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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
141

Theoretical Prediction of Changes in Protein Structural Stability upon Cosolvent or Salt Addition and Amino-acid Mutation / 共溶媒や塩の添加およびアミノ酸置換に伴う蛋白質立体構造安定性変化の理論的予測

Murakami, Shota 23 March 2017 (has links)
京都大学 / 0048 / 新制・課程博士 / 博士(エネルギー科学) / 甲第20481号 / エネ博第350号 / 新制||エネ||70(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー基礎科学専攻 / (主査)教授 木下 正弘, 教授 森井 孝, 教授 片平 正人 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM
142

Solute Chemistry and Isotopic Investigation of the Groundwater Flow Paths in Honey Lake Basin, Lassen County, California and Washoe County, Nevada

Henderson, Rachel M. 16 March 2007 (has links) (PDF)
Honey Lake Basin is a large, hydrologically closed valley with two playa lakes that are separated by a low elevation sill. The Basin has a complex hydrogeologic setting, with numerous groundwater flow paths that interact with surface waters and three basic aquifers; shallow, deep, and geothermal. Thirteen flow paths; eleven cold and two thermal, are identified and the geochemical evolution of those paths are characterized by integrating solute chemistry and isotopic data. The chemical flow paths include recharge in either granitoid or volcanic terrains in the Sierra Nevada Range and the Modoc Plateau, respectively. The groundwater then flows through alluvial fan and stream sedimentary environments and eventually flows through lacustrine and playa sediments in the closed basin. This investigating characterizes geochemical evolution of groundwater flow from both mafic and granitic terrains to lacustrine sediments with evaporite minerals, in a closed basin environment. Temperature data reveal that thermal waters circulate to 1.6-3.0 km and 2.8-3.8 km along two major fault zones. Shallow groundwaters above 17°C are determined to have a component of thermal water and mixing ratios are presented. δ18O and δD data show that deep groundwater was recharged by cooler, more humid precipitation from the last ice age, whereas shallow groundwaters reflect current meteoric conditions and show extensive evaporation trends. The two thermal flow paths show exchange with silicate minerals at high temperatures (>100°C). δ13C data show interaction with carbonate minerals in basin fill lacustrine sediments. 3H concentrations and 14C ages show that deep groundwaters throughout the Basin and shallower groundwaters in the center of the basin are not greatly affected by post-1952 recharge. Mean 14C ages range from modern to 23,500 years old. NETPATH was used to model geochemical evolution along the flow paths. Groundwater on the west side of the basin (granitic terrain) is typically low TDS (~150 mg/L) calcium-bicarbonate water and evolves into higher TDS (~300 mg/L) sodium-bicarbonate groundwater as it interacts with granitic rocks and then lacustrine sediments. Groundwater on the east side of the basin (mafic terrain) is typically low TDS (~200 mg/L) sodium-bicarbonate water and evolves into high TDS (~300 mg/L) sodium-bicarbonate water groundwater as it interacts with mafic rocks and then lacustrine sediments. Dissolution of silicate minerals and calcite, and ion exchange with clays is responsible for major chemistry changes. As both of these types of groundwaters come into contact with lacustrine sediments with evaporite minerals on the playas, dissolution of halite and gypsum dominate and the groundwater becomes extremely high in TDS (~ 1100 mg/L on the Honey Lake Playa and ~ 43,000 mg/L on the Fish Spring Playa) and strongly sodium-chloride in character.
143

A Conceptual Model OF Groundwater Flow in Spring Valley, NV, AND Snake Valley, NV-UT

