Species translocations result in demographic bottlenecks that may produce inbreeding depression and reduce genetic variation through random sampling and drift, an outcome that could decrease long-term fitness and adaptive potential of many New Zealand species. Despite considerable evidence for costs associated with inbreeding and reduced genetic variation, some species have recovered from a small number of individuals and are thriving, perhaps via high growth rates, differential survival of heterozygous individuals or inbreeding avoidance. I examined the genetic consequences of species translocations in saddlebacks (Philesturnus carunculatus) with additional data provided for robins (Petroica australis) where possible. I first assessed whether contemporary genetic variation represented historical levels or a decline following demographic bottlenecks. I then examined whether sequential demographic bottlenecks caused sequential genetic bottlenecks and reviewed whether populations founded with a small number of birds were likely to go extinct. This analysis was followed by an investigation of two mechanisms that may maintain or reduce fitness costs, differential survival of heterozygous individuals and mate choice to avoid genetically similar individuals. Evidence from museum specimens suggests that low levels of genetic variation in contemporary saddlebacks is no different to historical genetic variation in the only source population, Big South Cape Island. An ancient founding event to Big South Cape Island is probably the cause of severe genetic bottlenecking rather than the demographic bottleneck caused by rats in the 1960s. In robins, genetic variation decreased slightly between museum and contemporary samples suggesting that recent population declines and habitat fragmentation have caused reductions in current levels of genetic variation. Serial demographic bottlenecks caused by sequential translocations of saddlebacks did not appear to decrease genetic variation. Loss of genetic variation due to random sampling was probably minimized because the low level of genetic variation remaining in the species was probably represented in the number of birds translocated to new islands. Models assessing future loss of genetic variation via drift showed that high growth rates combined with high carrying capacity on large islands would probably maintain existing genetic variation. In contrast, low carrying capacity on small islands would probably result in considerable loss of genetic variation over time. Saddleback populations on small islands may require occasional immigrants to maintain long-term genetic variation. Saddleback and robin populations established with a small number of founders did not have an increased risk of failure, suggesting that inbreeding was not substantial enough to prevent populations from growing and recovering. However, modelling showed that translocated saddleback and robin populations grow exponentially even when egg failure rates (a measure of inbreeding depression) are extremely high. Although inbreeding depression may be considerable, populations may be judged healthy simply because they show strong growth rates. Discounting the problem of inbreeding depression may be premature especially under novel circumstances such as environmental change or disease. Finally, two mechanisms proposed to avoid or delay the costs of inbreeding depression and loss of genetic variation do not appear to be important in saddlebacks or robins. Heterozygosity was not related to survivorship in saddlebacks that successfully founded new populations, and neither saddlebacks nor robins chose genetically dissimilar mates to avoid inbreeding. In conclusion, most saddleback populations should not require genetic management, although populations on small islands will probably need occasional immigrants. In robins, large, unfragmented populations should be protected where possible.

