The high specific stiffness and strength of composites makes it advantageous for load carrying structures in the automotive industry. By successfully be able to numerically simulate the crush behaviour of composites, structure with high specific energy absorption can be implemented in the automotive industry. The purpose of this thesis is to verify the predictive capabilities of a crush model developed at SICOMP. Initially currently available material models are investigated. Puck’s criterion is deeper studied. An improvement of the criterion is suggested and the model is updated to be able to output fracture angles in Abaqus.The material model developed by SICOMP is a three-dimensional physically based damage model where failure initiation is estimated with proven failure criteria and damage growth is combined with friction to account for the right energy absorption. The crush damage model has been implemented in Abaqus/Explicit as a VUMAT subroutine. Numerical predictions are compared with experimental results. Specimens with different fibre layups and crash triggers are tested.

Grâce à leur géométrie spécifique, faite d’une superposition de couches unidirectionnelles de fibres continues, liées par des coutures plus ou moins complexes, les renforts NCF (Non-Crimp Fabric) possèdent une combinaison de propriétés intéressantes. Ces propriétés permettent l'utilisation de procédés de production tels que le procédé RTM (Resin Transfer Moulding) et permettent l’utilisation des caractéristiques de rigidité élevée des fibres dans la pièce finale. Ainsi, ces renforts trouvent des applications dans différents secteurs de l'industrie des composites et notamment en aéronautique. Les couches, formées de fibres parallèles juxtaposées, sont liées par différents types de coutures. Ce lien conduit à des propriétés différentes de celles observées sur un renfort tissé où les mèches de chaîne et de trame sont liées par entrelacement. Par conséquent, la cinématique de déformation des renforts NCF secs lors de la mise en forme peut être différente. Dans ce travail de recherche, nous menons d'abord une étude expérimentale sur les mécanismes de déformation se produisant lors de tests élémentaires et lors d’une expérience d’emboutissage. Plusieurs renforts NCF et un renfort interlock sont étudiés. Ensuite, nous introduisons un nouveau modèle pour la simulation de la mise en forme du renfort de composite NCF sec. Cette approche implique l’utilisation d’éléments finis lagrangien semi-discrets pour représenter les couches et d’éléments de barres pour représenter les coutures. Ce modèle nécessite un algorithme de contact spécifique pour gérer la relation entre les éléments finis. Une loi de frottement de Coulomb avec seuil de glissement est utilisée. Enfin, le modèle est validé par l’intermédiaire de l’essai de bias test puis la mise en forme sur un hémisphère est simulée et comparée à l'expérience. / Due to their specific geometry, made of overlapping layers of unidirectional plies of continuous fibres, linked by more or less complex stitching, non-crimp fabric (NCF) reinforcements have advantageous combination of properties. These properties enable the use of process in production such as RTM process and allow the full use of stiffness characteristics of the fibres in the final part. Thus, these reinforcements find applications in different areas of composites industry. The plies of juxtaposed parallel fibres are bound by a tricot or a chain stitching with a lead. This link leads to different properties of the NCF compared to those of a woven reinforcement where the warp and weft yarns are linked by the interweaving. Therefore, deformation kinematics of dry NCF reinforcements might be different. In this research work, we first carry out an experimental study on deformation mechanisms occurring during elementary tests and a drawing experiment. Several non-crimp fabrics and an interlock fabric are studied. Then, we introduce a new model for the simulation of the dry composite reinforcement preforming. This approach involves a semi discrete Lagrangian finite element to represent the plies and a truss element to represent the stitching. This model requires a specific contact algorithm to handle the relation between the finite elements. A Coulomb law with a friction threshold is used. Finally, the model is validated using the bias extension test and the preforming on a hemisphere is simulated and compared to the experiment.

