The thesis deals with the theory of 3D printing, materials for printing and bonding. It focuses on FDM printing and PLA material. It also compares gluing with other methods and deals with the distribution of adhesives, the gluing procedure and tests of glued joints. The work, based on literature studies, proposes an experiment to evaluate selected adhesives. The practical part contains a description, results and evaluation of the experiment. The evaluation of adhesives is based on tensile and shear strength.

Diploma thesis is aimed at deposition of thin films on glass fibers using plasma-enhanced chemical vapor deposition from tetravinylsilane as a monomer. Such surface modified glass fibers were used as reinforcements for fabrication of polymer composites with unsaturated polyester resin as a matrix. Chemical and optical properties of prepared thin films were characterized using infared spectroscopy and spectroscopic ellipsometry. An influence of deposited thin films on the shear strength of composite material was observed using short-beam shear test.

The present research is conducted to investigate the structural behaviour of continuously supported deep beams made with SCC. A series of tests on eight reinforced two-span continuous deep beams made with SCC was performed. The main parameters investigated were the shear span-to-depth ratio, the amount and configuration of web reinforcement and the main longitudinal reinforcement ratio. All beams failed due to a major diagonal crack formed between the applied mid-span load and the intermediate support separating the beam into two blocks: the first one rotated around the end support leaving the rest of the beam fixed on the other two supports. The amount and configuration of web reinforcement had a major effect in controlling the shear capacity of SCC continuous deep beams. The shear provisions of the ACI 318M-11 reasonably predicted the load capacity of SCC continuous deep beams. The strut-and-tie model recommended by different design codes showed conservative results for all SCC continuous deep beams. The ACI Building Code (ACI 318M-11) predictions were more accurate than those of the EC2 and Canadian Code (CSA23.3-04). The proposed effectiveness factor equations for the strut-and-tie model showed accurate predictions compared to the experimental results. The different equations of the effectiveness factor used in upper-bound analysis can reasonably be applied to the prediction of the load capacity of continuously supported SCC deep beams although they were proposed for normal concrete (NC). The proposed three dimensional FE model accurately predicted the failure modes, the load capacity and the load-deflection response of the beams tested. / Higher Education Institute in the Libyan Government

Knots are usually regarded as defects when grading lumber. In order to evaluate a member under out-of-plane loading, shear strength is one of the major mechanical properties, specifically, rolling shear (RS) strength is one of the critical mechanical properties of Cross-Laminated Timber (CLT), which determines the flexural strength of CLT under short-span bending loads. Lower grade lumber with a higher percentage of knots is recommended to be utilized for the cross-layer laminations which are mainly responsible for resisting shear stresses. Firstly, shear tests were performed in order to evaluate the effect of knots on longitudinal shear strength using shear blocks. After that, the effect of knots on the RS strength of 3-ply southern yellow pine CLT were investigated by experimental tests and an analytical model. Center-point bending tests with a span-to-depth ratio of 6 and two-plate shear tests with a loading angle of 14° were conducted on six CLT configurations composed of different types of cross layer laminations: clear flatsawn lumber with/without pith, lumber with sound knots with/without pith, and lumber with decayed knots with/without pith. The shear analogy method was implemented to evaluate the RS strength values from the bending test results, which were also compared against the results from the two-plate shear tests. It was found that: (1) The shear blocks containing sound knots had higher shear strength than matched clear shear blocks, the shear blocks containing unsound knots had lower shear strength than the matched clear shear blocks. (2) CLT specimens with cross-layer laminations with either sound knots or decayed knots had higher RS strength. (3) In general, the shear analogy method underestimated the RS strength of CLT specimens containing knots and pith.

The non-reactive Dreiding and the reactive ReaxFF atomic potentials were applied within a family of atom molecular dynamics (MD) simulations to investigate and understand interfacial adhesion in graphene/vinyl ester composites. First, a liquid vinyl ester (VE) resin was equilibrated in the presence of graphene surfaces and then cured, resulting in a gradient in the monomer distribution as a function of distance from the surfaces. Then the chemically realistic relative reactivity volume (RRV) curing algorithm was applied that mimics the known radical addition regiochemistry and monomer reactivity ratios of the VE monomers during three-dimensional chain-growth polymerization. Surface adhesion between the cured VE resin and the graphene reinforcement surfaces was obtained at a series of VE resin “crosslink densities.” Both pristine and oxidized graphite sheets were employed separately in these simulations using a Dreiding potential. The pristine sheets serve as a surrogate for pure carbon fibers while oxidizing the outer graphene sheets serve as a model for oxidized carbon fibers. Hence, the effects of local monomer distribution and temperature on the interphase region formation and surface adhesion can be investigated. Surface adhesion was studied at various curing conversions and as a function of temperature. Uniaxial loading simulations were performed at different curing conversions for both models to predict the composites’ modulus of elasticity, Poisson’s ratio, and yield strength. The same analysis was performed for the neat cured matrix. The glass transition temperature (Tg) for the homogenized composite and neat VE matrix was determined at different degrees of curing. Subsequent MD simulations were performed to predict structural damage evolution and fracture in the neat VE matrix. The ReaxFF potential was used to quantify irreversible damage due to bond breakage in the neat VE matrix for different degrees of cure, stress states, temperatures, and strain rates. The predicted damage mechanisms in the bulk VE thermosetting polymer were directly compared to those for an amorphous polyethylene (PE) thermoplastic polymer.

