Ph.D. / Electrical Engineering / A novel combinatory on-line technique coupling Electrochemistry (EC) with Inductively Coupled Plasma - Mass Spectrometry (ICP-MS) for in-situ quantitative determination of the corrosion mechanism in magnetic thin film structures has been developed in this research. Detailed construction of a system and a comprehensive methodology was described in this dissertation. Uniformly coated multi-layer magnetic thin film samples with multi-elemental alloys containing CoCrPtB and CrMo/Cr on the Ni/P substrate were used in this research for demonstrations. In-situ quantifications conducted in a series of experiments revealed that elemental dissolution was a predominant mechanism during corrosion courses of metallic thin film materials. At the microscopic scale, using results from depletion rate determination as well as cross-sectional analyses of microstructures and magnetic features, elemental passivity was observed to occur, depending on corrosion conditions. Without external influences, surface topographic measurements indicated that passive film could be produced at the macro-scale. The dependence of the dissolution rate of each metallic ion of alloys on electrolyte concentration, potential bias, scanning rate, and corrosion duration suggested that the most critical influential factor in corrosion mechanisms was epitaxial microstructures with strongly-oriented arrangements of grains and grain boundaries. Through the use of cross-sectional microstructural analysis, including high resolution TEM micrography, electron FFT diffraction, and nano-probe with EDS profiling, variations of elemental spatial distributions at grains and grain boundaries due to the corrosion phenomena were discovered, which provided a comprehensive understanding of occurrences of micro-corrosion in thin film structures. Because of the unique magnetic property of magnetic thin films, extensive studies of field strengths from the surface were also performed in this research. Important magnetization variations were noticed when cross-sectional images were obtained. Finally, models of corrosion kinetics in the multiple layers of magnetic thin film structures were proposed.

A non-iterative receiver is proposed to achieve near capacity performance on intersymbol interference (ISI) channels. There are two main ingredients in the proposed design. i) The use of a novel BCJR-DFE equalizer which produces optimal soft estimates of the inputs to the ISI channel given all the observations from the channel and L past symbols exactly, where L is the memory of the ISI channel. ii) The use of an encoder structure that ensures that L past symbols can be used in the DFE in an error free manner through the use of a capacity achieving code for a memoryless channel. Computational complexity of the proposed receiver structure is less than that of one iteration of the turbo receiver. We also provide the proof showing that the proposed receiver achieves the i.i.d. capacity of any constrained input ISI channel. This DFE-based receiver has several advantages over an iterative (turbo) receiver, such as low complexity, the fact that codes that are optimized for memoryless channels can be used with channels with memory, and finally that the channel does not need to be known at the transmitter. The proposed coding scheme is universal in the sense that a single code of rate r; optimized for a memoryless channel, provides small error probability uniformly across all AWGN-ISI channels of i.i.d. capacity less than r: This general principle of a proposed non-iterative receiver also applies to other signal processing functions, such as timing recovery, pattern-dependent noise whiten ing, joint demodulation and decoding etc. This makes the proposed encoder and receiver structure a viable alternative to iterative signal processing. The results show significant complexity reduction and performance gain for the case of timing recovery and patter-dependent noise whitening for magnetic recording channels.