Hector�s dolphin (Cephalorhynchus hectori) is an endangered coastal species endemic to New Zealand. Their distribution, like other marine organisms, is intertwined with the dynamics of their local habitats, and at a larger scale, the coastal waters around New Zealand. The main purpose of this thesis was to identify specific habitat requirements of this rare dolphin. Hector�s dolphin distribution around the South Island was quantified along several temporal and spatial scales. Large-scale density analyses of abundance surveys found over half of the South Island�s current population occurred within only three main regions. Two of these strongholds are along the west coast and the third is located around Banks Peninsula on the east coast. Smaller-scale analyses at Banks Peninsula found the majority of the dolphin community was preferentially using core regions within the marine mammal sanctuary. Monthly surveys showed that in summer and autumn statistically more dolphins occurred within inshore regions ([less than or equal to]one kilometre), spread throughout the surveyed coastline. From May through winter, dolphin densities rapidly declined. Remaining dolphins were significantly clumped in more offshore waters of eastern regions. The lowest encounter rates occurred between August and September. Certain 'hotspots' consistently had higher dolphin densities throughout the study period while others were preferred seasonally. To address habitat preferences, surveys simultaneously collected oceanographic samples using a CTD profiler. In general, physical variables of the Peninsula�s eastern and southeastern waters varied less, despite being regularly exposed to upwellings and the varied presence of sub-tropical waters. Semi-sheltered bays and shallow inshore waters were highly variable and more susceptible to spatially discrete influences, such as localised river outflows and exchange events. Several hydrographic features were seasonally predictable due to their dependence on climate. The stratification and location of the two dominant water masses (neritic and sub-tropical) accounted for over half of the temporal and spatial variability observed in oceanographic data. Possible relationships between oceanographic features and aggregations of dolphins within Banks Peninsula were examined using global regression and a spatial technique known as geographical weighted regression (GWR). GWR models out-performed corresponding global models, despite differences in degrees of freedom and increased model complexity. GWR results found relationships varied over localised scales that were concealed by global methods. Monthly GWR models suggested the seasonal presence and strength of local oceanographic fronts influenced dolphin distribution. Dolphin aggregations coincided with the steepest gradients between water masses along eastern regions of the Peninsula, and strong exchange events along the edges of the study area. The continued survival of this endangered species is contingent on its protection. Long-term monitoring programmes are needed for the three main strongholds identified in this study. The occurrence of Hector�s dolphin 'hotspots' along frontal zones within Banks Peninsula also suggests alternative and increased protection strategies are needed for this sanctuary to be effective. In light of this thesis� findings and based on marine protection research, future sanctuaries need to consider why Hector�s dolphins are preferentially using particular regions and how their association with certain oceanographic features can help make informed decisions on more appropriate protected areas.

As human beings we are continually interacting with the landscape, and have been doing so throughout the entire course of our evolution. This thesis specifically investigates the way in which hunter-gatherers negotiate and interact with their landscapes, focusing on three patterns of behaviour: wayfinding, mapmaking and territoriality. An examination of the relevant international literature reveals that globally, hunter-gatherer groups both past and present share a number of similarities with regard to their wayfinding and mapmaking techniques, territorial behaviour. A case study of Maori interaction with the landscape of prehistoric and protohistoric Te Wai Pounamu [the South Island] provides further support for the central argument that hunter-gatherers collectively negotiate and interact with the landscape in distinctive ways. This is contrasted with the interaction of European explorers and travellers with the 19th century landscape of Te Wai Pounamu in Chapter 5. It is determined that hunter-gatherers use detailed cognitive or 'mental' maps to navigate their way through a range of landscape from dense forests to barren plains. These maps often consist of sequences of place names that represent trails. These cognitive maps are most commonly developed through direct interaction with the landscape, but can also be formed vicariously through ephemeral maps drawn with the purpose of communicating geographical knowledge. Prior to European contact, little importance seems to have been given to artefactual or 'permanent' maps within hunter-gatherer societies as the process of mapmaking was generally regarded as more significant than the actual product. Although the literature on hunter-gatherer territoriality is complex and in some cases conflicting, it is contended that among a number of hunter-gatherer groups, including prehistoric and protohistoric Maori in Te Wai Pounamu, interaction and negotiation with the landscape was/is not restricted to exclusive territories marked by rigidly defined boundaries. Among these groups, a specific method of territoriality known as 'social boundry defence' was/is employed. This involves controlling access to the social group inhabiting an area rather than access to the area itself, as with groups utilising the territorial method of 'perimeter defence'.

