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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
401

A Lysimeter Study of Vadose Zone Porosity and Water Movement in Gypsum Amended Soils

Tirado-Corbala, Rebecca 14 December 2010 (has links)
No description available.
402

Structural Assessment of the Glulam Arches at Stockholm Central Station

Naumburg, Anders, Krönlein, Kasper January 2020 (has links)
The purpose of this master’s thesis was to investigate if suspension of heavy objectsis possible in the glulam arches at Stockholm Central Station. The main goal was todetermine the arches’ load carrying capacity’s utility ratio, in order to give knowledgeif additional loading can be added.The study included a thorough investigation of available blueprints and calculationreports established during and after the process of design and erection of the arches.In addition, an on-site-inventory was made to confirm and verify the studied material.A method to approximate semi-probabilistic material strength-properties, based onold deterministic material strength properties, was used.When the material had been summarized concluding geometrical attributes, loads, andmaterial properties a calculation model of the arch was developed. The global geometrydescribing the arch’s shape mathematically was established through measures onblueprints and analytical calculations in Mathcad. A finite element method (FEM) wasthen used to calculate reaction- and internal forces and buckling modes taking accountfor 2nd order effects. Once calculation of intrenal forces had been made, the structuralcapacity was checked analytically according to Eurocode’s failure criterion.The results showed that the arches do not fulfill required carrying capacity forEurocode’s symmetric- and non-symmetric distributed snow load. The failurecriterion not fulfilled were simultaneously bending and compression, lateral torsionalbuckling and simultaneously tension perpendicular to grain and shear.It is therefore concluded that suspension of heavy objects is not suitable with thepresent condition of the arch. In order to realize suspension, it is suggested thatreinforcement measures have to be conducted. It is also suggested that shear andiiiflexural carbon fiber reinforced polymer (CFRP) reinforcement would be a suitablemethod of enhancing the strength and stiffness of the arches, without disrupting theiraesthetics and integrity.
403

Ekolodsmätningars förhållning mot olika insamlings- och interpolationsmetoder : En fallstudie på sjön Öjaren, Sandviken

