With the ever-increasing demands of the nuclear power community to extend fuel cycles and overall core-lifetimes in a safe and economic manner, it is becoming more necessary to extend the working knowledge of nuclear fuel performance. From the atomistic to the macroscopic level, great morphological changes occur within the fuel over its lifetime. The main initial damaging events produced by fuel recoils from fast neutrons and fission fragment spiking leads to the onset of grain growths and fuel restructuring. Therefore, it is desirable to have a more detailed understanding of the initial events leading to fuel morphology changes at the atomistic level. However, this is difficult to achieve with the fission fragments due to the wide variability of their species (charge, mass, and energy) and the large averaging of their relative yields in the nuclear data files. This work is our first iteration at developing a general methodology to characterize a procedure, based on Monte Carlo principles, for generating individual fission event result channels and analyzing their specific response in the fuel. We utilized the nuclear reaction simulation tool, TALYS, to generate energy-dependent fission fragment yield distributions for different fissile/fissionable isotopes. These distributions can then be used in conjunction with fuel isotopics and a neutron energy spectrum to generate a fission-reaction-rate-averaged distribution of the fission fragment yields. We then used Monte Carlo sampling to generate the result channels from individual fission events, using the Q-value of the prompt fission system to either accept or reject. The simulation tool: Transport of Ions in Matter (TRIM) was used to characterize the general response of the fission fragment species within Uranium Dioxide (UO2), including the range, energy loss, displacements, recoils, etc. These responses were then correlated which allowed for the quick calculation of the response of the individual fission fragment species generated from the Monte Carlo sampling. As an example of this strategy, we calculated the response on a PWR fuel pin where MCNP was used to generate a high-fidelity neutron energy spectrum.

Les détecteurs de radiations nucléaires sont des outils importants dans de nombreux domaines tels que dans les réacteurs nucléaires, la sécurité nationale, mais ils sont également primordiaux dans des applications médicales. Les progrès récents dans la technologie des semi-conducteurs permettent la réalisation de détecteurs très efficaces et quasi-insonores qui permettent la détection de différents types de radiations nucléaires. Le carbure de silicium (SiC) est une bande semi-conductrice large, grâce à sa conductivité thermique élevée et à une résistance élevée aux rayonnements, il est adapté pour les environnements difficiles où peuvent exister des flux élevés de température et de rayonnement. Le but du projet européen (I_SMART) est ainsi de prouver la fiabilité de nouvelles méthodes de réalisation de détecteurs de radiations nucléaires et d'étudier leur performance dans différents types d'irradiation (neutrons rapides et thermiques) et à différentes températures. Différentes méthodes ont été utilisées pour réaliser les détecteurs de rayonnement SiC. Par exemple l'implantation d'ions de bore a été utilisé pour créer la couche de conversion de neutrons soit dans le contact métallique ou directement en SiC. Les détecteurs fabriqués ont été testés dans le réacteur nucléaire BR1, mettant en lumière la présence de neutrons thermiques. En outre, ces détecteurs détectent des neutrons rapides sous n’importe quelle température. En outre, les détecteurs utilisés montrent leur stabilité sous différents flux de neutrons qui indiquent la fiabilité de ces nouveaux modes de réalisation de détecteurs de rayonnement qui pourraient remplacer ceux utilisés actuellement. / Nuclear radiation detectors are important tools in many fields such as in nuclear reactors, homeland security and medical applications. Recent advances in semiconductor technology allow construction of highly efficient low noise detectors for different nuclear radiations. Silicon carbide (SiC) is a wide band gap semiconductor with a high thermal conductivity and high radiation resistance. It is suitable for a harsh environment where high temperatures and radiation fluxes may exist. In the framework of the European project (I_SMART) the purpose of this work is to demonstrate the reliability of new methods of realizing nuclear radiation detectors and to study their performance under different types of irradiation (fast and thermal neutrons) and at elevated temperatures. Different methods have been used to realize SiC based-radiation detectors. For instance boron ion implantation has been used to create the neutron converter layer either in the metallic contact or directly in the SiC. The fabricated detectors have been tested in the BR1 nuclear reactor revealing the thermal neutron detection and the feasibility of gamma discrimination from thermal neutrons using one single detector. Such detectors are sensitive to fast neutrons with a stable response under elevated temperatures (up to 150 °C). Furthermore, the studied detectors show stability under different neutron fluxes, indicating a reliability of such new methods of realizing radiation detectors which could replace those of the current state of the art.