Magnetic recording systems have reached a point where the grain size can no longer be reduced due to energy stability constraints. As a new magnetic recording paradigm, two-dimensional magnetic recording (TDMR) relies on sophisticated signal processing and coding algorithms, a much less expensive alternative to radically altering the media or the read/write head as required for the other technologies. Due to 1) the significant reduction of grains per bit, and 2) the aggressive shingled writing, TDMR faces several formidable challenges. Firstly, severe interference is introduced in both down-track and cross-track directions due to the read/write head dimensions. Secondly, reduction in the number of grains per bit results in variations of bit boundaries which consequently lead to data-dependent jitter noise. Moreover, the bit to grain ratio reduction will cause some bits not to be properly magnetized or to be overwritten which introduces write errors to the system. The nature of write and read processes in TDMR necessitates that the information storage be viewed as a two-dimensional (2D) system. The challenges in TDMR signal processing are 1) an accurate read channel model, 2) mitigating the effect of inter-track interference (ITI) and inter-symbol interference (ISI) by using an equalizer, 3) developing 2D modulation/error correcting codes matching the TDMR channel model, 4) design of truly 2D detectors, and 5) computing the lower bounds on capacity of TDMR channel. The work is concerned with several objectives in regard to the challenges in TDMR systems. 1. TDMR Channel Modeling: As one of the challenges of the project, the 2D Microcell model is introduced as a read channel model for TDMR. This model captures the data-dependent properties of the media noise and it is well suited in regard to detector design. In line with what has been already done in TDMR channel models, improvements can be made to tune the 2D Microcell model for different bit to grain densities. Furthermore, the 2D Microcell model can be modified to take into account dependency between adjacent microtrack borders positions. This assumption will lead to more accurate model in term of closeness to the Voronoi model. 2. Detector Design: The need for 2D detection is not unique to TDMR systems. However, it is still largely an open problem to develop detectors that are close to optimal maximum likelihood (ML) detection for the 2D case. As one of the important blocks of the TDMR system, the generalized belief propagation (GBP) detector is developed and introduced as a near ML detector. Furthermore, this detector is tuned to improve the performance for the TDMR channel model. 3. Channel Capacity Estimation: Two dimensional magnetic recording (TDMR) is a new paradigm in data storage which envisions densities up to 10 Tb/in² as a result of drastically reducing bit to grain ratio. In order to reach this goal aggressive write (shingled writing) and read process are used in TDMR. Kavcic et al. proposed a simple magnetic grain model called the granular tiling model which captures the essence of read/write process in TDMR. Capacity bounds for this model indicate that 0.6 user bit per grain densities are possible, however, previous attempt to reach capacities are not close to the channel capacity. We provide a truly two-dimensional detection scheme for the granular tiling model based on generalized belief propagation (GBP). Factor graph interpretation of the detection problem is provided and formulated in this section. Then, GBP is employed to compute marginal a posteriori probabilities for the constructed factor graph. Simulation results show huge improvements in detection. A lower bound on the mutual information rate (MIR) is also derived for this model based on GBP detector. Moreover, for the Voronoi channel model, the MIR is estimated for the case of constrained and unconstrained input. 4. Modulation Codes: Constrained codes also known as modulation codes are a key component in the digital magnetic recording systems. The constrained code forbids particular input data patterns which lead to some of the dominant error events or higher media noise. The goal of the dissertation in regard to modulation codes is to construct a 2D modulation code for the TDMR channel which improves the overall performance of the TDMR system. Furthermore, we implement an algorithm to estimate the capacity of the 2D modulation codes based on generalized belief propagation (GBP) algorithm. The capacity is also calculated in presence of white and colored noise which is the case for TDMR channel. 5. Joint Detection and Decoding Schemes: In data recording systems, a concatenated approach toward the constrained code and error-correcting code (ECC) is typically used and the decoding is done independently. We show the improvement in combining the decoding of the constrained code and the ECC using GBP algorithm. We consider the performance of a combined modulation constraints and the ECC on a binary-input additive white Gaussian noise (AWGN) channel (BIAWGNC) and also over one-dimensional (1D) and 2D ISI channels. We will show that combining the detection, demodulation and decoding results in a superior performance compared to concatenated schemes.

