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Transport and transformations of nitrogen compounds in effluent from sand filter-septic system draintile fieldsBushman, Jennifer L. 12 February 1996 (has links)
A total of 44 intermittent sand filter-septic systems, in five counties of Western
Oregon, were sampled over a three-month period during the summer of 1995. The sand
filter systems varied in age from 36 months up to 167 months (3 to 13.9 years). Liquid
samples were taken from the septic tank and distribution box. In addition, soil samples
were taken adjacent to the disposal trench and away from the disposal field area (control).
All samples were analyzed for Total Kjeldahl Nitrogen (TKN) and nitrate and nitrite.
Nitrite was not detected in any of the samples. The average removal of total nitrogen
(TKN + nitrate) through the filter was found to be 43%. Nitrate was determined to be the
dominant form of nitrogen in the sand filter effluent making up 94% of the total nitrogen.
The age of the system was found not to be a predictor of the system's performance. Once
the effluent entered the disposal field, little if any transformation of nitrogen occurred at an
average depth of 30 inches (76.2 cm). / Graduation date: 1996
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The Development of a Parameterized Scatter Removal Algorithm for Nuclear Materials Identification System ImagingGrogan, Brandon Robert 01 May 2010 (has links)
This dissertation presents a novel method for removing scattering effects from Nuclear Materials Identification System (NMIS) imaging. The NMIS uses fast neutron radiography to generate images of the internal structure of objects non-intrusively. If the correct attenuation through the object is measured, the positions and macroscopic cross-sections of features inside the object can be determined. The cross sections can then be used to identify the materials and a 3D map of the interior of the object can be reconstructed. Unfortunately, the measured attenuation values are always too low because scattered neutrons contribute to the unattenuated neutron signal. Previous efforts to remove the scatter from NMIS imaging have focused on minimizing the fraction of scattered neutrons which are misidentified as directly transmitted by electronically collimating and time tagging the source neutrons. The parameterized scatter removal algorithm (PSRA) approaches the problem from an entirely new direction by using Monte Carlo simulations to estimate the point scatter functions (PScFs) produced by neutrons scattering in the object. PScFs have been used to remove scattering successfully in other applications, but only with simple 2D detector models. This work represents the first time PScFs have ever been applied to an imaging detector geometry as complicated as the NMIS. By fitting the PScFs using a Gaussian function, they can be parameterized and the proper scatter for a given problem can be removed without the need for rerunning the simulations each time. In order to model the PScFs, an entirely new method for simulating NMIS measurements was developed for this work. The development of the new models and the codes required to simulate them are presented in detail. The PSRA was used on several simulated and experimental measurements and chi-squared goodness of fit tests were used to compare the corrected values to the ideal values that would be expected with no scattering. Using the PSRA resulted in an improvement of the chi-squared test by a factor of 60 or more when applied to simple homogeneous objects.
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Assessment of passive decay heat removal in the General Atomics Modular Helium ReactorCocheme, Francois Guilhem 17 February 2005 (has links)
The purpose of this report is to present the results of the study and analysis of loss-of-coolant and loss-of-flow simulations performed on the Modular Helium Reactor developed by General Atomics using the thermal-hydraulics code RELAP5-3D/ATHENA. The MHR is a high temperature gas cooled reactor. It is a prismatic core concept for New Generation Nuclear Plant (NGNP). Very few reactors of that kind have been designed in the past. Furthermore, the MHR is supposed to be a highly passively safe concept. So there are high needs for numerical simulations in order to confirm the design. The project is dedicated to the assessment of the passive decay heat capabilities of the reactor under abnormal transient conditions. To comply with the requirements of the NGNP, fuel and structural temperatures must be kept under design safety limits under any circumstances. During the project, the MHR has been investigated: first under steady-state conditions and then under transient settings. The project confirms that satisfying passive decay heat removal by means of natural heat transfer mechanisms (convection, conduction and radiation) occurs.
