The use of composite materials in engineering practice and in particular nonmetallic composite materials in the preparation of elastic couplings (clutches) requires modeling of their mechanical behavior. The production of elastic couplings with a elastic element having reinforced polymer materials require studying the behavior of those materials for loads which are typical for their operation. In many modern structures of elastic clutches are used multilayer reinforced composites. This kind of materials are composed of separate layers with different orientation of reinforcing fibers. Several authors have studied the behavior of this type of laminated materials (Yongming L. 2005, Zhang Y.X., 2009). Factors,which determine the stress and deformation state of this type of elastic elements are: — structure and mechanical characteristics — matrix and reinforced material — connection between matrix and reinforced material — orientation of reinforcement. The aim of this paper is to investigate stress and strain state of elastic element of coupling, creating a model for determination of the state of threelayers nonmetallic material for manufacturing of nonmetallic elastic elements.

The report deals with the study of the resistence of the nonporous polymer materiále against permeation of the selected TICs, with the analysis of the running difussion processes and utilization of the acquired results for the selection of suitable barrier materials for the protective means.

Diploma thesis makes a summary of today’s state of CIPP methods designed for sewer relining. Thesis presents classification of CIPP methods between other NO-DIG technologies. Then CIPP methods are divided into groups according to the material used for the liner, applied resin, installation method and curing method. Designing of the CIPP liner used for sewer renovation is also part of this diploma thesis. The result of the theoretical part of this work is a table, which states suitability of particular methods for use in a sewer of specific technical properties. Practical part of bachelor’s thesis is dealing with the analysis of defects of an existing sewer in the city Přerov. Analysis was done due to the camera examination provided by the company Wombat s.r.o. Later the table developed in theoretical part was applied, and then the suitability of use of all parameters of CIPP liners was commented. At the end the plan of works is designed, with the plan for pumping of water included.

The use of composite materials in engineering practice and in particular nonmetallic composite materials in the preparation of elastic couplings (clutches) requires modeling of their mechanical behavior. The production of elastic couplings with a elastic element having reinforced polymer materials require studying the behavior of those materials for loads which are typical for their operation. In many modern structures of elastic clutches are used multilayer reinforced composites. This kind of materials are composed of separate layers with different orientation of reinforcing fibers. Several authors have studied the behavior of this type of laminated materials (Yongming L. 2005, Zhang Y.X., 2009). Factors,which determine the stress and deformation state of this type of elastic elements are: — structure and mechanical characteristics — matrix and reinforced material — connection between matrix and reinforced material — orientation of reinforcement. The aim of this paper is to investigate stress and strain state of elastic element of coupling, creating a model for determination of the state of threelayers nonmetallic material for manufacturing of nonmetallic elastic elements.

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Šiame darbe susisteminti ir palyginti pagrindiniai grunto standumo koeficientų nustatymo metodai. Aprašoma metodika, kaip iš grunto santykinio tankio galima apskaičiuoti dinaminį bei statinį tamprumo modulius. Pateikiamos šių grunto parametrų koreliacinės priklausomybės. Eksperimentiniais tyrimais įrodyta, kad silpnuose gruntuose egzistuoja netiesinė grunto tamprumo modulio priklausomybė nuo šalia grunto esančios priekrovos. Priekrovą traktuojant kaip tiesiškai priklausančią nuo gylio, išvesta tamprumo modulio silpnuose gruntuose priklausomybė nuo gylio. Rezervuarų skaičiavimui buvo pasinaudota 2 panašių konstrukcijų skaičiavimo metodikomis (tunelių metodika bei vamzdžių m.). Taip pat pasinaudota СНиП 2.06.09-84 tunelių projektavimo nurodymais. Konstrukcija sumodeliuota projektavimo programomis Robot Structural Analysis Pro, SCAD, Plaxis 2D. Taip pat pateiktas patobulintas modelis, atramas išskirstant į ploto vienetą, autoriaus nuomone, tinkamesnėmis plonasienėms mažo standumo konstrukcijoms. Skaičiuotiniuose modeliuose įvertinami visi pagrindiniai rezervuarų konstrukciniai elementai: galiniai kupolai, lengvosios sąstandos, špangautai. Laboratoriniais bandymais nustatytos ir įvertintos polimerinio kompozito konstrukcinės savybės: virtualus tamprumo modulis, Puasono koeficientas, valkšnumo koeficientas bei senėjimo faktorius. Išvadose apibendrinami rezultatai, taip pat suformuojami pasiūlymai, naudingi tolesniems tiriamiesiems darbams, bei panašių konstrukcijų... [toliau žr. visą tekstą] / Main methods to determine subgrade reaction is systemized in this master thesis work. Determination of static and dynamic deformation modulus, when relative soil density is known, are also familiarized. Correlation between the parameters is given in section 2. Experiments were made to prove that there is a link between deformation modulus and surcharge. If surcharge depends linearly from depth, then a function was created to predict deformation modulus values in weak soil when depth varies. 2 similar construction (pipes and tunnels) methods were used to design a buried tank. Design model was created by these design programs: Robot Structural Analysis Pro, SCAD, and PLAXIS 2D. An additional tank modelling method has been suggested by the author. Supports were assigned in plane instead of in a straight line. The updated model seems to better fit for low stiffness construction materials like GRP composites. In these design models all common tank structural elements were included: longitude domes, light and heavy stiffeners, orthotropic material. Main design parameters like virtual elastic modulus, Poisson ratio, creep factor, factor of durability. Results are summarized in conclusions. Suggestions were provided to help future researchers and designers with this kind of problems: structural design of composite polymer structures, design of buried thin-shelled tanks and evaluation of deformation modulus.

