted from the homogenized model. It is furthermore demonstrated that the effects of external battery loadings like battery stacks, casings, and external pressure can be captured by the model. The model can also capture the effect of various electrochemical cycling rates and mechanical parameters like layer thicknesses, stiffnesses, and swelling properties. The presented multi-scale model is fast, accurate and the efficiency of the method is demonstrated by comparisons to detailed finite element computations where each layer is individually modeled.

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Philosophiae Doctor - PhD (Chemistry) / Lithium ion capacitors are new and promising class of energy storage devices formed from a combination of lithium-ion battery electrode materials with those of supercapacitors. They exhibit better electrochemical properties in terms of energy and power densities than the above mentioned storage systems. In this work, lithium manganese oxide spinel (LiMn2O4; LMO) and lithium manganese phosphate (LiMnPO4; LMP) as well as their respective nickel-doped graphenised derivatives (G-LMNO and G-LMNP) were synthesized and each cathode material used to fabricate lithium ion capacitors in an electrochemical assembly that utilised activated carbon (AC) as the negative electrode and lithium sulphate electrolyte in a two-electrode system. The synthetic protocol for the preparation of the materials followed a simple solvothermal route with subsequent calcination at 500 - 800 ?C. The morphological, structural and electrochemical properties of the as prepared materials were thoroughly investigated through various characterisation techniques involving High resolution scanning electron microscopy (HRSEM), High resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), Small-angle X-ray scattering (SAXS), Electrochemical impedance spectroscopy (EIS), Cyclic voltammetry (CV) and Galvanostatic charge/discharge.

Indiana University-Purdue University Indianapolis (IUPUI) / Computational analysis of lithium ion batteries has been improved since Newman and et al. suggested the porous electrode theory. It assumed the electrode as a simple structure of homogeneous spherical particles. Bruggeman relationship which characterizes porous material by a simple equation was adopted in the homogeneous electrode model instead of the electrode morphology. To improve the prediction of a cell performance, the numerical analysis requires the realistic microstructure of the cell. Based on the experimentally determined microstructure of the positive and negative electrodes of a lithium ion battery (LIB) using x-ray micro/nano-CT technology, three dimensional (3D) simulations have been presented in this research. Tortuosity of the microstructures has been calculated by a linear diffusion equation to characterize the 3D morphology. The obtained tortuosity and porosity results pointed out that the Bruggeman relationship is not sufficiently estimate the tortuosity by the porosity of electrodes. We studied the diffusion-induced stress numerically based on realistic morphology of reconstructed particles during the lithium ion intercalation process. Diffusion-induced stresses were simulated at different C rates under galvonostatic conditions and compared with spherical particles. The simulation results showed that the intercalation stresses of particles depend on their geometric characteristics. The highest von Mises stress and tresca stress in a real particle are several times higher than the stresses in a spherical particle with the same volume. With the reconstructed positive electrode structure, local effects in the LIB cathode electrode during galvanostatic discharge process have been studied. The simulation results reported that large current density usually occurs at the joints between cathode active material particles and in the small channels in electrolyte, which will generate high electric joule power. By using the 3D real image of a LIB cathode electrode, numerical simulation results revealed that the spatial distribution of variable fields such as concentration, voltage, reaction rate, overpotential, and etc. in the cathode electrode are complicated and non-uniform, especially at high discharge rates.

