Several recent projects in building science have examined the hygric performance of building materials. Most building materials adsorb from and desorb water vapour to their environments. This phenomenon could be used to help control relative humidity fluctuations in buildings, experienced during periods of moisture production such as cooking, washing or bathing. They could also be used to reduce the need for mechanical ventilation and air conditioning to remove excess moisture. To understand how a building material responds to transient changes in relative humidity, testing is required.<p> This thesis outlines the testing performed on gypsum board, a common wall and ceiling finishing material used inside buildings. The effect of paint coatings on the gypsum boards and heat and mass transfer coefficients of the air passing over the gypsum bed was tested. The data produced from these experiments was used to validate several numerical models through an International Energy Agency/Energy Conservation in Buildings and Community Systems (IEA/ECBCS), Annex 41: Whole Building Heat, Air and Moisture Response. The validated models are important for simulating the process of adsorption and desorption in building materials to predict failure in the building envelope and expected indoor air conditions.<p> A sensitivity analysis is also presented which examines the effects of the sorption isotherm and vapour permeability of the gypsum and paints as well as the heat and mass transfer coefficients the boards are exposed to. The sensitivity range used was determined from the tests performed on the gypsum boards and paints which were also performed during the work of Annex 41.<p> The results of this thesis produced a high quality data which can also be used to validate future numerical models. All information required for validation of future models is available such as dimensions of test section, test conditions, material properties and the experimental data.<p> The results show that when designing for passive humidity control in buildings using gypsum boards, the most influential factor is the type of coating or paint applied to the surface. The sensitivity analysis showed that material properties such as vapour permeability and the sorption isotherms, for the expected temperature range, should be well known for increased accuracy of the simulation. The material properties were determined from inter-laboratory testing at 14 different institutions to achieve confident values.<p> The effect of increasing the heat and mass transfer coefficients, over the range of coefficients studied in this thesis, showed negligible differences in the results. The simulated results had very good agreement between the models and were mostly within experimental uncertainty of the measurements.

Field pea is the most produced and exported pulse crop in Canada, and makes a major contribution to Western Canadian agricultural diversification programs. Canada is now the world largest exporter of pea, lentil and chickpea and is fourth in dry bean. The demand for Canadian pulse products is steadily rising and the export market would continue to rise with the expected increased in production. Field pea exported to countries with tropical climates is at particular risk due to rapid loss of quality. It is therefore important to develop practical strategies for safe storage of feed pea. Knowledge on the moisture adsorption and spoilage characteristics of pea stored in adverse storage conditions is important in the transportation and storage of this export commodity. <p> This study was initiated to examine the conditions that lead to quality losses in storage and transport of pea. Tropical and subtropical conditions were simulated in airtight chambers. Relative humidities (RH) of 60, 70, 80 and 90% were created by saturated salt solutions in airtight chambers at temperatures of 10, 20 and 30°C, while the same range of humidity was provided by dilute sulphuric acid in airtight chambers at 40°C in environmental cabinets. The four RH levels at each temperature for both whole and feed-grade pea were tested in duplicate. The samples were observed for changes in moisture content (MC), mold appearance and RH in specific time intervals. The amount of produced carbon dioxide (CO2) was measured in airtight chambers during storage to control the condition existing in sealed airtight chambers. Also, all components of feed-grade pea were exposed to RH of 90% and temperature of 40°C in separate airtight chambers to find the effect of each component on mold appearance. Molds were identified after appearance on the samples in order to pinpoint potential toxicity. <p> Both feed and whole sound peas became molded after a short time of storage at high temperatures and high RH, but those stored at 70% and below did not develop mold after 175 days at 30 and 40°C (experiment duration) and 216 days at 10 and 20°C (experiment duration). Molds were identified mostly as species of Aspergillus and Penicillium. The amount of CO2 in the airtight chambers showed almost no difference from the ambient CO2 except at high temperature and high RH when samples had gone molded. <p> Moisture adsorption equations were developed based on the moisture adsorption data in dynamic environment. Although the Page model showed to fit the data better, the exponential model was chosen to fit the data because its parameters can be better expressed as a function of temperature and RH of the storage environment. <p> The mold-free days for both feed pea and clean pea were modeled at temperatures of 10, 20, 30 and 40°C and RH of 80 and 90%.