Karlsson, Erik, Sjöström, Benjamin January 2020 (has links)
Traditionellt har större fartyg bestyckade med ekolod använts för att utföra batymetriska mätningar av sjö- och havsbottnar. Att utföra mätningar i grunda vatten har varit problematiskt eftersom större fartyg inte kan nå dessa grunda vatten. För att tackla det problemet har mindre obemannade ytfarkoster (USV) utvecklats för att mäta grunda vatten. Dessa USVs hjälper även till vid områden nära stenar som inte har fått uppdaterade djupvärden. Den här undersökningens syfte är att utvärdera hur en Seafloor HydroLite TM enkelstrålsekolod monterad på en USV skiljer sig från insamlingsmetoderna GNSS och med måttband. Den syftar även till att utvärdera vilken interpolationsteknik som är mest lämpad för skapande av djupmodeller med enkelstrålsekolodsdata. Det kommer också studeras hur tvärsektioner påverkar djupmodellerna skapade med enkelstrålsekolod. De experimentella mätningarna med GNSS, måttband och enkelstrålsekolod utfördes i sjön Öjaren som ligger utanför Sandviken. I undersökningen inmättes totalt 91 punkter med GNSS och måttband samt 8 mätstråk och 9 tvärsektioner med enkelstrålsekolod monterad på en USV. Djupmodellerna skapades i Surfer 10 med interpolationsteknikerna kriging, natural neighbor och triangulation with linear interpolation. Alla beräkningar genomfördes i Microsoft Excel och data insamlat med måttband ansågs vara det sanna värdet vid jämförelsen mellan insamlingsmetoderna. Resultaten visade att djupmodellerna skapade med GNSS-data är snarlika till djupmodellerna skapade med måttbandsdata samt att djupmodellerna med GNSS-data visar på den minsta skillnaden mot djupmodellerna skapade med enkelstrålsekolodsdata. Resultatet från jämförelsen mellan interpolationsteknikerna visar på att användandet av de olika interpolationsteknikerna inte har en signifikant påverkan på djupmodellen. Våra slutsatser av undersökningen blev att användande av ett enkelstrålsekolod kan bidra till att skapa en mer detaljerad djupmodell än om enbart GNSS eller måttbandsdata används. Det är också en mer kostnadseffektiv metod eftersom mer data kan samlas in på kortare tid. Det kan dock uppstå felmätningar vid insamlade av data med enkelstrålsekolod som kan vara svåra att upptäcka. Tilläggande av tvärsektioner kan bidra till att skapa en ännu mer detaljerad djupmodell och kan användas som kontrollpunkter vid kontroll av enkelstrålsekolodsdata. / Traditionally, large vessels armed with echo sounders have been used to conduct bathymetric surveys of the seas and oceans. Conducting surveys of shallow water have been troublesome since larger vessels cannot reach and survey shallow waters. To tackle that problem smaller unmanned surface vessels (USV) have been developed to survey shallow waters. It also helps in the areas closest to rocks that do not have updated depth measurements. This study aims to assess how a Seafloor HydroLite TM single-beam echo sounder mounted on a USV differs from other surveying methods. It also aims to evaluate which interpolation methods is most suitable for creating depth models by utilizing single-beam echo sounder data. It will also be studied how cross section lines affect the created depth using the USV. The experimental surveys with GNSS, measuring tape and single-beam echo sounder were used in the lake Öjaren that is located outside of Sandviken. In this study a total of 91 points were collected with GNSS and measuring tape and 8 sounding lines and 9 cross sections lines were collected using echo sounder mounted on the USV. The depth models were created in Surfer 10 using different interpolation methods i.e. kriging, natural neighbor and triangulation with linear interpolation. All calculation were performed in Microsoft Excel and the measurements collected with measuring tape were assumed as a “true” value to evaluate the different surveying techniques. The results showed that the depth model obtained using GNSS data is close to the depth model created using measuring tape data and shows lowest difference in comparison to the USV technique. The results from the comparison between interpolation methods showed that the use of different interpolation methods not have a significant impact on the depth model. The study concludes that the use of a single-beam echo sounder can help to create a more detailed depth model than using GNSS or measuring tape. It is also a cost effective method that helps collect more data in a short time. Though, some errors can appear in the data collected using the single-beam echo sounder that can be hard to detect. The cross section lines can contribute to a more detailed depth model and can be used as control points.
404