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Tribochemical investigation of microelectronic materialsKulkarni, Milind Sudhakar 02 June 2009 (has links)
To achieve efficient planarization with reduced device dimensions in integrated circuits, a better understanding of the physics, chemistry, and the complex interplay involved in chemical mechanical planarization (CMP) is needed. The CMP process takes place at the interface of the pad and wafer in the presence of the fluid slurry medium. The hardness of Cu is significantly less than the slurry abrasive particles which are usually alumina or silica. It has been accepted that a surface layer can protect the Cu surface from scratching during CMP. Four competing mechanisms in materials removal have been reported: the chemical dissolution of Cu, the mechanical removal through slurry abrasives, the formation of thin layer of Cu oxide and the sweeping surface material by slurry flow. Despite the previous investigation of Cu removal, the electrochemical properties of Cu surface layer is yet to be understood. The motivation of this research was to understand the fundamental aspects of removal mechanisms in terms of electrochemical interactions, chemical dissolution, mechanical wear, and factors affecting planarization. Since one of the major requirements in CMP is to have a high surface finish, i.e., low surface roughness, optimization of the surface finish in reference to various parameters was emphasized. Three approaches were used in this research: in situ measurement of material removal, exploration of the electropotential activation and passivation at the copper surface and modeling of the synergistic electrochemical-mechanical interactions on the copper surface. In this research, copper polishing experiments were conducted using a table top tribometer. A potentiostat was coupled with this tribometer. This combination enabled the evaluation of important variables such as applied pressure, polishing speed, slurry chemistry, pH, materials, and applied DC potential. Experiments were designed to understand the combined and individual effect of electrochemical interactions as well as mechanical impact during polishing. Extensive surface characterization was performed with AFM, SEM, TEM and XPS. An innovative method for direct material removal measurement on the nanometer scale was developed and used. Experimental observations were compared with the theoretically calculated material removal rate values. The synergistic effect of all of the components of the process, which result in a better quality surface finish was quantitatively evaluated for the first time. Impressed potential during CMP proved to be a controlling parameter in the material removal mechanism. Using the experimental results, a model was developed, which provided a practical insight into the CMP process. The research is expected to help with electrochemical material removal in copper planarization with low-k dielectrics.
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Ecosystem response to dam removalLejon, Anna G.C. January 2012 (has links)
This thesis aims to improve our understanding of how riverine ecosystems respond to dam removal. Riverine and particularly riparian ecosystems are among the most variable and important features of all landscapes. They connect landscape elements both longitudinally and laterally, and are governed by processes such as flooding, erosion and deposition that create dynamic, diverse and heterogeneous habitats. In fact, riparian zones are among the world’s most species-rich habitats. Worldwide there are millions of dams that fragment stream and river systems, regulate flows and degrade ecosystems. Dams impact freshwater, marine and terrestrial ecosystems and threaten biodiversity by disrupting organism movements and energy flows in the landscape. An important upstream effect of dams is inundation of habitats and development of new shorelines around impounded areas. Effects downstream of dams are mainly caused by changed hydrological regimes and retention of organic and inorganic materials in reservoirs, leading to reduced transport and dispersal of for example seeds to reaches downstream. The removal of dams create expectations that biota will eventually recover. We have studied a number of dam removal projects in Sweden. Our experimental results showed that following dam removal, newly exposed soils in former impoundments were rapidly colonized by pre-removal species. Their species richness increased slightly with time and their species composition indicated a slow change towards that in the reference site. In addition, the vegetation in formerly impounded areas showed a direction of change from lentic riparian plants (high proportion of aquatics) towards lotic ones, consisting of native perennials typical of free-flowing streams. We also found that the apprehensions that former impoundments would turn into pools of mud did not come true; in fact, a process towards more pristine channel morphology was observed. After removal there was erosion and downstream transport of sediment. We found only minor effects on macroinvertebrate communities. For example, a few species decreased over the years, suggesting that dam removal in itself might cause a temporary disturbance. This highlights the importance of long-term studies after dam removal, and also the importance of comparisons with pre-removal conditions and stretches unaffected by dams. Thorough documentation of executed dam removal projects and distribution of the results and experiences are tremendously important in the planning process of future decommissioning projects. Also, our experiences have taught us that in order to attain a successful dam removal it is important to involve stakeholders such as non-governmental organizations and local inhabitants in the process.