Gillespie, Jeremy Micheal 07 February 2008 (has links) (PDF)
A geochemical study of major springs and wells in Spring Valley, Nevada, and Snake Valley, Utah-Nevada was initiated in response to the Clark, Lincoln and White Pine Counties Groundwater Development Project proposed by the South Nevada Water Authority (SNWA). Water budget estimates suggest that interbasin flow accounts for a significant portion (~25%) of the water budgets in Spring and Snake Valleys. Although interbasin flow is possible in some areas, alternative plausible explanations place significant uncertainty on water budget allocations. To examine the plausibility of local and interbasin flow paths the groundwater flow in Spring and Snake Valleys was evaluated using solute and isotopic data. Evidence for local flow paths includes: 1) stable isotope values in local areas which are similar to isotope values in adjacent recharge zones; 2) measurable 3H content and 14C activities ≥ 50 pmc in most samples which suggests short residence times; and 3) plausible geochemical models of local flow paths. Previously defined interbasin flow paths in southern Spring Valley are marked by samples that have low 14C activities (mean = 20.14 pmc), which are consistent with long residence times and can be explained by either interbasin flow from adjacent basins or deep circulation in the basin-fill sediments of Spring Valley. Interbasin flow from southern Spring Valley to southern Snake Valley cannot be confirmed or rejected based on the current data and modeling constraints, which result in plausible models involving both local flow paths and interbasin flow paths. Interbasin flow from northern Spring Valley to northern Snake Valley is unlikely and can be explained by the deep circulation of groundwater that is mixed with modern recharge. The plausibility of alternative explanations to describe previously defined interbasin flow paths suggests that water budget allocations in Spring and Snake Valleys should be redistributed or reevaluated. The use of existing water budgets that allocate large components of water to interbasin flow to determine the distribution of water resources may result in incorrect estimations of available resources.
144

Numerical modelling of solute transport processes using higher order accurate finite difference schemes. Numerical treatment of flooding and drying in tidal flow simulations and higher order accurate finite difference modelling of the advection diffusion equation for solute transport predictions.

Chen, Yiping January 1992 (has links)
The modelling of the processes of advection and dispersion-diffusion is the most crucial factor in solute transport simulations. It is generally appreciated that the first order upwind difference scheme gives rise to excessive numerical diffusion, whereas the conventional second order central difference scheme exhibits severe oscillations for advection dominated transport, especially in regions of high solute gradients or discontinuities. Higher order schemes have therefore become increasingly used for improved accuracy and for reducing grid scale oscillations. Two such schemes are the QUICK (Quadratic Upwind Interpolation for Convective Kinematics) and TOASOD (Third Order Advection Second Order Diffusion) schemes, which are similar in formulation but different in accuracy, with the two schemes being second and third order accurate in space respectively for finite difference models. These two schemes can be written in various finite difference forms for transient solute transport models, with the different representations having different numerical properties and computational efficiencies. Although these two schemes are advectively (or convectively) stable, it has been shown that the originally proposed explicit QUICK and TOASOD schemes become numerically unstable for the case of pure advection. The stability constraints have been established for each scheme representation based upon the von Neumann stability analysis. All the derived schemes have been tested for various initial solute distributions and for a number of continuous discharge cases, with both constant and time varying velocity fields. The 1-D QUICKEST (QUICK with Estimated Streaming Term) scheme is third order accurate both in time and space. It has been shown analytically and numerically that a previously derived quasi 2-D explicit QUICKEST scheme, with a reduced accuracy in time, is unstable for the case of pure advection. The modified 2-D explicit QUICKEST, ADI-TOASOD and ADI-QUICK schemes have been developed herein and proved to be numerically stable, with the bility sta- region of each derived 2-D scheme having also been established. All these derived 2-D schemesh ave been tested in a 2-D domain for various initial solute distributions with both uniform and rotational flow fields. They were further tested for a number of 2-D continuous discharge cases, with the corresponding exact solutions having also been derived herein. All the numerical tests in both the 1-D and 2-D cases were compared with the corresponding exact solutions and the results obtained using various other difference schemes, with the higher order schemes generally producing more accurate predictions, except for the characteristic based schemes which failed to conserve mass for the 2-D rotational flow tests. The ADI-TOASOD scheme has also been applied to two water quality studies in the U. K., simulating nitrate and faecal coliform distributions respectively, with the results showing a marked improvement in comparison with the results obtained by the second order central difference scheme. Details are also given of a refined numerical representation of flooding and drying of tidal flood plains for hydrodynamic modelling, with the results showing considerable improvements in comparison with a number of existing models and in good agreement with the field measured data in a natural harbour study.
145