Syfte – Syftet med studien är att Identifiera förbättringsmöjligheter och kritiska faktorer genom att studera returflödet för litiumjonbatterier ur ett miljöperspektiv. Genom att studera returflödet för litiumjonbatterier kan det hjälpa till att ta reda på hur flödet kan se ut för att minimera miljöpåverkan. Detta görs för att bidra med kunskap till återvinningsbranschen om hur returflödet för litiumjonbatterier ser ut idag och hur det förbättras i framtiden.  För att uppnå syftet med studien har två frågeställningar tagits fram:  [1] Hur kan returflödet för litiumjonbatterier förbättras ur ett miljöperspektiv?  [2] Vilka kritiska faktorer kan beaktas vid utformningen av returflödet för litiumjonbatterier?  Metod – Studien har utförts som en fallstudie på ett av Sveriges största återvinningsbolag. Forskarna startade med en förstudie i form av en ostrukturerad observation på fallföretagets återvinningsstation. Vidare hölls en ostrukturerad workshop med den strategiska logistikchefen och en affärsutvecklare inom batterier på fallföretaget. Förstudien gav forskarna en fördjupad kunskap i det aktuella ämnet och därpå kunde ett teoretiskt ramverk byggas upp för att stödja studien. För att uppfylla studiens syfte och besvara frågeställningarna har kvalitativ datainsamling i form av tre intervjuer och dokumentationsstudie utförts. För att besvara studiens syfte har det teoretiska ramverket och den insamlade empirin analyserats och ställts mot varandra.  Resultat – Returflödet för litiumjonbatterier kan förbättras genom att utforma ett navsystem. Navsystemet innebär i praktiken att det kan anläggas mellanlagringstationer där litiumjonbatterierna plockas isär och djupurladdas. Mellanlagringen minimerar avståndet som litiumjonbatterierna behöver fraktas innan de är djupurladdade vilket bidrar till att enklare emballage kan användas och ökad fyllnadsgrad vid transport. Enklare emballage och ökad fyllnadsgrad bidrar till att minska miljöpåverkan i returflödet för litiumjonbatterier. En optimeringsmodell kan användas för att minimera antalet tonkilometer som krävs för att transportera litiumjonbatterier mellan flödets alla delar. Vidare identifierades kritiska faktorer som påverkar returflödets utformning. De kritiska faktorerna som identifierades var:  - Ökade volymer  - Farligt gods  - Skadade batterier  - Nytt forskningsområde  - Osäkerhet i varifrån LIB kommer in i flödet  Studien har bidragit med kunskap för återvinningsbranschen genom att besvara frågeställningarna och därför anses studiens syfte uppnått.  Implikationer – Studiens resultat kan användas av återvinningsbranschen för att förstå returflödet av litiumjonbatterier och hur flödet kan förbättras. Resultatet kan även ge indikationer på vilka kritiska faktorer som behöver tas hänsyn till vid utformning av returflödet för litiumjonbatterier. Studien bidrar med kunskap till vidare forskning inom området för hanteringen av litiumjonbatterier.  Begränsningar – Det kan ifrågasättas om studien kan generaliseras för alla parter i återvinningsbranschen då studien bygger sitt resultat på endast ett fall. Studiens ämne är outforskat och därmed inte helt okomplicerat att studera på grund av brist på kunskap och tidigare forskning. Det studerade ämnet består av processer som inte finns på plats idag och således kan studiens resultat inte valideras då scenariot är en bit bort i framtiden. / Purpose – The purpose of the study is to identify opportunities for improvement and critical factors by studying the return flow of lithium-ion batteries from an environmental perspective. By investigating the return flow of lithium-ion batteries, it can help to find out what the flow might look like to minimize the environmental impact. This is done to contribute knowledge to the recycling industry about what the return flow for lithium-ion batteries looks like today and how it can be improved in the future.  To achieve the purpose of the study, two research questions have been raised:  [1] How can the reverse logistics for the collection of lithium-ion batteries be improved from an environmental perspective?  [2] What critical factors can be considered in the design of reverse logistics for lithium-ion batteries?  Method – The study was carried out as a case study at one of Sweden's largest recycling companies. The researchers started with a pilot study in the form of an unstructured observation at the case company recycling station. Furthermore, an unstructured workshop was held with the strategic logistics manager and a battery business developer at the case company. The pilot study gave the researchers an in-depth knowledge of the current subject and then a theoretical framework could be built up to support the study. In order to fulfil the purpose of the study and answer the research questions, qualitative data collection in the form of three interviews and documentation studies has been performed. To answer the purpose of the study the theoretical framework and the collected empirical data have been analysed and set against each other.  