• Refine Query
  • Source
  • Publication year
  • to
  • Language
  • 27
  • 13
  • 13
  • 3
  • 1
  • 1
  • 1
  • 1
  • 1
  • 1
  • 1
  • 1
  • 1
  • Tagged with
  • 76
  • 76
  • 28
  • 14
  • 13
  • 13
  • 11
  • 9
  • 9
  • 9
  • 9
  • 8
  • 8
  • 7
  • 6
  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
21

On the late Precambrian-early Paleozoic metavolcanic and metasedimentary rocks of the Queen Maud Mountains, Antarctica, and a comparison with rocks of similar age from Southern Africa /

Stump, Edmund January 1976 (has links)
No description available.
22

The lead and zinc deposits in the sedimentary rocks of East Tennessee and Southwest Virginia

Reid, Joseph Hugh. January 1930 (has links) (PDF)
Thesis (Professional Degree)--University of Missouri, School of Mines and Metallurgy, 1930. / The entire thesis text is included in file. Typescript. Title from title screen of thesis/dissertation PDF file (viewed October 30, 2009) Includes bibliographical references (p. 27) and index (p. 28).
23

Provenance Analysis of the Sperm Bluff Formation, southern Victoria Land, Antarctica

Savage, Jeni Ellen January 2005 (has links)
Beacon Supergroup rocks of probable Devonian age, containing conglomerate clasts of lithologies unknown in outcrop in southern Victoria Land (SVL) occur in the St Johns Range to Bull Pass Region, SVL, Antarctica. The Lower Taylor Group sedimentary rocks, herein called the Sperm Bluff Formation, unconformably rest on the regionally extensive Kukri Erosion Surface that truncates local basement. The basement complex includes three Plutonic Suites, Dry Valley (DV) 1a, DVIb and DV2 of the Granite Harbour Intrusives that intrude metasedimentary rocks of the Koettlitz Group. Allibone et al. (1993b) suggested a SVL terrane accretion event may have occurred about the same time as accretion of a terrane known as the Bowers terrane in northern Victoria Land (NVL) based on changing chemistry of the CambroOrdovician granitoids. Further, it is suggested that conglomerate clasts of the Sperm Bluff Formation may have been derived from this postulated terrane (Allibone et al., 1993b; and Turnbull et al., 1994). Following extensive fieldwork provenance studies and basin analysis of the sedimentary Sperm Bluff Formation are used here to test these ideas. The Sperm Bluff Conglomerate of Turnbull et al. (1994) is re-interpreted as the Sperm Bluff Formation and described using a lithofacies-based approach. The Sperm Bluff Formation is divided into six lithofacies including 1) Conglomerate Lithofacies; 2) Pebbly Sandstone Lithofacies; 3) Crossbedded Sandstone Lithofacies; 4) Parallelbedded Lithofacies; 5) Low-angle Crossbedded Lithofacies; and 6) Interbedded Siltstone/Sandstone Lithofacies. The intimate field association of the Conglomerate, Pebbly Sandstone and Crossbedded Sandstone Lithofacies ties them to the Conglomerate Lithofacies Association whereas the other three units are independent. The Conglomerate Lithofacies Association is interpreted to represent a wavedominated deltaic environment, based on the presence of broad channels, pervasive crossbedding, paleocurrent and trace fossil data. Both Parallel-bedded and Low-angle Crossbedded Sandstone Lithofacies are interpreted as a foreshore-shore face shallow marine setting on the basis of low-angle crossbeds and trace fossil assemblages. The Interbedded Siltstone and Sandstone Lithofacies is interpreted as an estuarine environment based on alternating siltstone/sandstone beds and the presence of flaser and lenticular bedding, small crossbedded dune sets, mud drapes, syneresis cracks and diverse paleocurrent directions. An estuarine setting is tentatively favoured over a lagoonal setting due to the presence of syneresis cracks small channels and the proximity to a river delta. I suggest that the Sperm Bluff Formation is likely a lateral correlative