Recentemente, nanopartículas (NP) de FePt de fase tetragonal de face centrada (fct) em sistemas auto-organizados tem sido sintetizados como potenciais candidatos para gravação magnética de ultra-alta densidade (UHMR), devido a sua elevada anisotropia magnetocristalina. Entretanto, o alinhamento magnético de NP esféricas tem sido constantemente um problema, pois os eixos de fácil magnetização das NP permanecem randomicamente orientados nas três direções. Na tentativa de superar os problemas decorrentes da falta de alinhamento magnético, trabalhos recentes sugerem que NP alongadas em sistemas auto-organizados orientados perpendicularmente a superfície do substrato como possível solução para a textura e alinhamento magnético. Até o presente momento, as sínteses de nanobastões (NB) e de nanofios (NF) de FePt reportadas na literatura levam a obtenção de NP na fase cúbica de face centrada (fcc), a qual possui baixa anisotropia magnetocristalina e se mostrou termicamente instável, resultando em NP esferoidais após o processo de recozimento para a transformação da fase fcc para fct. Neste trabalho, NP de Fe55Pt55 com tamanho e composição química controlada e morfologia de nanofios e nanobastões foram sintetizadas através da adequação do método do poliol modificado. Além disso, as condições de sínteses foram ajustadas para a obtenção direta das NP na fase fct. Sistemas auto-organizados de NB orientados longitudinalmente ou perpendicularmente em arranjos hexagonais compactos foram obtidos utilizando, respectivamente, ácido oléico (AO) e oleilamina (Oam) ou hexadecilamina (HDA) como agentes espaçadores. Sistemas de NB orientados perpendicularmente com alinhamento magnético devido à anisotropia de forma combinado com as propriedades magnéticas resultantes da fase parcialmente tetragonal obtida sugerem um forte candidato a aplicação em UHMR com densidade de gravação magnética na ordem de terabits/pol2. / Recently, self-assembled FePt nanoparticles (NP) in face-centered tetragonal phase (fct) has been synthesizes as potential candidates for Ultra-High Magnetic Recording Systems (UHMR) due to high magnetocrystalline anisotropy. However, the magnetic alignment of these self-assembled fct-FePt nanoparticles also has been a constant limiting factor, since the axes of easy magnetization of spherical nanoparticles are presented randomly oriented in three directions. Concerning to avoid these restrictions arising from magnetic alignment, one-dimensional NP perpendicularly oriented on the magnetic medium surface has been reported as a possible solution for texture and magnetic alignment. To date, the reported nanorods (NR) and nanowires (NW) synthesized in the literature showed face centered cubic phase (fcc) which present poor magnetocrystalline anisotropy, instead the fct desirable phase, and were found to be thermally unstable resulting in spheroidal NP after annealing required to phase transformation from fcc to fct. In this work, Fe55Pt45 NP with morphologies varying from nanospheres, NR with different lengths up to NW were synthesized by a modified polyol process. Furthermore, the synthesis conditions were adjusted to obtain FePt NP directly in fct phase. Either longitudinal or perpendicular self-assembled NR systems in a hexagonal compact array were obtained using oleic acid (OA) and oleylamine (Oam) or hexadecylamine (HAD), respectively, as molecular organic spacers. Perpendicularly oriented NR system led to magnetic alignment due to shape anisotropy and combined with the magnetic properties due to partial tetragonal phase suggest a strong future candidate to ultra-high magnetic density recording applications capable to achieve density of Terabits/in2.

