This thesis presents the problem surrounding green marketing, which involves the lack of knowledge of green consumption by the consumer, and the threats of green washing from companies who present green marketing without achieving the green marketing criteria. An implementation of the green marketing theories in the cases of Patagonia and Klättermusen: green marketing five “I’s” and the green marketing three “C’s” was done in order to understand if the two companies fit the green marketing profile. This thesis aims to contribute to gain deeper knowledge from the outdoor consumer perspective on green marketing campaigns, and answer the question to how effective these campaigns are to the outdoor consumer, through a qualitative research.

Les dynamiques territoriales sont le résultat des jeux d'acteurs au sein d'un espace géographique déterminé. Les comprendre suppose de cerner les stratégies d'acteurs et leurs rapports au territoire. L'ancrage progressif d'un espace à la frontière de l'écoumène dans l'économie du tourisme induit des changements socio-spatiaux importants. Quelles logiques sociogéographiques caractérisent alors la mise en tourisme des confins de nature ? Les dynamiques des destinations touristiques sont abondamment étudiées, mais celles des confins de nature ne le sont pas. Lieux marginaux, périphériques ou frontaliers, ils sont omniprésents dans les imaginaires du voyage, car chargés d'altérité, et constituent des objets géographiques à part entière [partie I]. Dans un monde toujours plus urbanisé, les confins de nature les moins connus, qualifiés de Wilderness par les Anglo-saxons, attirent de plus en plus les touristes de toutes origines.L'analyse des spécificités physiques, des données statistiques et cartographiques des confins touristiques de nature montre la pertinence spatiale de la notion. L'interprétation des discours d'acteurs du tourisme de nature permet d'en préciser les attributs sociaux culturels et les imaginaires qui s'y rattachent. Les territoires de nature sont des construits sociaux, le produit d'une organisation culturelle singulière. Différentes représentations sociales, individuelles ou collectives, produisent des discours et des logiques d'acteurs. Il en résulte différentes formes de développements des espaces touristiques, qui sont étatiques, industrielles, traditionalistes, entrepreneuriales, écologiques, alternatives ou récréatives [partie II].L'apparition d'une forme dépend de conditions historiques et culturelles sur un territoire. Il est possible de les identifier sur un espace de nature grâce à l'analyse du discours des acteurs du tourisme et aux matérialités spatiales qui résultent de leurs actions. Les dynamiques à l'œuvre sur un territoire de pratiques récréatives sont tributaires des rapports qu'entretiennent des collectifs d'acteurs ayant des conceptions différenciées du développement. Des confrontations et des compromis entre des formes de développement touristique s'établissent dans le temps et dans l'espace [partie III]. Malgré des représentations de la nature et des justifications économiques distinctes, celles-ci peuvent s'unir face à une menace affectant leurs intérêts. C'est le cas, par exemple, lors des conflits environnementaux, autour de l'usage industriel des ressources hydriques. En revanche des politiques publiques voulant favoriser le développement économique du territoire tendent à n'appuyer qu'une forme de développement et attiser alors les affrontements idéologiques. L'analyse des projets publics et privés dans la région d'Aysén en Patagonie chilienne montre que les projets d'États favorisent de manière partiale certains acteurs du territoire. Seuls certains projets, tels que celui du tourisme scientifique, parviennent à fédérer les acteurs. Ceci est rendu possible par un processus de participation active à un projet territorialisé, culturel plus que commercial, basé sur le partage de connaissances et une spécification de la ressource touristique. L'action d'un animateur et médiateur, responsable de l'ingénierie territoriale, assure la mise en œuvre de l'initiative collective.Une lecture par les formes de développement touristique apparait comme particulièrement pertinente pour caractériser les systèmes émergents. L'étude des tensions à l'œuvre dans les confins de nature révèle des processus caractéristiques des sociétés contemporaines, le tourisme étant au cœur des contradictions de nos civilisations ancrées dans les métropoles. / Territorial dynamics are the result of a games of actors within a given geographical area. Understanding them involves identifying the actors' strategies and their relationship to the territory. The gradual investment of at the frontier of civilization to the tourism economy induces significant socio-spatial changes. What are the socio-geographical logics that characterize the tourism transformation of the nature borderlands? The dynamics of tourism destinations are extensively studied but those of nature's borderlands are not. Marginal, peripheral or frontier places are strong in the traveler's imaginaries, they are exotic and constitute geographical objects of their own [part I]. In an ever more urbanized world, the lesser-known areas of nature, defined as Wilderness in the Anglo-Saxon culture, are attracting evermore tourists of all origins.The analysis of the physical particularities, statistical and cartographic data of Touristic Nature Borderland shows the spatial relevancy of the notion. A critical analysis of nature tourism actors' speeches shows their the social-cultural attributes and the imaginaries associated to them. Nature territories are social constructs, they result of a unique cultural organization. Different social representations, individual or collective, generate actor's speeches and actions. They build different Tourism Development Forms that have different logics; state, industrial, traditionalist, entrepreneurial, ecological, alternative or recreational [Part II].The appearance of a form depends on historical and cultural conditions of a territory. It is possible to identify them on a nature area by analyzing tourism actor's speeches and the spatial materiality which result from their actions. The dynamics at work in a recreational area are the result of the existing relationships between group of actors with different conceptions of development. Confrontations and agreements between Tourism Development Forms arise in time and space [part III]. Despite distinct representations of nature and economical justifications, they can unite against a threat to their interests. This is the case, for example, during environmental conflicts, around the industrial use of water resources. On the other hand, public policies wanting to promote the economic development of the territory tend to support only one form of development and thus favor ideological confrontations. The analysis of public and private projects in the region of Aysén in Chilean Patagonia, shows that these favor in partial manner certain actors of the territory. Only some projects, such as scientific tourism, manage to unite actors. This is made possible by empowering them trough a territorial project, cultural rather than commercial, based on the sharing of knowledges and the specification of the tourism resources. The work of a facilitator and mediator, in charge of territorial engineering, insures the collective initiative.A reading through the Tourism Development Forms proves particularly relevant for emerging systems. The study of the existing conflicts in Nature based Borderlands reveals processes that are characteristic of modern societies, tourism being at the heart of the contradictions of our civilization anchored in the metropolis.