Grâce à leur géométrie spécifique, faite d'une superposition de couches unidirectionnelles de fibres continues, liées par des coutures plus ou moins complexes, les renforts NCF (Non-Crimp Fabric) possèdent une combinaison de propriétés intéressantes. Ces propriétés permettent l'utilisation de procédés de production tels que le procédé RTM (Resin Transfer Moulding) et permettent l'utilisation des caractéristiques de rigidité élevée des fibres dans la pièce finale. Ainsi, ces renforts trouvent des applications dans différents secteurs de l'industrie des composites et notamment en aéronautique. Les couches, formées de fibres parallèles juxtaposées, sont liées par différents types de coutures. Ce lien conduit à des propriétés différentes de celles observées sur un renfort tissé où les mèches de chaîne et de trame sont liées par entrelacement. Par conséquent, la cinématique de déformation des renforts NCF secs lors de la mise en forme peut être différente. Dans ce travail de recherche, nous menons d'abord une étude expérimentale sur les mécanismes de déformation se produisant lors de tests élémentaires et lors d'une expérience d'emboutissage. Plusieurs renforts NCF et un renfort interlock sont étudiés. Ensuite, nous introduisons un nouveau modèle pour la simulation de la mise en forme du renfort de composite NCF sec. Cette approche implique l'utilisation d'éléments finis lagrangien semi-discrets pour représenter les couches et d'éléments de barres pour représenter les coutures. Ce modèle nécessite un algorithme de contact spécifique pour gérer la relation entre les éléments finis. Une loi de frottement de Coulomb avec seuil de glissement est utilisée. Enfin, le modèle est validé par l'intermédiaire de l'essai de bias test puis la mise en forme sur un hémisphère est simulée et comparée à l'expérience.

Since its beginnings, the aerospace industry has been interested in lowering the weight of aircraft. Moving from performance and economic drivers to environmental design parameters, the weight has continuously been a major focus for this industry. A possible option to reduce weight is to use lighter materials such as fibre reinforced polymer composites (FRPC). This type of material has the potential to be used into cold or moderate high-temperature sections of aero-engines. One major obstacle that hinders composite insertion into aero-engines is the lack of predictive models. In recent years, there has been increasing interest in multiscale modelling as a possible approach to reliably predict composite behaviour. This modelling refers to the simulation of a material’s behaviour through multiple scales, passing on information from one scale to another. The purpose of the present work is to use a commercially available software tool (Altair Multiscale Designer™) to virtually characterize an FRPC made from a non-crimp fabric reinforcement based on its individual constituent properties. The studied composite was a carbon fibre and epoxy system developed by GKN Aerospace. In order to achieve this, a well-characterized unidirectional (UD) carbon fibre prepreg composite was used to calibrate the software. After calibration and verification, different repetitive unit cells were created to capture the non-crimp fabric (NCF) architecture where the effect of fibre waviness was studied. The calibration step allowed for fairly accurate and acceptable results when testing unidirectional or ±45 laminates with different tested UD prepreg material systems. The higher deviation from experimental values was up to 20% with these laminates’ configurations. When simulating more complex layups, such as quasi-isotropic ones, the simulations resulted in over-predicting up to 40% of the composite strength in comparison to experimental data. The study of NCF composites appeared to be more complicated than anticipated. Their complex architecture exhibits complicated failure modes, which could not be captured by the software tool. Large inaccuracy up to 100% were observed between simulation and experimental values of the laminate strengths. In spite of its limitations, the study of NCF composites allowed for a deeper understanding of the software functionalities and findings on the fibre waviness impact onto the predicted stiffness, while the strength of the laminate did not show dependency with the fibre waviness.

