<p> Detailed Neodymium isotopic mapping was performed on grey gneisses from the Algonquin Park area of Ontario, in the Central Gneiss Belt of the southwestern Grenville Province. The Neodymium model ages determined were based upon the Depleted Mantle Model of DePaolo ( 1981c ) . The use of this model is supported by Lead-Lead dating of zircons obtained from an orthogneissic sample. </p> <p> The wide range of model ages found ( 1.5 - 1.86 Ga ) is attributed to the presence of a northwestward dipping, Andean style, ensialic continental margin arc that was active in the Mid-Proterozoic between 1.50 Ga and 1.65 Ga. The diapiric rise of plutons produced by the subduction zone intruded continental margin at least as old as 1.86 Ga as indicated by the oldest pluton in the field area. Variable amounts of mixing occurred between these orogenic rocks and the existing crustal rocks as illustrated by the variable Neodymium model ages determined for grey gneisses collected between 10 Km and 60 Km north of the Central Metasedimentary Belt Boundary Zone. Major element analysis and subsequent tectonic and petrographic discrimination diagrams such as the AFM plot and the granitoid discrimination diagram of LeFort and Debon ( 1983 ) also indicate that the rocks in the Algonquin Park area are calc-alkaline, and are similar to the Peruvian Coastal Batholith. </p> <p> For grey gneisses analyzed within 10 Km of the Central Metasedimentary Belt Boundary Zone, the range of ages is far more restricted, suggesting that an island arc approximately 1.45 Ga was transported by the subducting slab and later sutured onto the existing continental margin. </p> / Thesis / Bachelor of Science (BSc)

<p> Field observation at seven outcrops and subsequent polished section studies reveal that lead and zinc mineralization in the Hamilton vicinity occurred after the lithification of the host carbonates. The availability of open structures and the presence of potential reducing agents are the main controlling factors of sulphide deposition, The absence of an igneous source demands an origin of the metals from the sedimentary country rocks. Analysis of 14 shales and 12 dolomites by atomic absorption for Cu, Pb, and Zn indicates that the argillaceous rocks are potential source of the heavy metals. Furthermore, a simple leaching experiment has demonstrated that concentrated brine (sodium chloride solution) can preferentially leach lead and zinc from the shales. A mode of origin involving preferential.leaching can then adequately explain the scarcity of copper minerals in the Mississippi Valley-Type ore, It is suggested that better controlled leaching experiments at various temperatures should be done in conjunction with more extensive field work to check the plausibility of such a theory. </p> / Thesis / Bachelor of Science (BSc)

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The purpose of this study was to examine the relationships between age, gender and fatigue resistance, and further, to determine the relative influence that estrogen status, membrane excitability, absolute force and muscle length have over the development of fatigue. A total of 48 subjects, classified by age and gender participated in this study; 12 young males (25.3 ± 2.1 yrs.), 12 young females (23.5 ± 2.1 yrs.), 12 elderly males (71.7 ± 5.6 yrs.) and 12 elderly females (69.5 ± 4.6 yrs.). The young females were all eumenorrheic, not taking oral contraceptives and tested in the mid-follicular phase of the menstral cycle. None of the elderly females were on hormone replacement therapy. A 3 minute paradigm of intermittent maximal voluntary contractions (MVC) was used to fatigue the adductor pollicis muscle, in which 5s MVC's were alternated with 2s rest periods. In addition, maximal twitches were evoked in each 2s rest period. No gender difference in fatigability was evident between young males and young females when considering the fatigue index of the evoked twitch (FI-PT) (young males: 39.8 ± 26.7%, young females: 36.6 ± 19.0%). There was also no gender difference in fatigability found between elderly males and elderly females when considering the FI-PT (elderly males: 24.9 ± 26.6%, elderly females: 16.4 ± 48.9%). However, potentiation of the evoked twitches during fatigue may have confounded these measures. When considering the changes in voluntary force during fatigue, there was a strong trend for a gender by time interaction between young males and young females.(p=0.06), which suggests that the former were more fatigable. The trend for this gender difference was also apparent in the voluntary fatigue index (FI-MVC) (young males: 44.7 ± 10.5%, young females: 37.8 ± 14.1 %; p=0.12). Similarly, young males had a significant decrease in M-wave amplitude during the fatigue protocol and a trend for a decrease in M-wave area (p=0.08), while young females showed no significant decreases in either M-wave measure during the fatigue protocol. There was no gender difference found between the elderly males and elderly females when considering the FI-MVC (elderly males: 24.2 ± 10.7%, elderly females: 26.3 ± 14.5%). Both groups also showed small but significant reductions in theM-wave amplitude during the fatigue protocol, although M-wave area was well maintained. The fact that a strong trend for a gender difference in fatigability was found in the young subjects but not the elderly subjects, suggests that estrogen may possess fatigue resisting properties, even during short duration exercise in which glycogen depletion is not a concern. With respect to the age-related differences in fatigue, elderly males were found to be significantly more fatigue resistant than young males as indicated by the FI-MVC (p<0.01), and the significant age by time interaction during the fatigue protocol (p<0.01). In contrast, only a trend was found for an age by time interaction between the young and elderly females during the fatigue protocol (p=0.06). This trend for an age-related difference in fatigue amongst women was also reflected in the FI- MVC (p=0.13). / Thesis / Master of Science (MSc)

