The objective of this study is to examine core-shell type plasmonic metamaterials aimed at the development of materials with unique electromagnetic properties. The building blocks of metamaterials under study consist of gold as a metal component, and silica and precipitated calcium carbonate (PCC) as the dielectric media. The results of this study demonstrate important applications of the core-shells including scattering suppression, airborne obscurants made of fractal gold shells, photomodification of the fractal structure providing windows of transparency, and plasmonics core-shell with a gain shell as an active device. Plasmonic resonances of the metallic shells depend on their nanostructure and geometry of the core, which can be optimized for the broadband extinction. Significant extinction from the visible to mid-infrared makes fractal shells very attractive as bandpass filters and aerosolized obscurants. In contrast to the planar fractal films, where the absorption and reflection equally contribute to the extinction, the shells' extinction is caused mainly by the absorption. This work shows that the Mie scattering resonance of a silica core with 780 nm diameter at 560 nm is suppressed by 75% and only partially substituted by the absorption in the shell so that the total transmission is noticeably increased. Effective medium theory supports our experiments and indicates that light goes mostly through the epsilon-near-zero shell with approximately wavelength independent absorption rate. Broadband extinction in fractal shells allows as well for a laser photoburning of holes in the extinction spectra and consequently windows of transparency in a controlled manner. Au fractal nanostructures grown on PCC flakes provide the highest mass normalized extinction, up to 3 m^2/g, which has been demonstrated in the broad spectral range. In the nanoplasmonic field active devices consist of a Au nanoparticle that acts as a cavity and the dye molecules attached to it via thin silica shell as the active medium. Such kind of devices is considered as a nano-laser or nano-amplifier. The fabricated nanolasers were studied for their photoluminescence kinetic properties. It is shown that the cooperative effects due to the coupling of dye molecules via Au nanoparticle plasmons result in bi-exponential emission decay characteristics in accord with theory predictions. These bi-exponential decays involve a fast superradiant decay, which is followed by a slow subradiant decay. To summarize, this work shows new attractive properties of core-shell nanoparticles. Fractal Au shells on silica cores prove to be a good scattering suppressor and a band pass filter in a broadband spectral range. They can also be used as an obscurant when PCC is used as the core material. Finally, gold nanoparticles coated with silica with dye results in bi-exponential decays.

Since its inception, the field of nonlinear optics has only increased in importance as a result of a growing number of applications. The efficiency of all parametric nonlinear optical processes is limited by challenges associated with phase-matching requirements. To address this constraint, a variety of approaches, such as quasi-phase-matching, birefringent phase matching, and higher-order-mode phase matching have historically been used to phase-match interactions. However, the methods demonstrated to date suffer from the inconvenience of only being phase-matched for one specific arrangement of beams, typically co-propagating along the same axis. This stringency of the phase-matching requirement results in cumbersome optical configurations and large footprints for integrated devices. In this thesis, we show that phase-matching requirements in parametric nonlinear optical processes may be satisfied for all orientations of input and output beams when using zero-index media: a condition of omnidirectional phase matching. To validate this theory, we perform experimental demonstrations of phase matching for five separate FWM beam configurations to confirm this phenomenon. Our measurements constitute the first experimental observation of the simultaneous generation of a forward- and backward-propagating signal with respect to the pump beams in a medium longer than a free-space optical wavelength, allowing us to determine the coherence length of our four-wave-mixing process. Our demonstration includes nonlinear signal generation from spectrally distinct counter-propagating pump and probe beams, as well as the excitation of a parametric process with the probe beam's wave vector orthogonal to the wave vector of the pump beam. By sampling all of these beam configurations, our results explicitly demonstrate that the unique properties of zero-index media relax traditional phase-matching constraints, and provide strong experimental evidence for the existence of omnidirectional phase matching in zero-index media. This property can be exploited to facilitate nonlinear interactions and miniaturize nonlinear devices, and adds to the established exceptional properties of low-index materials.