WARREN_DISSERTATION_FINAL_DRAFT.pdf

Patrick Warren (14101158) 11 November 2022 (has links)
<p>An investigation of the influence of three alloying elements Chromium, Phosphorus, and Nitrogen with the solute types of oversized substitutional, undersized substitutional, and interstitial on the irradiation induced microstructural evolution and hardening</p>
146

LONGITUDINAL SOLUTE TRANSPORT IN OPEN-CHANNEL FLOW - A Numerical Simulation Study on Longitudinal Dispersion, Surface Storage Effects, Transverse Mixing, Uncertainties and Parameter-Transferring Problems

Zhang, Wei January 2011 (has links)
The longitudinal solute transport modeling is critical in river and stream water quality management, control, and the mitigation of hazardous riverine spills. One of the widely used "deadzone" model is the transient storage model (TSM). TSM is a significant improvement over the advection-dispersion model (ADM), but it cannot simulate the breakthrough curve (BTC) immediately after a large pool. Additionally, the calibration (parameterization) method is challenged by the non-identifiability which is common to all inverse modeling, and it seems TSM cannot be easily used as a predictive tool, more of an interpretive tool of solute transport, i.e., is the parameter set calibrated via inverse modeling transferable? Pools are fundamental stream morphology unit in streams with mixed bed materials in pool-riffle or pool-step sequences. Understanding of how a pool impacts the longitudinal solute transport is the first step towards improving current model such as TSM or developing new models. By introducing a dimensionless group, e= Q/(Dt W) (where, Q is the average volumetric flow rate; Dt is an average transverse dispersion coefficient; W is the channel flow width), derived from non-dimensionalization of the governing equations of one of the most rigorous 2-dimansional (2D) (depth-averaged) model, Mike21, this work presents an alternative way of longitudinal solute transport investigation. Using the 2D fully hydrodynamic Mike21, numerical experiments were conducted on hypothetical streams in this dissertation. Simulation study on hypothetical stream with pool reveals that a pool's effects on longitudinal solute transport are manifested by three aspects: boosting longitudinal spreading (concentration peak attenuation), causing a solute plume delay and increasing solute residence time. These effects fade like a "wake" as the solute plume moves downstream. e provides an insight into the physics of longitudinal transport; it outlines a relative transverse mixing intensity of a stream. The internal transport and mixing condition (including the secondary circulations) in a pool together with the pool's dimensions determine the pool's storage effects especially when e &gt;&gt;1. The BTCs downstream from a pool may be "heavy tailed" (i.e., have enormously slow decaying rate) which cannot be modeled by the TSM. Results also suggest that the falling limb of a BTC more accurately characterizes the pool's storage effects because the corresponding solute has more chance to sample the entire storage area. n a more fundamental perspective, the predictive ability of inverse modeling parameterized model is discussed and conclusion is made about the role of a stream/river system's nonlinearity in determining the predictability; a misleading mis-nomenclature in TSM application is also demonstrated with a numerical experiment. / Civil Engineering
147