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No description available.

SammanfattningSyfteSyftet med föreliggande studie var att undersöka om olika förbehandlingar av metallens yta påverkar bindningsstyrkan mellan CoCr och porslin.Material och metodSexton metallbasar med totalt 64 porslinscylindrar tillverkades genom gjutning av CoCr och porslinsuppläggning (de olika skikten; bondingagent, opak och dentin). Metallbasarna delades slumpmässigt in i 4 grupper; SB 50 sandblästrade med 50 m Al2O3, SB 250 sandblästrade med 250 m Al2O3, OASB oxiderade med atmosfäriskt tryck och sandblästrade med 250 m Al2O3, samt kontrollgrupp OVSB oxiderade i vakuumtryck och sandblästrade med 250 m Al2O3, samtliga grupper blästrades med 3 bars tryck. Efter glansbränning termocyklades provkropparna i 5000 cykler, förvarades fuktigt i 36o C och testades enligt ISO/TS11405:2016. Resultaten analyserades med one-way ANOVA, Tukey´s test. Signifikansnivån sattes till  = 0,05. Brottytorna analyserades visuellt och fotograferades i mikroskop. ResultatMedelvärdet för samtliga grupper var likvärdiga men med stor skillnad i spridning inom grupperna. Brotten delades in i tre grupper, adhesiv-, kohesiv- och blandfraktur.Slutsats Med reservation för de begränsningar som finns inom föreliggande studie kan följande slutsatser dras:•De olika förbehandlingsmetoderna, oxidering med vakuum eller atmosfäriskt tryck följt av sandblästring eller enbart sandblästring med olika kornstorlekar, ger ingen specifik skillnad vad gäller bindningsstyrkan mellan metall och porslin.•Oxidering med vakuum har ingen negativ inverkan på bindningsstyrkan mellan metall och porslin. De-gasing av metallen kan utföras.•Sandblästring med 50 μm hade större spridning inom gruppen än de övriga tre grupperna. •Studiens nollhypotes kan bekräftas. / Abstract PurposeThe purpose of the present study was to investigate whether various pretreatments affect the bond strength between CoCr and porcelain.Material and method64 porcelain cylinders were manufactured (bonding agent, opaque, dentin) divided on sixteen metal bases. The metal bases were randomly divided into 4 groups; SB 50 sandblasted with 50 m Al2O3, SB 250 sandblasted with 250 m Al2O3, OASB oxidized with atmospheric pressure and then sandblasted with 250 m Al2O3 and control group OVSB oxidized in vacuum and then sandblasted with 250 m Al2O3. All groups were sandblasted with 3 bars pressure. After glazefiring, the specimens were thermocycled 5000 cycles, stored in moist at 36o C and tested according to ISO / TS11405: 2016. The results were analyzed with one-way ANOVA, Tukey's test with significance level  = 0.05. The fracture surfaces were analyzed visually and photographed in microscope.ResultsThe mean values in all groups were equivalent but with large difference in standard deviation within the groups. The fractures were divided into three groups, adhesive-, cohesive and mixed fractures.ConclusionWithin the limitations of the study, the following conclusions can be drawn: •The different pretreatment methods, vacuum or atmospheric pressure, oxidation with or without sandblasting do not affect the bond strength between metal and porcelain.•Oxidation with vacuum does not adversely affect the bonding strength between metal and porcelain. De-gasing of the metal can be performed.•Sandblasting with 50 μm had a greater deviation within the group than the other groups•The study's null-hypothesis can be confirmed