The ambivalence of many prehistorians toward curio collections has meant that, although they recognise some of their shortcomings, they nevertheless use collections as if they had qualities of archaeological assemblages. In this dissertation it is posited and then demonstrated that curio collections are very different entities to archaeological assemblages. In order to use collections in valid constructions of New Zealand�s pre-European past, the processes that led to their formation need to be understood. It is only then that issues of representation can be addressed. In order to better understand the collecting process, a study of the activity of 24 curio collectors who operated in the Murihiku region of southern New Zealand during the period between 1865 and 1975 was undertaken. The study was structured about two key notions: the idea of the �filter� and the idea that tools and ornaments have a �life history� that extends from the time that raw material was selected for the manufacture to the present. The notion of the filter made possible a determination of the effects of particular behaviours on patterns of collector selectivity and the extent and nature of provenance recording; and the extended concept of life history recognised that material culture functions in multiple cultural and chronological contexts-within both indigenous and post-contact spheres. Examination of the collecting process led to the identification of five curio collecting paradigms: curio collecting for the acquisition of social status, curio collecting for financial return, curio collecting as an adjunct to natural history collecting, curio collecting as an adjunct to historical recording, and ethnological or culture-area curio collecting. Filtering processes associated with each paradigm resulted in particular, but not always distinctive, patterns of curio selectivity and styles of provenance recording. A switch in the focus of attention from examination of curio collectng processes generally to the study of the filtering processes that shaped collections from a specific archaeological site-the pre-European Otago Peninsula site of Little Papanui (J44/1)- enabled some evaluation of individuual collection representation. A database recording up to 19 attributes for each of 6282 curios localised to �Little Papanui� in Otago Museum enabled 31 dedicated or �ardent� collectors who operated at the site to be identified. These 31 dedicated collectors were grouped according to the paradigm that best described their collecting behaviour. It was found that the greater proportion of these dedicated collectors (n=12, 39%) had been influenced by the ethnological or culture-area collecting paradigm. These 12 collectors were responsible for recovering a remarkable 5645 curios or nearly ninety-percent (89.86%) of the meta-collection. Because curio collections lack meaningfully recorded stratigraphic provenance, it is the technological and social context in which tools and ornaments functioned that must become the focus of curio collection studies. Appropriate studies of technological and social and context focus upon evaluations of raw material sourcing, evaluations of manufacture technique and assessments of tool and ornament use and reuse (and integrative combinations of these modes of study). These sorts of evaluation require large collections compiled in the least selective manner possible and the collections need to be reliably localised to specific sites. Collections compiled by the ethnological or culture-area collectors have these qualities. Collections compiled within other paradigms lack locality information and were assembled in highly selective manners.

Precipitation is one of the atmospheric variables that characterize the climate of a region. The South Island of New Zealand (SI of NZ) has an unusually large number of distinct regional climates and its climatic diversity includes the coldest, wettest, driest and windiest places in New Zealand. This thesis focuses on identifying precipitation trends and rainfall fluctuations for the SI of NZ. First, homogeneity of 184 precipitation series is assessed with the combination of three homogeneity tests (Standard Normal Homogeneity Test, Easterling & Peterson test, Vincent�s Multiple Linear Regression). More than 60% of tested time series are found to contain at least one inhomogeneity. About 50% of the inhomogeneities can be traced to information in the station history files with nearly 25% of all inhomogeneities caused by the relocation of the precipitation gauge. Five coherent precipitation regions are defined by the Principal Component Analysis. The objective of identifying the periods of water deficit and surplus in spatial and temporal domains is achieved by using Standardized Precipitation Index (SPI). The SPI series (for 3, 6, 12, 24 and 48 months time scales) are calculated for each region and used for analysis of dry and wet periods. Clear differences in the frequency, length and intensity of droughts and wet periods were found between individual regions. There is a positive (i.e. increase in wet periods) trend in SPI time series for the North, Westland and Southland regions during the 1921-2003 period at all times scales, and a negative trend for Canterbury during the same period. The results show longer wet periods than dry periods at all time scales. Extreme heavy precipitation, which causes floods, is the most common type of natural disaster accounting for about 40% of all natural disasters worldwide. A set of ten extreme indices is calculated for 51 stations throughout the South Island for the period 1951-2003. The west-east division is found to be the dominant feature of extreme precipitation trends for all extreme indices with more frequent and more intense extreme precipitation in the west/southwest and with a declining trend in the east. The significant decrease in extreme precipitation frequency was detected in Canterbury with 3 days less of precipitation above the long-term 95th percentile by 2003 as compared to 1951. The variability of precipitation, expressed by the SPI, is correlated with local New Zealand atmospheric circulation indices and large-scale teleconnections. The precipitation variability in the South Island is governed largely by the local circulation characteristics, mainly the strength and position of the westerly flow. The increase in precipitation in the West and SouthEast is associated with enhanced westerlies. The correlations between New Zealand�s circulation indices and regional SPI are seasonally robust. The SouthEast region exhibits a strong relationship with the Southern Oscillation Index on seasonal and annual time scales,and with Interdecadal Pacific Oscillation at the decadal scale. The predictability of seasonal precipitation one season ahead is very limited.