Floodplain Hydrology and Biogeochemistry

Jones, Charles Nathaniel 04 September 2015 (has links)
River-floodplain connectivity is defined as the water mediated transfer of materials and energy between a river or stream and its adjacent floodplain. It is generally accepted that restoring and/or enhancing river-floodplain connectivity can reduce the downstream flux of reactive solutes such as nitrogen (N) and phosphorus (P) and thus improve downstream water quality. However, there is little scientific literature to guide ecological engineering efforts which optimize river-floodplain connectivity for solute retention. Therefore, the aim of my dissertation research was to examine feedbacks between inundation hydrology and floodplain biogeochemistry, with an emphasis on analyzing variation experienced along the river continuum and the cumulative effects of river-floodplain connectivity at the basin scale. This was completed through four independent investigations. Field sites ranged from the Atchafalaya River Basin, the largest river-floodplain system in the continental US, to the floodplain of a recently restored headwater stream in Appalachia. We also developed a method to examine river-floodplain connectivity across large- river networks and applied that methodology to US stream network. Largely, our results highlight the role floodwater residence time distributions play in floodplain biogeochemistry. In headwater streams, residence times restrict redox dependent processes (e.g. denitrification) and downstream flushing of reactive solutes is the dominant process. However, in large-river floodplains, redox dependent processes can become solute limited because of prolonged residence times and hydrologic isolation. In these floodplains, the dominant process is often autochthonous solute accumulation. Further, results from our modeling study suggest large-river floodplains have a greater impact on downstream water quality than floodplains associated with smaller streams, even when considering cumulative effects across the entire river network. / Ph. D.
148

Modeling the effects of Transient Stream Flow on Solute Dynamics in Stream Banks and Intra-meander Zones