Informe de Seminario para optar al grado de Licenciado en Historia / Seminario de Grado: Entre el mundo árabe-islámico, Europa y América: migraciones e identidades en transformación en las dinámicas contemporáneas

Texte remanié de : Tesis doctoral : filosofia y letras : Buenos aires : 2003. / Les 9 premières pages sont en chiffres romains. Bibliogr. p. 179-196.

La partie inférieure de la rivière Colorado constitue une frontière naturelle entre les régions argentines de la Pampa et de la Patagonie. Dans cette zone géographique, carrefour entre diverses provinces et régions, les études phytogeographiques et zoogéographiques ont montré l’existence de caractéristiques environnementales particulières. Le projet « Investigations archéologiques dans la partie inférieure de la rivière Colorado », au sein duquel s’inscrit ce travail, a pour objectif principal d’étudier la culture matérielle des chasseurs-cueilleurs de cette zone géographique afin de comprendre leur adaptation et leur évolution durant l’Holocène entre 3 000 et 250 ans BP. Les dynamiques de peuplement de la Pampa et de la Patagonie à la fin de l’Holocène (environ 1000-250 ans BP) ont été décrites par plusieurs chercheurs comme une mosaïque de groupes qui témoigne de contacts inter-ethniques et d’échanges à différentes échelles (locale, extra-régionale, trans-andine). L’objectif de cette thèse est de définir l’organisation technologique des groupes de chasseurs-cueilleurs qui occupent la zone géographique concernée durant la fin de l’Holocène. Pour y répondre, les matières premières exploitées sont caractérisées. De plus, les méthodes de débitage et l’analyse économique des assemblages lithiques sont identifiées par le biais de l’approche théorique et méthodologique de la chaîne opératoire. Les résultats de cette thèse montrent une constance des savoir-faire technologiques tout au long de la fin de l’Holocène. Les changements technologiques perçus dans les comportements à la fin de l’Holocène tardif (environ 1000-250 ans BP) sont dus aux choix parmi les méthodes, les matières premières et les types d’outils connus ou disponibles de ceux les plus efficaces pour lesquels la production s’intensifie à partir de 1000 BP. Les changements comportementaux discernés dans le système de la technologie lithique sont accompagnés voire résultent d’une réorganisation du système social dans son ensemble. Plus généralement, cette situation est également observée dans les sociétés de chasseurs-cueilleurs des zones ou régions voisines (Pampa et Nord Patagonie) à la fin de l’Holocène tardif. / The lower Colorado River is considered the geographical boundary between [the Argentinean regions of Pampa and Patagonia]. In this area converges various provinces and regions, as well as phytogeographical and zoogeographical sub-domains that give to the environment ecotonal characteristics. The project Archaeological Investigations in the Lower Colorado River, which is part of this work, has as its central objective the study of the material culture, adaptation and evolution of hunter-gatherer peoples who occupied the area during the Holocene-3000-250 years BP. The population’s dynamics of the Pampas and Patagonia regions in the final late Holocene (ca. 1000-250 years BP) was described by several researchers as a complex map of inter-ethnic contacts and networks between groups at local, extra-regional and transandean range scale. The aim of this thesis is to define the technological patterns of hunter-gatherer groups who inhabited the studied area during the late Holocene. In order to do so, the nature and presentation of raw materials exploited is stated, and the different methods of debitage and economic analysis of the lithic assemblages are identified, within the theoretical and methodological approach of chaîne opératoires. The results of this thesis allow concluding that during the late Holocene the basis of technological knowledge is kept constant. The technological changes experienced in behavior toward the final late Holocene (ca. 1000-250 years BP) are due to the choice among methods, materials, and types of instruments known and available, of those with proven efficacy, whose production was intensified in the last 1000 years B.P. The behavioral changes linked to lithic technological system are accompanied by -or produced as a result of- reorganization of the social system as a whole. In general terms, this situation is also observed in hunters gathered societies in neighboring areas and regions (Pampean and Northen Patagonic regions) towards final late Holocene.