The purpose of this project is to explore aspects of a design that makes an electronic key feel precious toa user. The goal is to find information that is useful when designing electronic keys and to serve as partof the research in the project Precious Keys. Several prototypes and designs were created and evaluated,each over a period of several weeks. The designs each had different prominent aspects that were theorisedto carry preciousness and these aspects were analysed during the evaluation process. The designs werethen compared and iteratively improved upon in order to explore each aspect properly. The result showedthat function, visual appeal, fiddle-friendliness, history with the key and friction had the most impact onperceived preciousness. Creating the key with your own hands proved to be the most effective way tocreate preciousness through history. The aspects “unity” and “augmentation” were also discussed butcould not be proven to have an impact on perceived preciousness. In line with presented theories, thisstudy shows clear relations between aspects of design that have a positive impact on the perceivedpreciousness and electronic keys. It is even possible to grade these in terms of most impact to least impact.The study also has shown that first-person research is arguably a good method to research the topic. / Syftet med detta arbete är att utforska designaspekter som gör att en elektronisk nyckel känns värdefull för en användare. Målet är att hitta information som är användbar vid design av elektroniska nycklar och att låta detta arbete fungera som en del av forskningen i projektet Precious Keys. Flera prototyper togs fram och utvärderades, var och en under några veckors tid. De olika utformningarna hade olika framträdande aspekter som enligt teori skulle kunna bidra till att nycklarna skulle kännas värdefulla, och dessa aspekter analyserades under utvärderingsprocessen. Prototyperna jämfördes sedan och förbättrades iterativt för att utforska varje aspekt ordentligt. Resultatet visade att funktion, estetik, hur tillåtande nyckeln var att leka med i handen, erfarenheter med nyckeln samt friktion hade störst inverkan på upplevt värde. Att med egna händer skapa nyckeln visade sig också vara den erfarenhetsaspekt som hade störst inverkan. Aspekterna ”enhetlighet” och ”patina/föråldring” diskuterades också men kunde inte bevisas ha en inverkan på upplevt värde. I enlighet med uppvisad teori är det möjligt att koppla resultatet från denna studie till värdeskapande design-aspekter hos elektroniska nycklar. Det går även att se till vilken grad olika aspekter anses ha en effekt. Studien har även visat att förstapersonsforskning kan användas för att undersöka ämnet.

Ever growing demands for portability and functionality have always governed the electronic technology innovations. IC downscaling with Moore s law and system miniaturization with System-On-Package (SOP) paradigm has resulted and will continue to result in ultraminiaturized systems with unprecedented functionality at reduced cost. The trend towards 3D silicon system integration is expected to downscale IC I/O pad pitches from 40µm to 1- 5 µm in future. Device- to- system board interconnections are typically accomplished today with either wire bonding or solders. Both of these are incremental and run into either electrical or mechanical barriers as they are extended to higher density of interconnections. Alternate interconnection approaches such as compliant interconnects typically require lengthy connections and are therefore limited in terms of electrical properties, although expected to meet the mechanical requirements. As supply currents will increase upto 220 A by 2012, the current density will exceed the maximum allowable current density of solders. The intrinsic delay and electromigration in solders are other daunting issues that become critical at nanometer size technology nodes. In addition, formation of intermetallics is also a bottleneck that poses significant mechanical issues. Recently, many research groups have investigated various techniques for copper-copper direct bonding. Typically, bonding is carried out at 400oC for 30 min followed by annealing for 30 min. High thermal budget in such process makes it less attractive for integrated systems because of the associated process incompatibilities. In the present study, copper-copper bonding at ultra fine-pitch using advanced nano-conductive and non-conductive adhesives is evaluated. The proposed copper-copper based interconnects using advanced conductive and non-conductive adhesives will be a new fundamental and comprehensive paradigm to solve all the four barriers: 1) I/O pitch 2) Electrical performance 3) Reliability and 4) Cost. This thesis investigates the mechanical integrity and reliability of copper-copper bonding using advanced adhesives through test vehicle fabrication and reliability testing. Test vehicles were fabricated using low cost electro-deposition techniques and assembled onto glass carrier. Experimental results show that proposed copper-copper bonding using advanced adhesives could potentially meet all the system performance requirements for the emerging micro/nano-systems.