<p>The demand for the faster information transport and better computational abilities is ever increasing. In the last few decades, the electronic industry has met this requirement by increasing the number of transistors per square inch. This lead to the scaling of devices to tens of nm. However, the speed of the electronics is limited to few GHz. Using light, the operating speed of photonic devices can be much larger than GHz. But the photonic devices are diffraction limited and hence the size of photonic device is much larger than the electronic components. Plasmonics is an emerging field with light-induced surface excitations, and can manipulate the light at nanoscale. It can bridge the gap between electronics and photonics. </p> <p>With the present scaling of devices to few nm, the scientific community is looking for alternatives for continued progress. This has opened up several promising routes recently, including two-dimensional materials, quantum computing, topological computing, spintronics and valleytronics. The discovery of graphene has led to the immense interest in the field of two-dimensional materials. Two dimensional-materials have extraordinary properties compared to its bulk. This work discusses the applications of plasmonics in this emerging field of two-dimensional materials and for heat assisted magnetic recording.</p> <p>Black phosphorus is an emerging low-direct bandgap two-dimensional semiconductor, with anisotropic optical and electronic properties. It has high mobility and is promising for photo detection at infrared wavelengths due to its low band gap. We demonstrate two different plasmonic designs to enhance the photo responsivity of black phosphours by localized surface plasmons. We use bowtie antenna and bowtie apertures to increase the absorption and polarization selectivity respectively. Plasmonic structures are designed by numerical electromagnetic simulations, and are fabricated to experimentally demonstrate the enhanced photo responsivity of black phosphorus. </p> <p>Next, we look at another emerging two-dimensional material, bismuth telluride selenide (Bi₂Te₂Se). It is a topological insulator with an insulating bulk but conducting electronic surface states. These surface states are Dirac like, similar to graphene and can lead to exotic plasmonic phenomena. We investigated the optical properties of Bi₂Te₂Se and found that the bulk is plasmonic below 650 nm wavelength. We study the distinct surface plasmons arising from the bulk and surface state of the topological insulator, Bi₂Te₂Se. The propagating surface plasmons at a nanoscale slit in Bi₂Te₂Se are imaged using near-field scanning optical microscopy. The surface state plasmons are studied with a below band gap excitation of 10.6 µm wavelength and the surface plasmons of the bulk are studied with a visible wavelength of 633 nm. The surface state plasmon wavelength is 100 times shorter than the incident wavelength in sharp contrast to the plasmon wavelength of the bulk. </p> <p>Next, we look at the application of plasmonics in heat assisted magnetic recording (HAMR). HAMR is one of the next generation data storage technology that can increase the areal density to beyond 1 Tb/in². Near-field transducer (NFT) is a key component of the HAMR system that locally heats the recording medium by concentrating light below the diffraction limit using surface plasmons. In this work, we use density-based topology optimization for inverse design of NFT for a desired temperature profile in the recording medium. We first perform an inverse thermal calculation to obtain the required volumetric heat generation (electric field) for a desired temperature profile. Then an inverse electromagnetic design of NFT is performed for achieving the desired electric field. NFT designs for both generating a small heated spot size and a heated spot with desired aspect ratio in recording medium are demonstrated. The effect of waveguide, write pole and moving recording medium on the heated spot size is also investigated. </p>

<div>The response time of magnetization switching in current spintronic devices is limited to nanosecond timescales due to the precessional motion of the magnetization during reversal. To overcome this limit two routes of investigation leading to novel recording and logic devices are considered in this thesis: 1) Magnetic tunnel junction structures where the recording and reference layers are replaced by synthetic ferrimagnets and switching is induced by spin transfer torque and 2) Hybrid magneto-photonic devices where switching is induced by plasmon-enhanced all-optical switching. To circumvent limitations of the materials and magnetic properties of CoFeB, the most utilized alloy in spintronics, hcp-CoCrPt, a material that exhibits superior perpendicular anisotropy and thermal stability, is chosen as the ferromagnetic electrode in this work. Whereas actual devices based on the two schemes aforementioned are still in the process of being fabricated, through collaborative work with our international collaborators, this thesis describes fundamental magnetic and structural characterization needed for the realization of said ultrafast switching devices. The magnetic switching behavior of