The presented paper aims at the problems of fluvial lakes in middle course of the Elbe River which has been influenced by the human activity since the Middle Ages. The oxbow lakes which are extremely precious ecosystems contributing to the stability of the river ecosystem show not only the changes of the course of the Elbe River. With regard to sedimenting a great amount of pollutants, these lakes also tell about the industrial pollution to which the river was exposed mainly in the second half of the 20th century due to insufficient precautions on industrial sources causing contamination. 5 cut lakes between Hradec Králové and Mělník have been studied within this research. These lakes differ in the intensity of communication with the river, in the distance from significant sources of industrial pollution and in the use of nearby land. The research included morphometric and bathymetric measures, observation of hydrological regime, seasonal measures in the water column and regular analysis of surface water samples. Profiles of sediments in the length that the used technology allowed were sampled, so that older anthropogenic load could be found out. The amount of organic carbon and concentration of selected metal and arsenic (Ag, Cd, Cr, Cu, Fe, Hg, Mn, Pb and Zn) were stated apart from grain size...

The Bîc River in the Republic of Moldova is a heavily polluted water body. Along the river stretch, from a small creek in Sipoteni close to the river mouth at Gura Bîcului, sediment samples were taken using a very cost-effective method and analyzed for a number of pollutants. The results showed very high levels of petroleum products in and downstream of the city of Chişinău, situated in the middle of the river basin, ex-ceeding even the guideline value for cleanup of industrial land. Concentrations of heavy metals were detected at all sample points, exceeding the Lowest Effect Level (LEL) in 37 out of 48 samples and the Probable Effect Level (PEL) in four of them. High concentrations of nutrients (N and P) were detected, especially outside of the city, where concentrations exceeded even the Severe Effect Level (SEL) for both N and P at one site. DDT concentrations were highest at the beginning of the river, the concentrations becoming lower and lower when getting closer to the river mouth. At three of the six sampling sites, DDT concentrations exceeded the LEL. PCB levels were lower than the LEL. This was attributed to unsuitable handling of the samples before analysis and therefore the PCB concentration levels requires further investiga-tion. The continued monitoring of the sediments is of great need, therefore a proposal for a monitoring program was written. It was estimated that Bîc contributes 118000 tons of suspended particles to Dniester each year, almost 60 % more per km2 than Dniester contributes to the Black Sea.

Copper remains at elevated levels in the aquatic environment of Stockholm due to diffuse urban sources. Management of these diffuse sources requires their quantification but they cannot be measured directly by field observations. The working hypothesis of this thesis was that Copper levels in the sediments of urban lakes would reflect diffuse emissions within their catchment areas. In order to test this hypothesis, a source – transport – storage conceptual model was developed for tracing the urban diffuse sources of Copper to the sediment in the urbanised catchment. A substance flow analysis (SFA) approach was taken in the source module and a fate, mass-balance model was applied in the lake module. Five separate urban lakes (Judarn, Laduviken, Långsjön, Råcksta Träsk and Trekanten) within the Stockholm area and a main water flow pathway from Lake Mälaren to the inner archipelago of the Baltic Sea, through Stockholm, were selected as case studies.  In comparison to actual source strength data in the literature for the five case study lakes, the SFA approach gave similar results to previous models, but with reduced uncertainty. The SFA approach was also able to indicate the actual sources of urban copper, which was not accomplished by the other approaches and which is a great advantage in managing the sources. For the five lakes in Stockholm, traffic and copper roofs were found to be major contributors of Copper. For the three more polluted lakes, good agreement was obtained between simulated sediment copper contents and independent field observations, thereby supporting the applicability of the model in such cases. Furthermore, simulation results showed sediment copper content to be linearly dependent on the urban load. While this suggests that the urban copper sediment level reflects the urban load, considerable integration of this load over time (decade(s)) was suggested by the simulation results, so time must be allowed in order to detect a change in the urban load by field monitoring of the sediments.  Published data on the main water flow pathway from Lake Mälaren to the archipelago showed a peak in sediment copper content close to the city centre, confirming a considerable urban influence. An approach to quantitatively follow Cu from its urban source through such a complex, aquatic system was developed and applied to Stockholm. The compliance of future quantitative model results with monitoring data may help test the choices made in this conceptual model and the applicability of the model. Data availability proved to be a major obstacle to achieving a quantitative model, particularly as several municipalities with different levels of data availability surround the main water flow pathway studied.  Finally, the applicability of the quantitative, coupled source – transport – storage was demonstrated in a simplified scenario analysis. The ability of the model to estimate the copper load to air and soil and to the urban aquatic environment was also demonstrated. / QC 20110324

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv. / Härtill 4 uppsatser.

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