Thesis (M.Sc. (Eng.))--University of the Witwatersrand, Faculty of Engineering and the Built Environment, School of Chemical and Metallurgical Engineering, 2016. / The world is gradually shifting to renewable clean energy and away from fossil fuels which are considered to have a finite reserve and have negative impact on the environment. Many alternatives have been developed including biofuels. Of the biofuel family, not all products are produced at the same level given the differences in technological advancements. Commonly produced biofuels which are commercialised are bioethanol and biodiesel. Given that a large number of vehicles operate using gasoline, there is a need to develop biogasoline specific processes to produce biogasoline. Bioethanol is used as a blending agent and has a drawback of engine corrosion. Biogasoline can be used for blending or to substitute gasoline in existing motors. The main objective of the project was to produce biogasoline from waste cooking oil using nano-particle catalyst for better performance. A Co-Mo/Al2O3 catalyst was synthesized and tested in two processes namely thermal cracking and hydrocracking. The waste cooking oil used in this study was pre-treated to remove salts and excess water prior to cracking process. Various analytical techniques were then used to characterize the catalyst, waste cooking oil and the products. Waste cooking oil was successfully pre-treated for salt removal with salt dropping from 13.18% to 4.37%. Effect of catalyst performance on thermal cracking proved to be minimal with temperature being the major factor in cracking. The catalyst performed better under hydrocracking with effects of catalyst calcination temperature and catalyst/oil ratio being more apparent as opposed to thermal cracking. Highest percentage biogasoline achieved under thermal cracking was 81.6% at a reaction temperature of 600°C. The highest percentage biogasoline achieved under hydrocracking was 75.7% at a reaction temperature of 210°C, using calcined catalyst at 700°C, catalyst/oil mass ratio of 1/75 and reaction time of 1hr. The biogasoline produced had low sulphur content. The highest sulphur containing product for hydrocracking was 7.4% and that for thermal cracking was 1.3%. It is recommended that the hydrocracking and thermal cracking methods be used for biogasoline production and that further research be done on the optimization of the biogasoline production process and synthesis of nano Co-Mo catalyst. / MT2016

A dissertation submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, in fulfillment of the requirements for the degree of Doctor of Philosophy in Engineering, October 2017 / The dwindling fossil reserves coupled with environmental pollution necessitate the search for clean and sustainable energy resources. Biohydrogen is emerging as a suitable alternative to fossil fuels and has received considerable attention in recent years due to its economic, social, and environmental benefits. However, the industrial application of biohydrogen has been hindered by low yield. Therefore, development of novel techniques to enhance the yield is of immense importance towards large-scale production of biohydrogen. Thus, this research effort explored various options to enhance the yield of biohydrogen during dark fermentation process. Some options explored included (i) the utilization of feedstocks from the agricultural, industrial and municipal sectors, (ii) parametric optimization of biohydrogen production, (iii) investigation of biohydrogen production using metal ions and nitrogen gas sparging, and (iv) assessing the feasibility of biohydrogen scale-up study to pave the way for pilot-scale development. Solid biowaste feedstocks consisting of apple, bread, brewery residue, cabbage, corn-cob, mango, mealie-pap, pear, potato, and sugarcane were investigated for dark fermentative biohydrogen production using anaerobic mixed sludge. The experimental results showed that substrates which are rich in carbohydrates are suitable for dark fermentative biohydrogen-producing bacteria. Consequently, a maximum biohydrogen fraction of 43.98, 40.32 and 38.12% with a corresponding cumulative biohydrogen yield of 278.36, 238.32 and 215.69 mL H2/g total volatile solids (TVS) was obtained using potato, cabbage, and brewery wastes, respectively. Based on these results, potato waste was chosen as a suitable substrate for subsequent biohydrogen production studies. Parametric optimization was carried out on biohydrogen production via dark fermentation using potato waste as the substrate. Effects of operating variables such as pH, temperature, fermentation time, and substrate concentration were investigated via response surface methodology (RSM) approach using a two-level-four factor (24) central composite design (CCD). The obtained predictive model (statistical model) was used to explain the main and interaction effects of the considered variables on biohydrogen production. In addition, the model was employed in the optimization of the operating conditions. Consequently, a secondorder polynomial regression with a coefficient of determination (R2) of 0.99 was obtained and used in the explanation and optimization of operating variables. The optimum operating conditions for biohydrogen production were 39.56 g/L, 5.56, 37.87 oC and 82.58 h for potato waste concentration, pH, temperature and fermentation time, respectively, with a corresponding biohydrogen yield of 68.54 mL H2/g TVS. These results were then validated experimentally and a high biohydrogen yield of 79.43 mL H2/g TVS indicating a 15.9% increase was obtained. Furthermore, the optimized fermentation conditions were applied in the scale-up study of biohydrogen production that employed anaerobic mixed bacteria (sludge) which was immobilized in calcium alginate beads. A biohydrogen fraction of 56.38% with a concomitant yield of 298.11 mL H2/g TVS was achieved from the scale-up study. The research also investigated the influence of metal ions (Fe2+, Ca2+, Mg2+ and Ni2+) on biohydrogen production from suspended and immobilized cells of anaerobic mixed sludge using the established optimal operating conditions. A maximum biohydrogen fraction of 45.21% and a corresponding yield of 292.8 mL H2/g TVS was achieved in fermentation using Fe2+ (1000 mg/L) and immobilized cells. The yield was 1.3 times higher than that of suspended cultures. The effect of nitrogen gas sparging on biohydrogen conversion efficiency (via suspended and immobilized cells) was studied as well. Cell immobilization and nitrogen gas sparging were effective for biohydrogen production enhancement. A maximum biohydrogen fraction of 56.98% corresponding to a biohydrogen yield of 294.83 mL H2/g TVS was obtained in a batch process using nitrogen gas sparging with immobilized cultures. The yield was 1.8 and 2.5 times higher than that of nitrogen gas sparged and non-sparged suspended cell system, respectively. Understanding the functional role of microorganisms that actively participate in dark fermentation process could provide in-depth information for the metabolic enhancement of biohydrogen-producing pathways. Therefore, the microbial composition in the fermentation medium of the optimal substrate (potato waste) was examined using PCR-based 16S rRNA approach. Microbial inventory analysis confirmed the presence of Clostridium species which are the dominant biohydrogen-producing bacteria. The results obtained from this research demonstrated the potential of producing biohydrogen using South African solid biowaste effluents. These feedstocks are advantageous in biohydrogen production because they are highly accessible, rich in nutritional content, and cause huge environmental concerns. Furthermore, optimization techniques using these feedstocks will play a pivotal role towards large-scale production of biohydrogen by increasing throughput and reducing the substrate costs which accounts for approximately 60% of the overall costs. The findings from this research also provide a solid basis for further scale-up and techno-economic studies. Such studies are necessary to evaluate the competitiveness of this technology with the traditional processes of hydrogen production. In summary, the findings from this research effort have been communicated to researchers in the area of biohydrogen process development in the form of peer-reviewed international scientific publications and conference proceedings, and could provide a platform for developing an economic biohydrogen scaled-up process. / CK2018