Satellite altimetry has been traditionally used in the past few decades to measure elevation of land ice, quantify changes in ice topography and infer the mass balance of large and remote areas such as the Greenland and Antarctic ice sheets. Radar altimetry is particularly well suited to this task due to its all-weather year-round capability of observing the ice surface. However, monitoring of ice caps and ice fields - bodies of ice with areas typically smaller than ~ 10,000 km2 - has proven more challenging. The large footprint of a conventional radar altimeter and coarse ground track coverage are less suited to observing comparatively small regions with complex topography. Since 2010, the European Space Agency’s CryoSat-2 satellite has been collecting ice elevation measurements over ice caps and ice fields with its novel radar altimeter. CryoSat-2’s smaller inter-track spacing provides higher density of observations compared to previous satellite altimeters. Additionally, it generates more accurate measurements because (i) the footprint size is reduced in the along-track direction by means of synthetic aperture radar processing and (ii) interferometry allows to precisely locate the the across-track angle of arrival of a reflection from the surface. Furthermore, the interferometric capabilities of CryoSat-2 allow for the processing of the delayed surface reflections after the first echo. When applied over a sloping surface, this procedure generates a swath of elevations a few km wide compared to the conventional approach returning a single elevation. In this thesis, swath processing of CryoSat-2 interferometric data is exploited to generate topographic data over ice caps and ice fields. The dense elevation field is then used to compute maps of elevation change rates at sub-kilometer resolution with the aim of quantifying ice volume change and mass balance. A number of algorithms have been developed in this work, partly or entirely, to form a complete processing chain from generating the elevation field to calculating volume and mass change. These algorithms are discussed in detail before presenting the results obtained in two selected regions: Iceland and Patagonia. Over Icelandic ice caps, the high-resolution mapping reveals complex surface elevation changes, related to climate, ice dynamics and sub-glacial, geothermal and magmatic processes. The mass balance of each of the six largest ice caps (90% of Iceland’s permanent ice cover) is calculated independently for the first time using spaceborne radar altimetry data. Between October 2010 and September 2015 Icelandic ice caps have lost a total of 5.8± 0.7 Gt a ̄1, contributing 0.016± 0.002 mm a ̄1 to eustatic sea level rise. This estimate indicates that over this period the mass balance was 40% less negative than the preceding 15 years, a fact which partly reflects the anomalous positive balance year across the Vatnaj ̈okull ice cap (~ 70% of the glaciated area) in 2014/15. Furthermore, it is demonstrated how swath processing of CryoSat-2 interferometric data allows the monitoring of glaciological processes at the catchment scale. Comparison of the geodetic estimates of mass balance against those based on in situ data shows good agreement. The thesis then investigates surface elevation change on the Northern and Southern Patagonian Ice Fields to quantify their mass balance. This area is characterized by some of the fastest flowing glaciers in the world, displaying complex interactions with the proglacial environments (including marine fjords and freshwater lakes) they often drain into. Field observations are sparse due to the inaccessibility of these ice fields and even remotely sensed data are limited, often tied to comparisons to the topography in 2000 as measured by the Shuttle Radar Topography Mission. Despite gaps in the spatial coverage, in particular due to the complex topography, CryoSat-2 swath radar altimetry provides insight into the patterns of change on the ice fields in the most recent period (2011 to 2017) and allows to independently calculate the mass balance of glaciers or catchments as small as 300 km2. The northern part of the Southern Patagonian ice field displays the strongest losses due to a combination between ice dynamics and warming temperatures. In contrast Pio XI, the largest glacier on this ice field and in South America, is advancing and gaining mass. Between April 2011 and march 2017, the two ice fields combined have lost an average of 21.29± 1.98 Gt a ̄1 (equivalent to 0.059± 0.005 mm a ̄1 eustatic sea level rise), 24% and 42% more negative when compared to the periods 2000-2012/14 and 1975-2000. In particular the Northern Patagonian ice field, responsible for one third of the mass loss, is losing mass 70% faster compared to the first decade of the 21st century. These results confirm the overall strong mass loss of the Patagonian ice fields, second only to glaciers and ice caps in Alaska and the Canadian Arctic, and higher than High Mountain Asia, which all extend over areas ~ 5-8 times larger (excluding glaciers at the periphery of the Greenland and Antarctic ice sheets).