The need of a stable production of At-211 is necessary to continue research in alpha-particle targeted radionuclide therapy. Our objectives were to establish the production of Astatine-211 at Texas A&M Cyclotron Institute, optimize the production methods to reduce the generation of contaminants and maximize At-211 production, and assess the radiological safety aspects of At-211 production. The production of the alpha-particle emitting radionuclide At-211 was performed at the Texas A&M Cyclotron Institute using the K500 superconducting cyclotron following the production reaction Bi-209(α, 2n)At-211 using a thick bismuth target of 500 μm. We carried out two irradiation experiments where the initial energy of the alpha-particle beam, 80 MeV, was degraded using multiple copper and aluminum foils to 27.8 and 25.3 MeV, respectively. The end of beam time was 4 hours for both experiments. The resulting At-211 yields were 36.0 and 12.4 MBq/μA-h, respectively. Several impurities were produced using the 27.8 MeV, which included At-210 and Po-210. However, when the 25.3 MeV beam was used, the impurities At-210 and Po-210 were resolved and other contaminants were minimized to less than 0.8% of At-211 yield. The production yields were in accordance to previous published results. From the success of these initial experiments, additional steps were taken to produce At-211 in excess quantities for distillation purposes. In order to obtain viable quantities of At-211, the gross yield needed to be increased due to losses that are incurred during distillation and radioactive decay. The ability to produce high yields of this isotope required a redesign of the target and use of the K150 cyclotron using a higher beam intensity.

The purpouse of the master's thesis is study problematic of focused ion beams and their material influence. In this thesis are described interactions in the sample after impact of ion beam, use and applications of FIB systems. Second part of thesis are simulations of ion influence on different kinds of materials by the help of SRIM program.

The radioactive ion implantation wear measuring method (RII) has been used for many years as a tool to make highly sensitive real-time in-situ measurements of wear and corrosion in metallic or ceramic materials. The method consists of the controlled implantation of radioactive ions of limited decay time in a thin layer at the surface of the material. The progressive abrasion of the material results in a decline in radioactivity which is followed to monitor material losses. The application of RII to control the wear of polymers is potentially of interest, but it has been lagging behind because of uncertainties related to possible changes in material properties during and after the implantation, and to the exact shape of implantation profiles. In this thesis, we investigate these issues on two thermoplastic elastomers typically used for making the soles of sport shoes, among which one contains radiation-sensitive unsaturated bonds, using as ions 7Be, 7Li and Kr. The results of the sample characterisation indicate that the 7Be and 7Li implantations, under properly-selected conditions, do not induce significant modifications in the materials. The implantation of a stack of polymer thin films and the activity measurements performed to determine the implantation profile are also presented. The experimental results on the ion implantation profiles and the determination of calibration curves are presented and discussed in comparison with simulated results. The results indicate that it is possible to predict the implantation profile by means of simulations. This bodes well for the application of the RII method to polymer materials. In the last part, an experimental study is presented regarding the possible redistribution of the implanted 7Be after implantation. Since very few existing experimental techniques are able to detect light elements implanted in polymer targets at fluences less or equal to 1012 cm-2, with implantation depths of a few µm, a new method is presented, which implies the use of plasma etching techniques in order to remove layers of polymers and measuring the remaining activity after each step. Our results indicate that a redistribution of the implanted ions takes place during the implantation process, resulting in a scrambling of the initial implantation profile. Nevertheless, provided a suitable methodology be used, wear measurements in polymers by using the RII method are still possible, as we propose in the thesis.