Atualmente, o Brasil é o maior fabricante de celulose branqueada de eucalipto do mundo. Geralmente as fibras virgens de Eucalyptus spp. são utilizadas na fabricação de papéis para imprimir, tissue e especiais. Papéis para embalagens, tipicamente Kraftliners, precisam de uma grande resistência mecânica e são produzidos principalmente a partir de pastas Kraft de coníferas não branqueadas. Por outro lado, nanoceluloses fabricadas a partir de biomassa são consideradas um dos materiais sustentáveis mais interessantes para o século, com excelentes propriedades como baixa densidade, elevadas propriedades mecânicas, alta hidrofilicidade, grande área superficial com reatividade química e elevado valor econômico. Desde 2012 o uso de nanoceluloses na fabricação de papel ganhou impulso. As nanoceluloses têm sido adicionadas em pastas mecânicas e Kraft branqueadas para fabricação do papel, incrementando notavelmente as suas propriedades mecânicas, mas há preocupações sobre a diminuição da drenabilidade, da porosidade e da opacidade do papel. Poucos estudos foram desenvolvidos visando a aplicação de nanoceluloses em fibras não branqueadas, ainda que tenham aplicações em pastas branqueadas e/ou mecânicas. Portanto, o presente trabalho visa desenvolver o uso de nanoceluloses para melhorar as propriedades mecânicas em fibras não branqueadas. Em primeiro lugar, tomaram-se os finos primários do branqueamento de celulose de Pasta Kraft de Eucalipto como a matéria-prima para produzir dois tipos de nanocelulose. A celulose microfibrilada (MFC) é produzida diretamente por homogeneização mecânica utilizando equipamento Masuko. A celulose nanofibrilada (CNF) é produzida por oxidação mediada por TEMPO e homogeneizada por GEA. Em segundo lugar, selecionaram-se com as fibras virgens de Pasta Kraft Marrom de Pinho (PKPM) com número Kappa 36,1 e Pasta Kraft de Eucalipto Não Branqueada (PKEP), obtida na saída de estágio de deslignificação com oxigênio, com número Kappa 9,21, e todas as fibras foram refinadas até atingir o mesmo grau Shopper-Riegler (33±1 SR). Os experimentos com PKPM são conduzidas como uma referência a papéis Kraftliners tradicionais, com ou sem nanocelluloses. Também obteve folhas manuais com pasta branqueada Kraft de eucalipto, adicionando nanoceluloses, para compreender o efeito da lignina presente em PKEP. A receita e os aditivos químicos aplicados aqui são os mesmos que na produção industrial. Os principais resultados são: o uso de CNF (ou MFC) e agentes químicos, separadamente, na pasta PKEP, aumenta as resistências mecânicas dos papéis, no entanto, quando aplicadas CNF (ou MFC) em PKMP sem aditivos químicos, as resistências à tração e a estouro diminuem, e a resistência ao rasgo permanece constante. Como a terceira parte do estudo, delineamento de experimentos teve a configuração composto central com o ponto central em 1% de CNF (ou MFC) e 1% de agentes químicos (polímero+amido+cola), e seus pontos axiais foram 0,3%-1,7% de CNF (ou MFC), e 0,15%-0,85% de agentes químicos. O ponto ótimo de equilíbrio dos índices de rasgo (mN.m2/g) /estouro (kPa.m2/g) /tração (N.m/g) de (10,00/2,25/36,56 para CNF e 12,88/4,25/57,62 para MFC), obteve-se com a adição de 1,03% de CNF e 0,65% de amido, ou com a adição de menos de 0,01% de MFC e de 1% de amido. Finalmente, foram aplicadas CNF ou MFC por impregnação direta no centro da direção-z, considerando que o papel tem forças que interagem em 3D. Os resultados mostram que a PKEP atinge a qualidade do Kraftliner de pinus obtendo um índice de tração de 52,58 N.m/g utilizando 1% de CNF, ou 47,40 N.m/g utilizando 1% de MFC. Também, o custo de utilização do CNF ou MFC na fabricação do papel é avaliado, resultando em estimativas de 0,9494 US$/kg ou 0,3036 US$/kg, com a adição de 1% de CNF ou 1% de MFC, respectivamente, em pasta PKEP. Este trabalho mostra que a aplicação de nanocelulose em Kraftliner tradicional com fibras de pinus com todos os agentes químicos não tem vantagens reais. No entanto, o uso de CNF e MFC tecnicamente e economicamente tem vantagens superiores em pasta Kraft de eucalipto