Understanding the hydrological controls on subsurface flow and transport is of considerable importance in the study of reclaimed landscapes in the oil sands region of Canada. A significant portion of the reclaimed landscape will be comprised of a thin veneer (~ 1 m) of clay-rich reclamation soil overlying saline-sodic shale overburden, which is a waste by-product from the mining process. The global objective of this study was to investigate the first-order controls on soil moisture and salt transport dynamics within clay-rich reclamation covers overlying low permeability waste substrates. The study site is located in a cold, semi-arid climate in the oil sands region of northern Alberta. Preferential flow was the dominant mechanism responsible for the development of perched water table conditions on the cover-waste interface during the spring snow melt. Hydrological and geochemical data indicated that snowmelt infiltration occurs via the macroporosity while the ground is still frozen. An isotope hydrograph separation conducted on water collected in a weeping tile confirmed the presence of fresh snowmelt water at the onset of subsurface flow. This water transitions to a chemical signature that is comprised of approximately 80% connate pore water as a result of chemical equilibration between pore water in the soil matrix and fresh water in the macropores.<p>Detailed mapping of the spatial distribution of soil moisture and salts within a reclamation cover indicated the lower-slope positions are wetter due to the accumulation surface run-off and frozen ground infiltration in spring. Increased soil moisture conditions in lower-slope positions accelerate salt ingress, while drier conditions in middle and upper-slope positions attenuate salt ingress. The data indicated that fresh snowmelt water is bypassing the soil matrix higher in the cover profile. Subsurface flow and deep percolation are key mechanisms mitigating vertical salt ingress in lower and upper slope positions. The mesotopography of the cover-waste interface imposes a direct control on the depth of perched water and the downslope routing of water. Undulations in the cover-waste interface cause the depth of perched water to vary considerably (± 20 60 cm) over short distances (< 5 m), while saturated subsurface flow is routed through the lowest elevations in the cover profile. A numerical analysis of subsurface flow was able to simulate both the discharge rate and cumulative volume of flow to a weeping tile. Composite hydraulic functions were used in the simulations to account for the increased hydraulic conductivity and drainable porosity created by the macroporosity at near-saturated conditions. The transient Na+ concentration of discharge water was modelled using the concept of an equivalent porous medium. The good match between measured and modelled data verified the conceptual model, which contends that saturated subsurface flow is dominated by the fracture network and that the concentration of discharge water is function of the depth of perched water. Finally, the results from this study suggest the mesotopography of the cover-waste interface could be used to manage excess water and salts within the landscape.

As a hygroscopic salt, granular potash can easily absorb large quantities of water vapor from humid air during storage and transportation processes. Subsequent drying will result in potash particles sticking together to form clumps or cakes. In order to avoid or decrease caking, it is essential to know the local history of moisture content and moisture movement in a bed of potash. In this thesis, experimental measurements and numerical simulations are used to investigate moisture transport and redistribution by capillarity, gravity and diffusion effects within a potash bed. <p> The important properties required to model moisture transfer in granular porous potash (i.e. porosity, permeability, specific surface area and irreducible saturation) are investigated experimentally and theoretically. It is shown that for a mixture with a wide range of particle sizes the potash bed properties can be predicted knowing the properties for each narrow range of particle size in the mixture. <p> An experimental test facility was designed and constructed to test moisture transfer within a potash bed. The test procedures are presented along with an uncertainty analysis. The moisture content spatial distribution for different particle sizes under different initial conditions is investigated and data are presented. <p>A one-dimensional transient numerical model of moisture transport accounting for diffusion, capillarity and gravity effects within potash beds is developed. Two different moisture transport mechanisms are presented. In a wet region, where local moisture saturation level, S, is larger than an irreducible saturation, S0, liquid water exists as continuous liquid film on the particles; moisture is transferred by liquid film movement due to capillarity and gravity effects. In a dry region where S is less than S0, water vapor diffusion is the only mechanism of moisture transfer and water is adsorbed in layers on the surfaces. <p> From the experimental data and numerical simulation analysis, it is shown that the irreducible saturation, S0, is a strong function of particle size. It will decrease with a particle size increase. <p> The numerical model is validated by comparison with some typical experimental case studies. Agreement between the experimental data and simulation results is well within the experimental 95% uncertainty bounds. It is concluded from this research that the complex moisture transport process by diffusion, capillarity and gravity effects within a potash bed can be modeled and simulated. Experimental and simulation results indicate that direct water drainage will more readily occur for large particle sizes than for small particles for the same initial moisture content.