of the Altar Mt Formation of the Middle Taylor Group, in particular the Odin Arkose Member. This interpretation is based on arkosic nature of the sedimentary rocks, regional paleocurrent patterns, the presence of salmon pink grits at Gargoyle Turrets and trace fossil assemblages. The upper most lithofacies at Mt Suess, the Low-angle Crossbedded Sandstone Lithofacies that only occurs at this site is- suggested as a lateral correlative to the Arena Sandstone, which stratigraphically overlies the Altar Mt Formation, based on quartzose composition, clay matrix, stratigraphic position and trace fossils present. Provenance analysis was carried out on sedimentary rocks and conglomerate clasts using clasts counts of conglomerates, petrographic analysis of clasts, point counts of sandstones and clasts, geochemistry and V-Pb detrital zircon analysis. Conglomerate clasts lithologies include dominantly silicic igneous clasts and finely crystalline quartzite clast amongst other subordinate lithologies such as vein quartz, schist, schorl rock, gneiss and sandstone. Despite past identification of granitoid clasts in the Sperm Bluff Formation (Turnbull et al., 1994), none were found. Rhyolitic clasts of the Sperm Bluff Formation have compositions typical of highly evolved subduction related rocks, although they have undergone post-emplacement silicification. Wysoczanski et al. (2003) date rhyolite and tuff clasts between 497±17 Ma and 492±8 Ma, placing them within error of all three Dry Valley Magmatic Suites and removing the likelihood of correlation to NVL volcanic rocks. Petrographic analysis suggests they are components of a silicic magmatic complex. Chemically the volcanic clasts appear to represent a single magmatic suite (Sperm Bluff Clast Suite), and are clearly related to the Dry Valley Plutonic Suites. Although clasts are not constrained beyond doubt to one Suite, DV2 is the best match. Quartzite clasts of the Sperm Bluff Formation are too pure and old to be derived from a local source. Detrital zircon V-Pb ages for the quartzite suggest zircons were derived from the East Antarctic Craton, and that the quartzite source rocks were deposited prior to the Ross-Delamarian Orogeny. Quartzite with a similar age signature has not been identified; however, the Junction Formation sandstone of northwest Nelson has a similar age spectrum. Sandstones from the Sperm Bluff Formation indicate derivation from a felsic continental block provenance, which contain elements of volcanic, hyperbyssal and plutonic rocks. They are arkosic to quartzose in composition and conspicuously lack plagioclase. Detrital zircon analyses give a strong 500 Ma peak in all 3 samples, characteristic of a Ross-Delamarian Orogen source, with few other peaks. The dominance of a single peak is highly suggestive oflocal derivation. The sedimentary rocks of the Sperm Bluff Formation are interpreted to be derived predominantly from the basement rocks they now overlie. The presence of the regionally extensive Kukri Erosion Surface at the lower contact of the Beacon Supergroup rocks implies an intermediate source must have existed. This most likely contained all components of the formation. I suggest that the DV2 Suite was emplaced in a subsiding, extensional intra-arc setting. Erosion of the uplifted arc region probably occurred from Late Ordovician to Silurian times with deposition of sediments in a subsiding intra-arc basin. Erosion of the rhyolitic complex in this region probably occurred, however, it is likely that some was preserved. Inversion of this basin prior to the Devonian probably provided the means for these sediments to be deposited as the Sperm Bluff Fonnation.
24

Effet des Fluides et des Fréquences sur les propriétés élastiques des grès et carbonates / Effect of Fluids and Frequencies on Properties Elastics of sandstones and carbonates.