The Alpine Fault is the major structure of the Pacific-Australian plate boundary through New Zealand�s South Island. During dextral reverse fault slip, a <5 million year old, ~1 km thick mylonite zone has been exhumed in the hanging-wall, providing unique exposure of material deformed to very high strains at deep crustal levels under boundary conditions constrained by present-day plate motions. The purpose of this study was to investigate the fault zone rheology and mechanisms of strain localisation, to obtain further information about how the structural development of this shear zone relates to the kinematic and thermal boundary constraints, and to investigate the mechanisms by which the viscously deforming mylonite zone is linked to the brittle structure, that fails episodically causing large earthquakes. This study has focussed on the central section of the fault from Harihari to Fox Glacier. In this area, mylonites derived from a quartzofeldspathic Alpine Schist protolith are most common, but slivers of Western Province-derived footwall material, which can be differentiated using mineralogy and bulk rock geochemistry, were also incorporated into the fault zone. These footwall-derived mylonites are increasingly common towards the north. At amphibolite-facies conditions mylonitic deformation was localised to the mylonite and ultramylonite subzones of the schist-derived mylonites. Most deformation was accommodated by dislocation creep of quartz, which developed strong Y-maximum crystallographic preferred orientation (CPO) patterns by prism (a) dominant slip. Formation of this highly-oriented fabric would have led to significant geometric softening and enhanced strain localisation. During this high strain deformation, pre-existing Alpine Schist fabrics in polyphase rocks were reconstituted to relatively well-mixed, finer-grained aggregates. As a result of this fabric homogenisation, strong syn-mylonitic object lineations were not formed. Strain models show that weak lineations trending towards ~090� and kinematic directions indicated by asymmetric fabrics and CPO pattern symmetry could have formed during pure shear stretches up-dip of the fault of ~3.5, coupled with simple shear strains [greater than or equal to]30. The preferred estimate of simple:pure shear strain gives a kinematc vorticity number, W[k] [greater than or equal to]̲ 0.9997. Rapid exhumation due to fault slip resulted in advection of crustal isotherms. New thermobarometric and fluid inclusion analyses from fault zone materials allow the thermal gradient along an uplift path in the fault rocks to be more precisely defined than previously. Fluid inclusion data indicate temperatures of 325+̲15�C were experienced at depths of ~45 km, so that a high thermal gradient of ~75�C km⁻� is indicated in the near-surface. This gradient must fall off to [ less than approximately]l0�C km⁻� below the brittle-viscous transition since feldspar thermobarometry, Ti-inbiotite thermometry and the absence of prism(c)-slip quartz CPO fabrics indicate deformation temperatures did not exceed ~ 650�C at [greater than or equal to] 7.0-8.5�1.5 kbar, ie. 26-33 km depth. During exhumation, the strongly oriented quartzite fabrics were not favourably oriented for activation of the lower temperature basal(a) slip system, which should have dominated at depths [less than approximately]20 km. Quartz continued to deform by crystal-plastic mechanisms to shallow levels. However, pure dislocation creep of quartz was replaced by a frictional-viscous deformation mechanism of sliding on weak mica basal planes coupled with dislocation creep of quartz. Such frictional-viscous flow is particularly favoured during high-strain rate events as might be expected during rupture of the overlying brittle fault zone. Maximum flow stresses supported by this mechanism are ~65 Mpa, similar to those indicated by recrystallised grain size paleopiezometry of quartz (D>25[mu]m, indicating [Delta][sigma][max] ~55 MPa for most mylonites). It is likely that the preferentially