Au cours des dernières décennies, l'étude des paléoenvironnements de l’Hemisphere Sud s’est développée avec les informations fournies par l'analyse des carottes de glace polaires et plus récemment à partir des carottes de glace prélevées dans les Andes. Bien que les zones tropicales et subtropicales de l'Amérique du Sud jouent un rôle majeur dans la chimie atmosphérique globale en raison de l’existence de réservoirs importants, les échanges entre l’équateur et les hautes latitudes sud restent encore peu documentés. Même si d’autres archives apportent des informations sur le climat passé, il existe peu de données de la composition atmosphérique des moyennes latitudes de l’Hémisphère Sud, aussi bien en termes de variabilité naturelle que d’impact anthropique.Ce travail est basé sur l'analyse d'une carotte de glace de 122 m extraite d’un site d'altitude en Patagonie (Monte San Valentin 46º 35' S, 73º19' W, 3723 m). Outre l’établissement de profils à haute résolution des ions minéraux et organiques obtenus par chromatographie ionique, nous avons réalisé une étude des précipitations susceptibles d'influencer le site, fournissant ainsi une base pour l'interprétation de l'archive de glace.Ce site se caractérise par l’enregistrement d’événements à caractère marin et continental. Nous avons démontré que, sur ce glacier, les contributions marines primaires et secondaires ne sont pas synchrones et qu’elles sont très probablement sousreprésentées dans le profil en raison de processus d'accumulation. Contrairement au sel de mer, une partie importante des aérosols biogéniques marins est associée à un apport influencé par des contributions continentales diluées. L’apport continental est complexe : il est composé d’événements ponctuels de combustion, de retombées volcaniques et d’émissions par les sols. Il correspond à presque la moitié de la quantité totale de sulfate déposé. Cette contribution importante et omniprésente de sulfate est associée au nitrate et au chlorure, mais mieux cerner son origine nécessiterait des recherches plus poussées. La comparaison de notre archive glaciochimique avec des éruptions volcaniques datées et le début de la colonisation en Patagonie nous a permis de proposer quelques repères pour la datation de la carotte, qui reste à ce jour encore incertaine. Enfin, aucune tendance anthropique claire n’a été décelée à partir de l’évolution du bruit de fond des espèces continentales, excepté l'ammonium, lui pouvant être mis en relation avec l’utilisation croissante d'engrais après les années 1960. / Although tropical and subtropical South America play an important role in atmospheric global and hemispheric chemistry due to the coexistence of big reservoirs with large-scale atmospheric patterns, exchanges between tropics and higher latitudes have remained poorly documented. During the last few decades, the study of past climate and atmospheric composition has benefited greatly by information provided by ice core analysis. In the Southern Hemisphere, a large amount of data is now available from polar ice cores and more recently from ice cores recovered in the Andes. Despite a few studies on climate reconstruction, there is a lack of information on past atmospheric composition in Southern mid-latitudes, in terms of both natural variability and anthropogenic impact. This work is based on the analysis of a 122 m ice core extracted from a high altitude site in the Northern Patagonian Icefield (Monte San Valentin 46º 35'S, 73º19' W, summit at 4032 m.a.s.l., drilling plateau at 3723 m.a.s.l.). Besides high-resolution measurements of mineral and organic ions, a study of the precipitation events likely to influence the site was conducted in order to provide a basis for the interpretation of the ice archive. The selected site registers precipitation events of marine and continental origin. We have demonstrated that marine primary and biogenic contributions are not synchronous and they are very likely underrepresented along the ice archive due to the effect of accumulation processes. Contrary to sea salt, a significant part of marine biogenic aerosol is associated with a complex and diluted continental fingerprint. The continental imprint was studied in terms of background trends and major events involving combustion processes, urban pollution, volcanic and soil emissions. This set of mixed sources is responsible for almost half of the total sulfate input. This important and ubiquitous sulfate concentration is related to that of nitrate and chloride and its understanding in terms of sources and transport needs further research. A comparison of our records with documented volcanic eruptions and Patagonian settlement periods allowed us to propose a few dating horizons, although an accurate dating of the entire core has not been possible so far. Background trends of continental species do not show any trend that can be clearly associated with an anthropogenic influence, except for ammonium, which increases likely in response to fertilizer consumption after ca. 1960.