Pimienta, Lucas 12 February 2015 (has links)
La sismique et la sismologie sont des moyens puissants pour comprendre la croûte terrestre.Ces deux méthodes reposent notamment sur une compréhension approfondie de la propagation des ondes sismiques dans des milieux sédimentaires saturés en fluides.Ce travail a pour but de comprendre les effets statique et dynamique du fluide sur la réponse élastique de roches clastiques saturées.Deux points spécifiques de l'interaction fluide-roche sont étudiées: (i) l'intéraction physico-chimique, le « shear weakening », affectant la réponse élastique de la roche; et (ii) l'interaction mécanique, le « frequency effect », induisant une dépendance des propriétés élastiques à la fréquence de mesure.Deux types de roches sont étudiés: les grès et les calcaires.Ces échantillons de roche sont sélectionnés pour leurs propriétés isotropes et leur forte concentration en un minéral dominant: le quartz pour les grès et la calcite pour les carbonates.Le phénomène de « shear weakening » est d’abord étudié pour de très faibles saturations en eau afin de tester l’effet de l'adsorption.Aucun affaiblissement n’est mesuré dans les carbonates, au contraire un affaiblissement élastique global est observé dans certains grès : Les modules de cisaillement et d’incompressibilité sont également affectés.L'effet ne semble pas provenir d'une différence intrinsèque entre les minéraux de quartz et de calcite, mais d’une différence microstructurale entre roches. Un modèle micromécanique est développé, montrant que les deux paramètres clef sont le caractère granulaire et le degré de cimentation de la roche.Le même résultat est obtenu pour les compressibilités mesurées lors des saturations totales en eau.Ces deux études montrent que l'adsorption est la cause du « shear weakening », et implique un affaiblissement élastique global dans les roches granulaires peu cimentées (gréseuses et probablement carbonatées).L'effet de fréquence est étudié dans des grès de Fontainebleau et de Berea. Deux méthodes sont étudiées, toutes deux basées sur le principe de "stress-strain" (i.e. contrainte-déformation): l'oscillation "isotrope" (de la pression de confinement) et "déviatorique" (de la contrainte déviatorique).Ces deux modes d'oscillations sont tout d’abord calibrés à l’aide de plusieurs standards (e.g. aluminium, verre, gypse, plexiglass).Les échantillons de roche, saturés par des fluides de différentes viscosités, sont ensuite mesurés avec ces deux modes d'oscillation.Pour le premier mode d'oscillation, dit "isotrope", ce travail a permis de (i) mettre en évidence trois régimes élastiques distincts;et (ii) mesurer à la fois la conséquence (i.e. dispersion et atténuation du module d'incompressibilité) et la cause (i.e. écoulement fluide global) de la transition en fréquence entre état drainé et état non-drainé.Pour le second mode d'oscillation, dit "déviatorique", le module de Young et le coefficient de Poisson sont mesurés sur une gamme de fréquence apparente de [10-3;105] Hz.Pour un échantillon de grès de Fontainebleau, les deux transitions élastiques sont observées. Les mesures sont cohérentes avec les théories existantes.Un modèle 1D, prenant en compte les conditions de bord du système, est finalement développé. Ce modèle donne des résultats cohérents, et explique l'effet du volume mort sur les propriétés mesurées dans le cas d'une oscillation « isotrope ». / Seismics or Seismology are powerful tools to investigate Earth's crust. However, both rely on seismic waves that travelled through fluid-saturated sedimentary layers. This work, mainly experimental, aims at understanding the static and dynamic effects of the saturating fluid on the elastic response of clastic rocks.In this framework, two specific studies are emphasized:(i) the rock-fluid physico-chemical interaction, often addressed as the "shear weakening" effect, thought to affect the rock overall elastic response; and (ii) the rock-fluid mechanical interaction, addressed as "frequency effect", thought to induce a dependence of elastic properties to the measuring frequency.Two main rock types are investigated: Sandstone and Limestone. All rock samples are chosen to be isotropic and composed of a dominant mineral content, i.e. quartz for sandstone and calcite for limestone.
25

Provenance Analysis of the Sperm Bluff Formation, southern Victoria Land, Antarctica