Effects of Solar Soft X-rays on Earth's Atmosphere

Samaddar, Srimoyee 06 February 2023 (has links)
The soft x-rays (wavelengths less than 30 nm) emitted by the sun are responsible for the production of high energy photoelectrons in the D and E regions of the ionosphere, where they deposit most of their energy. The photoelectrons created by this process are the main drivers for dissociation of nitrogen ($N_2$) molecules in the altitude range below 200 km. The dissociation of $N_2$ is one of main mechanisms responsible for the production of nitric oxide (NO) at these altitudes. These processes are important to understand because NO plays a critical role in controlling the temperatures of various regions of Earth's atmosphere. In order to estimate the dissociation rate of $N_2$ we need its dissociation cross-sections. The dissociation cross-sections of $N_2$ due to inelastic collisions with electrons is primarily es- timated from the cross-sections of its excitation states (using predissociation factors) and dissociative ionization channels. Predissociation is the transition without emission of radi- ation from a stable excited state to an unstable excited state of a molecule that leads to dissociation. Unfortunately, the lack of cross-section data, particularly at high electron en- ergies and of higher excited states of N 2 and N 2 + , introduces uncertainty in the dissociation cross-section and subsequently the dissociation rate calculation, which leads to uncertainties in the NO production rate. We have updated a photoelectron model with thoroughly-revised electron impact cross- section data of all major species and experimentally determined predissociation factors. The dissociation rates of $N_2$ using this model are compared to the dissociation rates obtained using another existing (Solomon and Qian [2005]) model. A parameterized version of the updated dissociation rates are used in a one-dimensional global average thermospheric/ ionospheric model, ACE1D (Atmospheric Chemistry and Energetics), to obtain the updated production rates of NO. In the final chapter, we use the ACE1D model to show that the energies deposited by the solar soft x-rays in the lower thermosphere at altitudes between 100 -150 km affect the temperature of the Earth's thermosphere at altitudes well above 300 km. By turning off the input solar flux in the different wavelength bins of the model iteratively, we are able to demonstrate that the maximum change in exospheric temperature is due to changes in the soft solar x-ray bins. We also show, using the thermodynamic heat equation, that the molecular diffusion via non-thermal photoelectrons is the main source of heat transfer to the upper ionosphere/thermosphere. Moreover, these temperature changes and heating effects of the solar soft x-rays are comparable to that of the much stronger He II 30.4nm emission. Finally, we show that the uncertainties in the solar flux irradiance at these soft x-rays wavelengths result in corresponding uncertainties in the modeled exospheric temperature, and these uncertainties increase substantially with increased solar activity. / Doctor of Philosophy / The radiation from the sun covers a wide range of the electromagnetic spectrum. The soft x-rays with wavelengths less than 30 nm are the most energetic and variable part of the spectrum, and would have detrimental effects on humans were they not absorbed by the atmosphere. The absorption of soft x-rays by the Earth's atmosphere at altitudes near 100- 150 km creates ionized and energized particles. These energetic changes can affect and even damage the satellites in low Earth orbit, and can cause radio communication blackouts and radiation storms (large quantities of energetic particles, protons and electrons accelerated by processes at and near the Sun). Therefore, we need to have good models that can quantify these changes in order to correctly predict their effects on our atmosphere, and help to mitigate any harmful effects. The soft x-rays and the extreme ultraviolet (EUV) are responsible for ionization of the major neutral species, $N_2$ , $O_2$ and O, in the Earth's atmosphere, which leads to the production of ions and energetic photoelectrons. These high energy photoelectrons can cause further ion- ization, excitation and dissociation. We study the dissociation of $N_2$ by these photoelectrons to create neutral N atoms. The N atoms created via this process combine with the $O_2$ in the atmosphere to produce nitric oxide (NO), which is one of the most important minor constituents because of its role in regulating atmospheric heating/cooling. The production of NO peaks near 106 km altitude, where most of the energy of the soft x-rays are deposited. However, they also affect the temperature of the upper atmosphere well above this altitude. This is because the energy of the photoelectrons is conducted to the upper atmosphere by collisions of electrons and ions with ambient neutral atoms and molecules, thus increasing their temperature. In this study, we use modeling of soft x-ray irradiance, photoelectron ionization, excitation and dissociation rates and atmospheric neutral temperature to quantify the effects of soft x-rays on the Earth's atmosphere.
405

Application of complex trace attributes to reflection seismic data near Charleston, South Carolina

Miller, Steven B. January 1985 (has links)
Complex trace attribute analysis has been applied to 24-fold VIBROSEIS reflection data acquired on the Atlantic Coastal Plain near Charleston, S. C., to yield an expanded interpretation of a Mesozoic basin concealed beneath Coastal Plain sediments. Complex trace attributes express the seismic trace in terms of a complex variable and emphasize different components of the original seismogram. Attributes derived from synthetic seismograms of thin beds are used to interpret the patterns observed on the real data. Complex trace attributes derived from the original seismic trace complement the interpretation of a Mesozoic basin originally imaged by conventional data. The combination of single-sweep recording and use of complex trace attributes is believed to support an interpretation of a transition from basin border conglomerates into finer-grained siltstones nearer to the center of the basin. / Master of Science / incomplete_metadata
406