Electric power has become a basic necessity of human life. The major share of electric power comes from fossil fuel which results in global warming and pollution. A share of generated power comes from nuclear power which is equally dangerous. Big hydro projects take away lots of fertile land. The continuous usage of fossil fuel also poses a threat of petroleum and coal getting over in the near future. The only way out of this energy scarcity is to depend more and more on renewable sources like solar, wind and micro-hydro. At present, instead of having preference over any particular source of renewable energy, effort should be made to extract power from every possible energy source available in whatever form it is and use it in an optimal way. Like any renewable energy sources, the wind power contains large potential for harnessing energy that has been well understood hundreds of years ago. The importance of wind power generation has come to focus recently both at installation and research level and lot of activities are being carried out for efficient use of wind energy. There are different types of wind turbine designs available in the literature. But the most commercially used model is the two or three blade horizontal axis propeller type wind turbine. Research has shown that variable speed operation of this type of turbine is advantageous over fixed speed operation in terms of total energy synthesis. The most commonly used machines for wind power conversion are synchronous machine, squirrel cage induction machine and slip ring induction machine (SRIM). Variable speed operation using synchronous machine or squirrel cage induction machine requires large ratings of the power converters. However, SRIM based variable speed wind generator is advantageous over other schemes due to its inherent advantages like lower power rating for the converters, higher energy capture and the flexibility of sharing reactive power between the stator and the rotor. SRIM is used for both grid connected and stand alone applications and have been reported in the literature. The grid connected applications have received major attention in the literature whereas there are only a very few instances of its stand alone counterparts. There are many places both within and outside India where utility grid has not yet reached or the available grid is very weak. Moreover, in many of the places, the transmission line is so long that the losses in the system are extremely high. Isolated wind power generation can be of great advantage in such places where the available wind power is harnessed and utilized locally. This has been the motivation to go for proposing an isolated wind power generation scheme in this thesis. The proposed scheme is designed to supply power to the load even when very low or no wind power is available. Therefore, a battery bank is also a part of the system. The power converter assembly of the proposed scheme has three major components. One is the rotor side converter which is connected to the rotor terminals of the SRIM. The second one is the stator side converter with output LC filter which is connected to the stator side. These two converters share a common DC link which is interfaced to the battery bank through a multi phase bi-directional fly-back DC-DC converter. Fig. 1. Overall block diagram of the proposed stand alone wind power generator Functionally, this thesis proposes a system as shown in Fig. 1, which has primarily two components with multiple energy ports viz. (i) the SRIM is one triple energy port component and (ii) the proposed power conditioner is another triple energy port component. The SRIM device consists of (i) a mechanical energy port that is interfaced with the windmill shaft (ii) an AC port through the stator windings that is interfaced with the micro-grid/load and (iii) a third port which is also an AC port through the rotor windings of the SRIM that interfaces with an AC port of the proposed power conditioner. The proposed power conditioner is another triple energy port device which consists of (i) a DC energy port that interfaces with a battery/accumulator, (ii) an AC port that interfaces with the rotor windings of the SRIM and (iii) another AC port that generates the micro-grid that is connected to the load and the stator port of the SRIM. The proposed power conditioner provides the frame work for managing the energy flow from the mechanical port of the SRIM to the rotor and accumulator as well as from the mechanical port to the stator/load and accumulator. Further, energy interaction can also take place between the stator and the rotor externally through the power conditioner. The power interfaces on all three energy ports of the proposed power conditioner poses several challenges that have been discussed in this thesis. This thesis focuses on developing schemes to solve these challenges as explained below. Speed sensorless control is a natural choice for slip ring induction machine because of the flexibility of sensing both stator and rotor currents. There are different methods proposed in the literature which deal with the speed sensorless control of slip ring induction machine. However, the elimination of the measurement noise in the flux position estimation is not sufficiently addressed. It is important to address this issue as this would lead to deterioration in rotor side control of SRIM if the measurement noise is not eliminated. Primarily, the schemes which use