In Sweden, there exists a large number of dams. Many of them are founded on rock masses normally affected by the presence of sub-horizontal rock fractures, which makes sliding along rock joints under the dam foundation one of the most critical failure mechanism. Various attempts have been made to relate the peak shear strength of rock joints to measurable parameters. However, the uncertainty in the determination of the shear strength of rock joints is nonetheless still significant.The main aim of this thesis is to investigate, develop and apply analytical and numerical techniques for estimation of peak shear strength of natural and unfilled rock joints. In a first step, the peak shear strength of several natural and unfilled rock joint was calculated by using surface aperture measurements from high-resolution optical scanning and a modified version of the analytical criterion previously developed by Johansson and Stille in 2014. In a second step, PFC2D was utilised to perform numerical shear tests on two-dimensional profiles selected from high-resolution optical scanning on unweathered and perfectly mated tensile induced rock joints.The results from the analytical approach show that the calculated peak shear strengths of the analysed samples are in good agreement compared with the laboratory investigations. Conversely, the obtained results from the numerical approach show lower peak shear strengths in the analysed two-dimensional profiles compared with the conducted laboratory shear tests.The analytical approach together with the advanced techniques to measure surface roughness available today, may be a possible way forward towards a methodology to determine peak shear strength of large-scale natural rock joints in-situ. / Bergsprickors skjuvhållfasthet är en avgörande faktor för att kunna bestämma säkerheten mot gliding för dammar där sub-horisontella utbredda bergsprickor existerar. Samtidigt är parametern svår att bestämma då den påverkas av flera faktorer som sprickytans råhet, vittringsgrad, normalspänning, skala samt passning. Skjuvhållfasthet av bergsprickor kan bestämmas genom att använda empiriska och analytiska brottkriterier samt numeriska metoder. Problemet med de befintliga metodikerna är att de inte beaktar inverkan från sprickans passning. Detta innebär att hållfastheten riskerar att överskattas.Det övergripande syftet med denna licentiatuppsats är att studera, utveckla och tillämpa analytiska och numeriska metoder för uppskattning av skjuvhållfasthet för naturliga och ofyllda bergsprickor. I ett första steg beräknades skjuvhållfastheten för ett antal naturliga och ofyllda bergsprickor. Detta gjordes genom att mäta aperturen baserat på högupplöst skanning och en vidareutvecklad version av det analytiska kriteriet som föreslogs av Johansson och Stille 2014. I ett andra steg användes PFC2D för att genomföra numeriska skjuvtester på två-dimensionella sprickprofiler baserat på högupplöst skanning av perfekt passade och draginducerade bergsprickor.Resultaten från uppskattad skjuvhållfasthet med den analytiska metodiken visar på en bra överensstämmelse i jämförelse med de utförda skjuvförsöken. Resultaten från de utförda analyserna med PFC2D visar på en något lägre skjuvhållfasthet än vad som observeras i verkligheten.Den utvecklade analytiska metodiken, tillsammans med de avancerade tekniker som idag finns för att mäta sprickytornas råhet, bedöms kunna utgöra ett första steg mot att bättre kunna bestämma den storskaliga skjuvhållfastheten för bergsprickor i fält. / <p>QC 20190402</p>

Reservoir release patterns are determined by a number of purposes, the most fundamental of which is to manage water resources for human use. Managing our water resources means not only controlling the water in reservoirs but also determining the optimum release rate taking into account factors such as reservoir stability, power generation, water supply for domestic, industrial, and agricultural uses, and the river ecosystem. However, riverbank stability has generally not been considered as a factor, even though release rates may have a significant effect on downstream riverbank stability. Riverbank retreat not only impacts land properties but also damages structures along the river such as roads, bridges and even buildings. Thus, reservoir releases need to also take into account the downstream riverbank stability and erosion issues. The study presented here investigates the riverbank stability and erosion at five study sites representing straight as well as inside and outside channel meander bends located on the lower Roanoke River near Scotland Neck, North Carolina. Extensive laboratory and field experiments were performed to define the hydraulic and geotechnical properties of the riverbank soils at each site. Specifically, soil water characteristic curves were determined using six different techniques and the results compared to existing mathematical models. Hydraulic conductivity was estimated using both laboratory and in situ tests. Due to the wide range of experimentally obtained values, the values determined by each of the methods was used for transient seepage modeling and the modeling results compared to the actual ground water table measured in the field. The results indicate that although the hydraulic conductivities determined by in situ tests were much larger than those typically reported for the soils by lab tests, numerical predictions of the ground water table using the in situ values provided a good fit for the measured ground water table elevation. Shear strengths of unsaturated soils were determined using multistage suction controlled direct shear tests. The test method was validated, and saturated and unsaturated shear strength parameters determined. These parameters, which were determined on the basis of results from both laboratory and field measurements, and the associated boundary conditions, which took into account representative flow rates and patterns including peaking, drawdown and step-down scenarios, were then utilized for transient seepage analyses and slope stability analyses performed using SLIDE, a software package developed by Rocscience. The analyses confirmed that the riverbanks are stable for all flow conditions, although the presence of lower permeability soils in some areas may create excess pore water pressures, especially during drawdown and step-down events, that result in the slope becoming unstable in those locations. These findings indicate that overall, the current reservoir release patterns do not cause adverse impacts on the downstream riverbanks, although a gradual drawdown after a prolonged high flow event during the wet season would reduce unfavorable conditions that threaten riverbank stability. / Ph. D.