A Numerical Based Determination of Stress Intensity Factors for Partially Cracked Flexural I-shaped Cross-sections

Someshwara Korachar, Eshwari 19 April 2019 (has links)
The AASHTO LRFD design specifications and the AASHTO manual for bridge evaluation are consistently revised using knowledge of previous bridge failures. Although modern steel structures are designed to resist fatigue cracking from service loads, cracks in the tension flanges of steel bridge girders have been observed as a result of stress concentrations, design errors, welding quality control, and vehicular impacts. Cracks can grow in size with time and active cyclic live loads and may result in a member fracture. Fracture is a dangerous limit state which occurs with little to no warning. One method to quantify the stress field in the vicinity of a crack tip is by calculating the Stress Intensity Factor (SIF) around the crack tip. Finding SIFs for a cracked geometry may help an engineer to determine the fracture potential based on crack dimensions found during the inspection. Rolled I-beam and steel plate girders are extensively used as bridge superstructure members to efficiently carry live loads. This research was focused on determining Stress Intensity Factors (SIFs) of partially cracked I-sections using Finite Element Analysis. Two different tension flange crack profiles were studied: edge cracks, and full-width cracks. The SIF solutions were further used to study the fracture behavior and stress redistribution in the partially cracked flexural I-shaped members. / Master of Science / Steel is one of the fundamental materials used in the construction of bridge structures, and steel girder bridges are one of the most common types of bridge structures seen in the United States. Past bridge failures have helped engineers to understand shortcomings in design specifications, and AASHTO codes have been developed and revised over the years to reflect an improved understanding and evolution of engineering behavior. Engineers must make sure that a design is robust enough for functional use of the component during its service life. It is also equally important to understand the potential chances of failure and make the structure strong enough to overcome any failure mechanisms. Fracture is one structural failure mode which occurs with little to no warning and hence is very dangerous. One efficient way to quantify the stress field in the vicinity of a crack tip is by calculating the Stress Intensity Factor (SIF) around a crack tip. Fracture literature is available which describes different methods of determining SIFs for cracked members. However, there are no solutions available to find a SIF of a partially cracked flexural I-shaped members. This research was focused on determining Stress Intensity Factors and studying the fracture behavior of partially cracked I-sections using Finite Element Analysis. The resulting SIF solutions were further used to study the fracture behavior and stress redistribution in partially cracked flexural I-shaped members.
407

Axial Capacity of Circular Concrete-filled Tube Columns

Giakoumelis, G., Lam, Dennis January 2004 (has links)
No / The behaviour of circular concrete-filled steel tubes (CFT) with various concrete strengths under axial load is presented. The effects of steel tube thickness, the bond strength between the concrete and the steel tube, and the confinement of concrete are examined. Measured column strengths are compared with the values predicted by Eurocode 4, Australian Standards and American Codes. 15 specimens were tested with 30, 60 and 100 N/mm2 concrete strength, with a D/t ratio from 22.9 to 30.5. All the columns were 114 mm in diameter and 300 mm in length. The effect due to concrete shrinkage is critical for high-strength concrete and negligible for normal strength concrete. All three codes predicted lower values than that measured during the experiments. Eurocode 4 gives the best estimation for both CFT with normal and high-strength concrete.
408

Reconfigurable Devices using Liquid Crystal at Microwave Frequencies in Substrate Integrated Waveguide