algebraic relation between the estimated rotor current in stator reference frame and the sensed rotor current, are prone to measurement noise. On the other hand, the schemes, which use rotor back-emf integration, are affected by DC drift problems, though they are not much affected by measurement noise. The proposed stator flux position estimation scheme incorporates the benefits obtained from both the above schemes while eliminating the disadvantages inherent to them. The rotor flux position is estimated by integrating the rotor back-electromotive force. The stator flux is then obtained from the rotor flux estimate. This integration mechanism leads to several problems like dc drift and lack of error decaying mechanism. This estimation scheme solves the above problems including reduction in the propagation of noise in the sensed current to the estimated rotor side unit vectors. On the implementation front, this scheme also eliminates the need for differentiating the unit vectors for estimating slip frequency. This makes the proposed flux estimator very robust. The proposed scheme is simulated and experimentally verified. There is an internal DC bus within the proposed power conditioner that manages the energy flow through the three energy ports. The internal DC bus is interfaced to an external accumulator or battery through a power interface called the multi phase bi-directional dc-dc converter. It is generally advantageous to have the motor rated for higher voltages in order to achieve better efficiencies for a given power rating as compared to low voltage motors. This implies higher DC bus voltage. On the other hand, it is advantageous to have the battery bank rated for low voltage in order to improve the volumetric efficiency which is better at lower battery bank voltages. Both these are contradictory requirements. The above problem is solved in this thesis by proposing a multi power port topology using a bidirectional fly-back converter that is capable of handling multiple power sources and still maintain simplicity and features like high gain, wide load variations and lower output current ripple. As a spin-off, the scheme can handle parallel energy transfer from even a eutectic combination of batteries without any additional control circuitry for parallel operation. Further, the scheme also incorporates a novel transformer winding technique which significantly reduces the leakage inductance of the coupled inductor. The proposed multi-port bidirectional converter is analyzed by including non-idealities like leakage inductance. The DC bus voltage regulation requirement is not very stringent because it is not directly fed to any load. Therefore, hysteresis voltage regulation with small proportional correction is used for DC bus voltage control. The proposed converter is built and experimentally verified in the proposed system as well as in a hybrid-electric vehicle prototype. The third port of the proposed power conditioner interfaces with the stator of the SRIM and the load. The stator/load needs to be connected to a stiff micro-grid. The control requirement of the micro-grid is very stringent because, even for a sudden variation in the wind speed or the load, the grid voltage magnitude and frequency should not change. The dynamic response of the grid voltage controller has to be very fast. Moreover, the grid voltage must be balanced in presence of unbalanced loading. This thesis proposes a converter called the stator side converter along with three phase L-C filter at its output to form the micro-grid. A generalized control scheme is proposed wherein the negative sequence components and the harmonics can be eliminated at the micro-grid by means of feed-forward compensators included in the fundamental positive synchronous reference frame alone. The theoretical foundation for this scheme is developed and discussed in the thesis. In isolated locations linear loads constitute a significant percentage of the total load. Therefore, on the implementation front, only the compensation of fundamental negative sequence is demonstrated. One more necessity for compensating the fundamental negative sequence is that, the SRIM offers only leakage impedance to the fundamental negative sequence components resulting in high fundamental negative sequence current even for a small fundamental negative sequence voltage present at the micro-grid. The proposed scheme ensures balanced three phase currents at the SRIM windings and the full unbalanced current is provided from the stator side converter. This scheme is validated both by simulation and experimentation. The proposed power conditioner is integrated and used in the implementation of the entire wind power generation scheme that is proposed in the thesis. The maximum power point tracking of the wind power unit is also incorporated in the proposed system. The simulation and experimental results are also presented. Finally, the engineering issues involved in the implementation of the proposed scheme are discussed in detail highlighting the hardware configuration and the equipments used. The wind turbine is emulated using a chopper controlled DC motor. The shaft torque of the DC motor is controlled to give the Cp−λ characteristic of a typical windmill. The control issues of the DC machine to behave as a wind turbine are also explained. Finally the thesis is concluded by a statement of potentials and possibilities for future work in this research area.