Savage, Jeni Ellen January 2005 (has links)
Beacon Supergroup rocks of probable Devonian age, containing conglomerate clasts of lithologies unknown in outcrop in southern Victoria Land (SVL) occur in the St Johns Range to Bull Pass Region, SVL, Antarctica. The Lower Taylor Group sedimentary rocks, herein called the Sperm Bluff Formation, unconformably rest on the regionally extensive Kukri Erosion Surface that truncates local basement. The basement complex includes three Plutonic Suites, Dry Valley (DV) 1a, DVIb and DV2 of the Granite Harbour Intrusives that intrude metasedimentary rocks of the Koettlitz Group. Allibone et al. (1993b) suggested a SVL terrane accretion event may have occurred about the same time as accretion of a terrane known as the Bowers terrane in northern Victoria Land (NVL) based on changing chemistry of the CambroOrdovician granitoids. Further, it is suggested that conglomerate clasts of the Sperm Bluff Formation may have been derived from this postulated terrane (Allibone et al., 1993b; and Turnbull et al., 1994). Following extensive fieldwork provenance studies and basin analysis of the sedimentary Sperm Bluff Formation are used here to test these ideas. The Sperm Bluff Conglomerate of Turnbull et al. (1994) is re-interpreted as the Sperm Bluff Formation and described using a lithofacies-based approach. The Sperm Bluff Formation is divided into six lithofacies including 1) Conglomerate Lithofacies; 2) Pebbly Sandstone Lithofacies; 3) Crossbedded Sandstone Lithofacies; 4) Parallelbedded Lithofacies; 5) Low-angle Crossbedded Lithofacies; and 6) Interbedded Siltstone/Sandstone Lithofacies. The intimate field association of the Conglomerate, Pebbly Sandstone and Crossbedded Sandstone Lithofacies ties them to the Conglomerate Lithofacies Association whereas the other three units are independent. The Conglomerate Lithofacies Association is interpreted to represent a wavedominated deltaic environment, based on the presence of broad channels, pervasive crossbedding, paleocurrent and trace fossil data. Both Parallel-bedded and Low-angle Crossbedded Sandstone Lithofacies are interpreted as a foreshore-shore face shallow marine setting on the basis of low-angle crossbeds and trace fossil assemblages. The Interbedded Siltstone and Sandstone Lithofacies is interpreted as an estuarine environment based on alternating siltstone/sandstone beds and the presence of flaser and lenticular bedding, small crossbedded dune sets, mud drapes, syneresis cracks and diverse paleocurrent directions. An estuarine setting is tentatively favoured over a lagoonal setting due to the presence of syneresis cracks small channels and the proximity to a river delta. I suggest that the Sperm Bluff Formation is likely a lateral correlative of the Altar Mt Formation of the Middle Taylor Group, in particular the Odin Arkose Member. This interpretation is based on arkosic nature of the sedimentary rocks, regional paleocurrent patterns, the presence of salmon pink grits at Gargoyle Turrets and trace fossil assemblages. The upper most lithofacies at Mt Suess, the Low-angle Crossbedded Sandstone Lithofacies that only occurs at this site is- suggested as a lateral correlative to the Arena Sandstone, which stratigraphically overlies the Altar Mt Formation, based on quartzose composition, clay matrix, stratigraphic position and trace fossils present. Provenance analysis was carried out on sedimentary rocks and conglomerate clasts using clasts counts of conglomerates, petrographic analysis of clasts, point counts of sandstones and clasts, geochemistry and V-Pb detrital zircon analysis. Conglomerate clasts lithologies include dominantly silicic igneous clasts and finely crystalline quartzite clast amongst other subordinate lithologies such as vein quartz, schist, schorl rock, gneiss and sandstone. Despite past identification of granitoid clasts in the Sperm Bluff Formation (Turnbull et al., 1994), none were found. Rhyolitic clasts of the Sperm Bluff Formation have compositions typical of highly evolved subduction related rocks, although they have undergone post-emplacement silicification. Wysoczanski et al. (2003) date rhyolite and tuff clasts between 497±17 Ma and 492±8 Ma, placing them within error of all three Dry Valley Magmatic Suites and removing the likelihood of correlation to NVL volcanic rocks. Petrographic analysis suggests they are components of a silicic magmatic complex. Chemically the volcanic clasts appear to represent a single magmatic suite (Sperm Bluff Clast Suite), and are clearly related to the Dry Valley Plutonic Suites. Although clasts are not constrained beyond doubt to one Suite, DV2 is the best match. Quartzite clasts of the Sperm Bluff Formation are too pure and old to be derived from a local source. Detrital zircon V-Pb ages for the quartzite suggest zircons were derived from the East Antarctic Craton, and that the quartzite source rocks were deposited prior to the Ross-Delamarian Orogeny. Quartzite with a similar age signature has not been identified; however, the Junction Formation sandstone of northwest Nelson has a similar age spectrum. Sandstones from the Sperm Bluff Formation indicate derivation from a felsic continental block provenance, which contain elements of volcanic, hyperbyssal and plutonic rocks. They are arkosic to quartzose in composition and conspicuously lack plagioclase. Detrital zircon analyses give a strong 500 Ma peak in all 3 samples, characteristic of a Ross-Delamarian Orogen source, with few other peaks. The dominance of a single peak is highly suggestive oflocal derivation. The sedimentary rocks of the Sperm Bluff Formation are interpreted to be derived predominantly from the basement rocks they now overlie. The presence of the regionally extensive Kukri Erosion Surface at the lower contact of the Beacon Supergroup rocks implies an intermediate source must have existed. This most likely contained all components of the formation. I suggest that the DV2 Suite was emplaced in a subsiding, extensional intra-arc setting. Erosion of the uplifted arc region probably occurred from Late Ordovician to Silurian times with deposition of sediments in a subsiding intra-arc basin. Erosion of the rhyolitic complex in this region probably occurred, however, it is likely that some was preserved. Inversion of this basin prior to the Devonian probably provided the means for these sediments to be deposited as the Sperm Bluff Fonnation.
26

