Screen-printed carbon electrodes (SPCEs) have garnered much attention as sensors due to their simplicity and relatively low cost. However, to impart necessary selectivity and sensitivity for specific applications, modification of the SPCE surface, which can involve time-consuming procedures or costly equipment/materials, is typically required. Here, a simple nitrogen-doping process based on NH4OH was used to modify SPCEs prepared from commercially available ink for electrochemical detection of H2O2, a common target for biosensing strategies and indicator of cell stress. XPS studies showed that NH4OH treatment of SPCEs led to a nearly 5-fold increase in surface nitrogen content (from 0.28% to 1.34%). Compared to SPCEs, nitrogen-doped SPCEs (N-SPCEs) demonstrated enhanced current and lower onset potentials for H2O2 reduction. Amperometric detection of H2O2 at an applied potential of -0.4 V (vs. Ag/AgCl) using N-SPCEs also exhibited a wider linear range, lower detection limit, and higher sensitivity than SPCEs.

The aim of this work is to prepare white emitting electroluminescent device using printing techniques. Preparation options are discussed in order to minimise reabsorption in the phosphor layer and thus increase the overall radiation intensity. Model devices were prepared, the active layer of phosphor printed in a pattern of stripes and circles. The impact of the applied voltage and frequency was studied on these devices. It has been shown that, in terms of white emission, it is better to use the patterns compared to the phosphor mixture. The ratios of emission intensities of both phosphors are more even, therefor closer to the white light. The output of this work is model designed to determine the necessary frequency area for obtaining the white emission of ACEL device.

In a wireless system, the frequency-reconfigurable RF components are highly desired because one such component can replace multiple RF components to reduce the size, cost, and weight. Typically, the reconfigurable RF components are realized using capacitive varactors, PIN diodes, or MEMS switches. Most of these RF switches are expensive, rigid, and need tedious soldering steps, which are not suitable for futuristic flexible and wearable applications. Therefore, there is a need to have a solution for low cost, flexible, and easy to integrate RF switches. All the above-mentioned issues can be alleviated if these switches can be simply printed at the place of interest. In this work, we have demonstrated vanadium dioxide (VO2) based RF switches that have been realized through additive manufacturing technologies (inkjet printing and screen printing), which dramatically brings the cost down to a few cents. Also, no soldering or additional attachment step is required as the switch can be simply printed on the RF component. The printed VO2 switches are configured in two types (shunt configuration and series configuration) where both types have been characterized with two activation mechanisms (thermal activation and electrical activation) up to 40 GHz. The measured insertion loss of 1-3 dB, isolation of 20-30 dB, and switching speed of 400 ns are comparable to other non-printed and expensive RF switches. As an application for the printed VO2 switches, a fully printed frequency reconfigurable filter has also been designed in this work. An open-ended dual-mode resonator with meandered loadings has been co-designed with the VO2 switches, resulting in a compact filter with decent insertion loss of 2.6 dB at both switchable frequency bands (4 GHz and 3.75 GHz). Moreover, the filter is flexible and highly immune to the bending effect, which is essential for wearable applications. Finally, a multi-parameter (switch thickness, width, length, temperature) model has been established using a customized artificial neural network (ANN) to achieve a faster simulation speed. The optimized model’s average error and correlation coefficient are only 0.0003 and 0.9905, respectively, which both indicate the model’s high accuracy.

This work places itself in the field of textile design, printed surface patterns and pleating. The primary motive for this work is to bring together pleating and surface patterns by designing surface patterns that are the main component of the pleating. The aim is to combine printed surface patterns with pleating in order to design contemporary two-sided textiles for a spatial context. Different pleating patterns have been tested in combination with material and scale. Small paper sketches have been used to develop the surface patterns and to see how the different surface patterns are merging with each other when printed on both sides of the fabric. The printing method that has been used is transfer print. The result is a collection of three different textiles printed with surface patterns on both sides of the fabric. For further development the textiles can be placed in an interior context and serve as room dividers.

Clear plastic fluidic devices with ports for incorporating electrodes to enable electrochemiluminescence (ECL) measurements were prepared using a low-cost, desktop three-dimensional (3D) printer based on stereolithography. Electrodes consisted of 0.5 mm pencil graphite rods and 0.5 mm silver wires inserted into commercially available 1/4 in.-28 threaded fittings. A bioimaging system equipped with a CCD camera was used to measure ECL generated at electrodes and small arrays using 0.2 M phosphate buffer solutions containing tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate ([Ru(bpy)3]2+) with 100 mM tri-n-propylamine (TPA) as the coreactant. ECL signals produced at pencil graphite working electrodes were linear with respect to [Ru(bpy)3]2+ concentration for 9-900 μM [Ru(bpy)3]2+. The detection limit was found to be 7 μM using the CCD camera with exposure time set at 10 s. Electrode-to-electrode ECL signals varied by ±7.5%. Device performance was further evaluated using pencil graphite electrodes coated with multilayer poly(diallyldimethylammonium chloride) (PDDA)/DNA films. In these experiments, ECL resulted from the reaction of [Ru(bpy)3]3+ with guanines of DNA. ECL produced at these thin-film electrodes was linear with respect to [Ru(bpy)3]2+ concentration from 180 to 800 μM. These studies provide the first demonstration of ECL measurements obtained using a 3D-printed closed-channel fluidic device platform. The affordable, high-resolution 3D printer used in these studies enables easy, fast, and adaptable prototyping of fluidic devices capable of incorporating electrodes for measuring ECL.