Yes / This paper presents a novel on-chip antenna using standard CMOS-technology based on metasurface implemented on two-layers polyimide substrates with a thickness of 500 μm. The aluminium ground-plane with thickness of 3 μm is sandwiched between the two-layers. Concentric dielectric-rings are etched in the ground-plane under the radiation patches implemented on the top-layer. The radiation patches comprise concentric metal-rings that are arranged in a 3 × 3 matrix. The antennas are excited by coupling electromagnetic energy through the gaps of the concentric dielectric-rings in the ground-plane using a microstrip feedline created on the bottom polyimide-layer. The open-ended feedline is split in three-branches that are aligned under the radiation elements to couple the maximum energy. In this structure, the concentric metal-rings essentially act as series left-handed capacitances CL that extend the effective aperture area of the antenna without affecting its dimensions, and the concentric dielectric rings etched in the ground-plane act as shunt left-handed inductors LL, which suppress the surface-waves and reduce the substrates losses that leads to improved bandwidth and radiation properties. The overall structure behaves like a metasurface that is shown to exhibit a very large bandwidth of 0.350–0.385 THz with an average radiation gain and efficiency of 8.15dBi and 65.71%, respectively. It has dimensions of 6 × 6 × 1 mm3 that makes it suitable for on-chip implementation. / This work is partially supported by RTI2018-095499-B-C31, Funded by Ministerio de Ciencia, Innovación y Universidades, Gobierno de España (MCIU/AEI/FEDER,UE), and innovation programme under grant agreement H2020-MSCA-ITN-2016 SECRET-722424 and the fnancial support from the UK Engineering and Physical Sciences Research Council (EPSRC) under grant EP/E022936/1. / Research Development Fund Publication Prize Award winner, March 2020

The first part of this Thesis deals with the analysis of piecewise-smooth mechanical systems and the definition of special stability criteria in presence of non-conservative follower forces. To illustrate the peculiar stability properties of this kind of dynamical system, a reference 2 d.o.f. structure has been considered, composed of a rigid bar, with one and constrained to slide, without friction, along a curved profile, whereas the other and is subject to a follower force. In particular, the curved constraint is assumed to be composed of two circular profiles, with different and opposite curvatures, defining two separated subsystems. Due to this jump in the curvature, located at the junction point between the curved profiles, the entire mechanical structure can be modelled by discontinuous equations of motion, the differential equations valid in each subsystem can be combined, leading to the definition of a piecewise-smooth dynamical system. When a follower force acts on the structure, an unexpected and counterintuitive behaviour may occur: although the two subsystems are stable when analysed separately, the composed structure is unstable and exhibits flutter-like exponentially-growing oscillations. This special form of instability, previously known only from a mathematical point of view, has been analysed in depth from an engineering perspective, thus finding a mechanical interpretation based on the concept of non-conservative follower load. Moreover, the goal of this work is also the definition of some stability criteria that may help the design of these mechanical piecewise-smooth systems, since classical theorems cannot be used for the investigation of equilibrium configurations located at the discontinuity. In the literature, this unusual behaviour has been explained, from a mathematical perspective, through the existence of a discontinuous invariant cone in the phase space. For this reason, starting from the mechanical system described above, the existence of invariant cones in 2 d.o.f. mechanical systems is investigated through Poincaré maps. A complete theoretical analysis on piecewise-smooth dynamical systems is presented and special mathematical properties have been discovered, valid for generic 2~d.o.f. piecewise-smooth mechanical systems, which are useful for the characterisation of the stability of the equilibrium configurations. Numerical tools are implemented for the analysis of a 2~d.o.f. piecewise-smooth mechanical system, valid for piecewise-linear cases and extendible to the nonlinear ones. A numerical code has been developed, with the aim of predicting the stability of a piecewise-linear dynamical system a priori, varying the mechanical parameters. Moreover, “design maps” are produced for a given subset of the parameters space, so that a system with a desired stable or unstable behaviour can easily be designed. The aforementioned results can find applications in soft actuation or energy harvesting. In particular, in systems devoted to exploiting the flutter-like instability, the range of design parameters can be extended by using piecewise-smooth instead of smooth structures, since unstable flutter-like behaviour is possible also when each subsystem is actually stable. The second part of this Thesis deals with the numerical analysis of an elastic cloak for transient flexural waves in Kirchhoff-Love plates and the design of special metamaterials for this goal. In the literature, relevant applications of transformation elastodynamics have revealed that flexural waves in thin elastic plates can be diverted and channelled, with the aim of shielding a given region of the ambient space. However, the theoretical transformations which define the elastic properties of this “invisibility cloak” lead to the presence of a strong compressive prestress, which may be unfeasible for real applications. Moreover, this theoretical cloak must present, at the same time, high bending stiffness and a null twisting rigidity. In this Thesis, an orthotropic meta-structural plate is proposed as an approximated elastic cloak and the presence of the prestress has been neglected in order to be closer to a realistic design. With the aim of estimating the performance of this approximated cloak, a Finite Element code is implemented, based on a sub-parametric technique. The tool allows the investigation of the sensitivity of specific stiffness parameters that may be difficult to match in a real cloak design. Moreover, the Finite Element code is extended to investigate a meta-plate interacting with a Winkler foundation, to analyse how the substrate modulus transforms in the cloak region. This second topic of the Thesis may find applications in the realization of approximated invisibility cloaks, which can be employed to reduce the destructive effects of earthquakes on civil structures or to shield mechanical components from unwanted vibrations.