Mahmood, Muhammad Nasir 11 May 2021 (has links)
The docotoral thesis titled 'Modeling the effects of Transient Stream Flow on Solute Dynamics in Stream Banks and Intra-meander Zones' investigates flow and solute dynamcis across surface water-groundwater interface under dynamic flow conditons through numerical simulations. The abstract of the thesis is as follows: Waters from various sources meet at the interface between streams and groundwater. Due to their different origins, these waters often have contrasting chemical signatures and therefore mixing of water at the interface may lead to significant changes in both surface and subsurface water quality. The riparian zone adjacent to the stream serves as transition region between groundwater and stream water, where complex water and solute mixing and transport processes occur. Predicting the direction and the magnitude of solute exchanges and the extent of transformations within the riparian zone is challenging due to the varying hydrologic and chemical conditions as well as heterogeneous morphological features which result in complex, three-dimensional flow patterns. The direction of water flow and solute transport in the riparian zone typically varies over time as a result of fluctuating stream water and groundwater levels. Particularly, increasing groundwater levels can mobilize solutes from the unsaturated zone which can be subsequently transported into the stream. Such complex, spatially and temporally varying processes are hard to capture with field observations alone and therefore modeling approaches are required to predict the system behavior as well as to understand the role of individual factors. In this thesis, we investigate the inter-connectivity of streamthe s and adjacent riparia zones in the context of water and solute exchanges both laterally for bank storage and longitudinally for hyporheic flow through meander bends. Using numerical modeling, the transient effect of stream flow events on solute transport and transformation within the initially unsaturated part of stream banks and meander bends have been simulated using a systematic set of hydrological, chemical and morphological scenarios. A two dimensional variably saturated media groundwater modeling set up was used to explore solute dynamics during bank flows. We simulated exchanges between stream and adjacent riparian zone driven by stream stage fluctuations during stream discharge events. To elucidate the effect of magnitude and duration of discharge events, we developed a number of single discharge event scenarios with systematically varying peak heights and event duration. The dominant solute layer was represented by applying high solute concentration in upper unsaturated riparian zone profile. Simulated results show that bank flows generated by high stream flow events can trigger solute mobilization in near stream riparian soils and subsequently export significant amounts of solutes into the stream. The timing and amount of solute export is linked to the shape of the discharge event. Higher peaks and increased duration significantly enhance solute export, however, peak height is found to be the dominant control for overall lateral mass export. The mobilized solutes are transported towards the stream in two stages (1) by return flow of stream water that was stored in the riparian zone during the event and (2) by vertical movement to the groundwater under gravity drainage from the unsaturated parts of the riparian zone, which lasts for significantly longer time (> 400 days) resulting in a theoretically long tailing of bank outflows and solute mass outfluxes. Our bank flow simulations demonstrate that strong stream discharge events are likely to mobilize and export significant quantity of solutes from near stream riparian zones into the stream. Furthermore, the impact of short-term stream discharge variations on solute exchange may sustain for long times after the flow event. Meanders are prominent morphological features of stream systems which exhibit unique hydrodynamics. The water surface elevation difference across the inner bank of a meander induces lateral hyporheic exchange flow through the intrameander region, leading to solute transport and reactions within intra-meander region. We examine the impact of different meander geometries on the intra-meander hyporheic flow field and solute mobilization under both steady-state and transient flow conditions. In order to explore the impact of meander morphology on intrameander flow, a number of theoretical meander shape scenarios, representing various meander evolution stages, ranging from a typical initial to advanced stage (near cut off ) meander were developed. Three dimensional steady-state numerical groundwater flow simulations including the unsaturated zone were performed for the intra-meander region for all meander scenarios. The meandering stream was implemented in the model by adjusting the top layers of the modeling domain to the streambed elevation. Residence times for the intra-meander region were computed by advective particle tracking across the inner bank of meander. Selected steady state cases were extended to transient flow simulations to evaluate the impact of stream discharge events on the temporal behavior of the water exchange and solute transport in the intra-meander region. Transient hydraulic heads obtained from the surface water model were applied as transient head boundary conditions to the streambed cells of the groundwater model. Similar to the bank storage case, a high concentration of solute (carbon source) representing the dominant solute layer in the riparian profile was added in the unsaturated zone to evaluate the effect of stream flow event on mobilization and transport from the unsaturated part of intrameander region. Additionally, potential chemical reactions of aerobic respiration by the entry of oxygen rich surface water into subsurface as well denitrification due to stream and groundwater borne nitrates were also simulated. The results indicate that intra-meander mean residence times ranging from 18 to 61 days are influenced by meander geometry, as well as the size of the intra-meander area. We found that, intra-meander hydraulic gradient is the major control of RTs. In general, larger intra-meander areas lead to longer flow paths and higher mean intra-meander residence times (MRTs), whereas increased meander sinuosity results in shorter MRTs. The vertical extent of hyporheic flow paths generally decreases with increasing sinuosity. Transient modeling of hyporheic flow through meanders reveals that large stream flow events mobilize solutes from the unsaturated portion of intra-meander region leading to consequent transport into the stream via hyporheic flow. Advective solute transport dominates during the flow event; however significant amount of carbon is also consumed by aerobic respiration and denitrification. These reactions continue after the flow events depending upon the availability of carbon source. The thesis demonstrates that bank flows and intra-meander hyporheic exchange flows trigger solute mobilization from the dominant solute source layers in the RZ. Stream flow events driven water table fluctuations in the stream bank and in the intra-meander region transport substantial amount of solutes from the unsaturated RZ into the stream and therefore have significant potential to alter stream water quality.:Declaration Abstract Zusammenfassung 1 General Introduction 1.1 Background and Motivation 1.2 Hydrology and Riparian zones 1.2.1 Transport processes driven by fluctuation in riparian water table depth 1.2.1.1 Upland control 1.2.1.2 Stream control 1.2.2 Biochemical Transformations within the Riparian Zone 1.3 Types and scales of stream-riparian exchange 1.3.1 Hyporheic Exchange 1.3.1.1 Small Scale Vertical HEF 1.3.1.2 Large Scale lateral HEF 1.3.2 Bank Storage 1.4 Methods for estimation of GW-SW exchanges 1.4.1 Field Methods 1.4.1.1 Direct measurement of water flux 1.4.1.2 Tracer based Methods 1.4.2 Modeling Methods 1.4.2.1 Transient storage models 1.4.2.2 Physically based models 1.5 Research gaps and need 1.6 Objectives of the research 1.7 Thesis Outline 2 Flow and Transport Dynamics during Bank Flows 2.1 Introduction 2.2 Methods 2.2.1 Concept and modeling setup 2.2.2 Numerical Model 2.2.3 Stream discharge events 2.2.4 Model results evaluation 2.3 Results and discussion 2.3.1 Response of water and solute exchange to stream discharge events 2.3.1.1 Water exchange time scales 2.3.1.2 Stream water solute concentration 2.3.2 Solute mobilization within the riparian zone 2.3.3 Influence of peak height and event duration on solute mass export towards the stream 2.3.4 Effects of event hydrograph shape on stream water solute concentration 2.3.5 Model limitations and future studies 2.4 Summary and Conclusions Appendix 2 3 Flow and Transport Dynamics within Intra-Meander Zone 3.1 Introduction 3.2 Methods 3.2.1 Meander Shape Scenarios 3.2.2 Surface Water Simulations 3.2.3 3D Groundwater Flow Simulations with Modeling code MIN3P 3.2.3.1 Steady Flow Simulations 3.2.3.2 Stream flow event and Solute Mobilization Set-up 3.2.4 Reactive Transport 3.3 Results and Discussion 3.3.1 Groundwater heads and flow paths in the saturated intrameander zone 3.3.1.1 Groundwater heads 3.3.1.2 Flow paths and isochrones 3.3.1.3 Vertical extent of flow paths 3.3.2 Intra-Meander Residence Time Distribution 3.3.3 Factors affecting intra-meander flow and residence times 3.3.3.1 intra-meander hydraulic gradient 3.3.3.2 Maximum penetration depth 3.3.3.3 Meander sinuosity 3.3.3.4 intra-meander area (A) 3.3.4 Influence of Discharge Event on intra-meander Flow and Solute Transport 3.3.4.1 Spatial distribution of groundwater head and solute concentration 3.3.4.2 Time scales of intra-meander groundwater heads and solute transport 3.3.4.3 Solute export during stream discharge event 3.3.5 Intra-meander reactive transport during stream discharge event 3.3.5.1 Impact of stream discharge on aerobic respiration and denitrification 3.3.5.2 DOC mass removal during stream discharge event 3.4 Summary and Conclusions Appendix 3 4 General Summary and Conclusions 4.1 Summary 4.2 Conclusions 4.2.1 Flow and Transport Dynamics in Near Stream Riparian Zone (Bank Flows) 4.2.2 Flow and Transport Dynamics within Intra-Meander Zone 4.3 Model Limitations and Future Studies Bibliography Acknowledgement
149