não branqueada (e deslignificada com oxigênio), obtendo-se propriedades superiores às de fibras longas. / Nowadays, Brazil is the largest manufacturer of Bleached Eucalyptus Kraft Pulp in the world. Mostly the Eucalyptus spp. virgin fibres are used in papermaking to manufacture printing, tissue and specialty papers. Packaging papers, typically Kraftliners, have high demands for mechanical strength and are made mostly from Unbleached Softwood Kraft Pulp. Other side, nanocelluloses from biomass are considered one of the most interesting sustainable materials for the Century, with excel properties such as low density, high mechanical properties, high hydrophilicity, large surface area with chemical reactivity and high economic value. Since 2012 the use of nanocellulose in papermaking experienced a great momentum. Nanocelluloses are added in bleached or mechanical pulp in papermaking to increase significantly the mechanical properties, but there are concerns about the decreasing of the drainability, the porosity and the opacity of the paper. A very few studies were developed on the application of nanocelluloses in an unbleached Kraft pulp, even there are its applications on bleached pulps and mechanical pulps. Therefore, the present work aims to develop the application of nanocelluloses to increase the mechanical properties of the unbleached fibers, specifically for Kraftliners, and show the way to replace the softwood fibers with the low-cost hardwood fibers. Firstly, the primary fines from bleaching area of Eucalyptus Kraft pulp, obtained from an industrial residue, was the raw material for nanocellulose production of two nanocelluloses. The microfibrillated celluloses (MFC) are produced with direct mechanical homogenization using Masuko. The nanofibrillated cellulose (NCF) is produced with oxidation mediated by TEMPO and homogenization using GEA. Secondly, as virgin fibers were selected the Unbleached Pine Kraft Pulp (USKP) with Kappa number 36.1 and the Unbleached Eucalyptus Kraft Pulp (UEKP) just after the oxygen delignification stage with the Kappa number 9.21. All the fibres (USKP and UEKP) was refining at the same Shopper-Riegler (33±1 SR). USKP experiments are conducted as reference to traditional Kraftliners, with or without nanocelluloses. Also the virgin bleached Eucalyptus Kraft pulp with nanocelluloses addition for the handsheet paper helps to understand the role of lignin in UEKP. The recipe and chemicals applied here are the same of the industrial production. The main results are: the use CNF (or MFC) and chemical agents, separately, in UEKP, promote the mechanical resistances, however when applied CNF (or MFC) in UPKP without chemicals, the tensile and burst properties decreased and tear remains constant. As the third group of the study, the design of the experiments was conducted in the star configuration with centre point as 1% CNF (or MFC) and 1.00% chemical agents (polymers+starch+chemical agents) and, the axial points were 0.3%-1.7% NCF (or MFC) and 0.15%-0.85 of chemical agents. The optimum point from the balanced tear (mN.m2/g) /burst (kPa.m2/g) /tensile (N.m/g) index point of view with 10.00/2.25/36.56 for (1.03% CNF and 0.65% starch) and 12.88/4.25/57.62 for (<0.001% MFC and 1% starch). Finally, it is applied here the direct impregnation of the center of z-direction with 1% of CNF and MFC, considering that the paper has 3D interacting forces. The results show that the UEKP reaches the pinus Kraftliner quality with 52.58 N.m/g (Tensile Index) using 1% CNF or 47.40 N.m/g using 1% MFC. Also, the cost of use CNF or MFC in papermaking is evaluated, resulting in the estimates of 0.9494 US$/kg or 0.3036 US$/kg, the addition of 1% CNF or 1% MFC in UEKP. This work shows that the application of nanocellulose in traditional Kraftliner with pinus fibres with all chemical agents has no real advantages. However, the use of CNF and MFC technically and economically has superior advantages in Eucalyptus unbleached (and oxygen delignified) Kraft pulp, resulting in such properties superior to those of long fibres.