Sustaining the global population depends upon modern agricultural practices reliant on large inputs of nitrogen (N) fertilizer, but export of excess N from agroecosystems has negative environmental consequences, such as accelerated eutrophication and associated water quality degradation. The challenges posed by diffuse and widespread nutrient pollution in agricultural drainage waters necessitate cost-effective, adaptable, and reliable solutions. In this context, enhanced denitrification approaches developed over the last several decades have produced denitrifying bioreactors that harness the ability of ubiquitous soil microorganisms to convert bioavailable N into inert N gas, thereby removing bioavailable N from an ecosystem. Denitrifying bioreactors are edge-of-field structures that consist of organic carbon substrate and support the activity of denitrifying soil bacteria that remove N from intercepted nutrient-enriched drainage waters. The potential to improve bioreactor performance and expand their application beyond the Midwest to the agriculturally significant Mid-Atlantic region was investigated with a three-pronged approach: 1) a pilot study investigating controls on N removal, 2) a laboratory study investigating controls on emission of greenhouse gases nitrous oxide (N2O), methane (CH4), and carbon dioxide (CO2), and 3) a field study of one of the first denitrifying bioreactors implemented in the Atlantic Coastal Plain. The pilot and laboratory studies tested the effect of amending woodchip bioreactors with biochar, an organic carbon pyrolysis product demonstrated to enhance microbial activity. The pilot-scale study provides evidence that either hardwood- of softwood-feedstock biochar may increase N removal in woodchip bioreactors, particularly under higher N loading. The results from the laboratory experiment suggest the particular pine-feedstock biochar tested may induce greater greenhouse gas emissions, particularly of the intermediate product of denitrification and potent GHG nitrous oxide. The field study evaluated performance of a biochar-amended woodchip bioreactor installed on a working farm. Two years of monitoring data demonstrated that the bioreactor successfully removed N from drainage waters, but at relatively low rates constrained by low N loading that occurred in the absence of fertilizer application during continuous soy cropping at the site (10.0 kg NO3--N ha-1 yr-1 or 4.86 g NO3- -N m-3 d-1 on the basis of bed volume reached the bioreactor.) Removal rates averaged 0.41 g m-3 d-1 (8.6% removal efficiency), significantly lower than average rates in systems receiving greater N loading in the Midwest, and more similar to installations in the Maryland Coastal Plain. Greenhouse gas fluxes were within the range reported for other bioreactors, and of the N removed an average of only 0.16% was emitted from the bed surface as N2O. This case study provides useful measurements of bioreactor operation under low N loading that informs the boundaries of bioreactor utility, and may have particular regional relevance. The pilot and field studies suggest that wood-based biochars may enhance N removal and may not produce problematic quantities of greenhouse gases, respectively. However, the laboratory study raises the need for caution when considering the costs and benefits amending woodchip bioreactors with biochar and accounting for the effect on greenhouse gas emissions in this calculation, because the tested pine biochar significantly increased these emissions. / PHD