oriented prism (a) slip system was activated during these events, so the Y-maximum CPO fabrics were preserved. Simple numerical models show that activation of this slip system is favoured over the basal (a) system, which has a lower critical resolved shear stress (CRSS) at low temperatures, for aggregates with strong Y-maximum orientations. Absence of pervasive crystal-plastic deformation of micas and feldspars during activation of this mechanism also resulted in preservation of mineral chemistries from the highest grades of mylonitic deformation (ie. amphibolite-facies). Retrograde, epidote-amphibolite to greenschist-facies mineral assemblages were pervasively developed in ultramylonites and cataclasites immediately adjacent to the fault core and in footwall-derived mylonites, perhaps during episodic transfer of this material into and subsequently out of the cooler footwall block. In the more distal protomylonites, retrograde assemblages were locally developed along shear bands that also accommodated most of the mylonitic deformation in these rocks. Ti-in-biotite thermometry suggests biotite in these shear bands equilibrated down to ~500+̲50�C, suggesting crystal-plastic deformation of this mineral continued to these temperatures. Crossed-girdle quartz CPO fabrics were formed in these protomylonites by basal (a) dominant slip, indicating a strongly oriented fabric had not previously formed at depth due to the relatively small strains, and that dislocation creep of quartz continued at depths [less than or equal to]20 km. Lineation orientations, CPO fabric symmetry and shear-band fabrics in these protomylonites are consistent with a smaller simple:pure shear strain ratio than that observed closer to the fault core (W[k] [greater than approximately] 0.98), but require a similar total pure shear component. Furthermore, they indicate an increase in the simple shear component with time, consistent with incorporation of new hanging-wall material into the fault zone. Pre-existing lineations were only slowly rotated into coincidence with the mylonitic simple shear direction in the shear bands since they lay close to the simple shear plane, and inherited orientations were not destroyed until large finite strains (<100) were achieved. As the fault rocks were exhumed through the brittle-viscous transition, they experienced localised brittle shear failures. These small-scale seismic events formed friction melts (ie. pseudotachylytes). The volume of pseudotachylyte produced is related to host rock mineralogy (more melt in host rocks containing hydrated minerals), and fabric (more melt in isotropic host rocks). Frictional melting also occurred within cataclastic hosts, indicating the cataclasites around the principal slip surface of the Alpine Fault were produced by multiple episodes of discrete shear rather than distributed cataclastic flow. Pseudotachylytes were also formed in the presence of fluids, suggesting relatively high fault gouge permeabilities were transiently attained, probably during large earthquakes. Frictional melting contributed to formation of phyllosilicate-rich fault gouges, weakening the brittle structure and promoting slip localisation. The location of faulting and pseudotachylyte formation, and the strength of the fault in the brittle regime were strongly influenced by cyclic hydrothermal cementation processes. A thermomechanical model of the central Alpine Fault zone has been defined using the results of this study. The mylonites represent a localised zone of high simple shear strain, embedded in a crustal block that underwent bulk pure shear. The boundaries of the simple shear zone moved into the surrounding material with time. This means that the exhumed sequence does not represent a simple 'time slice' illustrating progressive fault rock development during increasing simple shear strains. The deformation history of the mylonites at deep crustal P-T conditions had a profound influence on subsequent deformation mechanisms and fabric development during exhumation.