O campo vulcânico Patagônico é composto pelo vulcanismo datado do Quaternário ao Cretáceo e está amplamente distribuído no ambiente geotectônico de extra back-arc continental. Onze vulcões associados à ocorrência de xenólitos mantélicos estão situados dos 36°13’S aos 44°52’S. Estes vulcões são dominantemente compostos por basanitos e a basaltos alcalinos, que são divididos em dois grupos com base em aspectos petrográficos, geoquímicos e isotópicos. (Grupos I e II). Estes Grupos estão relacionados a fontes mantélicas similares, mas foram submetidos a diferentes processos metassomáticos. Os Grupos I e I foram gerados a partir de baixas taxas de fusão a partir de uma fonte mantélica do tipo OIB na zona de estabilidade da granada, mas o Grupo II tem características de manto enriquecido (EMII) possivelmente herdadas de um agente metassomático relacionado à zona de subducção, enquanto que o Grupo I demonstra assinatura geoquímica de magmas tipo OIB relacionados a fontes mantélicas ricas em flogopita. Os basaltos alcalinos do vulcão Agua Poca (37º01’S - 68º07’W) pertencem ao Grupo II e são traquibasaltos. O vulcão Agua Poca é definido é piroclástico monogenético, é composto por intercalações de camadas de spatter e cinder, hospeda xenólitos mantélicos e está localizado a oeste da Província de La Pampa, no extremo norte da Argentina. As amostras de xenólitos mostram textura protogranular, protogranular a porfiroclástica, porfiroclástica e porfiroclástica a equigranular e são compostos por olivina (fosterita), ortopiroxênio (enstatita), clinopiroxênio (diopsídio) e espinélio (sp). Os xenólitos estudados são peridotitos da fácies espinélio e piroxenitos anidros em basaltos alcalinos do Pleistoceno com #Mg em rocha total de 89 a 91. As assinaturas geoquímicas desses xenólitos mostram correlação negativa entre os principais óxidos quando dispostos contra o #Mg e estão empobrecidos em elementos incompatíveis em relação ao manto primitivo (MP). Os xenólitos do vulcão Agua Poca são caracterizados pelo empobrecimento de ETRP e ETRM normalizados para o MP e pelo fracionamento de ETRL em relação aos ETRP (CeN/YbN = 0,15-0,5), com exceção da amostra HAP10 (1,46). Esse comportamento indica que os xenólitos do terreno Cuyania são o resultado de 1 a 10% de fusão do DMM (Manto Depletado) ou de 8 a 17% do MP (Manto Primitivo). Em geral, os peridotitos mostram anomalias positivas de Ba, U, Ta, Pb, Zr e Ti; e anomalias negativas de Rb, Th, Nb, La e Y, enquanto que os piroxenitos mostram anomalias positivas de Ba, U, Ta e Pb; e anomalias negativas de Th, Nb, La, Zr, Hf, Ti e Y. Curvas de mistura calculadas para o resíduo de fusão do MP/DMM com a composição de fluídos/sedimentos derivados de ambientes de subducção indicam interação do manto com até 3% de fluídos/sedimentos. As razões 87Sr/86Sr (0,702874 - 0,704999, com média de 0,704035) são muito similares àquelas definidas para peridotitos com fonte tipo OIB. Agua Poca tem razões 87Sr/86Sr, que estão abaixo daquelas definidas para peridotitos metassomatizados (usualmente >0,705). As razões de Nb/Ta sugerem a presença de um reservatório eclogítico refratário subductado fusão parcial gerando líquidos alcalinos com razões Nb/Ta supercondríticas. / The Patagonian Volcanic Field composed of late Cretaceous to Quaternary volcanism is widely distributed in a continental extra back-arc geotectonic environment. Eleven monogenetic volcanoes accompanied with ultramafic xenoliths are situated from 36°13′S to 44°52′S. These volcanoes are dominantly composed of basanite to alkaline basalt, which are divided into two groups, based on mineralogy, geochemical and isotope compositions (Groups I and II). These Groups are originated from the similar subcontinental mantle sources, but were undergone to different metasomatism processes. Groups I and II were generated from low melting degrees of an OIB-like garnet peridotite, but the Group II has enriched mantle (EMII) characteristics possibly inherited from on-going subduction related metasomatism, while Group I demonstrates the OIB-like signature, which might result from phlogopite-bearing in the subcontinental lithosphere. The alkaline basalts from Agua Poca volcano (37º01’S - 68º07’W) belong to the Group II and are trachybasalts. The Agua Poca volcano is a monogenetic pyroclastic volcano composed by intercalation of spatter and cinder layers, host ultramafic mantle xenoliths and is located in the West of the La Pampa Province, Northernmost of Argentine Patagonia. The xenoliths show protogranular, protogranular to porphyroclastic, porphyroclastic and porphyroclastic to equigranular textures, and are composed of olivine (fosterite), orthopyroxene (enstatite), clinopyroxene (diopside) and spinel (sp). The studied xenoliths are anhydrous spinel-bearing peridotite and pyroxenite xenoliths in Pleistocene alkali basalts with whole rock Mg# from 88 to 91. Geochemical signatures of the mantle xenoliths show negative correlation between main oxides against Mg# and depletion in incompatible elements compared to primitive mantle (PM). Agua Poca mantle xenoliths are characterized by flat Sun & McDonough (1989) primitive mantle (PM) normalized HREE and MREE patterns, and depletion of LREE compared to HREE (CeN/YbN = 0.15-0.5), with exception of the HAP10 (1.46) sample. These characteristics suggest that partial melting event is the main process responsible for the generation of these xenoliths. Model calculations suggest that the xenoliths are the result of 1 to 10% of DMM (Depleted Mantle MORB) or 8 to 17% of PM partial melting. Peridotite samples show positive anomalies of Ba, U, Ta, Pb, Zr and Ti; and negative anomalies of Rb, Th, Nb, La and Y, while the pyroxenite samples show positive anomalies of Ba, U, Ta and Pb; and negative anomalies of Th, Nb, La, Zr, Hf, Ti and Y. Mixing curves calculated to mixtures of melting residue of PM/DMM and fluid or sediment compositions related to subduction tectonic setting end members suggest up to 3% of interaction of the fluid sediment on the depleted mantle residue. 87Sr/86Sr ratios (0.702874 - 0.704999, with average of 0.704035) are similar to those defined to peridotites with OIB source (87Sr/86Sr = 0.70244 to 0.70502), being close to Depleted Mantle (DM; 87Sr/86Sr = 0.7023 to 0.7032) values. Nb/Ta ratios suggest that Agua Poca xenoliths were undergone to partial melting processes that generated alkaline magmas with superchondritic Nb/Ta ratios.