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A study of some aspects of gas-slag-metal interactions : Towards dynamic process model and controlEk, Mattias January 2012 (has links)
The present thesis deals with the development of a new type of dynamic model for metallurgical reactors. It also covers some of the theoretical aspects of steelmaking that is necessary to include in such an application. The thesis consists of modeling work, high temperature experiments and cold model experiments. Two different aspects of slags in the oxygen steelmaking were investigated. In the first study, slag samples were equilibrated with copper at 1923K in order to study their capacities in capturing phosphorous. Some of the samples were liquid-solid mixtures. The solid phases in these samples were identified by SEM analysis. The identified phases were found to agree well with Thermocalc calculations while the amount of solid fractions didn’t. The phosphorous distribution between the different phases was examined. The phosphate capacities of the samples were evaluated. The MgO content didn’t show any appreciable impact on the phosphate capacity. Furthermore the activities of FeO in the liquid slag samples were calculated and were found to deviate positively from ideality. In the second study the foaming height of CaO-SiO2-FeO slags by the reaction with hot metal was investigated. It was found that the foaming height increased with increasing FeO content up to 20-25%. The foaming height was seen to decrease with increased viscosity. The present results indicated that simply using foaming index for converter slag might lead to wrong conclusion. Simulation experiments using cold model at room temperature were conducted. Cold model experiments were carried out in order to study the penetration depth due to an impinging gas jet on the surface of a liquid metal. The liquid alloy Ga-In-Sn was used to simulate steel. And an HCl solution was used to simulate the slag. A comparison with predictions of existing models was made and a new model parameter was suggested. The observation of the movement of metal droplets generated by the gas jet was also made. The low velocity of droplets suggested that the turbulent viscosity played important role and the droplets could have long resident time in the slag. Furthermore a study of the effect of gas flow rate on homogenization and inclusion removal in a gas stirred ladle was carried out. Both industrial trials and cold model experiments were conducted. As an auxiliary tool CFD was used to predict the mixing times and was found to agree well with both the model experiments and industrial data. The increase of flow rate of inert gas would not improve the mixing substantially at higher flow rates. The water model study showed also that the gas flow rate had negligible effect on the rate of inclusion removal. Both the experiments and CFD calculation strongly suggested that low gas flow rate should be applied in the ladle treatment. Lastly a new approach to a dynamic process model of 300 ton BOF converter was made. The main feature was to utilize the velocity vectors obtained by CFD simulation. In the standalone model, the steel melt domain was sliced into 1000 cells. Based on the imported velocity vectors from the CFD calculation, the mass transfer of carbon and phosphorus was calculated taking into account the slag metal reactions. The mass exchange between slag and metal was considered to be dominated by the metal droplet formation due to oxygen jet. The convergence of the model calculation and the promising comparison between the model prediction and the industrial data strongly suggested that the proposed approach would be a powerful tool in dynamic process control. However, more precise descriptions of other process aspects need to be included before the model can be practically employed in a dynamic controlling system. / <p>QC 20120829</p>
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Effects of seed size and habitat on recruitment patterns in grassland and forest plantsLönnberg, Karin January 2012 (has links)
A trade-off between seed size and seed number is central in seed ecology, and has been suggested to be related to a trade-off between competition and colonization, as well as to a trade-off between stress tolerance and fecundity. Large seeds endure hazards during establishment, such as shading, drought, litter coverage and competition from other plants, better than do small seeds, due to a larger amount of stored resources in the seed. Small seeds, however, are numerous and small-seeded species are therefore more fecund. Moreover, a pattern with small-seeded species being associated with open habitats and large-seeded species being associated with closed habitats has been reported in the literature. In this thesis I assess effects of seed size on recruitment, and how relationships between seed size and recruitment may relate to habitat conditions. Seed sowing experiments were performed in the field to assess inter- and intra-specific relationships between seed size and recruitment in open and closed habitats (Paper I and II). Seed removal experiments were performed in the field to assess what effects seed predation may have on a relationship between seed size and recruitment (Paper III). A garden experiment was performed based on contests between larger-seeded and smaller-seeded species, in order to examine different models on co-existence of multiple seed size strategies. The results showed that there was a weak positive relationship between seed size and recruitment in the field, and that this relationship was only weakly and inconclusively related to habitat (Paper I and II). Seed removal was negatively related to seed size in closed habitats and unrelated to seed size in open habitats (Paper III). This indicates that any positive relationship between seed size and recruitment may be an effect of higher seed removal in small-seeded species. However, when grown under controlled conditions in a garden experiment, there was a clear advantage of larger-seeded species over smaller-seeded species (Paper IV). This advantage was unaffected by seed density, indicating that there was no competitive advantage of the larger-seeded species. Instead, indirect evidence suggests that larger-seeded species exhibit higher tolerance to stress. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Manuscript. Paper 4: Accepted.</p><p> </p>
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STUDY OF BACTERIAL COMMUNITIES : – A WASTEWATER TREATMENT PERSPECTIVERodriguez Caballero, Adrian January 2011 (has links)
In this thesis, the application of molecular microbiology methods to understand wastewater treatment bio-reactions is described. Two different wastewater treatment systems were chosen for the experimental work. Firstly; the activated sludge processes at two different facilities in Sweden (Västerås and Eskilstuna) were investigated and compared in a context where low temperatures can affect the efficiency of the nitrogen removal performance in terms of nitrification. Initially, fluorescence in situ hybridization (FISH) was utilised in order to quantify some of the species involved in ammonia and nitrite oxidation at Västerås, providing information on how the different communities react to decreasing temperatures. Then, the polymerase chain reaction (PCR), cloning-sequencing method was employed in order to study the composition of the ammonia oxidizing bacteria (AOB) community at the same two wastewater treatment plants (WWTPs). Secondly; the potential use of constructed wetlands for the treatment of winery wastewater was studied. High ethanol concentration artificial wastewater with and without inorganic nutrients (nitrates and phosphates) was fed in a set of pilot-scale constructed wetlands. Pollutant removal performance and enzyme activity tests were carried out. Additionally, the bacterial community structure was investigated by means of denaturing gradient gel electrophoresis (DGGE). In the first set of studies it was shown that the AOB population which plays a major role in nitrifying reactors presented a seasonal shift and a higher diversity at Västerås during winter time, while the nitrification performance maintained stable levels and the ammonia removal efficiency increased. Thus, the higher ammonia removal efficiency at Västerås could be related to the diversity of the AOB population composition. Lastly, when constructed wetlands were in focus, the differential effects of ethanol and nutrients over the chemical oxygen demand (COD) removal performance were proven. In fact, the addition of nutrients on one of the experimental wetlands increased the COD (ethanol) removal and supported the maintenance of a bacterial population similar to the control wetland (no ethanol added). In conclusion, both studies proved a strong relationship between process performance (pollution removal) and the dynamics of the bacterial communities involved.