Effects of fracture geometry on fluid flow through the Monterey Formation, California : an application of a 3D discrete fracture simulator /

Schaefer, Richard Alan, January 1994 (has links)
Thesis (M.Sc.)--Memorial University of Newfoundland, 1994. / Typescript. Bibliography: leaves 161-168. Also available online.
27

Petrophysical evaluation of sandstone reservoirs of the Central Bredasdorp Basin, Block 9, offshore South Africa

Parker, Irfaan January 2014 (has links)
>Magister Scientiae - MSc / This contribution engages in the evaluation of offshore sandstone reservoirs of the Central Bredasdorp basin, Block 9, South Africa using primarily petrophysical procedures. Four wells were selected for the basis of this study (F-AH1, F-AH2, F-AH4, and F-AR2) and were drilled in two known gas fields namely F-AH and F-AR. The primary objective of this thesis was to evaluate the potential of identified Cretaceous sandstone reservoirs through the use and comparison of conventional core, special core analysis, wire-line log and production data. A total of 30 sandstone reservoirs were identified using primarily gamma-ray log baselines coupled with neutron-density crossovers. Eleven lithofacies were recognised from core samples. The pore reduction factor was calculated, and corrected for overburden conditions. Observing core porosity distribution for all wells, well F-AH4 displayed the highest recorded porosity, whereas well F-AH1 measured the lowest recorded porosity. Low porosity values have been attributed to mud and silt lamination influence as well as calcite overgrowths. The core permeability distribution over all the studied wells ranged between 0.001 mD and 2767 mD. Oil, water, and gas, were recorded within cored sections of the wells. Average oil saturations of 3 %, 1.1 %, and 0.2 % were discovered in wells F-AH1, F-AH2, and F-AH4. Wells F-AH1 to F-AR2 each had average gas saturations of 61 %, 57 %, 27 %, and 56 % respectively; average core water saturations of 36 %, 42 %, 27 %, and 44 % were recorded per well.
28

Palaeobotanical Analysis of Certain Upper Ordovician Sedimentary Rocks Emphasizing Microfossil Fragments

Thorne, William 10 1900 (has links)
Several methods for the palaeobotanical analysis of inorganic rocks are developed and through the employment of these methods both microfossils and macrofossils have been recovered from certain Upper Ordovician Strata. These fragments are assigned to series, basing such designation upon their sources and individual morphological characteristics. The problematical identity and biological importance of these fragments is discussed, and their practical usage in problems of correlation is considered. / Thesis / Master of Science (MSc)
29

A comparison between diamictites at the Witteberg-Dwyka contact in southern South Africa

