Des méthodes électrochimiques classiques, et des caractérisations photoélectrochimiques (PEC), utiliséesex-situ et in-situ, ont permis d’étudier le phénomène de Shadow Corrosion, considéré ici comme une corrosion galvanique entre des alliages de zirconium et de nickel, corrosion influencée par l’environnement chimique et l’irradiation de ces alliages. Une cellule électrochimique simulant les conditions d’un réacteur à eau bouillante (REB), permettant l’illumination UV--Visible des échantillons et le contrôle de la chimie de l’eau, a été conçue, développée et validée. Cette cellule a permis de mesurer pour la première fois des spectres en énergie de photocourant d’un alliage de zirconium, in-situ en milieu REB simulé. Par ailleurs, les résultats expérimentaux obtenus tendent à montrer que les impuretés de type cations métalliques jouent un rôle important dans le mécanisme d’activation du couplage galvanique, donc potentiellement dans le mécanisme d’activation du phénomène de Shadow Corrosion, alors que la présence d’oxygène et/ou de peroxyde d’hydrogène n’induit pas de différences significatives du comportement électrochimique des échantillons. Il est montré également que l’illumination UV--Visible des échantillons, qui amplifie notablement les courants de couplage, est un paramètre important du phénomène de Shadow Corrosion. / Conventional electrochemical methods as well as photoelectrochemical characterisations (PEC), performedex-situ et in-situ, were used to study the Shadow corrosion phenomenon, considered as a galvanic corrosion between Zr-based and Ni-based alloys. The Shadow corrosion is influenced by the chemical environment and the irradiation of these alloys. An electrochemical cell , simulating the conditions of a boiling water reactor (BWR), allowing the illumination of the samples with UV--Visible as well as monitoring the water chemistry was designed, developed and validated. The cell allowed, for the first time, recording of emph{in-situ} photocurrent energy spectra on a Zr-based alloy in simulated BWR environment. Furthermore, the obtained experimental results pointed out that the metallic cation impurities played an important role in the activation mechanism of the galvanic coupling, thus potentially in the activation mechanism of the Shadow corrosion phenomenon, whereas the presence oxygen and/or hydrogen peroxide did not induce significant differences in terms of electrochemical behavior of the samples. It was also shown that the illumination of the sample with UV--visible light, which significantly amplified the galvanic current, is an important parameter of the Shadow corrosion phenomenon.

Les récents progrès en neuroimagerie ont permis, au cours des dernières années, de faire avancer les connaissances sur les maladies neurologiques et psychiatriques en offrant la possibilité de mieux comprendre l’évolution des maladies neurodégénératives et la nature du comportement, des émotions, de la personnalité, et de la cognition. Plusieurs défis éthiques ont émergés suite à l’utilisation de ces nouvelles technologies d’imagerie cérébrale. La perspective des chercheurs concernant les pratiques d’évaluation des protocoles de recherche en neuroimagerie ainsi que les défis éthiques, sociaux et légaux auxquels font face les chercheurs n'ont pas encore été étudiés, même s’ils constituent des acteurs clés. Nous avons entrepris une étude empirique sur les perspectives des chercheurs quant au processus d'évaluation par les comités d’éthique de la recherche (CÉR) afin d’examiner les enjeux éthiques, légaux et sociaux liés à la pratique de la neuroimagerie au Canada. Pour ce faire, nous avons expédié un questionnaire en ligne et réalisé des entrevues semi-structurées avec des chercheurs en neuroimagerie et des présidents des CÉR. Les entrevues ont été transcrites et analysées à l'aide du logiciel d'analyse qualitative Nvivo. Nos résultats ont mis en lumière plusieurs aspects éthiques légaux et sociaux suscitant une attention particulière afin de remédier aux défis actuels dans la recherche en neuroimagerie ainsi qu’au processus d’évaluation de la recherche par les CÉR. Nos données comportent également des recommandations provenant des chercheurs eux-mêmes afin d'améliorer le processus d'évaluation. Finalement, notre propre expérience avec cette étude multicentrique nous a permis de constater plusieurs des défis mentionnés par les chercheurs. / Over the past years, advances in neuroimaging have allowed for a better understanding of neurologic and psychiatric disorders and yielded insights into behavior, emotion, personality, and cognition as well as allowed for a deeper understanding of neurodegenerative diseases. In light of the uses of these new imaging technologies, several ethical issues have emerged. The perspectives of researchers on current ethics review of neuroimaging protocols and ethical, legal and social issues present in neuroimaging have not been investigated, even though they are key stakeholders. We undertook an empirical study of researcher perspectives regarding the REB review process to examine ethical, legal and social issues associated with the practice of neuroimaging in Canada. We conveyed an online questionnaire survey and conducted semi-structured interviews with neuroimaging researchers and REB chairs. Interviews were transcribed and analyzed using the NVivo qualitative analysis software. Our results put into perspective emerging ethical, social and legal issues which are important challenges to address in the field of neuroimaging as well as practical challenges in the REB process. Our data also contain recommendations, coming from the neuroimagers themselves, in order to improve the evaluation process. Finally, our experience conducting this research has allowed us to confirm the challenges and stakeholders faced by neuroimagers.