O campo vulcânico Patagônico é composto pelo vulcanismo datado do Quaternário ao Cretáceo e está amplamente distribuído no ambiente geotectônico de extra back-arc continental. Onze vulcões associados à ocorrência de xenólitos mantélicos estão situados dos 36°13’S aos 44°52’S. Estes vulcões são dominantemente compostos por basanitos e a basaltos alcalinos, que são divididos em dois grupos com base em aspectos petrográficos, geoquímicos e isotópicos. (Grupos I e II). Estes Grupos estão relacionados a fontes mantélicas similares, mas foram submetidos a diferentes processos metassomáticos. Os Grupos I e I foram gerados a partir de baixas taxas de fusão a partir de uma fonte mantélica do tipo OIB na zona de estabilidade da granada, mas o Grupo II tem características de manto enriquecido (EMII) possivelmente herdadas de um agente metassomático relacionado à zona de subducção, enquanto que o Grupo I demonstra assinatura geoquímica de magmas tipo OIB relacionados a fontes mantélicas ricas em flogopita. Os basaltos alcalinos do vulcão Agua Poca (37º01’S - 68º07’W) pertencem ao Grupo II e são traquibasaltos. O vulcão Agua Poca é definido é piroclástico monogenético, é composto por intercalações de camadas de spatter e cinder, hospeda xenólitos mantélicos e está localizado a oeste da Província de La Pampa, no extremo norte da Argentina. As amostras de xenólitos mostram textura protogranular, protogranular a porfiroclástica, porfiroclástica e porfiroclástica a equigranular e são compostos por olivina (fosterita), ortopiroxênio (enstatita), clinopiroxênio (diopsídio) e espinélio (sp). Os xenólitos estudados são peridotitos da fácies espinélio e piroxenitos anidros em basaltos alcalinos do Pleistoceno com #Mg em rocha total de 89 a 91. As assinaturas geoquímicas desses xenólitos mostram correlação negativa entre os principais óxidos quando dispostos contra o #Mg e estão empobrecidos em elementos incompatíveis em relação ao manto primitivo (MP). Os xenólitos do vulcão Agua Poca são caracterizados pelo empobrecimento de ETRP e ETRM normalizados para o MP e pelo fracionamento de ETRL em relação aos ETRP (CeN/YbN = 0,15-0,5), com exceção da amostra HAP10 (1,46). Esse comportamento indica que os xenólitos do terreno Cuyania são o resultado de 1 a 10% de fusão do DMM (Manto Depletado) ou de 8 a 17% do MP (Manto Primitivo). Em geral, os peridotitos mostram anomalias positivas de Ba, U, Ta, Pb, Zr e Ti; e anomalias negativas de Rb, Th, Nb, La e Y, enquanto que os piroxenitos mostram anomalias positivas de Ba, U, Ta e Pb; e anomalias negativas de Th, Nb, La, Zr, Hf, Ti e Y. Curvas de mistura calculadas para o resíduo de fusão do MP/DMM com a composição de fluídos/sedimentos derivados de ambientes de subducção indicam interação do manto com até 3% de fluídos/sedimentos. As razões 87Sr/86Sr (0,702874 - 0,704999, com média de 0,704035) são muito similares àquelas definidas para peridotitos com fonte tipo OIB. Agua Poca tem razões 87Sr/86Sr, que estão abaixo daquelas definidas para peridotitos metassomatizados (usualmente >0,705). As razões de Nb/Ta sugerem a presença de um reservatório eclogítico refratário subductado fusão parcial gerando líquidos alcalinos com razões Nb/Ta supercondríticas. / The Patagonian Volcanic Field composed of late Cretaceous to Quaternary volcanism is widely distributed in a continental extra back-arc geotectonic environment. Eleven monogenetic volcanoes accompanied with ultramafic xenoliths are situated from 36°13′S to 44°52′S. These volcanoes are dominantly composed of basanite to alkaline basalt, which are divided into two groups, based on mineralogy, geochemical and isotope compositions (Groups I and II). These Groups are originated from the similar subcontinental mantle sources, but were undergone to different metasomatism processes. Groups I and II were generated from low melting degrees of an OIB-like garnet peridotite, but the Group II has enriched mantle (EMII) characteristics possibly inherited from on-going subduction related metasomatism, while Group I demonstrates the OIB-like signature, which might result from phlogopite-bearing in the subcontinental lithosphere. The alkaline basalts from Agua Poca volcano (37º01’S - 68º07’W) belong to the Group II and are trachybasalts. The Agua Poca volcano is a monogenetic