CoCrPt-Ru-CoCrPt synthetic ferrimagnets with perpendicular magnetic anisotropy have been studied in the temperature range from 2K to 300K. It was found that two sets of magnetic transitions occur in the CoCrPt-Ru-CoCrPt ferrimagnet systems studied. The first set exhibits three magnetization states in the 50K – 370K range, whereas the second involves only two states in the 2K and 50K range. The magnetic hysteresis curves of the synthetic ferrimagnet are assessed using an energy diagram technique which accurately describes the competition between interlayer exchange coupling energy, Zeeman energy, and anisotropy energy in the system. This energy diagram analysis is then used to predict the changes in the magnetic hysteresis curves of the synthetic ferrimagnet from 200K to 370K. This represents the potential operation temperature extrema that a synthetic ferrimagnet could be expected to operate at, were it to be utilized as a free layer in a memory or sensor spintronic device in the device configuration described in this dissertation.</div><div>Circularly polarized fs laser pulses generate large opto-magnetic fields in magnetic materials, through the inverse Faraday effect. These fields are attributed to be largely responsible for achieving ultrafast all-optical magnetization switching (AOS). All experimental demonstrations of AOS thus far have been realized on thin films over micron-sized irradiated regions. To achieve magnetization switching speeds in the ps and potentially fs time regimes, this work proposes the use of surface plasmon resonances at the interface of hybrid magneto-photonic heterostructures. In addition to the ability of plasmon resonances to confine light in the nm scale, the resonant excitation can largely enhance induced opto-magnetic fields in perpendicular magnetic anisotropy materials. This requires strong spin-photon coupling between the plasmonic and the magnetic materials, which thus requires the minimization of seed layers used for growth of the magnetic layer. This work reports on the development of ultrathin (1 nm thick) interlayers to control the growth orientation of hcp-Co alloys grown on the refractory plasmonic material, TiN, to align the magnetic axis out-of-plane. CoCrPtTa seed layers down to 1 nm were developed to seed the growth of CoCrPt, and the dependence of the quality of the CoCrPt is investigated as Ta composition is varied in the seed layer. Whereas bismuth iron garnet (BIG) meets the magneto-optical requirements for a hybrid magneto-photonic material, its magnetic and structural properties are highly sensitive to the Bi:Fe ratio and must be grown epitaxially on single crystalline substrates. Therefore, in this work we have investigated alternative materials that offer superior magnetic properties and are amenable to growth on inexpensive substrates. Opto-magnetic field enhancements up to 2.6x in Co-ferrite magneto-photonic heterostructures have been obtained via finite element analysis modelling. Alternative materials for plasmon-enhanced all-optical switching such as Co/Pd multilayers have also been investigated. Successful growth of Co/Pd multilayers on TiN using ultrathin Ti interlayers has been achieved. </div><div><br></div>

Two dimensional magnetic recording (TDMR) achieves high areal densities by reducing the size of a bit comparable to the size of the magnetic grains resulting in two dimensional (2D) inter symbol interference (ISI) and very high media noise. Therefore, it is critical to handle the media noise along with the 2D ISI detection. In this paper, we tune the generalized belief propagation (GBP) algorithm to handle the media noise seen in TDMR. We also provide an intuition into the nature of hard decisions provided by the GBP algorithm. The performance of the GBP algorithm is evaluated over a Voronoi based TDMR channel model where the soft outputs from the GBP algorithm are used by a belief propagation (BP) algorithm to decode low-density parity check (LDPC) codes.

Advanced scanning magnetoresistive microscopy (SMRM) — a robust magnetic imaging and probing technique — is presented. It utilizes conventional recording heads of a hard disk drive as sensors. The spatial resolution of modern tunneling magnetoresistive sensors is nowadays comparable with more commonly used magnetic force microscopes. Important advantages of SMRM are the ability to detect pure magnetic signals directly proportional to the out-of-plane magnetic stray field, negligible sensor stray fields, and the ability to apply local bipolar magnetic field pulses up to 10 kOe with bandwidths from DC up to 1 GHz. The performance assessment of this method and corresponding best practices are discussed in the first section of this work. An application example of SMRM, the study on chemically ordered L10 FePt is presented in a second section. A constructed heater unit of SMRM opens the path to investigate temperature-dependent magnetic properties of the medium by recording and imaging at elevated temperatures. L10 FePt is one of the most promising materials to reach limits in storage density of future magnetic recording devices based on heat-assisted magnetic recording (HAMR). In order to be implemented in an actual recording scheme, the medium