Sánchez Marín, Juan Rafael 02 December 2019 (has links)
[ES] La cantidad de servicios de telecomunicación se ha incrementado signiticativamente en las últimas décadas. El uso de teléfonos inteligentes, así como el Internet de las Cosas, está generando una saturación del espectro electromágnetico. Por tanto, los requisitos de los sistemas de microondas han cambiado para adaptarse a estos nuevos avances. Para satisfacer estas necesidades, se busca el desarrollo de dispositivos de bajo coste, volumen, peso y consumo. Además, interesa que sean espectralmente eficientes y fácilmente integrables con otros dispositivos. Entre todos los dispostivos de microondas, los filtros son elementos clave dentro de los sistemas de comunicaciones móviles e inalámbricas. Es por ello que el diseño de filtros que cumplan con los requisitos mencionados se ha convertido en un tema de gran interés. Para dar respuesta a este problema ha surgido la tecnología de Guía de Onda Integrada en Sustrato (Substrate Integrated Waveguide (SIW)), que permite la implementación de filtros con un reducido tamaño y fácilmente integrables con otros dispositivos en tecnología planar. Dicha tecnología presenta unas prestaciones en cuanto a manejo de potencia y pérdidas mejores que la tecnología de circuito impreso (Printed Circuit Board (PCB)), aunque no llegan a ser iguales que las de la guía de onda clásica. Por otro lado, la saturación espectral también lleva al estudio de filtros con respuestas variables en frecuencia, es decir, que puedan cambiar su frecuencia central y ancho de banda con el fin de adaptarse a las necesidades del sistema. Por ello, el objetivo general de esta Tesis es el análisis y diseño de nuevos filtros reconfigurables en tecnología integrada. El trabajo empieza con el estudio de los fundamentos de los filtros de microondas hasta llegar al diseño de resonadores reconfigurables en tecnología SIW usando el cristal líquido como material de reconfiguración. En primer lugar, se ha estudiado la influencia que los cambios en el valor de la permitividad dieléctrica en el interior de las estructuras filtrantes pueden tener en la respuesta de las mismos. En particular, se desarrollan filtros alternando secciones de línea con y sin dieléctrico dentro de una SIW vacía, Empty Substrate Integrated Waveguide (ESIW). Una vez hecho esto, se procede al estudio de materiales que tengan un valor de permitividad dieléctrica variable de alguna forma. En concreto, se ha realizado la caracterización de diferentes mezclas de cristal líquido a la frecuencia de microondas. Dicho material cambia su valor de permitividad cuando se le aplica un campo eléctrico o magnético. Dado que para la reconfiguración de la respuesta de los filtros se requiere de una estructura desacoplada en baja frecuencia, es decir, con más de un conductor, se ha desarrollado una estrategia para el desacoplo de la estructuras ESIW, la tecnología Decoupled Empty Substrate Integrated Waveguide (DESIW). Por último, se han diseñado resonadores en dicha tecnología DESIW, que se han llenado de cristal líquido y aplicado unos campos de polarización, consiguiendo variar su respuesta en frecuencia. Dichos resonadores constituyen el elemento básico para el desarrollo de filtros de microondas. Es por ello que el conocimiento obtenido en la Tesis es una buena base para futuros trabajos esta tecnología que permitan conseguir filtros de altas prestaciones. / [CA] La quantitat de serveis de telecomunicació s'ha incrementat significativament en les últimes dècades. L'ús de telèfons intel$\cdot$ligents, així com la internet de les coses, està generant una saturació de l'espectre electromagnètic. Per tant, els requisits dels sistemes de microones han canviat per a adaptar-se a aquests nous avanços. Per a satisfer aquestes necessitats, se cerca el desenvolupament de dispositius de baix cost, volum, pes i consum. A més, interessa que siguen espectralment eficients i fàcilment integrables amb altres dispositius. Entre tots els dispositius de microones, els filtres són elements clau dins dels sistemes de comunicacions mòbils i sense fil. És per això que el disseny de filtres que complisquen els requisits esmentats s'ha convertit en un tema de gran interès. Per a donar resposta a aquest problema ha sorgit la tecnologia de Guia d'Ona Integrada en Substrat (Substrate Integrated Waveguide (SIW)), que permet la implementació de filtres amb una reduïda grandària i fàcilment integrables amb altres dispositius en tecnologia planar. Aquesta tecnologia presenta unes prestacions quant a maneig de potència i pèrdues millors que la tecnologia de circuit imprès (Printed Circuit Board (PCB)), encara que no arriben a ser iguals que les de la guia d'ona clàssica. D'altra banda, la saturació espectral també porta a l'estudi de filtres amb respostes variables en freqüència, és a dir, que puguen canviar la seua freqüència central i l'amplada de banda amb la finalitat d'adaptar-se a les necessitats del sistema. Per això, l'objectiu general d'aquesta