NiTiHf high temperature shape memory alloys are attractive due to their high operating temperatures (>100 oC) and acceptable transformation strain compared to NiTi. However, NiTiHf has limitations due to their lack of ductility and low strength, resulting in poor shape memory properties. In this study, Pd has been added to NiTiHf alloys in an attempt to improve their shape memory behavior. A combined approach of quaternary alloying and precipitation strengthening was used. The characterization of a Ni45.3Ti29.7Hf20Pd5 (at. %) polycrystalline alloy was performed in compression after selected aging treatments. Transmission electron microscopy was used to reveal the precipitation characteristics. Differential scanning calorimetry, load-biased (constant stress) thermal cycling experiments and isothermal stress cycling (superelasticity) tests were utilized to investigate the effects of aging temperature and time. The crystal structure and lattice parameters were determined from X-ray diffraction analysis. Significant improvement in the shape memory properties of Ni45.3Ti29.7Hf20Pd5 was obtained through precipitation strengthening. The effects of chemical composition (effects of Hf content replacing with Ti) on the shape memory properties of NiTiHfPd alloys were also revealed. Orientation dependence of the shape memory properties in aged Ni45.3Ti29.7Hf20Pd5 single crystals were investigated along the [111], [011] and [-117] orientations. The shape memory properties were determined to be strong functions of orientation and aging condition. A perfect superelastic behavior (with no irrecoverable strain) with 4.2 % recoverable compressive strain was obtained in the solutionized condition at stress levels as high as 2.5 GPa while 2 % shape memory strain under a bias stress of 1500 MPa was possible in an aged [111] oriented single crystal. A mechanical hysteresis of 1270 MPa at -30 oC, which is the largest mechanical hysteresis that the authors are aware of in the SMA literature, was observed along the [111] orientation. Finally, thermodynamic analyses were conducted to reveal the relationships between microstructure (e.g. precipitate size and interparticle distances) and martensitic transformations in Ni45.3Ti29.7Hf20Pd5 SMAs. Precipitate characteristics were found to be effective on the elastic energies for nucleation, propagation with dissipation energy and these energies influenced the TTs and the constant stress shape memory properties in Ni45.3Ti29.7Hf20Pd5 alloys.

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The feasibility of using superelastic shape memory alloys in the retrofit of multiple frame bridges is investigated. First, three shape memory alloy constitutive models with various levels of complexity are compared in order to determine the significance of including subloops and cyclic loading effects on the structural response. The results show that the structural response is more sensitive to the shape memory alloys strength degradation and residual deformation than the sublooping behavior. Next, two parametric studies are conducted to explore the sensitivity of hinge opening to the mechanical behavior of the superelastic shape memory alloys. The first study is focused on the hysteretic properties of the alloy that could vary depending on the chemical composition or the manufacturing process of the alloy, while the second study targets the changes in the mechanical behavior of shape memory alloys resulting from the variability in the ambient temperature. The results show that the hysteretic behavior of shape memory alloys has only a slight effect on the bridge hinge opening as long as the recentering property is maintained. A detailed study on the effect of temperature shows that a reduction in the ambient temperature tends to negatively affect the hinge opening while an increase in temperature results in a slight improvement. Next, a parametric study is conducted to examine the effectiveness of shape memory alloy retrofit devices in limiting hinge openings in bridges with various properties. In addition, a comparison is made with other devices such as conventional steel restrainers, metallic dampers, and viscoelastic solid dampers. The results illustrate that superelastic shape memory alloys are superior in their effectiveness compared to other devices in the case of bridges with moderate period ratios and high level of ductility, especially when subjected to strong earthquakes.