The technical and scientific challenges to provide reliable sources energy for US and global economy are enormous tasks, and especially so when combined with strategic and recent economic concerns of the last five years. It is clear that as part of the mix of energy sources necessary to deal with these challenges, fuel cells technology will play critical or even a central role. The US Department of Energy, as well as a number of the national laboratories and academic institutions have been aware of the importance such technology for some time. Recently, car manufacturers, transportation experts, and even utilities are paying attention to this vital source of energy for the future. In this thesis, a review of the main fuel cell technologies is presented with the focus on the modeling, and control of one particular and promising fuel cell technology, aluminum air fuel cells. The basic principles of this fuel cell technology are presented. A major part of the study consists of a description of the electrochemistry of the process, modeling, and simulations of aluminum air FC using Matlab Simulink™. The controller design of the proposed model is also presented. In sequel, a power management unit is designed and analyzed as an alternative source of power. Thus, the system commutes between the fuel cell output and the alternative power source in order to fulfill a changing power load demand. Finally, a cost analysis and assessment of this technology for portable devices, conclusions and future recommendations are presented. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2013.

Many issues related to the design and implementation of a maximum power point tracking (MPPT) converter as part of a photovoltaic (PV) system are addressed. To begin with, variations of the single diode model for a PV module are compared, to determine whether the simplest variation may be used for MPPT PV system modeling and analysis purposes. As part ot this determination, four different DC/DC converters are used in conjunction with these different PV models. This is to verify consistent behavior across the different PV models, as well as across the different converter topologies. Consistent results across the different PV models, will allow a simpler model to be used for simulation ana analysis. Consistent results with the different converters will verify that MPPT algorithms are converter independent. Next, MPPT algorithms are discussed. In particular,the differences between the perturb and observe, and the incremental conductance algorithms are explained and illustrated. A new MPPT algorithm is then proposed based on the deficiencies of the other algorithms. The proposed algorithm's parameters are optimized, and the results for different PV modules obtained. Realistic system losses are then considered, and their effect on the PV system is analyzed ; especially in regards to the MPPT algorithm. Finally, a PV system is implemented and the theoretical results, as well as the behavior of the newly proposed MPPT algorithm, are verified. / by Thomas Bennett. / Thesis (Ph.D.)--Florida Atlantic University, 2012. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

Barometric distillation is an alternative method of producing fresh water by desalination. This proposed process evaporates saline water at low pressure and consequently low temperature; low pressure conditions are achieved by use of barometric columns and condensation is by direct contact with a supply of fresh water that will be augmented by the distillate. Low-temperature sources of heat, such as the cooling water rejected by electrical power generating facilities, can supply this system with the latent heat of evaporation. Experiments are presented that show successful distillation with a temperature difference between evaporator and condenser smaller than 10ê C. Accumulation of dissolved gases coming out of solution, a classic problem in lowpressure distillation, is indirectly measured using a gas-tension sensor. The results of these experiments are used in an analysis of the specific energy required by a production process capable of producing 15 liters per hour. With a 20ê C difference, and neglecting latent heat, this analysis yields a specific energy of 1.85 kilowatt-hour per cubic meter, consumed by water pumping and by removal of non-condensable gases. / by Eiki Martinson. / Thesis (M.S.C.S.)--Florida Atlantic University, 2010 / Includes bibliography. / Electronic reproduction. Boca Raton, Fla., 2010. Mode of access: World Wide Web.