tesi és l'anàlisi i el disseny de nous filtres reconfigurables en tecnologia integrada. El treball comença amb l'estudi dels fonaments dels filtres de microones, fins a arribar al disseny de ressonadors reconfigurables en tecnologia SIW usant el cristall líquid com a material de reconfiguració. En primer lloc, s'ha estudiat la influència que els canvis en el valor de la permitivitat dielèctrica a l'interior de les estructures filtrants poden tenir en la resposta d'aquestes. En particular, es desenvolupen filtres que alternen seccions de línia amb dielèctric i sense dins d'una SIW buida, Empty Substrate Integrated Waveguide (ESIW). Una vegada fet això, es procedeix a l'estudi de materials que tinguen un valor de permitivitat dielèctrica variable d'alguna forma. En concret, s'ha realitzat la caracterització de diferents mescles de cristall líquid a la freqüència de microones. Aquest material canvia el seu valor de permitivitat quan se li aplica un camp elèctric o magnètic. Atès que per a la reconfiguració de la resposta dels filtres es requereix una estructura desacoblada en baixa freqüència, és a dir, amb més d'un conductor, s'ha desenvolupat una estratègia per al desacoblament d'estructures ESIW, la tecnologia Decoupled Empty Substrate Integrated Waveguide (DESIW). Finalment, s'han dissenyat ressonadors en aquesta tecnologia DESIW, que s'han omplit de cristall líquid i aplicat uns camps de polarització, i s'ha aconseguit variar la seua resposta en freqüència. Aquests ressonadors constitueixen l'element bàsic per al desenvolupament de filtres de microones. És per això que el coneixement obtingut en la tesi és una bona base per a futurs treballs d'aquesta tecnologia que permeten aconseguir filtres d'altes prestacions. / [EN] The number of telecommunication services has increased significantly in recent decades. The use of smartphones, as well as the Internet of Things, is generating a saturation of the electromagnetic spectrum. Therefore, the requirements of microwave systems have changed to adapt to these new developments and related challenges. For achieving these needs, the development of devices with low cost, volume, weight and power consumption is sought. In addition, it interests to be spectrally efficient, to offer high performance, and to be easily integrated with other devices. Among all microwave devices, filters are key elements within mobile and wireless communication systems. In this context, the design of filters that meet the aforementioned requirements has become a topic of great interest. For solving this problem, Substrate Integrated Waveguide (SIW) technology has emerged, which allows the implementation of filters with a small size and to be easily integrated with other devices in planar technology. This technology has better power handling and loss performance than Printed Circuit Board (PCB) technology, although they do not have the performance of the classic waveguide counterpart. On the other hand, the spectral saturation also leads to the study of filters with tunable frequency response, that is, they can change their central frequency and bandwidth, in order to fulfil the changing system requirements. Therefore, the general objective of this PhD Thesis work is the analysis and design of new reconfigurable filters in integrated technology. The work begins with the study of the basics of microwave filters until the design of reconfigurable resonators in SIW technology, using Liquid Crystal (LC) as reconfiguration material. Firstly, the influence that the change of the dielectric permittivity value inside the filtering structures have on the frequency response has been studied. Particularly, filters have been obtained by alternating line sections with and without dielectric material inside an empty SIW (Empty Substrate Integrated Waveguide (ESIW)). Once this is done, it is proceed to the study of materials that have a variable dielectric permittivity value. Specifically, the characterization of different LC mixtures at microwave frequencies has been carried out. This material changes its permittivity value when an electric or magnetic bias field is applied. A low-frequency decoupled structure is required for the reconfiguration of filters, that is, structures with more than one conductor. For that, a strategy for decoupling ESIW structures has been developed, i.e, the Decoupled Empty Substrate Integrated Waveguide (DESIW) technology. Finally, some resonators have been designed in DESIW technology, which have been filled with LC. The use of LC allows to tune their frequency response. These resonators are basic elements for the development of microwave filters. So that, the knowledge obtained in this Thesis work is a good basis for future works in this technology that allow for achieving high performance filters. / Sánchez Marín, JR. (2019). Reconfigurable Devices using Liquid Crystal at Microwave Frequencies in Substrate Integrated Waveguide [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/132183
409

Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling

Peng, Zhe, Day, Douglas A., Ortega, Amber M., Palm, Brett B., Hu, Weiwei, Stark, Harald, Li, Rui, Tsigaridis, Kostas, Brune, William H., Jimenez, Jose L. 06 April 2016 (has links)
Oxidation flow reactors (OFRs) using low-pressure Hg lamp emission at 185 and 254 nm produce OH radicals efficiently and are widely used in atmospheric chemistry and other fields. However, knowledge of detailed OFR chemistry is limited, allowing speculation in the literature about whether some non-OH reactants, including several not relevant for tropospheric chemistry, may play an important role in these OFRs. These non-OH reactants are UV radiation, O(<sup>1</sup>D), O(<sup>3</sup>P), and O<sub>3</sub>. In this study, we investigate the relative importance of other reactants to OH for the fate of reactant species in OFR under a wide range of conditions via box modeling. The relative importance of non-OH species is less sensitive to UV light intensity than to water vapor mixing ratio (H<sub>2</sub>O) and external OH reactivity (OHR<sub>ext</sub>), as both non-OH reactants and OH scale roughly proportionally to UV intensity. We show that for field studies in forested regions and also the urban area of Los Angeles, reactants of atmospheric interest are predominantly consumed by OH. We find that O(<sup>1</sup>D), O(<sup>3</sup>P), and O<sub>3</sub> have relative contributions to volatile organic compound (VOC) consumption that are similar or lower than in the troposphere. The impact of O atoms can be neglected under most conditions in both OFR and troposphere. We define “riskier OFR conditions” as those with either low H<sub>2</sub>O (< 0.1 %) or high OHR<sub>ext</sub> ( ≥  100 s<sup>−1</sup> in OFR185 and > 200 s<sup>−1</sup> in OFR254). We strongly suggest avoiding such conditions as the importance of non-OH reactants can be substantial for the most sensitive species, although OH may still dominate under some riskier conditions, depending on the species present. Photolysis at non-tropospheric wavelengths (185 and 254 nm) may play a significant (> 20 %) role in the degradation of some aromatics, as well as some oxidation intermediates, under riskier reactor conditions, if the quantum yields are high. Under riskier conditions, some biogenics can have substantial destructions by O<sub>3</sub>, similarly to the troposphere. Working under low O<sub>2</sub> (volume mixing ratio of 0.002) with the OFR185 mode allows OH to completely dominate over O<sub>3</sub> reactions even for the biogenic species most reactive with O<sub>3</sub>. Non-tropospheric VOC photolysis may have been a problem in some laboratory and source studies, but can be avoided or lessened in future studies by diluting source emissions and working at lower precursor concentrations in laboratory studies and by humidification. Photolysis of secondary organic aerosol (SOA) samples is estimated to be significant (> 20 %) under the upper limit assumption of unity quantum yield at medium (1 × 10<sup>13</sup> and 1.5 × 10<sup>15</sup> photons cm<sup>−2</sup> s<sup>−1</sup> at 185 and 254 nm, respectively) or higher UV flux settings. The need for quantum yield measurements of both VOC and SOA photolysis is highlighted in this study. The results of this study allow improved OFR operation and experimental design and also inform the design of future reactors.
410

The properties of molecular ions

O'Connor, Caroline Sophie Scott January 1999 (has links)
No description available.

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