pyroclastic volcano composed by intercalation of spatter and cinder layers, host ultramafic mantle xenoliths and is located in the West of the La Pampa Province, Northernmost of Argentine Patagonia. The xenoliths show protogranular, protogranular to porphyroclastic, porphyroclastic and porphyroclastic to equigranular textures, and are composed of olivine (fosterite), orthopyroxene (enstatite), clinopyroxene (diopside) and spinel (sp). The studied xenoliths are anhydrous spinel-bearing peridotite and pyroxenite xenoliths in Pleistocene alkali basalts with whole rock Mg# from 88 to 91. Geochemical signatures of the mantle xenoliths show negative correlation between main oxides against Mg# and depletion in incompatible elements compared to primitive mantle (PM). Agua Poca mantle xenoliths are characterized by flat Sun & McDonough (1989) primitive mantle (PM) normalized HREE and MREE patterns, and depletion of LREE compared to HREE (CeN/YbN = 0.15-0.5), with exception of the HAP10 (1.46) sample. These characteristics suggest that partial melting event is the main process responsible for the generation of these xenoliths. Model calculations suggest that the xenoliths are the result of 1 to 10% of DMM (Depleted Mantle MORB) or 8 to 17% of PM partial melting. Peridotite samples show positive anomalies of Ba, U, Ta, Pb, Zr and Ti; and negative anomalies of Rb, Th, Nb, La and Y, while the pyroxenite samples show positive anomalies of Ba, U, Ta and Pb; and negative anomalies of Th, Nb, La, Zr, Hf, Ti and Y. Mixing curves calculated to mixtures of melting residue of PM/DMM and fluid or sediment compositions related to subduction tectonic setting end members suggest up to 3% of interaction of the fluid sediment on the depleted mantle residue. 87Sr/86Sr ratios (0.702874 - 0.704999, with average of 0.704035) are similar to those defined to peridotites with OIB source (87Sr/86Sr = 0.70244 to 0.70502), being close to Depleted Mantle (DM; 87Sr/86Sr = 0.7023 to 0.7032) values. Nb/Ta ratios suggest that Agua Poca xenoliths were undergone to partial melting processes that generated alkaline magmas with superchondritic Nb/Ta ratios.

O campo vulcânico Patagônico é composto pelo vulcanismo datado do Quaternário ao Cretáceo e está amplamente distribuído no ambiente geotectônico de extra back-arc continental. Onze vulcões associados à ocorrência de xenólitos mantélicos estão situados dos 36°13’S aos 44°52’S. Estes vulcões são dominantemente compostos por basanitos e a basaltos alcalinos, que são divididos em dois grupos com base em aspectos petrográficos, geoquímicos e isotópicos. (Grupos I e II). Estes Grupos estão relacionados a fontes mantélicas similares, mas foram submetidos a diferentes processos metassomáticos. Os Grupos I e I foram gerados a partir de baixas taxas de fusão a partir de uma fonte mantélica do tipo OIB na zona de estabilidade da granada, mas o Grupo II tem características de manto enriquecido (EMII) possivelmente herdadas de um agente metassomático relacionado à zona de subducção, enquanto que o Grupo I demonstra assinatura geoquímica de magmas tipo OIB relacionados a fontes mantélicas ricas em flogopita. Os basaltos alcalinos do vulcão Agua Poca (37º01’S - 68º07’W) pertencem ao Grupo II e são traquibasaltos. O vulcão Agua Poca é definido é piroclástico monogenético, é composto por intercalações de camadas de spatter e cinder, hospeda xenólitos mantélicos e está localizado a oeste da Província de La Pampa, no extremo norte da Argentina. As amostras de xenólitos mostram textura protogranular, protogranular a porfiroclástica, porfiroclástica e porfiroclástica a equigranular e são compostos por olivina (fosterita), ortopiroxênio (enstatita), clinopiroxênio (diopsídio) e espinélio (sp). Os xenólitos estudados são peridotitos da fácies espinélio e piroxenitos anidros em basaltos alcalinos do Pleistoceno com #Mg em rocha total de 89 a 91. As assinaturas geoquímicas desses xenólitos mostram correlação negativa entre os principais óxidos quando dispostos contra o #Mg e estão empobrecidos em elementos incompatíveis em relação ao manto primitivo (MP). Os xenólitos do vulcão Agua Poca são caracterizados pelo empobrecimento de ETRP e ETRM normalizados para o MP e pelo fracionamento de ETRL em relação aos ETRP (CeN/YbN = 0,15-0,5), com