The ageing state of the world's nuclear power infrastructure, and the need to reduce humanity s dependency on fossil fuels, requires that this electrical energy generating capacity is replaced. Economic factors, and its physical and chemical properties, make high purity iron-chromium binary alloys a strong candidate for use in the construction of the pressure vessels of the next generation of nuclear reactors. This relatively inexpensive metal retains the oxidation resistance property of so-called stainless steel alloys, and has demonstrated dimensional stability and low degradation under harsh experimental environments of temperature and radiation. In this work, we consider radiation induced interstitial damage to the atomic lattices of iron-chromium binary alloys using the atomistic modelling methods, Molecular Dynamics and Adaptive Kinetic Monte Carlo, simulating collision cascade sequences, and the migration of defects in the aftermath. Variations in chromium content does not effect the initial damage production in terms of the number of Frenkel pairs produced, but iron and chromium atoms are not evenly distributed in defect atoms with respect to the bulk concentration. In simulations conducted at low temperature, chromium is under-represented, and at high temperature, a greater proportion of interstitial atoms are chromium than in the lattice overall. The latter phenomena is most strongly pronounced in systems of low bulk chromium content. During the simulation of post-cascade defect migration, interstitials atoms are observed to form temporary clusters and vacancies align along adjacent lattice sites, with the two types of defect also migrating to annihilate by recombination. Calculating the energy spectra of cascade events corresponding to an example experimental configuration using the SRIM package, we investigated the evolution of lattice systems in which a sequence of multiple cascade events occurred, both with and without a physically representative time gap between events. These simulations gave us the opportunity to observe the behaviour of cascades in the proximity of damage remaining from previous events, such as the promotion of defect clustering when this occurs.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / Nessa tese foi feito um estudo preliminar, destinado à elaboração do programa experimental inicial para a primeira instalação da tomografia com prótons (pCT) brasileira por meio de modelagem computacional. A terapia com feixe de prótons é uma forma bastante precisa de tratamento de câncer. Atualmente, o planejamento de tratamento é baseado na tomografia computadorizada com raios X, alternativamente, a tomografia com prótons pode ser usada. Algumas questões importantes, como efeito de escala e a Curva de Calibração (fonte de dados iniciais para planejamento de terapia com prótons), foram estudados neste trabalho. A passagem de prótons com energias iniciais de 19,68MeV; 23MeV; 25MeV; 49,10MeV e 230MeV pelas camadas de materiais variados (água, alumínio, polietileno, ouro) foi simulada usando códigos Monte Carlo populares como SRIM e GEANT4. Os resultados das simulações foram comparados com a previsão teórica (baseada na solução aproximada da equação de transporte de Boltzmann) e com resultados das simulações feitas com outro popular código Monte Carlo MCNPX. Análise comparativa dos resultados das simulações com dados experimentais publicados na literatura científica para alvos grossos e na faixa de energias de prótons usada em medidas em pCT foi feita. Foi observado que apesar de que todos os códigos mostram os resultados parecidos alguns deslocamentos não sistemáticos podem ser observados. Foram feitas observações importantes sobre a precisão dos códigos e uma necessidade em medidas sistemáticas de frenagem de prótons em alvos grossos foi declarada. / In the present work a preliminary research via computer simulations was made in order to elaborate a prior program for the first experimental pCT setup in Brazil. Proton therapy is a high precise form of a cancer treatment. Treatment planning nowadays is performed basing on X ray Computer Tomography data (CT), alternatively the same procedure could be performed using proton Computer Tomography (pCT). Some important questions, as a scale effect and so called Calibration Curve (as a source of primary data for pCT treatment planning) were studied in this work. The 19.68MeV; 23MeV; 25MeV; 49.10MeV e 230MeV protons passage through varied absorbers (water, aluminum, polyethylene, gold) were simulated by such popular Monte Carlo packages as SRIM and GEANT4. The simulation results were compared with a theoretic prevision based on approximate solution of the Boltzmann transport equation and with simulation results of the other popular Monte Carlo code MCNPX. The comparative analysis of the simulations results with the experimental data published in scientific literature for thick absorbers and within the energy range used in the pCT measurements was made. It was noted in spite of the fact that all codes showed similar results some nonsystematic displacements can be observed. Some important observations about the codes precision were made and a necessity of the systematic measurements of the proton stopping power in thick absorbers was declared.