Soil solution samplers have certain inadequacies that limit their range of possible applications. Passive Capillary Samplers (PCAPS), which apply suction to the soil pore-water via a fiber glass wick, have shown promising results in preliminary experiments in regard to collection efficiency of water and of bromide tracers. The objectives of this study were to evaluate PCAPS under non-steady state field conditions with respect to (1) effect of installation procedure and operational characteristics, (2) ability to estimate the soil-water flux, and (3) ability to estimate the mean concentration of agrochemicals. At the same time, samplers were used to (4) evaluate the effect of a cereal rye (Secale cereale (L.)) cover crop on NO₃⁻ leaching. Thirty-two PCAPS and 32 suction cup samplers were installed below the root zone at a depth of 120 cm in a Willamette Variant loam wet soil (fine loamy mixed mesic Pachic Ultic Argixeroll). Samplers were installed in an ongoing cover crop/crop rotation study. Regarding overall performance, flux measurements were within 20 % of the native values as determined by a water balance. The air release from the sample bottles was a point of concern and might have slowed down the sampling rate. The installation procedure introduced bias into volume and concentration measurements of the part of the PCAPS closest to the refilled trench. The leachate concentration as calculated using the arithmetic mean of suction cup sampler measurements holds a significant bias, deviating by up to 97 % for bromide concentrations. Phosphate was not detected by the suction cup samplers indicating that ceramic cups should not be used for phosphate sampling. Matrix and preferential flow could clearly be distinguished using the PCAPS, showing that PCAPS are a valuable tool to assess the hydrology and solute transport mechanisms of a field site. The cover crop reduced NO₃⁻-N leaching significantly at the recommended N rate as evaluated by PCAPS. The cover crop reduced the seasonal mean NO₃⁻-N concentration at the recommended N rate from 13.5 mg LI to 8.1 mg L⁻¹, which is under the E.P.A. drinking water quality standard of 10 mg L⁻¹. The total NO₃⁻-N mass lost under the fallow treatment at the recommended N rate was 48 kg N ha⁻' which compares to 32 kg N ha⁻' under the cover crop treatment. Given the increasing problems with nitrate contamination of ground water, programs to support the cultivation of catch crops in conjunction with nitrogen soil testing should be considered as a relatively easy, effective, and biologically sound means to reduce nitrate concentrations in the recharge to the ground water in agricultural settings. / Graduation date: 1994

Three studies were undertaken from 2006 to 2007 to examine litter (dead plant material) in southwestern Manitoba pastures. First, the relationship between litter and soil microclimate was tested across five pasture sites. The amount of litter biomass was not strongly related to soil moisture, though near-surface soil temperatures were reduced when litter was present. Second, the effect of four simulated grazing strategies on the litter layer was measured in six pastures. It was found that after three years of simulated grazing, litter was present in largest quantities in the least-frequently grazed treatments. Finally, a field survey was conducted assessing the quantity of litter present in native pastures across Manitoba. Litter was quite variable and averaged 1902 kg/ha over two years. This research confirmed the value of litter as an indicator of sustainable pasture management, though it remains unclear whether litter is important to pastures from the perspective of soil microclimate. / October 2008

To assess the accuracy of the second-generation Prairie Agrometeorological Model (PAM2nd) as an agrometeorological model for spring wheat on the Canadian Prairies, a study was conducted to validate the model using field measurements. Results from model validation indicated soil moisture was being overestimated at most sites during the second half of the growing season, while soil moisture was underestimated during periods that experienced consecutive days of rainfall. Modifications to the model were implemented to improve the model's ability to simulate soil moisture. Evapotranspiration estimates from PAM2nd and the FAO56 Penmen-Monteith method were compared to water balance methods. Both models produced estimates that fell within the range of water balance ET measurement error. The similarity in performance of both models to estimate ET compared to the water balance ET means the adoption of either model could be justified. However, PAM2nd would be more appropriate because it requires fewer, more commonly measured, surface weather parameters. / February 2009