The incorporation of an ejector refrigeration cycle with a high temperature PEM fuel cell (HT-PEMFC) presents a novel approach to combined heat and power (CHP) applications. An ejector refrigeration system (ERS) can enhance the flexibility of a CHP system by providing an additional means of utilizing the fuel cell waste heat besides domestic hot water (DHW) heating. This study looks into the performance gains that can be attained by incorporating ejector refrigeration with HT-PEMFC micro-CHP (mCHP) systems (1 to 5kWe). The effectiveness of the ERS in utilizing fuel cell waste heat is studied as is the relulting enhancement to overall system efficiency. A test rig specially constructed to evaluate an ERS under simulated HT-PEMFC conditions is used to test the concept and verify modeling predictions. In addition, two separate analytical models were constructed to simulate the ERS test rig and a HT-PEMFC/ERS mCHP system. The ERS test rig was simulated using a Matlab based model, while two residential sized HT-PEMFC/ERS mCHP systems were simulated using a Simulink model. Using U.S. Energy Information Administration (EIA) air conditioning and DHW load profiles, as well as data collected from a large residential monitoring study in Florida, the Simulink model provides the results in system efficiency gain associated with supporting residential space cooling and water heating loads. It was found that incorporation of an ERS increased the efficiency of a HT-PEMFC mCHP system by 8 t0 10 percentage points over just using the fuel cell waste heat for DHW. In addition, results from the Matlab ERS test rig model were shown to match well with experimental results. / by Michel Fuchs. / Thesis (Ph.D.)--Florida Atlantic University, 2012. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

Thesis Submitted in Partial Fulfilment of the Requirements for the Degree of Master of Technology: Electrical Engineering (Energy) in the Department of Electrical, Electronic and Computer Engineering at the Cape Peninsula University of Technology, South Africa. / In photovoltaic power systems, the DC/AC conversion efficiency depends on weather conditions causing PV inverters to operate under fluctuating input power from PV modules. The peak efficiency stated by the inverter manufacturers are often used by project designers to estimate how much power PV plants can produce. However, the varying nature of the DC input power to the inverters, occasioned by varying irradiation and temperature, leads to deviations of the actual efficiency from the peak efficiency. Literature surveys prove that inverter efficiencies must be evaluated against local irradiation profiles to get more precise annual energy yield estimations, since meteorological conditions and solar irradiation profiles vary from one site to another around the planet.

Pulsing the flow of reactants in proton exchange membrane fuel cells (PEMFC) is a new frontier in the area of fuel cell research. Although power performance losses resulting from water accumulation also referred to as flooding, and power performance recovery resulting from water removal or purging, have been studied and monitored, the nexus between pulsing of reactants and power performance has yet to be established. This study introduces pulsing of reactants as a method of improving power performance. This study investigates how under continuous supply of reactants, pressure increase due to water accumulation, and power performance decay in PEMFCs. Furthermore, this study shows that power performance can be optimized through pulsing of reactants, and it investigates several variables affecting the power production under these conditions. Specifically, changes in frequency, duty cycle, and shifting of reactants as they affect performance are monitored and analyzed. Advanced data acquisition and control software allow multi-input monitoring of thermo-fluid and electrical data, while analog and digital controllers make it possible to implement optimization techniques for both discrete and continuous modes. / by Aquiles Perez. / Thesis (Ph.D.)--Florida Atlantic University, 2009. / Includes bibliography. / Electronic reproduction. Boca Raton, Fla., 2009. Mode of access: World Wide Web.

The goal of this Thesis is to demonstrate, through experimentation, that ocean waves have a positive effect on the performance of an offshore wind turbine. A scale model wind turbine was placed into a wave tank that was completely covered and fitted with a variable speed fan to create different wind and wave conditions for testing. Through testing, different power coefficient vs. tip speed ratio graphs were created and a change in power coefficient was observed between steady operating conditions and operating conditions with waves. The results show a promising increase in power production for offshore wind turbines when allowed to operate with the induced motion caused by the amplitude and frequency of water waves created. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2013.

The objective of the research is to develop various green-house gas (GHG) mitigations scenarios in the energy demand and supply sectors for state of Florida through energy and environment modeling tool called LEAP (Long Range Energy Alternative Planning System Model) for 2010-2050. The GHG mitigation scenarios consist of various demand and supply side scenarios. One of the GHG mitigation scenarios is crafted by taking into account the available renewable resources potential for power generation in the state of Florida and then the comparison has been made for transformation sector and corresponding GHG emissions through this newly developed mitigation scenario versus Business As Usual and Florida State Policy scenario. Moreover two master mitigation scenarios (Electrification and Efficiency and Lifestyle) were crafted through combination of certain GHG mitigation scenarios. The energy demand and GHG emissions assessment is performed for both master mitigation scenarios versus business As Usual scenario for 2010 – 2050. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection