Functionally graded materials processed by the thermal spray techniques such as electron beam physical vapor deposition and plasma spray forming are known to have an orthotropic structure with reduced mechanical properties. Debonding related failures in these types of material systems occur due to embedded cracks that are perpendicular to the direction of the material property gradation. These cracks are inherently under mixed-mode loading and fracture analysis requires the extraction of the modes I and II stress intensity factors. The present study aims at developing semi-analytical techniques to study embedded crack problems in graded orthotropic media under various boundary conditions. The cracks are assumed to be aligned parallel to one of the principal axes of orthotropy. The problems are formulated using the averaged constants of plane orthotropic elasticity and reduced to two coupled integral equations with Cauchy type dominant singularities. The equations are solved numerically by adopting an expansion - collocation technique. The main results of the analyses are the mixed mode stress intensity factors and the energy release rate as functions of the material nonhomogeneity and orthotropy parameters. The effects of the boundary conditions on the mentioned fracture parameters are also duly discussed.

No description available.

Flame chemiluminescence has received increasing attention for its potential sensor and diagnostic applications in combustors. A number of studies have used flame chemiluminescence to monitor flame status, and combustor performance. While most of these studies have been empirical in nature, chemiluminescence modeling has the potential to provide a better understanding of the chemiluminescence processes and their dependence on various combustion operating conditions. The primary objective of this research was to identify and validate the important chemiluminescence reaction mechanisms for OH*, CH* and CO2*. To this end, measurements were performed at various operating conditions, primarily in laminar, premixed flames, fueled with methane, syngas (H2/CO) and Jet-A. The results are compared to 1-d laminar flame simulations employing the chemiluminescence mechanisms. The secondary objective was to use the experiments and validated chemiluminescence reaction mechanisms to evaluate the usefulness of flame chemiluminescence as a combustion diagnostic, particularly for heat release rate and equivalence ratio. The validation studies were able to identify specific mechanisms for OH*, CH* and CO2* that produced excellent agreement with the experimental data in most cases. The mechanisms were able to predict the variation of the chemiluminescence signals with equivalence ratio but not with pressure and reactant preheat. The possible reasons causing this disagreement could be due to the inaccuracies in the basic chemical mechanism used in the simulations, lack of accurate quenching data (for CH*), thermal excitation (for OH*) and radiative trapping (for OH* and CO2*) and interference from the emissions of other species (such as HCO and H2O), for CO2*. Regarding the utility of chemiluminescence for sensing, a number of observations can be made. In syngas-air flames, CO2* is a reasonable heat release rate marker, at least for very lean conditions. OH* shows some advantage in atmospheric-pressure methane and Jet-A flames in general, while CH* is advantageous at high pressure and very lean conditions at atmospheric pressure. The CO2*/OH* intensity ratio is not useful for sensing equivalence ratio in syngas flames, except maybe at very lean conditions. However, the CH*/OH* signal ratio is a promising approach for sensing equivalence ratio at low or very high pressure conditions in hydrocarbon flames. Thermal excitation and self-absorption processes for OH* chemiluminescence can become important for combustors operating at high pressure, high preheat and near stoichiometric conditions. Background subtracted chemiluminescence signals are recommended for sensing purposes.

Made available in DSpace on 2015-03-26T13:30:26Z (GMT). No. of bitstreams: 1 texto completo.pdf: 537077 bytes, checksum: 87b9c3bc305f8241b417b885c367acb1 (MD5) Previous issue date: 2009-07-24 / Conselho Nacional de Desenvolvimento Científico e Tecnológico / Several papers have been published recently to investigate the relationship between ecosystem functioning and biodiversity, even though a conclusive position regarding this subject is still lacking. This study tests the relationship between litter decomposition and nutrient release rates with litter arthropod species richness and composition. The hypotheses that (i) sites with higher litter arthropod species richness have higher decomposition and nutrient release rates, and (ii) litter arthropod species composition affects decomposition and nutrient release rates were tested, in a secondary re-growth forest in Brazil. Litter decomposition rates did not respond to litter arthropod species richness, suggesting a redundancy between arthropod species. This may signify that litter arthropod community is composed by groups of species that play similar roles in ecosystem functioning, so that the increase of species richness does not translate into changes of decomposition rates. On the other hand, there are group compositions that disfavor decomposition rates. When the mite groups Laelapidae and Trombidiinae, both composed of predator species, were present, there was a decrease of litter decomposition rates. These two groups could be considered as key-species, because they could decrease the abundance of several other groups that take part on the decomposition process. Concluding, even though several species apparently play similar roles on the decomposition process, there are some key-species that influence more dramatically the ecosystem process here analyzed. / Atualmente diversos trabalhos têm investigado a relação entre biodiversidade e funcionamento dos ecossistemas. Apesar disso ainda não há uma posição conclusiva quanto ao assunto. O objetivo deste trabalho foi verificar se há relação entre a riqueza e a composição de espécies de artrópodes de serapilheira e as taxas de decomposição e liberação de nutrientes. Para isso duas hipóteses foram testadas: (i) locais com maior riqueza de espécies de artrópodes de serapilheira têm maior taxa de decomposição e de liberação de nutrientes; (ii) a composição específica da comunidade de artrópodes de serapilheira afeta a taxa de decomposição e de liberação de nutrientes. A taxa de decomposição não respondeu significativamente à riqueza de espécies de artrópodes. Esse resultado sugere que há redundância entre as espécies de artrópodes, ou seja, a comunidade de artrópode estudada provavelmente é composta por grupos de espécies que têm papéis similares, de maneira que o aumento na riqueza não se traduz em modificação no funcionamento do ecossistema. Além disso, a composição específica do grupo de ácaros Laelapidae e Trombidiidae mostrou influência negativa sobre a taxa de decomposição, o que pode ser justificado devido ao hábito alimentar que os mesmos apresentam. Nesse caso, os dois grupos de ácaros poderiam ser exemplos de grupos-chave, uma vez que sua presença implica na diminuição significativa da taxa de decomposição. Dessa maneira, conclui-se que embora a maioria das espécies apresente papéis similares, existem espécieschave que podem estar presentes, desempenhando papel importante no funcionamento dos ecossistemas.

Afin d'assurer le contrôle de son parc de production d'électricité, EDF doit maîtriser le vieillissement de ses installations pour en garantir le bon fonctionnement dans la durée. Dans ce but, il est nécessaire de disposer d’outils performants pour le modéliser et simuler la propagation des défauts dans les structures.Dans ces travaux de thèse, on s’intéresse à la propagation de fissures avec la méthode X-FEM et notamment à l’étape de localisation de la fissure par une technique de courbes de niveau. Nous avons proposé une approche fondée sur une méthode de propagation d’information de distance dite fast marching method pour rendre cette étape plus robuste. Elle est applicable à tous types de mailles,linéaires ou quadratiques.De plus, le calcul du taux de restitution d’énergie et des facteurs d’intensité de contrainte en pointe de fissure doit être suffisamment précis pour permettre de calculer la direction et l’avancée de la fissure. Dans ce but, nous avons proposé d’étudier une méthode d’intégrale de domaine pour laquelle on soulève plusieurs difficultés liées à la représentation de la fissure dans un espace tridimensionnel. Plusieurs améliorations sont proposées pour rendre les calculs plus précis et plus robustes.Dans le cas des fissures à front courbe, nous avons identifié les limites de l'utilisation des champs asymptotiques obtenus en pointe de fissure sous l'hypothèse des déformations planes comme champs auxiliaires d’une méthode d’intégrale d’interaction et nous avons proposé de nouveaux champs de déplacements auxiliaires qui prennent en compte la courbure du front de fissure. Toutes ces approches sont développées et validées dans le logiciel code_aster. / In order to ensure the control of its nuclear power plants, EDF must guarantee that they function effectively over the long term. For this purpose, it is necessary to have efficient tools tomodel and simulate crack propagation in structures. In this PhD work, we are interested in the propagation of cracks with the X-FEM method which allows using the same mesh as for a structure without default. We target especially the reconstruction of thelevel sets that characterize the position of the crack after propagation. We have proposed a fast marching method approach based on the propagation of distance information from the crack surface to the whole structure to make this step more robust in the X-FEM propagation process. It is applicable to all types of meshes, linear or quadratic. The calculation of information characteristic of thecrack status such as the energy release rate and the stress intensity factors must be accurate enough to obtain the direction and advance of the crack front ateach propagation step. For this purpose, we proposed to study a domain integral method, for which several difficulties related to the representation of the crackin a three-dimensional space are identified. Several improvements are proposed to make the calculations more accurate and more robust. In the case of curved cracks front, we have identified the limitations of using asymptotic fields obtained under the plane deformation hypothesis as auxiliary fields of an interaction integral method and we have proposed new auxiliary displacement fields that take into account the curvature of the crack front. All these methods are developed and validated with EDF software code_aster.

Original analytical theories are developed for partitioning mixed-mode fractures on rigid interfaces in laminated orthotropic double cantilever beams (DCBs) based on 2D elasticity by using some novel methods. Note that although the DCB represents a simplified case, it provides a deep understanding and predictive capability for real applications and does not restrict the analysis to a simple class of fracture problems. The developed theories are generally applicable to so-called 1D fracture consisting of opening (mode I) and shearing (mode II) action only with no tearing (mode III) action, for example, straight edge cracks, circular blisters in plates and shells, etc. A salient point of the methods is to first derive one loading condition that causes one pure fracture mode. It is conveniently called the first pure mode. Then, all other pure fracture modes can be determined by using this pure mode and the property of orthogonality between pure mode I modes and pure mode II modes. Finally, these 2D-elasticity-based pure modes are used to partition mixed-mode fractures into contributions from the mode I and mode II fracture modes by considering a mixed-mode fracture as the superposition of pure mode I and mode II fractures. The partition is made in terms of the energy release rate (ERR) or the stress intensity factor (SIF). An analytical partition theory is developed first for a DCB composed of two identical linear elastic layers. The first pure mode is obtained by introducing correction factors into the beam-theory-based mechanical conditions. The property of orthogonality is then used to determine all other pure modes in the absence of through-thickness-shear forces. To accommodate through-thickness shear forces, first two pure through-thickness-shear-force pure modes (one pure mode I and one pure mode II) are discovered by extending a Timoshenko beam partition theory. Partition of mixed-mode fractures under pure through-thickness shear forces is then achieved by using these two pure modes in conjunction with two thickness-ratio-dependent correction factors: (1) a shear correction factor, and (2) a pure-mode-II ERR correction factor. Both correction factors closely follow a normal distribution around a symmetric DCB geometry. The property of orthogonality between all pure mode I and all pure mode II fracture modes is then used to complete the mixed-mode fracture partition theory for a DCB with bending moments, axial forces and through-thickness shear forces. Fracture on bimaterial interfaces is an important consideration in the design and application of composite materials and structures. It has, however, proved an extremely challenging problem for many decades to obtain an analytical solution for the complex SIFs and the crack extension size-dependent ERRs, based on 2D elasticity. Such an analytical solution for a brittle interfacial crack between two dissimilar elastic layers is obtained in two stages. In the first stage the bimaterial DCB is under tip bending moments and axial forces and has a mismatch in Young s modulus; however, the Poisson s ratios of the top and bottom layers are the same. The solution is achieved by developing two types of pure fracture modes and two powerful mathematical techniques. The two types of pure fracture modes are a SIF-type and a load-type. The two mathematical techniques are a shifting technique and an orthogonal pure mode technique. In the second stage, the theory is extended to accommodate a Poisson s ratio mismatch. Equivalent material properties are derived for each layer, namely, an equivalent elastic modulus and an equivalent Poisson s ratio, such that both the total ERR and the bimaterial mismatch coefficient are maintained in an alternative equivalent case. Cases for which no analytical solution for the SIFs and ERRs currently exist can therefore be transformed into cases for which the analytical solution does exist. It is now possible to use a completely analytical 2D-elasticity-based theory to calculate the complex SIFs and crack extension size-dependent ERRs. The original partition theories presented have been validated by comparison with numerical simulations. Excellent agreement has been observed. Moreover, one partition theory is further extended to consider the blister test and the adhesion energy of mono- and multi-layered graphene membranes on a silicon oxide substrate. Use of the partition theory presented in this work allows the correct critical mode I and mode II adhesion energy to be obtained and all the experimentally observed behaviour is explained.

Cross-ply composite laminates can develop very high density of transverse cracks in the 90-layer under severe thermal and mechanical loading conditions. At such high crack densities, two adjacent cracks start to interact, and a stress gradient is created in the region between these cracks. Due to the presence of high stress gradients, thickness averaging of longitudinal stress becomes obsolete. Thus, a detailed analysis of stress state along the thickness direction becomes necessary to study growth conditions of fiber sized microcracks initiated at the interface between 0-layer and 90-layer. Stress analysis at various crack densities is carried out in this project using finite element analysis or FEM as the main tool. This analysis is coupled with strain energy release rate (ERR) studies for a microcrack which grows in transverse direction from one interface to the other. The growth of this microcrack is found to be strongly influenced by the stress gradients and a presence of compressive stresses along midplane under tensile loading conditions at high crack densities.

<p>Fracture of silicon solar cells in photovoltaic (PV) modules are widely reported and a wellknown issue in the PV industry, since it is exposed to adverse climatic conditions and varying temperature loads. A commercial silicon solar cell is mainly composed of four different layers. This thesis investigates delamination failure and thermal fatigue failure due to alternating temperature loads using finite element method (FEM) simulation.</p> <p><br></p> <p>The delamination of the encapsulant (EVA) layer and the cell interface was simulated using</p> <p>finite element (FE) simulations in the COMSOL Multiphysics software. The adhesion between the</p> <p>layers were modeled using the cohesive zone model (CZM). The CZM parameters such as normal</p> <p>strength and penalty stiffness were used for the bilinear traction-separation law for the cohesive</p> <p>model in a 90-degree configuration. The critical energy release rate (𝐺𝐺𝑐𝑐) was experimentally calculated as one of the CZM parameters. A uniaxial tensile test of the upper layer of the cell was conducted to determine the material properties of the solar cell layers, and that information was</p> <p>later used for FE simulations. To validate the simulation, we compared the peeling force graph</p> <p>from the experiment and FE simulation, and it was found both graphs showed a maximum peeling</p> <p>force of 120 N.</p> <p><br></p> <p>Finite element simulations were also conducted to predict the stress variations in the silicon</p> <p>solar cell layer due to alternating temperatures. An alternating temperature function was developed</p> <p>using triangular waveform equations in the COMSOL Multiphysics software. For this simulation,</p> <p>a 3D model of the cell with a 90-degree peel arm was used, like in the peeling simulation. A</p> <p>maximum stress of 7.31 x 10−3 𝑁/𝑚𝑚2 was observed on the encapsulant (EVA)/cell layer, but no</p> <p>delamination was observed for the given temperature range. In future work, we plan to explore the</p> <p>calculation of fatigue life using thermal simulation to predict the reliability of a solar cell.</p>

Plants require N to complete their life cycle. Without adequate concentration of N, crops will not produce their potential yields. For turfgrass systems, N fertilizer application allows for the maintenance of functional, aesthetic, and recreational properties. However, fertilizer mismanagement is common and leads to N pollution in the environment. Controlled-release and slow-release fertilizers can enhance nitrogen (N)-use efficiency, reduce N pollution, minimize the need for repeated fertilizer applications, and reduce turfgrass shoot growth and associated costs. In order to evaluate the effectiveness of these fertilizers in the Intermountain West, research is needed. The timing of N release was evaluated for seven urea fertilizers: uncoated, sulfur coated (SCU), polymer-sulfur coated (PSCU), and four polymer-coated (PCU) with release timings of 45, 75, 120, and 180 d estimated release. These products were placed on bare soil, a Kentucky bluegrass (Poa pratensis L.) thatch layer, and incorporated into soil. These three placement treatments were replicated to allow for enough samples to be placed in two locations. The first was outside in a field to represent field conditions with diurnal fluctuating temperatures and the second was placed in a storage facility to replicate laboratory conditions with static diurnal temperatures. The PCU prills incorporated