The earth's ionosphere-thermosphere region is a coupled environment which is governed by interactions between the overlapping neutral constituents and ionospheric plasma. The mid-latitude thermosphere-ionosphere system is very complex owing to its sensitivity to both the polar and equatorial processes. The mid-latitudes is also a relatively unexplored and less understood region primarily due to the paucity of observing instruments that have traditionally been available. However, the past 9 years of mid-latitude expansion of the Super Dual Auroral Radar Network (SuperDARN) has provided new access to continuous large-scale observations of the sub-auroral ionosphere. On the other hand, the past 3 years of mid-latitude expansion of the North American Thermosphere Ionosphere Observation Network (NATION) Fabry-Perot interferometer array, has created a critical resource for measuring the thermospheric neutral winds. The overlap of these two observing networks in the mid-east North American sector has resulted in a strong ground-based large-scale platform for co-located study of mid-latitude thermosphere-ionosphere dynamics for the first time. The coupling between ions and neutrals is a very important process for controlling the thermospheric dynamics. Ion-neutral coupling at high latitudes has been studied in many previous papers, but there have been very few studies focused on the mid-latitude region. Hence, in this work we have studied the ion-neutral coupling mechanisms and timescales at mid-latitudes during disturbed geomagnetic conditions by using the co-located observations from the SuperDARN-NATION array. The study has focused on the main phase as well as the late recovery phase of a geomagnetic storm which occurred on October 2-3, 2013. Ion drag is known to drive the neutral circulation during the main phase of storm at auroral latitudes, while the neutral wind disturbance dynamo mechanism is known to generate ionospheric electric fields and currents during the recovery phase. By using the methods of ion-neutral momentum exchange theory and time lagged correlation analysis, we analyzed the timescales at which the ion-neutral coupling operates. The ions are observed to drive the neutral winds on a timescale of ~ 84 minutes in the storm main phase which is significantly faster than expected from the driving due to local ion-drag alone (~ 124 minutes). This suggests that along with ion-drag, other local and non-local storm-time influences like Joule heating are also playing an important part in driving the neutral winds. On the other hand, in the late recovery phase, the neutral winds are found to be strongly coupled with the ions and maintain the ion convection without any significant time delay which is consistent with effect of the 'disturbance dynamo' or 'neutral-flywheel' persisting well into the late recovery phase. The timescales and underlying physics understood through this work serve as an important contribution to our knowledge of ion-neutral coupling processes at the middle latitudes. Looking forward, the expansion of co-located SuperDARN-NATION coverage at mid-latitudes, and developments in the tools of large-scale visualization through FPI wind field mapping and SuperDARN convection maps, has created a very strong basis for using the results and analysis tools developed in this work for large-scale ion-neutral coupling characterization in future. / Master of Science

The data from the new mid-latitude radars of the Super Dual Auroral Radar Network (SuperDARN) provide new types of challenges and observations. We have developed a method for identifying periods of ionospheric backscatter that increase the number of data and reduce the average velocity in agreement with previous incoherent scatter radar (ISR) studies. Analysis of the data identified by this method clearly shows that different types of ionospheric irregularities are being observed in the mid-latitude region. One type of irregularity is clearly subauroral and equatorward of the plasmapause. Fitting a convection pattern to the Doppler velocities associated with subauroral ionospheric scatter reveals some interesting features. Subauroral convection is shown to be westward thought most of the night, with an eastward turning near dawn. The rotation factor of the ionosphere relative to the rotation of the earth is shown to be ~0.95, which is in good agreement with previous studies of plasmaspheric corotation. / Master of Science