Small form-factor packages with high integration density are driving the innovations in chip-to-package interconnections. Metallurgical interconnections have evolved from the conventional eutectic and lead-free solders to fine pitch copper pillars with lead-free solder cap. However, scaling down the bump pitch below 50-80µm and increasing the interconnect density with this approach creates a challenge in terms of accurate solder mask lithography and joint reliability with low stand-off heights. Going beyond the state of the art flip-chip interconnection technology to achieve ultra-fine bump pitch and high reliability requires a fundamentally- different approach towards highly functional and integrated systems. This research demonstrates a low-profile copper-to-copper interconnect material and process approach with less than 20µm total height using adhesive bonding at lower temperature than other state-of-the-art methods. The research focuses on: (1) exploring a novel solution for ultra-fine pitch (< 30µm) interconnections, (2) advanced materials and assembly process for copper-to-copper interconnections, and (3) design, fabrication and characterization of test vehicles for reliability and failure analysis of the interconnection. This research represents the first demonstration of ultra-fine pitch Cu-to-Cu interconnection below 200°C using non-conductive film (NCF) as an adhesive to achieve bonding between silicon die and organic substrate. The fabrication process optimization and characterization of copper bumps, NCF and build-up substrate was performed as a part of the study. The test vehicles were studied for mechanical reliability performance under unbiased highly accelerated stress test (U-HAST), high temperature storage (HTS) and thermal shock test (TST). This robust interconnect scheme was also shown to perform well with different die sizes, die thicknesses and with embedded dies. A simple and reliable, low-cost and low-temperature direct Cu-Cu bonding was demonstrated offering a potential solution for future flip chip packages as well as with chip-last embedded active devices in organic substrates.

Atualmente, o Brasil é o maior fabricante de celulose branqueada de eucalipto do mundo. Geralmente as fibras virgens de Eucalyptus spp. são utilizadas na fabricação de papéis para imprimir, tissue e especiais. Papéis para embalagens, tipicamente Kraftliners, precisam de uma grande resistência mecânica e são produzidos principalmente a partir de pastas Kraft de coníferas não branqueadas. Por outro lado, nanoceluloses fabricadas a partir de biomassa são consideradas um dos materiais sustentáveis mais interessantes para o século, com excelentes propriedades como baixa densidade, elevadas propriedades mecânicas, alta hidrofilicidade, grande área superficial com reatividade química e elevado valor econômico. Desde 2012 o uso de nanoceluloses na fabricação de papel ganhou impulso. As nanoceluloses têm sido adicionadas em pastas mecânicas e Kraft branqueadas para fabricação do papel, incrementando notavelmente as suas propriedades mecânicas, mas há preocupações sobre a diminuição da drenabilidade, da porosidade e da opacidade do papel. Poucos estudos foram desenvolvidos visando a aplicação de nanoceluloses em fibras não branqueadas, ainda que tenham aplicações em pastas branqueadas e/ou mecânicas. Portanto, o presente trabalho visa desenvolver o uso de nanoceluloses para melhorar as propriedades mecânicas em fibras não branqueadas. Em primeiro lugar, tomaram-se os finos primários do branqueamento de celulose de Pasta Kraft de Eucalipto como a matéria-prima para produzir dois tipos de nanocelulose. A celulose microfibrilada (MFC) é produzida diretamente por homogeneização mecânica utilizando equipamento Masuko. A celulose nanofibrilada (CNF) é produzida por oxidação