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Selective Laser Melting (SLM) of Additive Manufacturing is an attractive fabrication method that employs CAD data to selectively melt the metal powder layer by layer via a laser beam and produce a 3D part. This method not only opens a new window in overcoming traditional NiTi fabrication problems but also for producing porous or complex shaped structures. The combination of SLM fabrication advantages with the unique properties of NiTi alloys, such as shape memory effect, superelasticity, high ductility, work output, corrosion, biocompatibility, etc. makes SLM NiTi alloys extremely promising for numerous applications. The SLM process parameters such as laser power, scanning speed, spacing, and strategy used during the fabrication are determinant factors in composition, microstructural features and functional properties of the SLM NiTi alloy. Therefore, a comprehensive and systematic study has been conducted over Ni50.8 Ti49.2 (at%) alloy to understand the influence of each parameter individually. It was found that a sharp [001] texture is formed as a result of SLM fabrication which leads to improvements in the superelastic response of the alloy. It was perceived that transformation temperatures, microstructure, hardness, the intensity of formed texture and the correlated thermo-mechanical response are changed substantially with alteration of each parameter. The provided knowledge will allow choosing optimized parameters for tailoring the functional features of SLM fabricated NiTi alloys. Without going through any heat treatments, 5.77% superelasticity with more than 95% recovery ratio was obtained in as-fabricated condition only with the selection of right process parameters. Additionally, thermal treatments can be utilized to form precipitates in Ni-rich SLM NiTi alloys fabricated by low energy density. Precipitation could significantly alter the matrix composition, transformation temperatures and strain, critical stress for transformation, and shape memory response of the alloy. Therefore, a systematic aging study has been performed to reveal the effects of aging time and temperature. It was found that although SLM fabricated samples show lower strength than the initial ingot, heat treatments can be employed to make significant improvements in shape memory response of SLM NiTi. Up to 5.5% superelastic response and perfect shape memory effect at stress levels up to 500 MPa was observed in solutionized Ni-rich SLM NiTi after 18h aging at 350ºC. For practical application, transformation temperatures were even adjusted without solution annealing and superelastic response of 5.5% was achieved at room temperature for 600C-1.5hr aged Ni-rich SLM NiTi. The effect of porosity on strength and cyclic response of porous SLM Ni50.1 Ti49.9 (at%) were investigated for potential bone implant applications. It is shown that mechanical properties of samples such as elastic modulus, yield strength, and ductility of samples are highly porosity level and pore structure dependent. It is shown that it is feasible to decrease Young’s modulus of the SLM NiTi up to 86% by adding porosity to reduce the mismatch with that of a bone and still retain the shape memory response of SLM fabricated NiTi. The shape memory effect, as well as superelastic response of porous SLM Ni50.8Ti49.2,were also investigated at body temperature. 32 and 45% porous samples with similar behaviors, recovered 3.5% of 4% deformation at first cycle. The stabilized superelastic response was obtained after clicking experiments.

Shape Memory Alloys (SMAs) exhibit the ability to undergo large deformations but can recover permanent strains via heating (shape memory effect) or when stress is removed (superelastic effect). This study evaluates the comparative seismic performance of steel moment resisting frames (SMRFs) with innovative beam-to-column connections that use SMA bars as connecting elements. The performance evaluation studies are based on two types of SMA beam-to-column connections: (1) superelastic SMA connections with recentering capability; (2) martensitic SMA connections with high energy dissipation capacity. Fiber models for these SMA connections are implemented in the OpenSees finite element framework, and are verified against data from full-scale experimental tests that were performed on a prototype SMA connection in previous research at Georgia Tech. Three- and a nine-story model buildings with partially-restrained (PR) moment frames are selected from the SAC Phase II Project as case studies. Non-linear time history analyses on these model buildings, with and without SMA connections, are conducted using suites of ground acceleration records from the SAC Phase II project that represent different seismic hazard levels. Several SMA connections are designed for each structure, and their effect on peak and residual inter-story drift angles, connection rotations, and normalized dissipated hysteretic energy demands are investigated to determine the most suitable design. Finally, the seismic demands on the model buildings with conventional PR and selected SMA connections are evaluated in a probabilistic framework. The resulting seismic demand relationships are used to assess the effectiveness of the SMA connections in enhancing the building performance over a range of demand levels. The results of this performance evaluation show that the SMA connections are most effective in controlling structural response under high levels of seismic intensity leading to large deformation demands. In particular, the energy dissipating SMA connections are found to be effective in reducing maximum deformation demands, while the recentering SMA connections are more suitable for controlling residual deformations in the structure.