Microglial activation decreases retention of the protease inhibitor saquinavir: implications for HIV treatment

Dallas, Shannon, Block, Michelle, Thompson, Deborah, Bonini, Marcelo, Ronaldson, Patrick, Bendayan, Reina, Miller, David January 2013 (has links)
BACKGROUND:Active HIV infection within the central nervous system (CNS) is confined primarily to microglia. The glial cell compartment acts as a viral reservoir behind the blood-brain barrier. It provides an additional roadblock to effective pharmacological treatment via expression of multiple drug efflux transporters, including P-glycoprotein. HIV/AIDS patients frequently suffer bacterial and viral co-infections, leading to deregulation of glial cell function and release of pro-inflammatory mediators including cytokines, chemokines, and nitric oxide.METHODS:To better define the role of inflammation in decreased HIV drug accumulation into CNS targets, accumulation of the antiretroviral saquinavir was examined in purified cultures of rodent microglia exposed to the prototypical inflammatory mediator lipopolysaccharide (LPS).RESULTS:3H]-Saquinavir accumulation by microglia was rapid, and was increased up to two-fold in the presence of the specific P-glycoprotein inhibitor, PSC833. After six or 24 hours of exposure to 10 ng/ml LPS, saquinavir accumulation was decreased by up to 45%. LPS did not directly inhibit saquinavir transport, and did not affect P-glycoprotein protein expression. LPS exposure did not alter RNA and/or protein expression of other transporters including multidrug resistance-associated protein 1 and several solute carrier uptake transporters.CONCLUSIONS:The decrease in saquinavir accumulation in microglia following treatment with LPS is likely multi-factorial, since drug accumulation was attenuated by inhibitors of NF-kappabeta and the MEK1/2 pathway in the microglia cell line HAPI, and in primary microglia cultures from toll-like receptor 4 deficient mice. These data provide new pharmacological insights into why microglia act as a difficult-to-treat viral sanctuary site.
150