exceção da amostra HAP10 (1,46). Esse comportamento indica que os xenólitos do terreno Cuyania são o resultado de 1 a 10% de fusão do DMM (Manto Depletado) ou de 8 a 17% do MP (Manto Primitivo). Em geral, os peridotitos mostram anomalias positivas de Ba, U, Ta, Pb, Zr e Ti; e anomalias negativas de Rb, Th, Nb, La e Y, enquanto que os piroxenitos mostram anomalias positivas de Ba, U, Ta e Pb; e anomalias negativas de Th, Nb, La, Zr, Hf, Ti e Y. Curvas de mistura calculadas para o resíduo de fusão do MP/DMM com a composição de fluídos/sedimentos derivados de ambientes de subducção indicam interação do manto com até 3% de fluídos/sedimentos. As razões 87Sr/86Sr (0,702874 - 0,704999, com média de 0,704035) são muito similares àquelas definidas para peridotitos com fonte tipo OIB. Agua Poca tem razões 87Sr/86Sr, que estão abaixo daquelas definidas para peridotitos metassomatizados (usualmente >0,705). As razões de Nb/Ta sugerem a presença de um reservatório eclogítico refratário subductado fusão parcial gerando líquidos alcalinos com razões Nb/Ta supercondríticas. / The Patagonian Volcanic Field composed of late Cretaceous to Quaternary volcanism is widely distributed in a continental extra back-arc geotectonic environment. Eleven monogenetic volcanoes accompanied with ultramafic xenoliths are situated from 36°13′S to 44°52′S. These volcanoes are dominantly composed of basanite to alkaline basalt, which are divided into two groups, based on mineralogy, geochemical and isotope compositions (Groups I and II). These Groups are originated from the similar subcontinental mantle sources, but were undergone to different metasomatism processes. Groups I and II were generated from low melting degrees of an OIB-like garnet peridotite, but the Group II has enriched mantle (EMII) characteristics possibly inherited from on-going subduction related metasomatism, while Group I demonstrates the OIB-like signature, which might result from phlogopite-bearing in the subcontinental lithosphere. The alkaline basalts from Agua Poca volcano (37º01’S - 68º07’W) belong to the Group II and are trachybasalts. The Agua Poca volcano is a monogenetic pyroclastic volcano composed by intercalation of spatter and cinder layers, host ultramafic mantle xenoliths and is located in the West of the La Pampa Province, Northernmost of Argentine Patagonia. The xenoliths show protogranular, protogranular to porphyroclastic, porphyroclastic and porphyroclastic to equigranular textures, and are composed of olivine (fosterite), orthopyroxene (enstatite), clinopyroxene (diopside) and spinel (sp). The studied xenoliths are anhydrous spinel-bearing peridotite and pyroxenite xenoliths in Pleistocene alkali basalts with whole rock Mg# from 88 to 91. Geochemical signatures of the mantle xenoliths show negative correlation between main oxides against Mg# and depletion in incompatible elements compared to primitive mantle (PM). Agua Poca mantle xenoliths are characterized by flat Sun & McDonough (1989) primitive mantle (PM) normalized HREE and MREE patterns, and depletion of LREE compared to HREE (CeN/YbN = 0.15-0.5), with exception of the HAP10 (1.46) sample. These characteristics suggest that partial melting event is the main process responsible for the generation of these xenoliths. Model calculations suggest that the xenoliths are the result of 1 to 10% of DMM (Depleted Mantle MORB) or 8 to 17% of PM partial melting. Peridotite samples show positive anomalies of Ba, U, Ta, Pb, Zr and Ti; and negative anomalies of Rb, Th, Nb, La and Y, while the pyroxenite samples show positive anomalies of Ba, U, Ta and Pb; and negative anomalies of Th, Nb, La, Zr, Hf, Ti and Y. Mixing curves calculated to mixtures of melting residue of PM/DMM and fluid or sediment compositions related to subduction tectonic setting end members suggest up to 3% of interaction of the fluid sediment on the depleted mantle residue. 87Sr/86Sr ratios (0.702874 - 0.704999, with average of 0.704035) are similar to those defined to peridotites with OIB source (87Sr/86Sr = 0.70244 to 0.70502), being close to Depleted Mantle (DM; 87Sr/86Sr = 0.7023 to 0.7032) values. Nb/Ta ratios suggest that Agua Poca xenoliths were undergone to partial melting processes that generated alkaline magmas with superchondritic Nb/Ta ratios.