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / Nessa tese foi feito um estudo preliminar, destinado à elaboração do programa experimental inicial para a primeira instalação da tomografia com prótons (pCT) brasileira por meio de modelagem computacional. A terapia com feixe de prótons é uma forma bastante precisa de tratamento de câncer. Atualmente, o planejamento de tratamento é baseado na tomografia computadorizada com raios X, alternativamente, a tomografia com prótons pode ser usada. Algumas questões importantes, como efeito de escala e a Curva de Calibração (fonte de dados iniciais para planejamento de terapia com prótons), foram estudados neste trabalho. A passagem de prótons com energias iniciais de 19,68MeV; 23MeV; 25MeV; 49,10MeV e 230MeV pelas camadas de materiais variados (água, alumínio, polietileno, ouro) foi simulada usando códigos Monte Carlo populares como SRIM e GEANT4. Os resultados das simulações foram comparados com a previsão teórica (baseada na solução aproximada da equação de transporte de Boltzmann) e com resultados das simulações feitas com outro popular código Monte Carlo MCNPX. Análise comparativa dos resultados das simulações com dados experimentais publicados na literatura científica para alvos grossos e na faixa de energias de prótons usada em medidas em pCT foi feita. Foi observado que apesar de que todos os códigos mostram os resultados parecidos alguns deslocamentos não sistemáticos podem ser observados. Foram feitas observações importantes sobre a precisão dos códigos e uma necessidade em medidas sistemáticas de frenagem de prótons em alvos grossos foi declarada. / In the present work a preliminary research via computer simulations was made in order to elaborate a prior program for the first experimental pCT setup in Brazil. Proton therapy is a high precise form of a cancer treatment. Treatment planning nowadays is performed basing on X ray Computer Tomography data (CT), alternatively the same procedure could be performed using proton Computer Tomography (pCT). Some important questions, as a scale effect and so called Calibration Curve (as a source of primary data for pCT treatment planning) were studied in this work. The 19.68MeV; 23MeV; 25MeV; 49.10MeV e 230MeV protons passage through varied absorbers (water, aluminum, polyethylene, gold) were simulated by such popular Monte Carlo packages as SRIM and GEANT4. The simulation results were compared with a theoretic prevision based on approximate solution of the Boltzmann transport equation and with simulation results of the other popular Monte Carlo code MCNPX. The comparative analysis of the simulations results with the experimental data published in scientific literature for thick absorbers and within the energy range used in the pCT measurements was made. It was noted in spite of the fact that all codes showed similar results some nonsystematic displacements can be observed. Some important observations about the codes precision were made and a necessity of the systematic measurements of the proton stopping power in thick absorbers was declared.

The implementation of game elements has quintessentially uplifted the overall experience of applications in various domains and thereby expanding the customer base. This process is called gamification which has now been introduced in many domains. The purpose of the study is to understand gamification and how its impact would be if it is deployed in a financial savings application. The gamified elements are implemented based on a gamification framework called the Octalysis framework1. This Octalysis framework is a human-centric gamification framework which serves as a template to implement the required gamified elements. Based on a pre-study of financial applications and the Octalysis framework, two distinct prototypes (Version A and Version B) of the same mobile app concept were developed where the difference is the presence of gamified elements in one prototype. The evaluation is based on analyzing the impact the gamified elements have caused on the usability and the emotional engagement of the financial savings application. The participants are provided to interact with both prototypes and interviews are conducted to evaluate the emotional engagement and the usability of both the prototypes of the financial savings application. The study shows an increase in emotional engagement corresponding to the gamified elements whereas the usability more or less remained the same, indicating a deeper investigation of the gamified elements with regards to usability is required.