mediada por TEMPO e homogeneizada por GEA. Em segundo lugar, selecionaram-se com as fibras virgens de Pasta Kraft Marrom de Pinho (PKPM) com número Kappa 36,1 e Pasta Kraft de Eucalipto Não Branqueada (PKEP), obtida na saída de estágio de deslignificação com oxigênio, com número Kappa 9,21, e todas as fibras foram refinadas até atingir o mesmo grau Shopper-Riegler (33±1 SR). Os experimentos com PKPM são conduzidas como uma referência a papéis Kraftliners tradicionais, com ou sem nanocelluloses. Também obteve folhas manuais com pasta branqueada Kraft de eucalipto, adicionando nanoceluloses, para compreender o efeito da lignina presente em PKEP. A receita e os aditivos químicos aplicados aqui são os mesmos que na produção industrial. Os principais resultados são: o uso de CNF (ou MFC) e agentes químicos, separadamente, na pasta PKEP, aumenta as resistências mecânicas dos papéis, no entanto, quando aplicadas CNF (ou MFC) em PKMP sem aditivos químicos, as resistências à tração e a estouro diminuem, e a resistência ao rasgo permanece constante. Como a terceira parte do estudo, delineamento de experimentos teve a configuração composto central com o ponto central em 1% de CNF (ou MFC) e 1% de agentes químicos (polímero+amido+cola), e seus pontos axiais foram 0,3%-1,7% de CNF (ou MFC), e 0,15%-0,85% de agentes químicos. O ponto ótimo de equilíbrio dos índices de rasgo (mN.m2/g) /estouro (kPa.m2/g) /tração (N.m/g) de (10,00/2,25/36,56 para CNF e 12,88/4,25/57,62 para MFC), obteve-se com a adição de 1,03% de CNF e 0,65% de amido, ou com a adição de menos de 0,01% de MFC e de 1% de amido. Finalmente, foram aplicadas CNF ou MFC por impregnação direta no centro da direção-z, considerando que o papel tem forças que interagem em 3D. Os resultados mostram que a PKEP atinge a qualidade do Kraftliner de pinus obtendo um índice de tração de 52,58 N.m/g utilizando 1% de CNF, ou 47,40 N.m/g utilizando 1% de MFC. Também, o custo de utilização do CNF ou MFC na fabricação do papel é avaliado, resultando em estimativas de 0,9494 US$/kg ou 0,3036 US$/kg, com a adição de 1% de CNF ou 1% de MFC, respectivamente, em pasta PKEP. Este trabalho mostra que a aplicação de nanocelulose em Kraftliner tradicional com fibras de pinus com todos os agentes químicos não tem vantagens reais. No entanto, o uso de CNF e MFC tecnicamente e economicamente tem vantagens superiores em pasta Kraft de eucalipto não branqueada (e deslignificada com oxigênio), obtendo-se propriedades superiores às de fibras longas. / Nowadays, Brazil is the largest manufacturer of Bleached Eucalyptus Kraft Pulp in the world. Mostly the Eucalyptus spp. virgin fibres are used in papermaking to manufacture printing, tissue and specialty papers. Packaging papers, typically Kraftliners, have high demands for mechanical strength and are made mostly from Unbleached Softwood Kraft Pulp. Other side, nanocelluloses from biomass are considered one of the most interesting sustainable materials for the Century, with excel properties such as low density, high mechanical properties, high hydrophilicity, large surface area with chemical reactivity and high economic value. Since 2012 the use of nanocellulose in papermaking experienced a great momentum. Nanocelluloses are added in bleached or mechanical pulp in papermaking to increase significantly the mechanical properties, but there are concerns about the decreasing of the drainability, the porosity and the opacity of the paper. A very few studies were developed on the application of nanocelluloses in an unbleached Kraft pulp, even there are its applications on bleached pulps and mechanical pulps. Therefore, the present work aims to develop the application of nanocelluloses to increase the mechanical properties of the unbleached fibers, specifically for Kraftliners, and show the way to