Improving our understanding of the forces driving population decline and the processes that affect the dynamics of threatened populations is central to the success of conservation management. The application of genetic tools, including our ability to examine ancient DNA, has now revolutionised our ability to investigate these processes. The recent human settlement of the Pacific, particularly in New Zealand, provides a unique, accessible system for revealing anthropogenic impacts on native biota. In this thesis I use genetic analyses from modern, historic and subfossil DNA to investigate temporal and spatial genetic structuring of the endangered yellow-eyed penguin (Megadyptes antipodes), and use these analyses to answer questions related to the conservation of this species. The yellow-eyed penguin is endemic to the New Zealand region and currently breeds on the subantarctic Auckland and Campbell Islands and the southeast coast of the South Island. The current total population size is estimated around 6000-7000 individuals, of which more than 60% inhabit the subantarctic. Despite intensive conservation measures by governmental and local community agencies, population sizes have remained highly unstable with strong fluctuations in numbers on the South Island. The species was believed to be more widespread and abundant before human colonisation of New Zealand, thus current management assumed the mainland population to be a declining remnant of a larger prehistoric population. Genetic and morphological analyses of subfossil, historic and modern penguin samples revealed an unexpected pattern of penguin extinction and expansion. Only in the last few hundred years did M. antipodes expand its range from the subantarctic to the New Zealand mainland. This range expansion was apparently facilitated by the extinction of M. antipodes' previously unrecognised sister species, M. waitaha, following Polynesian settlement in New Zealand. The demise of M. waitaha is the only known human-mediated extinction of a penguin species. Despite M. antipodes' recent range expansion, genetic analyses of microsatellite markers reveal two genetically and geographically distinct assemblages: South Island versus subantarctic populations. We detected only two first generation migrants that had dispersed from the subantarctic to the South Island, suggesting a migration rate of less than 2%. Moreover, the South Island population has low genetic variability compared to the subantarctic population. Temporal genetic analyses of historic and modern penguin specimens further revealed that the harmonic mean effective population size of the M. antipodes South Island population is low (<200). These findings suggest that the South Island population was founded by only a small number of individuals, and that subsequent levels of gene flow have remained low. Finally, we present a novel approach to detect errors in historic museum specimen data in cases where a priori suspicion is absent. Museum specimens provide an invaluable resource for biological research, but the scientific value of specimens is compromised by the presence of errors in collection data. Using individual-based genetic analysis of contemporary and historic microsatellite data we detected eight yellow-eyed penguin specimens with what appear to be fraudulently labelled collection locations. This finding suggests errors in locality data may be more common than previously suspected, and serves as a warning to all who use archive specimens to invest time in the verification of specimen data. Overall, yellow-eyed penguins have a remarkable dynamic history of recent expansion, which has resulted in two demographically independent populations. These results reveal that anthropogenic impacts may be far more complex than previously appreciated.

The ambivalence of many prehistorians toward curio collections has meant that, although they recognise some of their shortcomings, they nevertheless use collections as if they had qualities of archaeological assemblages. In this dissertation it is posited and then demonstrated that curio collections are very different entities to archaeological assemblages. In order to use collections in valid constructions of New Zealand�s pre-European past, the processes that led to their formation need to be understood. It is only then that issues of representation can be addressed. In order to better understand the collecting process, a study of the activity of 24 curio collectors who operated in the Murihiku region of southern New Zealand during the period between 1865 and 1975 was undertaken. The study was structured about two key notions: the idea of the �filter� and the idea that tools and ornaments have a �life history� that extends from the time that raw material was selected for the manufacture to the present. The notion of the filter made possible a determination of the effects of particular behaviours on patterns of collector selectivity and the extent and nature of provenance recording; and the extended concept of life history recognised that material culture functions in multiple cultural and chronological contexts-within both indigenous and post-contact spheres. Examination of the collecting process led to the identification of five curio collecting paradigms: curio collecting for the acquisition of social status, curio collecting for financial return, curio collecting as an adjunct to natural history collecting, curio collecting as an adjunct to historical recording, and ethnological or culture-area curio collecting. Filtering processes associated with each paradigm resulted in particular, but not always distinctive, patterns of curio selectivity and styles of provenance recording. A switch in the focus of attention from examination of curio collectng processes generally to the study of the filtering processes that shaped collections from a specific archaeological site-the pre-European Otago Peninsula site of Little Papanui (J44/1)- enabled some evaluation of individuual collection representation. A database recording up to 19 attributes for each of 6282 curios localised to �Little Papanui� in Otago Museum enabled 31 dedicated or �ardent� collectors who operated at the site to be identified. These 31 dedicated collectors were grouped according to the paradigm that best described their collecting behaviour. It was found that the greater proportion of these dedicated collectors (n=12, 39%) had been influenced by the ethnological or culture-area collecting paradigm. These 12 collectors were responsible for recovering a remarkable 5645 curios or nearly ninety-percent (89.86%) of the meta-collection. Because curio collections lack meaningfully recorded stratigraphic provenance, it is the technological and social context in which tools and ornaments functioned that must become the focus of curio collection studies. Appropriate studies of technological and social and context focus upon evaluations of raw material sourcing, evaluations of manufacture technique and assessments of tool and ornament use and reuse (and integrative combinations of these modes of study). These sorts of evaluation require large collections compiled in the least selective manner possible and the collections need to be reliably localised to specific sites. Collections compiled by the ethnological or culture-area collectors have these qualities. Collections compiled within other paradigms lack locality information and were assembled in highly selective manners.