Grobbelaar, Mareli 04 1900 (has links)
Thesis (MSc)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: Diamictites are sedimentary deposits that originate from a number of different environments, the most common being associated with a glacial environment. Although this association is not, in all cases correct, it is still being used due to the lack of knowledge to confidently identify, classify and interpret a depositional environment for diamictite deposits. During the late Carboniferous to early Permian, two diamictite deposits formed during the development of the Cape Basin and Main Karoo Basin in the southern margins of South Africa. These deposits are known as the Miller diamictite and Dwyka diamictite. The latter is well known and was deposited during the Karoo-deglaciation. The Dwyka diamictite is often referred to as Dwyka Tillite. This is an inappropriate reference owing to that not all of the Dwyka deposits are directly formed as a result of glacial contact. The origin of the Miller diamictite is uncertain, but there are suggestions that its origin can be traced to either a glacial or debris flow deposit formed in a deltaic environment, thus referred to by some as a tillite and others as a diamictite. To establish the sedimentary environments of the above mentioned diamictite deposits in the study area, two facies models were presented with a notable bias for the second model. The first model represents a continuous sedimentation cycle between the closing of the Cape Basin and opening of the Main Karoo Basin, whereas the second model demonstrates an erosional break (hiatus) between the depositions of the above mentioned basins. Derived from the use of the second model, it can be concluded that the Miller diamictite can indeed be classified as a diamictite from a textural interpretation. Both diamictites (Miller and Dwyka) cannot be referred to as tillite deposits since none show evidence of direct glacial contact. The Miller and the Dwyka are both diamictites, but were formed in different sedimentary environments. The Miller diamictite is a product of debris flow deposits from the slope of a braided delta, whereas the Dwyka diamictite represents distal glacio-marine “rain-out” deposits. / AFRIKAANSE OPSOMMING: Diamiktiete is sedimentêre neerslae afkomstig vanaf verskillende omgewings en dit word meestal met n glasiale omgewing geassosieer. Alhoewel hierdie assosiasie nie in alle gevalle korrek is nie, word dit nog steeds gemaak as gevolg van die gebrek aan kennis om diamiktiete met selfvertroue te identifiseer, te klassifiseer en 'n afsettingsomgewing vir die sedimente te interpreteer. Gedurende die laat Karboon tot vroeë Permiese tydperk het twee diamiktiet afsettings gevorm gedurende die vorming van die Kaap Supergroep Kom en Karoo Kom in die suidelike grense van Suid-Afrika. Die afsetting staan bekend as die Miller diamiktiet en Dwyka diamiktiet. Laasgenoemde is redelik bekend en is gedurende die Karoo gletser ontvormings tydperk gesedimenteer. Die Dwyka diamiktiet word dikwels Dwyka Tilliet genoem, wat onvanpas is aangesien nie al die Dwyka neerslae direk gevorm het as gevolg van direkte glasiale kontak nie. Die oorsprong van die Miller diamiktiet is egter onseker. Dit word veronderstel dat die Miller diamiktiet óf deur 'n gletser, of puin vloei neerslag gevorm het in 'n deltaiese omgewing, dus word daarna verwys as 'n tilliet of ʼn diamiktiet. Om die sedimentêre omgewings van die twee bogenoemde diamiktiet afsettings in die studie area te bevestig, is twee fasies modelle aangebied met 'n voorkeur aan die tweede model. Die eerste fasies model verteenwoordig n siklus van ongebroke sedimentasie tydens die sluiting van die Kaapse Kom en die opening van die Karoo Kom. Die tweede fasies model verteenwoordig n hiatus tussen die afsetting van die bogenoemde komme. Gegrond op sy teksturele samestelling kan die Miller diamiktiet inderdaad as 'n diamiktiet geklassifiseer word. Beide diamiktiete (Miller en Dwyka) kan nie as tilliet neerslae beskou word nie, aangesien geen bewyse gelewer kan word van afsetting as gevolg van direkte glasiale kontak nie. Die Miller en Dwyka is n diamiktiet, maar is gevorm in verskillende afsettingsomgewings. Die Miller diamiktiet is 'n produk van die puin vloei neerslag vanaf die helling van ‘n delta, terwyl die Dwyka diamiktiet verteenwoordig ‘n afgeleë glasio-mariene “uit-reen” neerslae.
30

Estudo de propriedades petrofísicas de rochas sedimentares por Ressonância Magnética Nuclear / Petrophysical properties study of sedimentary rocks by Nuclear Magnetic Resonance