Förstudie till våtmark i Rimbo : Design för optimal hydrologi och kväverening

Jaremalm, Maria January 2005 (has links)
<p>The euthropthication of the Baltic Sea is a threat that is beginning to be taken seriously by the governments concerned. In Sweden, regulations concerning the allowed nitrogen (N) concentration in the effluent water from wastewater treatment plants are being tightened up. The Rimbo wastewater treatment plant has been imposed to reduce the annual mean concentration of total N in the effluent water to levels below 15 mg l-1. A more and more common way to reduce the nitrogen level in wastewater is to let the water pass through a wetland. This study investigates the possibility to build this kind of wetland at the outlet of the Rimbo wastewater treatment plant.</p><p>A prestudy of the topography, soil characteristics and groundwater flow indicates that the land area in question is well suited for the construction of a wetland. A proposal for the design has been made by using a physically based computer model developed in the PRIMROSE project (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE), which is financed by the EU. Analysis of the residence time distribution (RTD) is a tool for understanding wetland design characteristics and can be used for wetland engineering such as optimizing design for best possibleefficiency in nitrogen removal. In order to characterize the performance of a wetland, it is useful to translate the RTD to a key figure representing the treatment efficiency. In this work, two types of such key figures have been used. Key figure 1 gives the hydraulic efficiency and Key figure 2 gives an estimation of the nitrogen retention by an integration of hydraulic characteristics and the chemical transformation of nitrogen.</p><p>The results of this study show that constructing a wetland in Rimbo probably would be an efficient way to reduce the nitrogen level at the effluent of the wastewater plant below the limits of the regulations. In addition, a wetland would form a nice place of recreation for the people in Rimbo and also make a good habitat for birds.</p> / <p>Övergödningen i Östersjön är ett problem som uppmärksammas alltmer. Ett led i att minska kvävebelastningen på Östersjön är ökade krav på rening i de svenska kommunala reningsverken. Rimbo avloppsreningsanläggning har blivit ålagd ett riktvärde för totalkväve på 15 mg l-1 i utgående vatten, vilket motsvarar en reningsgrad som inte uppnås idag. Ett alltmer vanligt sätt att minska föroreningshalterna är att anlägga våtmarker i anslutning till reningsverken för att efterpolera spillvattnet. Det här arbetet är en del av en förstudie till en sådan våtmark i Rimbo.</p><p>En förundersökning av topografi, jordart och grundvattenflöden indikerar att det område som föreslagits i anslutning till reningsverket i Rimbo lämpar sig väl för ett våtmarksbygge. Förslag till utformning har tagits fram med hjälp av en fysikaliskt baserad modell över vattenströmning, utvecklad inom det EU-finansierade projektet PRIMROSE (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE). Analys av vattnets uppehållstidsfördelning ger förståelse för våtmarkens egenskaper och kan därför användas vid t ex optimering av våtmarksdesign med avseende på kväverening. För att på ett enkelt sätt kunna jämföra olika våtmarkers effektivitet är det praktiskt att översätta uppehållstidsfördelningen till ett nyckeltal för reningseffekten. I det här arbetet har två olika sådana nyckeltal beräknats. Det första ger den hydrauliska effektiviteten och det andra bygger på en metod där våtmarkens interna hydraulik integreras med den kemiska omvandlingen av kväve. Nyckeltal 1 ger ett mått på hur stor del av volymen i våtmarken som används för kväverening, medan Nyckeltal 2 ger ett mått på den procentuella kväveavskiljningen.</p><p>Den här förstudien visar att en våtmark sannolikt skulle vara ett utmärkt sätt att klara riktvärdet för kvävehalten vid reningsverket i Rimbo. Därutöver skulle en våtmark kunna utgöra ett positivt inslag i landskapet och öka den biologiska mångfalden, inte minst vad gäller fågelliv.</p>

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