Various nanostructured materials display unique and interesting optical properties. Specific nanoscale objects discussed in an experimental perspective in this dissertation include optical metamaterials, surface plasmon sensors, and two-dimensional materials. These nanoscale objects were fabricated, investigated optically, and their applications are assessed. First, one-dimensional magnetic gratings were studied, followed by their two-dimensional analog, the so-called "fishnet." Both were fabricated, characterized, and their properties, such as waveguiding modes, are examined. Interestingly, these devices can exhibit optical magnetism and even negative refraction; however, their general characterization at oblique incidence is challenging due to diffraction. Here, a new method of optical characterization of metamaterials which takes into account diffraction is presented. Next, surface plasmon resonance (SPR) was experimentally used in two schemes, for the first time, to determine the transition layer characteristics between a metal and dielectric. The physics of interfaces, namely the singularity of electric permittivity and how it can be electrically shifted, becomes clearer owing to the extreme sensitivity of SPR detection mechanisms. Finally, ultra-thin two-dimensional semiconducting materials had their radiative lifetime analyzed. Their lifetimes are tuned both by number of atomic layers and applied voltage biasing across the surface, and the changes in lifetime are suspected to be due to quenching or enhancement of non-radiative process rates.

I denna avhandling studeras elektromagnetisk vågutbredning i graderade materialkompositer med extraordinära egenskaper. Två sådana materialkompositsystem studeras särskilt, med hjälp av både analytiska och beräkningstekniska elektromagnetiska metoder. Det första systemet används för utvecklingen av en lovande icke-invasiv metod för cancerbehandling, som bygger på att tumören med insatta guldnanopartiklar värms upp med hjälp av mikrovågsstrålning. En vågledarstruktur föreslås bestående av ett tunt dielektriskt skikt med en kontinuerlig graderad materialövergång till dess omgivande material till vardera sidan av skiktet. Det tunna lagret består av cancervävnad med insatta guldnanopartiklar som drivs in i elektroforetisk svängning med hjälp av elektromagnetisk strålning. Analytiska lösningar för det givna vågledarproblemet erhålls, vilket möjliggör beräkning av absorptionskoefficienterna endast inom det tunna skiktet, vilket är viktigt för bedömning av genomförbarheten av den tänkta medicinska tillämpningen. De dispersiva dielektriska modellerna som beskriver de elektromagnetiska egenskaperna hos de relevanta biologiska vävnaderna föreslås och diskuteras. Numeriska simuleringar gjorda i COMSOL Multiphysics är i utmärkt överensstämmelse med och validerar de analytiska resultaten. Det andra systemet involverar vågutbredning från ett högerhänt material till ett vänsterhänt metamaterial i fri rymd. De två materialen är impedansmatchade, vilket säkerställer ingen reflektion, och det graderade gränssnittet mellan dem beskrivs av en kontinuerlig funktion. Metamaterialkompositer med rumsligt varierande materialparametrar har fått ett ökande teoretiskt och experimentellt intresse de senaste två decennierna. De är användbara för ett antal tillämpningar, såsom transformationsoptik. I denna uppsats diskuteras egenskaperna hos vänsterhänta material. Fältlösningarna till det impedansmatchade graderade gränssnittet härleds, och en numerisk modell utvecklas i COMSOL. Resultaten bekräftar de extraordinära egenskaperna hos vänsterhänta material. / In this thesis, electromagnetic wave propagation in graded material composites with extraordinary properties are studied. Two such material composite systems are studied in particular, using both analytical and computational electromagnetic methods. The first system is used for the development of a promising non-invasive method of cancer treatment based on heating the tumors with inserted gold nanoparticles by means of microwave radiation. A waveguide structure is proposed consisting of a thin dielectric layer with a continuous graded material transition to its surrounding materials to either side of the layer. The thin layer consists of cancer tissue with inserted gold nanoparticles that are driven into electrophoretic oscillation by means of electromagnetic radiation. Analytical solutions for the given waveguide problem are obtained, allowing the calculation of the absorption coefficients within the thin layer only, which is important for assessment of the feasibility of the envisioned medical application. The dispersive dielectric models describing the electromagnetic properties of the relevant biological tissues are proposed and discussed. Numerical simulations done in COMSOL Multiphysics are in excellent agreement with and validate the analytical results. The second system involves wave propagation from a right-handed material to a left-handed metamaterial in an open boundary system. The two materials are impedance-matched, thus ensuring no reflection, and the graded interface between them is described by a continuous function. Metamaterial composites with spatially varying material parameters have been given an increasing theoretical and experimental interest the last two decades. They are useful for a number of applications, such as transformation optics. In this thesis, the properties of left-handed media are discussed. The field solutions to the impedance-matched graded interface are derived, and a numerical model is developed in COMSOL. The results confirm the extraordinary properties of left-handed media. / <p>QC 20221129</p>