Control of moisture and heat flow through building enclosure assemblies is a critical component of overall building performance. This thesis shows that significant drying of moisture in wall assemblies is possible and that ventilation of cladding significantly increases the rate of drying in some assemblies without having detrimental impact on the enclosures thermal performance. A review found that thermal and moisture buoyancy, wind pressure gradients and mechanical equipment drive ventilation airflow. This ventilation flow can theoretically increase the effective water vapour permeance and thermal conductivity. Ventilation has the potential to increase outward drying through relatively impermeable claddings at the low flows expected to occur in service. The impact on thermal conductance is much less. A methodology for assessing the complicated airflow resistance characteristics of lap sidings was developed and applied to a representative vinyl siding. Field drying studies showed that the sample tested is well ventilated. Field brick veneer clad wall samples were also tested for system airflow resistance over a range of driving pressures. Theoretical predictions under-estimated the measured flow rate for given steady driving air pressures. Measurements of naturally driven cavity air speeds and smoke pencil testing showed that flow rates were commonly occurring that would in theory significantly affect the hygrothermal performance of the walls. This was confirmed with field drying studies. A field drying study of east-facing test wall with vinyl siding and brick veneer cladding was conducted in Waterloo, Ontario, Canada. Significant amounts of drying and inward moisture redistribution were measured. Wall sheathing dried quickly in hot summer conditions but in some cases significant inward driven moisture flow occurred. In cool and cold weather the wall dried more slowly and much less moisture moved inward. Increased cladding ventilation significantly increased drying rates and reduced internal wall assembly moisture levels. It was concluded that cladding ventilation acts to increase the effective vapour permeance of cladding and to reduce solar driven inward vapour drives. The use of spun bonded polyolefin sheathing membrane in lieu of #15 asphalt impregnated felt was found to improved hygrothermal performance in the test walls. The difference observed was concluded to be due to the higher vapour permeance of the spun bonded polyolefin and may not hold for wall assemblies with lower permeance sheathings (e. g. oriented strand board and foam plastic). Walls clad with vinyl siding dried faster than those clad with brick veneer. It was concluded that the vinyl siding is a well ventilated cladding system.

This thesis examines the feasibility of assimilating space borne remotely-sensed microwave data into WATClass using the ensemble Kalman filter. WATClass is a meso-scale gridded hydrological model used to track water and energy budgets of watersheds by way of real-time remotely sensed data. By incorporating remotely-sensed soil moisture estimates into the model, the model’s soil moisture estimates can be improved, thus increasing the accuracy of the entire model. Due to the differences in scale between the remotely sensed data and WATClass, and the need of ground calibration for accurate soil moisture estimation from current satellite-borne active microwave remote sensing platforms, the spatial variability of soil moisture must be determined in order to characterise the dependency between the remotely-sensed estimates and the model data and subsequently to assimilate the remotely-sensed data into the model. Two sets of data – 1996-1997 Grand River watershed data and 2002-2003 Roseau River watershed data – are used to determine the spatial variability. The results of this spatial analysis however are found to contain too much error due to the small sample size. It is therefore recommended that a larger set of data with more samples both spatially and temporally be taken. The proposed algorithm is tested with simulated data in a simulation of WATClass. Using nominal values for the estimated errors and other model parameters, the assimilation of remotely sensed data is found to reduce the absolute RMS error in soil moisture from 0.095 to approximately 0.071. The sensitivities of the improvement in soil moisture estimates by using the proposed algorithm to several different parameters are examined.

Control of moisture and heat flow through building enclosure assemblies is a critical component of overall building performance. This thesis shows that significant drying of moisture in wall assemblies is possible and that ventilation of cladding significantly increases the rate of drying in some assemblies without having detrimental impact on the enclosures thermal performance. A review found that thermal and moisture buoyancy, wind pressure gradients and mechanical equipment drive ventilation airflow. This ventilation flow can theoretically increase the effective water vapour permeance and thermal conductivity. Ventilation has the potential to increase outward drying through relatively impermeable claddings at the low flows expected to occur in service. The impact on thermal conductance is much less. A methodology for assessing the complicated airflow resistance characteristics of lap sidings was developed and applied to a representative vinyl siding. Field drying studies showed that the sample tested is well ventilated. Field brick veneer clad wall samples were also tested for system airflow resistance over a range of driving pressures. Theoretical predictions under-estimated the measured flow rate for given steady driving air pressures. Measurements of naturally driven cavity air speeds and smoke pencil testing showed that flow rates were commonly occurring that would in theory significantly affect the hygrothermal performance of the walls. This was confirmed with field drying studies. A field drying study of east-facing test wall with vinyl siding and brick veneer cladding was conducted in Waterloo, Ontario, Canada. Significant amounts of drying and inward moisture redistribution were measured. Wall sheathing dried quickly in hot summer conditions but in some cases significant inward driven moisture flow occurred. In cool and cold weather the wall dried more slowly and much less moisture moved inward. Increased cladding ventilation significantly increased drying rates and reduced internal wall assembly moisture levels. It was concluded that cladding ventilation acts to increase the effective vapour permeance of cladding and to reduce solar driven inward vapour drives. The use of spun bonded polyolefin sheathing membrane in lieu of #15 asphalt impregnated felt was found to improved hygrothermal performance in the test walls. The difference observed was concluded to be due to the higher vapour permeance of the spun bonded polyolefin and may not hold for wall assemblies with lower permeance sheathings (e. g. oriented strand board and foam plastic). Walls clad with vinyl siding dried faster than those clad with brick veneer. It was concluded that the vinyl siding is a well ventilated cladding system.