One-nucleon halo nuclei are exotic nuclei which can be seen as a core around which orbits a loosely-bound valence nucleon. They are usually studied through reactions such as elastic scattering and breakup. The ratio method has been developed as a tool to study one-neutron halo nuclei at high energies. It consists of the ratio of angular cross sections, breakup and elastic scattering, which removes most of the sensitivity to the reaction mechanism and to the reaction model. In the simple recoil excitation and breakup (REB) model, the ratio simplifies to a form factor dependent solely on the wave function of the projectile. By measuring this observable and comparing it to the REB form factor, i.e. in the ratio method, more detailed information on the structure of the halo could be obtained. For neutron-halo nuclei at high energy, the ratio observable obtained from accurate CDCC and DEA theoretical calculations follows its REB prediction. I study the extension of this method to lower energies of the reaction which could make the measurement appropriate to facilities such as SPIRAL2 (GANIL, Caen, France) and ReA12 at FRIB (Michigan State University) and to proton halos. This is done by comparing the REB form factor to dynamical calculations of the ratio. The reactions investigated are the reaction of 11Be, the archetypical one-neutron halo nucleus, on 12C, 40Ca and 208Pb targets at 20 MeV/nucleon and of 8B, the archetypical one-proton halo nucleus, on 12C, 58Ni and 208Pb targets at44 MeV/nucleon.For these reactions, the adiabatic assumption is no longer valid due to the effect of the Coulomb interaction. This effect is mainly visible at forward angle for 11Be and is aggravated for 8B by the fact that the halo is charged. The ratio works less well than for neutron-halos at intermediate and high energies. Nevertheless, the ratio is shown to be very sensitive to the orbital angular momentum l0 in which the halo is bound and its binding energy E0, i.e. the single-particle structure of the projectile. Variations of l0 and E0 induce visible changes in shape and in magnitude (up to several orders) of the ratio. Also, the agreement of the ratio with its REB prediction is best when the projectile is loosely-bound and for low l0, i.e. for s and p waves. The validity of the method is not affected by the use of energy ranges—or bins— in the projectile continuum. These tend to increase the cross section without changing the agreement of the ratio with its REB prediction. The applicability of the method is finally explored at high energy for proton-rich nuclei 17F, 25Al and 27P. I show that the ratio method works the latter since this nucleus is bound by a mere 0.870 MeV in the s-wave. For the other nuclei, although the agreement of the ratio with its REB prediction is less good than for neutron-halo nuclei at high energy, it still provides estimates of nuclear-structure features, such as l0 and E0 and could be applied in what can be called an approximate application of the ratio method. Heavy nuclei exhibit a neutron skin, i.e. a thin layer around the nucleus where only neutrons are found. The thickness of the skin is highly correlated with the slope of the symmetry energy. The process of coherent neutral-pion photoproduction is used to extract the nuclear density and hence the neutron-skin thickness of heavy nuclei. In order to analyse recent data on the photoproduction on 12C, 40,48Ca, 116, 120, 124Sn and 208Pb, I build a reaction code. My model uses the formalism of Kerman, McManus and Thaler (KMT) which allows to build the photoproduction matrix on a nucleus from the ones describing the elementary process on a single nucleon. Within the impulse approximation, the photoproduction is seen as the coherent sum of the photoproduction on each of the nucleons. In the plane wave impulse approximation (PWIA), no rescattering of the pion is considered after its production and the cross section is directly proportional to the Fourier transform of the density. Such process is taken into account at the distorted wave impulse approximation (DWIA) by considering a potential simulating the pion-nucleus interaction and built from the KMT formalism.The agreement of my model with the data is good, especially for 208Pb. The distortion has a significant impact on the photoproduction process. The sensitivity of the process to the density of the target is analysed by performing the calculations with several different densities calculated in different structure models. The distortion has the effect of deteriorating this sensitivity. In the particular case of a 208Pb target, the impact of variations of the neutron-skin thickness of around 0.1 fm on the photoproduction cross section is ten times smaller than the size of the error bars on the experimental data. These results, although less dramatic, hold for the tin targets, for which preliminary data exists. In the light of these results, the coherent neutral-pion photoproduction process does not seem to be suited in the study of the neutron-skin thickness. This conclusion goes in contrast to the results of recent measurements on 208Pb, for which the method was shown to be sensitive to fine details of the density. / Doctorat en Sciences de l'ingénieur et technologie / info:eu-repo/semantics/nonPublished