This research explores the wide range of potential applications of perovskite heterostructures (PHSs). Recently, researchers have made considerable progress in optoelectronic devices based on PHSs for energy-related and sensing applications. Here we begin by introducing the fundamental theory of PHS and focus on its optoelectronic properties. We focus on fabricating and characterizing advanced semiconducting heterostructure optoelectronics devices. The main objective of understanding their fundamental behavior is to tailor and improve their functionalities and empower different applications. Therefore, we propose the development of light management in photo detectors using the following scalable and cost-effective fabrication techniques: (i) The design of nano electronic and optoelectronic devices based on the layering of inorganic and organic hybrid Perovskite CH3NH3PbBr3/Molybdenum disulfide MoS2 single crystal. We developed a new method for stacking the n-type MoS2 single crystal with p-type Perovskite CH3NH3PbBr3 single crystal in the vertical direction, which enabled us to form a van der Waals heterojunction p–n diode. This demonstrates good current-voltage rectifying behavior in the dark and under light illumination. (ii) The use of inkjet-printed photo detectors using Graphene/Perovskite/Graphene (GPG) Heterostructures in the visible light region. This is achieved by fabricating a graphene/perovskite metal-semiconductor-metal (MSM) configuration through inkjet printing or by employing the hybrid approach (a combination of inkjet printing and transferred layers) as a high-gain visible light photo detector. This research opens a new path in the light management of optoelectronic devices.

Indiana University-Purdue University Indianapolis (IUPUI) / Metal 3D printing typically requires high energy laser or electron sources. Recently, 3D printing using metal filled filaments becomes available which uses PLA filaments filled with metal powders (such as copper, bronze, brass, and stainless steel). Although there are some studies on their printability, the detailed study of their sintering and characterizations is still missing. In this study, the research is focused on 3D printing of bronze filaments. Bronze is a popular metal for many important uses. The objectives of this research project are to study the optimal processing conditions (like printer settings, nozzle, and bed temperatures) to print bronze metal filament, develop the sintering conditions (temperature and duration), and characterization of the microstructure and mechanical properties of 3D printed specimens to produce strong specimens. The thesis includes three components: (1) 3D printing and sintering at selected conditions, following a design of experiment (DOE) principle; (2) microstructure and compositional characterizations; and (3) mechanical property characterization. The results show that it is feasible to print using bronze filaments using a typical FDM machine with optimized printing settings. XRD spectrums show that there is no effect of sintering temperature on the composition of the printed parts. SEM images illustrate the porous structure of the printed and sintered parts, suggesting the need to optimize the process to improve the density. The micro hardness and three-point bending tests show that the mechanical strengths are highly related to the sintering conditions. This study provides important information of applying the bronze filament in future engineering applications.

As the Internet-of-everything continues diversifying, wireless nods sensors, wearables, and smart-objects will require mature technologies to harvest energy from the environment in which they are installed. Out of the many energy forms, solar and artificial light are constantly present and the utilization solar technologies including organic photovoltaics can provide advantages including flexibility, semitransparency, and lightweight. Additionally, the incredibly low environmental footprint and reduced manufacturing costs associated with solution processing can provide an edge for entry into the industrial and consumer markets. While the utilization of conjugated polymers and nonfullerenes elevated the efficiencies of organic photovoltaic for commercialization, increasing the technological readiness level requires the development of protocols to translate lab performance of state-the-art-materials to scalable manufacturing techniques that can be adapted for roll-to-roll processing. This dissertation demonstrates the full fabrication of high-performance OPV devices through techniques such as inkjet printing and slot-die coating. The development of ink formulation frameworks based on solvent engineering, rheological and interface properties, and solubility parameters sets the base for standardized high-yield processes with reduced environmental footprint in line with circular carbon initiatives. Moreover, the utilization of engineering strategies involving intrinsic properties of materials, device architectures, and integration enables the development of complex energy harvesting and sensing devices for potential utilization in agrivoltaics and biosensing.

Pure copper is widely employed as the primary metal in thermal management and electromagnetic applications due to its exceptional electrical and thermal conductivity. Laser powder bed fusion (LPBF) is a versatile additive manufacturing technique that utilizes high laser energy to selectively melt and fuse successive layers of metal powder to create metallic components with intricate geometries. Nonetheless, LPBF of pure copper is known as a challenging manufacturing process attributed to low optical absorptivity, rapid dissipation of laser energy, and affinity to oxidation. This thesis focuses on the process development and optimization for LPBF of Cu. Firstly, the Process-structure-property relation was examined by assigning a wide range of process parameters to print Cu-LPBF coupons. The optimum process parameters were defined based on maximum relative density, which was obtained at the full laser power of the EOS M280. The results emphasized the significant impact of laser power and hatch spacing on the part quality. Second, Cu oxide exhibits higher optical absorption than pure copper, as reported in the literature. Therefore, the thin film of oxide that was created either on recycled or intentionally oxidized power particles would be a possible easy way to increase the heat energy absorbed from the laser beam. However, the current work emphasized the adverse effects of oxide presence on part quality, particularly when using a medium laser power machine. In this regard, a new method of in-situ Cu oxide reduction during LPBF was proposed to develop an easy and environment-friendly approach to recover the contaminated powder. Applying laser ablation on the powder surface and the solidified layers results in considerable improvement, where the oxygen content is reduced by 70% in the LPBF samples compared to the initial state of the oxidized powder. Finally, the power density of Cu-LPBF coils was improved by enhancing the filling factor and increasing the electrical conductivity. The dimensional limitation of Cu-LPBF fabricated parts was initially identified. The power of utilizing sample contouring was highlighted to upgrade surface quality. Adjusting beam offset associated with optimum scan track morphology upgraded the minimum feature spacing to 80 um. The electrical impedance of full-size Cu-LPBF coils, newly reported in this study, was measured and compared with solid wire. It can reflect the performance of Cu-LPBF coils (power factor) in high-frequency applications. / Thesis / Doctor of Philosophy (PhD)

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