Findings –The reverse logistics when collecting lithium-ion batteries can be improved by designing a hub and spoke system. The hub and spoke system are in practice that intermediate storage stations can be built where the lithium-ion batteries are disassembled and deep discharged. The intermediate storage minimizes the distance that the lithium-ion batteries need to be transported before they are deep discharged, which contributes to simpler packaging being used and an increased degree of filling during transport. Simpler packaging and an increased degree of filling help to reduce the environmental impact of the reverse logistics for lithium-ion batteries. An optimization model can be used to minimize the number of tonne-kilometres required to transport lithium-ion batteries between all parts of the flow. Furthermore, critical factors were identified that affect the design of the reverse logistics. The critical factors identified were:  - Growing volumes  - Dangerous goods  - Damaged batteries  - New phenomenon  - Uncertainty in where lithium-ion batteries come into the flow  The study has contributed knowledge for the recycling industry by answering the questions and therefore the purpose of the study is considered to have been achieved.  Implications – The results of the study can be used by the recycling industry to understand the reverse logistics of lithium-ion batteries and how the flow can be improved. The result can also give indications of which critical factors need to be considered when designing the return flow for lithium-ion batteries. The study contributes with knowledge to further research in the field of handling lithium-ion batteries.  Limitations – It can be questioned whether the study can be generalized for all parties in the recycling industry as the study bases its results on only one case. The subject of the study is unexplored and thus not completely uncomplicated to study due to lack of knowledge and previous research. The studied subject consists of processes that are not in place today and therefor the results of the study cannot be validated as the scenario is a bit far in the future.

Using alternating current in order to heat batteries at sub-zero temperatures is a method,which is investigated in-depth by an increasing number of study groups. The thesis considersthe resonance phenomenon with the intention to use alternating current amplificationand battery’s impedance in order to induce power dissipation inside the battery, and in thisway increase its temperature. A battery cell is thereby modelled as an impedance transferfunction, estimated from electrochemical impedance spectroscopy measurements, whichare taken for a LiNi 13Mn13Co13O2 cell. Note that at 1 kHz and room temperature (20 ◦C),the ohmic resistance of the selected cell amounts to only 0.76m. Five resonant circuitsare investigated and one of them is selected for further investigation, and as a basis for afilter design. The chosen resonant circuit lead to an LCL filter with current magnification.The experimental setup used for conducting practical experiments, offers the possibilityof operating the voltage source converter both as a Full-bridge and as a Half-bridge, withand without current control. For each possible configuration, an LCL filter and a currentcontroller are designed, taking into account the corresponding limitations in frequency,current and controller voltage. The filter design is based on a multiobjective optimizationmethod used to determine filter components that yield the highest gain value for everyconfiguration. The method minimizes two objective functions in order to find an optimalsolution. The first objective is the reversed absolute value of the gain, whereas thesecond one is the absolute impedance of the circuit, consisting of the filter and batterycells. The gain is thereby defined as the ratio between the induced cell current and thecurrent entering the circuit. The obtained results of the proposed method are experimentallyvalidated. Depending on how the filters were physically designed and taking intoaccount the corresponding voltage source converter configuration, gains of 16 were experimentallyachieved. Finally, the three investigated configurations are compared againstthe reference case (Half-bridge voltage source converter with current control and a singleinductor) regarding their power efficiencies. The power measurements showed that despitehigh obtained gains, the overall filter power losses remained approximately in thesame range, compared to the power losses of the reference case. This is due to the factthat