No description available.

<p>The thesis intends to explain in full detail the developed techniques and approaches for the modeling, design, and sensitivity analysis of nano-plasmoic structures. However, some examples are included for audiences of general microwave background. Although the thesis is mainly focused on simulation-based techniques, analytical and convex optimization approaches are also demonstrated. The thesis is organized into two parts. Part 1 includes Chapters 2-4, which cover the simulation-based modeling and sensitivity analysis approaches and their applications. Part 2 includes Chapters 5 and 6, which cover the analytical optimization approaches.</p> / <p>We propose novel techniques for modeling, adjoint sensitivity analysis, and optimization of photonic and nano-plasmonic devices. The scope of our work is generalized to cover microwave, terahertz and optical regimes. It contains original approaches developed for different categories of materials including dispersive and plasmonic materials. Artificial materials (metamaterials) are also investigated and modeled. The modeling technique exploits the time-domain transmission line modeling (TD-TLM) technique. Generalized adjoint variable method (AVM) techniques are developed for sensitivity analysis of the modeled devices. Although TLM-based, they can be generalized to other time-domain modeling techniques like finite difference time-domain method (FDTD) and time-domain finite element method (FEM).</p> <p>We propose to extend the application of TLM-based AVM to photonic devices. We develop memory efficient approaches that overcome the limitation of excessive memory requirement in TLM-based AVM. A memory reduction of 90% can be achieved without loss of accuracy and at a more efficient calculation procedure. The developed technique is applied to slot waveguide Bragg gratings and a challenging dielectric resonator antenna problem.</p> <p>We also introduce a novel sensitivity analysis approach for materials with dispersive constitutive parameters. To our knowledge, this is the first wide-band AVM approach that takes into consideration the dependence of material properties on the frequency. The approach can be utilized for design optimization of innovative nano-plasmonic structures. The design of engineered metamaterial is systematic and efficient. Beside working with engineered new designs, dispersive AVM can be utilized in bio-imaging applications. The sensitivity of the objective function with respect to dispersive material properties enables the exploitation of parameter and gradient based optimization for imaging in the terahertz and optical regimes. Material resonance interaction can be easily investigated by the provided sensitivity information.</p> <p>In addition to the developed techniques for simulation-based optimization, several analytical optimization algorithms are proposed to foster the parameter extraction and design optimization in terahertz and optical regimes. In terahertz time-domain spectroscopy, we have developed an efficient parameter based approach that utilizes the pre-known information about the material. The algorithm allows for the estimation of the optical properties of sample materials of unknown thicknesses. The approach has been developed based on physical analytical dispersive models. It has been applied with the Debye, Lorentz, Cole-Cole, and Drude model.</p> <p>Furthermore, we propose various algorithms for design optimization of coupled resonators. The proposed algorithms are utilized to transform a highly non-linear optimization problem into a linear one. They exploit an approximate transfer function of the coupled resonators that avoids negligible multiple reflections among them. The algorithms are successful for the optimization of very large-scale coupled microcavities (150 coupled ring resonators).</p> / Doctor of Philosophy (PhD)