into soil under field conditions generally released N over the estimated release period. However, when applied to bare soil or thatch, N from PCU had 80% or greater N release by 35 d after application regardless of expected release time. Fertilizers under laboratory conditions had minimal N release despite having similar average daily temperatures, suggesting that fluctuating temperatures impact N release. The PSCU and SCU treatments were no different from uncoated urea, showing no slow release properties for this particular product. Spring-applied N fertilizer trials were conducted over two years to determine the optimal N rate for Kentucky bluegrass. Similar PCU120 products were applied at 50, 75, and 100% of the recommended full rate, while also being compared to an unfertilized control and urea applied either all at once or split monthly. Spring-applied PCU showed minimal initial N response while urea applied all at once resulted in an initial spike of N uptake. Once PCU began to release N, there was minimal difference for all rates compared to urea split monthly for biomass growth, verdure, and shoot tissue N. Although at the 50% rate, there were a few sampling dates with slower growth and lower verdure. The decrease in verdure at this low rate was slight, and it is recommended that PCU could be applied effectively at a reduced rate between 50 and 75%. Although for better results, additional quick release N is required to compensate for early season lag in N release.

Road administrators have to make decisions regarding the maintenance and rehabilitation of many existing jointed Portland Cement Concrete (PCC) pavements in the road network. Since these pavements are in general expensive to rehabilitate, agencies often opt for overlaying the deteriorated PCC pavement with Hot Mix Asphalt (HMA), resulting in a composite pavement. Unfortunately, the tensile stresses and strains at the bottom of the overlay developed from the movement of the joints, which are caused by the traffic and the changes in temperature, will create cracks on the surface known as reflective cracking. Reflective cracking can reduce the life of a pavement by allowing water or other particles to get into the underlying layers, which causes the pavement structure to lose strength. To improve the performance of the composite pavement, road agencies have studied mitigations techniques to delay the initiation and propagation of those cracks reflected from the PCC joints and cracks. Traditionally, these studies have relied only on laboratory testing or nondestructive tests. This dissertation expands the traditional approach by adding full-scale Accelerate Pavement Testing (APT) to a laboratory effort to investigate enhanced asphalt overlays that delay the initiation and propagation of cracks reflected from the PCC joints. The study was organized into three complementary experiments. The first experiment included the first reflective cracking study of hot-mix asphalt (HMA) overlays over jointed Portland cement concrete pavements (PCCP) conducted at the Virginia APT facility. A Heavy Vehicle Simulator (HVS) was used to compare the reflective cracking performance of a Stone Matrix Asphalt (SMA) control mix with a modified mix with a synthetic fiber. The discussion includes the characterization of the asphalt mixes, the pavement structure, construction layout, the equipment used, the instrumentation installed, and lessons learned. Results showed that the fiber-modified mix had a higher resistance to fracture, which increases the pavement life by approximately 50%. The second experiment compared the cracking resistance of the same control and modified mixes in the laboratory. Four cracking resistance tests were performed on each mix. These four tests are: (1) Indirect Tensile Asphalt Cracking Test (IDEAL-CT), which measures the Cracking Test index (CTindex); (2) Semicircular Bend Test-Illinois (SCB-IL), which measures the critical strain energy release rate (Jc); (3) Semicircular Bend-Louisiana Transportation Research Center (SCB-LTRC), which measures the Flexibility Index (FI); and (4) Overlay Test (OT), which measures the Cracking Propagation Rate (CPR). The results from the four tests showed that the fiber-modified mix had a better resistance to cracking, confirming the APT test results. The laboratory assessment also suggested that the IDEAL-CT and SCB-IL test appear to be the most practical for implementation. The third phase evaluated the performance of mixes designed with a high content of Reclaimed Asphalt Pavement (RAP) and an