Curie temperature should be lowered. This will reduce the power requirements, and hence, wear and tear on a heat source — integrated plasmonic antenna. It is expected that the exchange coupling of FePt to thin Fe layers provides high saturation magnetization and elevated Curie temperature of the composite. The addition of Cu allows adjusting the magnetic properties such as perpendicular magnetic anisotropy, coercivity, saturation magnetization, and Curie temperature. This should lead to a lowering of the switching field of the hard magnetic FeCuPt layer and a reduction of thermally induced recording errors. In this regard, the influence of the Fe layer thickness on the switching behavior of the hard layer was investigated, revealing a strong reduction for Fe layer thicknesses larger than the exchange length of Fe. The recording performance of single-layer and bilayer structures was studied by SMRM roll-off curves and histogram methods at temperatures up to 180 °C In the last section of this work, SMRM advantages are demonstrated by various experiments on a two-dimensional magnetic vortex lattice. Magnetic vortex is a peculiar complex magnetization configuration which typically appears in a soft magnetic structured materials. It consists of two coupled sub-systems: the core, where magnetization vector points perpendicular to the structure plane, and the curling magnetization where magnetic flux is rotating in-plane. The unique properties of a magnetic vortex making it an object of a great research and technological interest for spintronic applications in sensorics or data storage. Manipulation of the vortex core as well as the rotation sense by applying a local field pulse is shown. A spatially resolved switching map reveals a significant "write window" where vortex cores can be addressed correctly. Moreover, the external in-plane magnet extension unit allow analyzing the magnetic vortex rotational sense which is extremely practical for magnetic coupling investigations of magnetic coupling phenomena.

<p>U radu su predstavljene nove tehnike dekodovanja maximum<br />transition run (MTR) kodova na principu finog odlučivanja.<br />Analizirane su performanse ovih tehnika u kombinaciji sa<br />za&scaron;titnim LDPC kodom na kanalima za magnetsko memorisanje<br />informacija, sa posebnim osvrtom na model kanala sa<br />dve staze za zapisivanje i dve glave za čitanje. U modelu kanala<br />je kori&scaron;ćena idealna E2PR4 ekvalizacija staza adekvatna<br />za sisteme sa visokom gustinom magnetskog zapisa.</p> / <p>This thesis presents the novel soft-decision decoding techniques<br />for decoding of the maximum transition run (MTR)<br />codes. Performances of such techniques have been analyzed<br />in combination with error correcting LDPC code over magnetic<br />recording channels, especially the two-track two-head<br />channel model. Ideal E2PR4 track equalization suitable for<br />high density magnetic recording has been used.</p>

The concept of percolated perpendicular media (PPM) for magnetic data storage is expected to surpass the areal storage density of 1 Tbit in -², which is regarded as the fundamental limit of conventional granular CoCrPt:oxide based recording media. PPM consist of a continuous ferromagnetic thin film with densely distributed defects acting as pinning sites for magnetic domain walls. In this study, practical realizations of PPM were fabricated by the deposition of [Co/Pt]8 multilayers with perpendicular magnetic anisotropy onto nanoperforated templates with various perforation diameters and periods. The structural defects given by the templates serve as pinning sites for the magnetic domain walls within the [Co/Pt]8 multilayers. Magnetometry at both the integral and the local level was employed to investigate the influence of the template on the magnetization reversal and the domain wall pinning. It was found, that magnetic domains can be pinned at the ultimate limit, between three adjacent pinning sites. The coercivity and the depinning field, which both are a measure for the strength of the magnetic domain wall pinning, were found to increase with increasing perforation diameter. The size of magnetic domains within the magnetic film appeared not to depend solely on the diameter of the nanoperforations or on the period of the template, but on the ration between diameter and period. By means of micromagnetic simulations it was found, that the presence of ferromagnetic material within the pinning site given supports the pinning of magnetic domain walls, compared to a pinning site that is solely given by a hole in the magnetic thin film. Investigation of the evolution of the magnetization in magnetic fields smaller than the coercive field revealed, that the energy barrier against thermally induced magnetization reversal is sufficiently large to provide long-term (> 10 years) stability of an arbitrary magnetization state. This could also be qualitatively supported by micromagnetic simulations. Static read/write tests with conventional hard disk recording heads revealed the possibility of imprinting bit patterns into the PPM under study. The minimum bit pitch that could be read back thereby depended on the period of the nanoperforated template.