Yes / In this review paper, a comprehensive study on the concept, theory, and applications of composite right/left-handed transmission lines (CRLH-TLs) by considering their use in antenna system designs have been provided. It is shown that CRLH-TLs with negative permittivity (ε <; 0) and negative permeability (μ <; 0) have unique properties that do not occur naturally. Therefore, they are referred to as artificial structures called “metamaterials”. These artificial structures include series left-handed (LH) capacitances (C L ), shunt LH inductances (L L ), series right-handed (RH) inductances (LR), and shunt RH capacitances (CR) that are realized by slots or interdigital capacitors, stubs or via-holes, unwanted current flowing on the surface, and gap distance between the surface and ground-plane, respectively. In the most cases, it is also shown that structures based on CRLH metamaterial-TLs are superior than their conventional alternatives, since they have smaller dimensions, lower-profile, wider bandwidth, better radiation patterns, higher gain and efficiency, which make them easier and more cost-effective to manufacture and mass produce. Hence, a broad range of metamaterial-based design possibilities are introduced to highlight the improvement of the performance parameters that are rare and not often discussed in available literature. Therefore, this survey provides a wide overview of key early-stage concepts of metematerial-based designs as a thorough reference for specialist antennas and microwave circuits designers. To analyze the critical features of metamaterial theory and concept, several examples are used. Comparisons on the basis of physical size, bandwidth, materials, gain, efficiency, and radiation patterns are made for all the examples that are based on CRLH metamaterialTLs. As revealed in all the metematerial design examples, foot-print area decrement is an important issue of study that have a strong impact for the enlargement of the next generation wireless communication systems. / This work was supported in part by the Ministerio de Ciencia, Innovación y Universidades, Gobierno de España (MCIU/AEI/FEDER, UE) under Grant RTI2018-095499-B-C31, in part by the Innovation Programme under Grant H2020-MSCA-ITN-2016 SECRET-722424, and in part by the financial support from the U.K. Engineering and Physical Sciences Research Council (EPSRC) under Grant EP/E022936/1.

The goal of this project is to study novel nanoscale excitation volumes, sensitive enoughto study individual chromophores and go on to study new and exciting self assemblyapproaches to this problem. Small excitation volumes may be engineered using light con-finement inside apertures in metal films. These apertures enhance fluorescence emissionrates, quantum yields, decrease fluorescence quenching, enable higher signal-to-noiseratios and allow higher concentration single chromophore fluorescence, to be studied byrestricting this excitation volume. Excitation volumes are reported on using the chro-mophore's fluorescence by utilising fluorescence correlation spectroscopy, which monitorsfluctuations in fluorescence intensity. From the correlation in time, we can find the res-idence time, the number of chromophores, the volume in which they are diffusing andtherefore the fluorescence emission efficiency. Fluorescence properties are a probe ofthe local environment, a particularly powerful tool due to the high brightness (quantumyield) fluorescent dyes and sensitive photo-detection equipment both of which are readilyavailable, (such as avalanche photodiodes and photomultiplier tubes). Novel materialscombining the properties of conducting and non-conducting materials at scales muchsmaller than the incident wavelength are known as meta-materials. These allow combi-nations of properties not usually possible in natural materials at optical frequencies. Theproperties reported so far include; negative refraction, negative phase velocity, fluorescenceemission enhancement, lensing and therefore light confinement has also been proposed tobe possible. Instead of expensive and slow lithography methods many of these materialsmay be fabricated with self assembly techniques, which are truly nanoscopic and otherwiseinaccessible with even the most sophisticated equipment. It was found that nanoscaled volumes from ZMW and HMMs based on NW arrays wereall inefficient at enhancing fluorescence. The primary cause was the reduced fluorescencelifetime reducing the fluorescence efficiency, which runs contrary to some commentatorsin the literature. NW based lensing was found to possible in the blue region of the opticalspectrum in a HMM, without the background fluorescence normally associated with a PAAtemplate. This was achieved using a pseudo-ordered array of relatively large nanowireswith a period just smaller than lambda / 2 which minimised losses. Nanowires in the traditionalregime lambda / 10 produced significant scattering and lead to diffraction, such that they werewholly unsuitable for an optical lensing application.