Since NiTi shape memory alloy (SMA) was discovered in the early 1960s, great progress has been made in understanding the properties and mechanisms of NiTi SMA and in developing associated products. For several decades, most of the scientific research and industrial interests on NiTi SMA has focused on its superelastic applications in the biomedical field and shape memory based “smart” devices, which involves the low strain rate (around 0.001 s^-1) response of NiTi SMA. Due to either stress-induced martensite phase transformation or stress induced martensite variant reorientation under the applied load, NiTi SMA has exhibited a high damping capacity in both austenitic and martensitic phase. Recently, there has been an increasing interest in exploitation of the high damping capacity of NiTi SMA to develop high strain rate related applications such as seismic damping elements and energy absorbing devices. However, a systematic study on the influence of strain, strain rate and temperature on the mechanical properties, phase transformation, microstructure and crystal structure is still limited, which leads to the difficulties in the design of products being subjected to high strain rate loading conditions. The four main objectives of the current research are: (1) achieve the single loading and the control of strain, constant strain rate and temperature in high strain rate compression tests of NiTi SMA specimens using Kolsky (split Hopkinson) compression bar; (2) explore the high strain rate compressive responses of NiTi SMA specimens as a function of strain (1.4%, 1.8%, 3.0%, 4.8%, and 9.6%), strain rate (400, 800 and 1200 s^-1), and temperature (room temperature (294 K) and 373 K); (3) characterize and compare the microstructure, phase transformation and crystal structure of NiTi SMAs before and after high strain rate compression; and (4) correlate high strain rate deformation with the changes of microstructure, phase transformation characteristics and crystal structure. Based on the results from this study, it was found that: (1) the compressive stress strain curves of martensitic NiTi SMAs under quasi-static loading conditions are different from those under high strain rate loading conditions, where higher strain hardening was observed; (2) the critical stress and stress plateau of martensitic NiTi SMAs are sensitive to the strain rate and temperature, especially at 373K, which results from the interplay between strain hardening and thermal softening; (3) the microstructure of martensitic NiTi SMA has changed with increasing strain rate at room temperature (294 K), resulting in the reduction in the area of ordered martensite region, while that area increases after deformation at elevated temperature (373K); (4) the phase transformation characteristic temperatures are more sensitive to deformation strain than strain rate; (5) the preferred crystal plane of martensitic NiTi SMA has changed from (11 ̅1)M before compression to (111)M after compression at room temperature (294 K), while the preferred plane remains exactly the same for martensitic NiTi SMA before and after compression at 373 K. Lastly, dynamic recovery and recrystallization are also observed after deformation of martensitic NiTi SMA at 373K.

NiTi-based shape memory alloys (SMAs) offer a good combination of high-strength, ductility, corrosion resistance, and biocompatibility that has served them well and attracted the attention of many researchers and industries. The alloys unique thermo-mechanical ability to recover their initial shape after relatively large deformations by heating or upon unloading due to a characteristic reversible phase transformation makes them useful as damping devices, solid state actuators, couplings, etc. However, there is a need to increase the temperature of the characteristic phase transformation above 150 °C, especially in the aerospace industry where high temperatures are often seen. Prior researchers have shown that adding ternary elements (Pt, Pd, Au, Hf and Zr) to NiTi can increase transformation temperatures but most of these additions are extremely expensive, creating a need to produce cost-effective high temperature shape memory alloys (HTSMAs). Thus, the main objective of this research is to examine the relatively unstudied NiTiZr system for the ability to produce a cost effective and formable HTSMA. Transformation temperatures, precipitation paths, processability, and high-temperature oxidation are examined, specifically using high energy X-ray Diffraction (XRD) measurements, in NiTi-20 at.% Zr. This is followed by an in situ XRD study of the phase growth kinetics of the favorable H-phase nano precipitates, formed in NiTiHf and NiTiZr HTSMAs, based on prior thermo-mechanical processing in a commercial NiTi-15 at.% Hf HTSMA to examine the final processing methods and aging characteristics. Through this research, knowledge of the precipitation paths in NiTiZr and NiTiHf HTSMAs is extended and methods for characterization of phases and strains using high energy XRD are elucidated for future work in the field.