Large amount of different types of industrial wastes are still not re-use as secondary raw materials in industry. The work deals with finding a new way how to use secondary raw materials, especially the possibilities of using recycled glass from different sources as a fillers in the polymer protective materials development for horizontal structures. The main task of this work is to develop a material with the desired physic - mechanical properties and further verifying the influence of particle shape on their chemical resistance. Result of this work will find advanced protective materials using secondary raw materials as alternatives to be in terms of economic and ecological efficiency replacement for conventional products.

Ce travail s’inscrit dans le développement de formulations performantes et processables pour les liners de réservoirs de stockage hyperbare. Une large gamme de formulations à base polyamide et polyépoxyde a ainsi été synthétisée en conditions contrôlées, représentatives du procédé de rotomoulage. Les systèmes polyamide ont été modifiés par copolymérisation statistique et les polyépoxydes par une phase dispersée micro- ou nano-structurée avec des thermoplastiques de haute Tg ou des copolymères blocs. Les propriétés morphologiques, thermiques, mécaniques et barrière de chaque formulation ont été caractérisées et confrontées au cahier des charges du matériau. En parallèle, l’influence des conditions opératoires et de la formulation sur les rhéocinétiques de polymérisation, de cristallisation, de gélification et/ou de séparation de phase a ainsi été établie. L’ensemble de ces résultats a été mis à profit afin d’identifier des relations structures – propriétés – processabilité en vue de l’application. Afin de valider le potentiel des formulations retenues, ces dernières ont été rotomoulées en conditions opératoires variables avec un suivi in situ de l’écoulement et ex situ de la viscosité. Ce travail a permis d’établir les fenêtres de processabilité de chaque formulation et de comprendre l’origine des défauts d’écoulement. / The aim of this present study is to develop efficient and processable formulations for the liners of high pressure storage tank. A wide range of formulations based on polyamide and polyepoxide has been synthesized under controlled conditions representative of the rotomolding process. The polyamide system has been modified by copolymerization and the polyepoxyde system by a micro- or nano-structured dispersed phase with high Tg thermoplastics or block copolymers. The morphological, thermal, mechanical and barrier properties of each formulation were characterized and compared to the specifications of the material. In parallel, the influence of operating conditions and formulation on the rheokinetics of polymerization, crystallization, gelation and / or phase separation has been established. All of these results have been exploited to identify structure - property - processability relationships for the application. To validate the potential of selected formulations, they were rotationally molded in variable operating conditions with flow monitoring and rheological measure. This work has established the processing windows of each formulation and has allowed an understanding of the origin of flow defects.

Actuellement, le procédé d’électrofilage également appelé electrospinning est une des voies les plus prometteuses permettant le design et le développement de nanofibres polymères poreuses. En effet, cette technique est simple d’utilisation, unique, modulable, à faible coût et est déjà couramment utilisée dans le milieu industriel. De part ces avantages, l’electrospinning fait l’objet d’un engouement grandissant de la recherche académique et industrielle dans plusieurs domaines d’applications tels que ceux de la filtration, la cosmétique, du textile, de l’ingénierie tissulaire et du domaine médical, notamment pour le relargage de molécules actives. De plus, cette technique est applicable sur de nombreux polymères synthétiques ou naturels et il est possible de contrôler de nombreux paramètres tels que la porosité, le diamètre des fibres ou encore la surface accessible. Un des premiers objectifs de cette thèse a été de développer des scaffolds pour le domaine de l’ingénierie des tissus neuronaux afin d’imiter les propriétés biologiques, physiques et mécaniques de la matrice extracellulaire native. Dans un premier temps, l’effet de l’alignement des fibres d’une matrice fluorée (PVDF) biocompatible a été étudié sur le comportement de cellules souches neurales de singe, en particulier les morphologies, l’adhésion cellulaire ainsi que leurs différentiations en cellules gliales ou neuronales. Dans un second temps, des scaffolds bioabsorbables composés de PLA et de PEG ont été synthétisés afin d’étudier l’influence de l’équilibre hydrophile-hydrophobe sur la culture de cellules souches neurales. Et dans une dernière partie, une véritable étude exploratoire a été réalisée afin de développer des textiles intelligents à base de PBAT contenant des curli, protéine bien connue pour sa capacité à chélater des métaux. / Currently, the electrospinning process is also one of the most promising routes for the design and development of polymer fibers. This technique is easy to use, unique, versatile, and low cost, which can be used to create fibers from a variety of starting materials. The structure, chemical and mechanical stability, functionality, and other properties of the fibers can be modified to match end applications. The first goal of this thesis was to develop scaffolds for the field of neural tissue engineering in order to mimic the biological, physical and mechanical properties of the native extracellular matrix. In the first time, the effect of fiber alignment of a biocompatible and fluorinated matrix denoted polyvinylidene fluoride (PVDF) was studied on the behavior of monkey neural stem cells particularly the morphology, cell adhesion and their differentiation in glial or neuronal cells. Secondly, bioabsorbable scaffolds composed of polylactide (PLA) and polyethylene glycol (PEG) polymers were synthesized to investigate the influence of the hydrophilic-hydrophobic balance on the culture of neural stem cells. Finally, an exploratory work was conducted to develop smart textiles based on poly(butylene adipate-co-terephthalate) (PBAT) containing curli as protein, well-known for its ability to chelate metals.

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