replace the softwood fibers with the low-cost hardwood fibers. Firstly, the primary fines from bleaching area of Eucalyptus Kraft pulp, obtained from an industrial residue, was the raw material for nanocellulose production of two nanocelluloses. The microfibrillated celluloses (MFC) are produced with direct mechanical homogenization using Masuko. The nanofibrillated cellulose (NCF) is produced with oxidation mediated by TEMPO and homogenization using GEA. Secondly, as virgin fibers were selected the Unbleached Pine Kraft Pulp (USKP) with Kappa number 36.1 and the Unbleached Eucalyptus Kraft Pulp (UEKP) just after the oxygen delignification stage with the Kappa number 9.21. All the fibres (USKP and UEKP) was refining at the same Shopper-Riegler (33±1 SR). USKP experiments are conducted as reference to traditional Kraftliners, with or without nanocelluloses. Also the virgin bleached Eucalyptus Kraft pulp with nanocelluloses addition for the handsheet paper helps to understand the role of lignin in UEKP. The recipe and chemicals applied here are the same of the industrial production. The main results are: the use CNF (or MFC) and chemical agents, separately, in UEKP, promote the mechanical resistances, however when applied CNF (or MFC) in UPKP without chemicals, the tensile and burst properties decreased and tear remains constant. As the third group of the study, the design of the experiments was conducted in the star configuration with centre point as 1% CNF (or MFC) and 1.00% chemical agents (polymers+starch+chemical agents) and, the axial points were 0.3%-1.7% NCF (or MFC) and 0.15%-0.85 of chemical agents. The optimum point from the balanced tear (mN.m2/g) /burst (kPa.m2/g) /tensile (N.m/g) index point of view with 10.00/2.25/36.56 for (1.03% CNF and 0.65% starch) and 12.88/4.25/57.62 for (<0.001% MFC and 1% starch). Finally, it is applied here the direct impregnation of the center of z-direction with 1% of CNF and MFC, considering that the paper has 3D interacting forces. The results show that the UEKP reaches the pinus Kraftliner quality with 52.58 N.m/g (Tensile Index) using 1% CNF or 47.40 N.m/g using 1% MFC. Also, the cost of use CNF or MFC in papermaking is evaluated, resulting in the estimates of 0.9494 US$/kg or 0.3036 US$/kg, the addition of 1% CNF or 1% MFC in UEKP. This work shows that the application of nanocellulose in traditional Kraftliner with pinus fibres with all chemical agents has no real advantages. However, the use of CNF and MFC technically and economically has superior advantages in Eucalyptus unbleached (and oxygen delignified) Kraft pulp, resulting in such properties superior to those of long fibres.

A new method for pre-impregnating nickel coated carbon fiber with a thermoplastic polymer to make towpreg, similar to a recently developed coating-line by João P. Nunes et al and a new electrically conductive thermoplastic are developed. A melted bath was used to help mitigate health concerns and waste for dispersion of nickel coated carbon fibers (NCF) in low density polyethylene (LDPE). This towpreg was then mixed with more LDPE or a mixture of LDPE and nickel nanostrands (NiNS) to a desired filler volume fraction to test the electrical conductivity of the composite. Some of these mixtures were then injection molded and tested again for conductivity as well as tensile and impact strength and compared to each other and the non-injection molded samples. It was found that mixing NiNS into the polymer in addition to NCF created a more conductive part than with NCF alone, in a couple orders of magnitude. Also, the shorter the NCF were, the greater the contribution of the NiNS to the electrical properties of the NCF filled material. The tensile strength was increased by adding the NCF and NiNS, while the impact strength (toughness) decreased.