enhanced asphalt-rubber extender, which comprises three primary components: plain soft bitumen, fine crumb rubber and an Activated Mineral Binder Stabilizer (AMBS). The experiment evaluated the fracture resistance of nine mixes designed with different rates of recycled asphalt pavement (RAP) and asphalt-rubber, compare them with a traditional mix, and propose an optimized mixture for use in overlays of concrete pavements. The mixes were designed with different rates of RAP (15, 30, 45%) and asphalt-rubber extender (0, 30, and 45%) following generally, the design requirements for an SMA mix in Virginia. The laboratory test recommended in the second experiment, IDEAL-CT and SCB-IL, were used to determine the fracture resistance of the mixes. The results showed that the addition of RAP decreases fracture resistance, but the asphalt-rubber extender improves it. A mix designed that replaced 30% of the binder with asphalt-rubber extender and 15% RAP had the highest resistance to fracture according to both. Also, as expected, all the mixed had a low susceptibility to rutting. / Doctor of Philosophy / Reflective cracking can reduce the life of a pavement by allowing water or other particles to get into the underlying layers, which causes the pavement structure to lose strength. To improve the performance of the composite pavement, road agencies have studied mitigations techniques that will delay the initiation and propagation of those cracks reflected from the PCC joints. Traditionally, these studies rely only on laboratory testing or nondestructive tests that will assist in the decision-making stage in a short time manner. This dissertation focusses on a reflective cracking study conducted through Accelerate Pavement Testing (APT) using a Heavy Vehicle Simulator (HVS) and laboratory testing. The first task used an HVS to evaluate reflective cracking of a Stone Matrix Asphalt (SMA) control mix and a modified mix with synthetic fiber. One lane was constructed with two layers of 1.5-inches of a control Stone Matrix Asphalt (SMA) mix and the second lane with an SMA mix modified with the synthetic fiber. Results from APT demonstrated that the modified SMA has a higher resistance to fracture which increases the pavement life by approximately 50%. The second task estimated the fracture resistance of the mixes studied in task one following the laboratory test: Indirect Tension Asphalt Cracking Test (IDEAL-CT), Texas Overlay Test (OT), Semi-Circular Bend-Louisiana Transportation Research Center (SCB-LTRC) and Semi-Circular Bend-Illinois (SCB-IL) to estimate the Cracking Test Index (CTindex), Cracking Propagation Rate (CPR), critical strain energy release rate (Jc) and Flexibility Index (FI), respectively. Results showed that the modified mix had a better resistance to cracking, confirming the APT test results. Specifically, CTindex results showed that the modified mix is more resistant than the control, with indices of 268.72 and 67.86. The estimated Jc indicated that less energy is required to initiate a crack for the control mix that achieved 0.48 kJ/m2 compared to the modified mix with synthetic fibers 0.54 kJ/m2. FI results for the control and fibers were 2.16 and 10.71, respectively. The calculated CPR showed that the control mix propagates a crack at a higher rate of 0.188 compared to the modified mix with a CPR of 0.152. The third phase evaluated the performance of mixes designed with a high content of Reclaimed Asphalt Pavement (RAP) and an enhanced asphalt-rubber extender, which comprises three primary components: plain soft bitumen, fine crumb rubber and an Activated Mineral Binder Stabilizer (AMBS). The experiment evaluated the fracture resistance of nine mixes designed with different rates of recycled asphalt pavement (RAP) and asphalt-rubber, compare them with a traditional mix, and propose an optimized mixture for use in overlays of concrete pavements. The mixes were designed with different rates of RAP (15, 30, 45%) and asphalt-rubber extender (0, 30, and 45%) following generally, the design requirements for an SMA mix in Virginia. The laboratory test recommended in the second experiment, IDEAL-CT and SCB-IL, were used to determine the fracture resistance of the mixes. The results showed that the addition of RAP decreases fracture resistance, but the asphalt-rubber extender improves it. A mix designed that replaced 30% of the binder with asphalt-rubber extender and 15% RAP had the highest resistance to fracture according to both. Also, as expected, all the mixed had a low susceptibility to rutting.