Souza, André Alves de 28 May 2012 (has links)
A Ressonância Magnética Nuclear (RMN) é uma das técnicas mais versáteis de investigação científica experimental, com destaque para o estudo da dinâmica, estrutura e conformação de materiais. Em particular, sua utilização na ciência do petróleo é uma de suas primeiras aplicações rotineiras. Metodologias desenvolvidas especificamente para atender esta comunidade científica mostraram-se desde cedo muito úteis, sendo o estudo da interação rocha/fluido uma de suas vertentes mais bem sucedidas. Desde então, importantes propriedades petrofísicas de reservatórios de óleo e gás têm sido determinadas e entendidas, tanto em laboratório quanto in-situ, nas próprias formações geológicas que armazenam esses fluidos. Entre estas propriedades, a permeabilidade, porosidade e molhabilidade de um reservatório figuram dentre as mais importantes informações estimadas. Com essa finalidade, a determinação e correlação dos possíveis efeitos que a interação rocha/fluido pode causar nos fenômenos de relaxação magnética e difusão molecular, tais como influência da susceptibilidade magnética e geometria do espaço poroso, foram estudados em onze rochas sedimentares retiradas de afloramentos, que possuem propriedades petrofísicas similares àquelas apresentadas por rochas reservatório de petróleo. Os resultados mostraram que os tipos de interação rocha/fluido, detectáveis pelos experimentos de RMN, são por sua vez influenciados pelas características geométricas e estruturais do meio poroso, sendo possível obter essas informações pelos resultados de RMN. Assim, este trabalho teve como objetivo principal estudar e estabelecer essas correlações, afim de se obter informações petrofísicas com maior acurácia e abrangência. Em particular, o estudo da razão T1/T2, que é a razão entre os tempos de relaxação longitudinal e transversal, típicos parâmetros envolvidos numa medida de RMN, mostrou ser um parâmetro útil no estabelecimento destas correlações. Ainda, diferentes metodologias para se medir estes e outros parâmetros de RMN foram estudadas e propostas, cuja interpretação conjunta mostrou ser fundamental para o entendimento dessas correlações. A permeabilidade das rochas, importante parâmetro que define as propriedades de transporte de fluidos dentro da matriz porosa, foi estimada aplicando-se essas metodologias propostas, mostrando excelentes resultados. Através do uso da técnica de RMN em estado-estacionário, esses resultados podem ser estendidos para a escala de well-logging, fato que aumenta consideravelmente a importância desses resultados. Uma vez consolidadas as medidas in-situ, as metodologias propostas deverão auxiliar a indústria de exploração e produção de petróleo a otimizar seus métodos e estratégias de produção, reduzindo seus custos e aumentando a vida útil de seus reservatórios. / The Nuclear Magnetic Resonance (NMR) technique is one of the most versatile techniques for scientific research, specially for the study of dynamics, structure and conformational of materials. In particular, its application in oil science is one of its first routine applications. Methodologies developed specifically to match this scientific community proved to be very useful, and the study of rock/fluid interactions is one of its most successful cases. Since then, important petrophysical properties of oil and gas reservoirs have been determined and understood both in the laboratory and inside the geological formations that store those fluids. Among these properties, the permeability, porosity and wettability of a reservoir formation are the most important information to be estimated. For this purpose, the determination and correlation of possible rock/fluid interaction effects that cause alterations on magnetic relaxation phenomena and molecular diffusion, such as the influence of the magnetic susceptibility and geometry of the porous space, were studied in eleven sedimentary rock cores taken from outcrops, since they have the same petrophysical properties presented by oil reservoir rocks. The results obtained confirmed that the types of rock/fluid interactions, detectable by the NMR experiments, are for instance influenced by the porous media geometry and structure, being possible so to obtain such information using those NMR results. Thus, the main goal of this work was the study and establishment of these correlations, in order to obtain petrophysical information with greater accuracy and comprehensiveness. In particular, the study of the T1/T2 ratio, which is the ratio of longitudinal and transverse relaxation times, common parameters strongly involved in a typical NMR measurement, was found to be useful in establishing those correlations. Moreover, different methodologies to measure this and other NMR parameters were studied and proposed, whose joint interpretation proved to be fundamental for the success of these correlations. The permeability of the rocks, an important parameter that controls the fluid transport properties inside the porous matrix, was estimated using the proposed methodologies, showing excellent results. Appling the steady-state NMR technique, those results could be extended to the well-logging scale, which could improve considerably the importance of that results. Once confirmed in measurements in-situ, the proposed methodologies will be able to help the production and exploration industry to optimize their production methods and strategies, thereby reducing production costs and increasing the reservoir lifetimes.

Page generated in 0.098 seconds