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The US Adoption towards IFRS under Special Consideration of LIFOLexell, Anna, Lindstedt, Kristina January 2010 (has links)
The United States Securities and Exchange Commission (SEC) issued a Roadmap in 2008 regarding a change in the American accounting standards system. The Roadmap proposes a potential adoption from the United States Generally Accepted Accounting Principles (US GAAP) to the International Financial Reporting Standards (IFRS). The objective with the adoption is to enhance a one-set of accounting standards used in the world in order to increase comparability between public limited companies in different jurisdictions. With the adoption, the valuation of inventories for American companies will change, since the Last-In, First-Out (LIFO) method is allowed under US GAAP, but not under IFRS. A study from 2008 shows that approximately 36 per cent of American public limited companies is using LIFO. They would therefore be forced to use another inventory valuation method, such as First-In, First-Out (FIFO). The LIFO method is normally used by companies exposed to inflation and increases the cost of goods sold (COGS) and consequently lowers the net income and income tax provision. With the potential adoption, these companies would face large increases of income tax provisions, which would affect them severely. This thesis is a review study with the objective to connect recent research with the SEC Roadmap in order to answer the following research questions: How will US companies that are using LIFO be affected by the inventory valuation change to FIFO, from an economic and accounting-based approach? What are the positive and negative aspects with a removal of LIFO regarding the IFRS adoption? There is a clear benefit for the US companies using LIFO regarding the smaller income tax provisions. Opponents consider that LIFO will disappear with the US adoption to IFRS. At the same time, recent research considers or doubts that the LIFO method will not face its death with the adoption from US GAAP to IFRS. As a conclusion, the negative effect of removing LIFO as a consequence of this adoption, is the implementation time period, which is too optimistic. Even though, the credibility with a shift from LIFO to FIFO will grow stronger and create a more comparable business world.
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Characterization of Bacterial Biofilms for Wastewater TreatmentAndersson, Sofia January 2009 (has links)
Research performed at the Division of Environmental Microbiology has over the last years resulted in the isolation of possible bacterial key-organisms with efficient nutrient removal properties (Comamonas denitrificans, Brachymonas denitrificans, Aeromonas hydrophila). Effective use of these organisms for enhanced nutrient removal in wastewater treatment applications requires the strains to be retained, to proliferate and to maintain biological activity within theprocess. This can be achieved by immobilization of the organisms using an appropriate system.Two putative immobilization systems, agar entrapment and biofilm formation, wereassessed. Surface attached biofilm growth provided better results with respect to cell retention,proliferation and microbial activity than immobilization in agar beads. Thus, biofilm physiology was further characterized using simplified systems of single, dual or multi strain bacterial consortia containing the key-organisms as well as other wastewater treatment isolates. Mechanisms for initial adherence, biofilm formation over time, dynamics and characteristics of extracellular polymeric substances (EPS) and exopolysaccharides, nutrient removal activity as well as the effect of bacterial interactions were investigated. The results showed that all theassessed bacterial strains could form single strain biofilm providing that a suitable nutrientsupply was given. Production of EPS was found to be critical for biofilm development and both EPS and polysaccharide residue composition varied with bacterial strain, culture conditions and biofilm age. Denitrification and phosphorus removal activity of the keyorganisms was maintained in biofilm growth. Co-culturing of two or more strains resulted in both synergistic and antagonistic effects on biofilm formation as well as the microbial activitywithin the biofilm. Bacterial interactions also induced the synthesis of new polysaccharideswhich were not produced in pure strain biofilms.The complexity of single and mixed strain biofilm development and the implications of interactions on biofilm performance were underlined in this study. The data presented can be useful for modeling of biofilm systems, serve as a tool for selection of bacterial strain combinations to use for bioaugmentation/bioremediation or provide a base for further experiment design. / QC 20100622
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