stray resistances of the designed LCL filters easily reached values of around 40m,which hindered an efficient power transfer with the chosen voltage source converter andthe used battery cells. This further indicates the importance of building filters with lowstray resistances and in this thesis, it represents a primary source of improvement. / Användandet av växelströ m fö r att värma upp batterier är en metod som fö r närvarande undersö ks av ett flertal forskargupper. Detta examensarbete fokuserar kring hur resonans kan nyttjas fö r att ö ka strö mfö rstärkningen och, pådetta sätt, ö ka effektutvecklingen i batteriet (av LiNi1/3Mn1/3Co1/3O2-typ). Battericellens impedans modelleras som en ö verfö ringsfunktion vars parametrar estimerats från tidigare genomfö rda impedansspektroskopimätningar. Vid 1 kHz och rumstemperatur är den cellens ohmska resistansen endast 0.76 mΩ. Fem mö jliga resonanta kretsar har undersö kts och en av dem valts ut fö r vidare undersö kningar. The utvalda kretsen är ett LCL-filter med vilken strö mfö rstärkning åstadkoms. Den experimentella uppställningen, i vilken praktiska test har genomfö rts, medger mö jligheten att nyttja den tillhö rande omriktaren både som en helbrygga och en halvbrygga, med och utan strö mreglering. Fö r varje mö jlig omriktarkonfiguration har ett LCL-filter och en strö mreglering tagits fram, med hänsyn tagen till uppställningens begränsningar i termer av frekvens, strö moch dc-spänningsnivå. Filtren är framtagna med hjälp av en multiobjektiv optimering vilken åstadkommer hö gsta strö mfö rstärkning mö jlig fö r varje omriktare och strö mregleringsval. Metoden minimerar tvåfunktioner fö r att finna en optimal lö sning. Den fö rsta funktionen beskriver inversen påströ mfö rstärkningen och den andra lastens (bestående av filter och tillhö rande battericell) impedans absolutbelopp. Den resulterande ö har validerats experimentellt och en strö mfö rstärkningsnivåpå 16 uppnåddes. Slutligen har de olika konfigurationerna jämfö rts i termer av verknings-grad. De genomfö rda effektmätningarna visar att trots att hö ga strö mfö rstärkningsnivåer var mö jliga såresulterade de associerade filterfö rlusterna till liknande verkningsgrader fö r alla studerade konfigurationer. Resultaten understryker fö rdelarna med hö geffektiva filtervilka representerar en mö jlig väg fö r vidare undersö kningar.

<p>Lithium-Ion Batteries (Li-ion batteries or LIBs) have been extensively used in a wide variety of industrial applications and consumer electronics. Additive Manufacturing (AM) or 3D printing (3DP) techniques have evolved to allow the fabrication of complex structures of various compositions in a wide range of applications. </p> <p><br></p> <p>The objective of the thesis is to investigate the application of 3DP to fabricate a LIB, using a modified process from the literature [1]. The ultimate goal is to improve the electrochemical performances of LIBs while maintaining design flexibility with a 3D printed 3D architecture. </p> <p><br></p> <p>In this research, both the cathode and anode in the form of specifically formulated slurry were extruded into filaments using a high-temperature pellet-based extruder. Specifically, filament composites made of graphite and Polylactic Acid (PLA) were fabricated and tested to produce anodes. Investigations on two other types of PLA-based filament composites respectively made of Lithium Manganese Oxide (LMO) and Lithium Nickel Manganese Cobalt Oxide (NMC) were also conducted to produce cathodes. Several filaments with various materials ratios were formulated in order to optimize printability and battery capacities. Finally, flat battery electrode disks similar to conventional electrodes were fabricated using the fused deposition modeling (FDM) process and assembled in half-cells and full cells. Finally, the electrochemical properties of half cells and full cells were characterized. Additionally, in parallel to the experiment, a 1-D finite element (FE) model was developed to understand the electrochemical performance of the anode half-cells made of graphite. Moreover, a simplified machine learning (ML) model through the Gaussian Process Regression was used to predict the voltage of a certain half-cell based on input parameters such as charge and discharge capacity. </p> <p><br></p> <p>The results of this research showed that 3D printing technology is capable to fabricate LIBs. For the 3D printed LIB, cells have improved electrochemical properties by increasing the material content of active materials (i.e., graphite, LMO, and NMC) within the PLA matrix, along with incorporating a plasticizer material. The FE model of graphite anode showed a similar trend of discharge curve as the experiment. Finally, the ML model demonstrated a reasonably good prediction of charge and discharge voltages. </p>