Rocks of the South Island of New Zealand are locally enriched in metalloids, namely arsenic (As), antimony (Sb) and boron (B). Elevated levels of As and Sb can be found in sulphide minerals mostly in association with mesothermal gold deposits, whereas B enrichment occurs in marine influenced coal deposits. The mobility of these metalloids is important because they can be toxic at relatively low levels (e.g. for humans >0.01 mg/L of As). Their mobilisation occurs naturally from background weathering of the bedrock. However, mining and processing of coal and gold deposits, New Zealand's most economically important commodities, can significantly increase metalloid mobility. In particular, historic mines and associated industrial sites are known to generate elevated metalloid levels because of the lack of site remediation upon closure. This work defines and quantifies geological, mining, post-mining and regional processes with respect to metalloid, especially As, mobility. At the studied historic gold mines, the Blackwater and Bullendale mines, Sb levels in mineralised rocks were generally negligible (<14 ppm) compared to As (up to 10,000 ppm). Thus, Sb concentrations in solids and in water were too low to yield any meaningful information on Sb mobility. In contrast, dissolved As concentrations downstream from mine sites were found to be very high (up to 59 mg/L) (background = 10⁻� mg/L). In addition, very high As concentrations were found in residues (up to 40 wt%) and site substrate (up to 30 wt%) at the Blackwater processing sites (background < 0.05 wt%). Here, roasting of the gold ore converted the orginal As mineral, arsenopyrite, into the mineral arsenolite (As[III] trioxide polymorph) and volatilised the sulphur. The resultant sulphur-defficient chemical system is driven by arsenolite dissolution and differs significantly from mine sites where arsenopyrite is the main As source. Arsenolite is significantly more soluble than arsenopyrite. In the surficial environment, arsenolite dissolution is limited by kinetics only, which are slow enough to preserve exposed arsenolite over decades in a temperate, wet climate. This process results in surface waters with up to ca. 50 mg/L dissolved As. In reducing conditions, dissolved As concentrations are also controlled by the solubility of arsenolite producing As concentrations up to 330 mg/L. Field based cathodic stripping voltammetry showed that the As[III]/As[V] redox couple, in particular the oxidation of As[III], has a major control on system pH and Eh. Site acidification is mainly caused by the oxidation of As[III], resulting in a close link between As[V] concentrations and pH. Similarly, a strong correlation between calculated (Nernstian) and measured (electrode) Eh was found in the surface environment, suggesting that the overall Eh of the system is, indeed, defined by the As[III]/As[V] redox couple. Once the metalloid is mobilised from its original source, its mobility is controlled by at least one of the following attenuation processes: (a) precipitation of secondary metalloid minerals, (b) co-precipitation with - or adsorption to - iron oxyhydroxide (HFO), or (c) dilution with background waters. The precipitation of secondary minerals is most favoured in the case of As due to the relatively low solubility of iron arsenates, especially at low pH (~0.1 mg/L). Observations suggest that scorodite can be the precursor phase to more stable iron arsenates, such as kankite, zykaite, bukovskyite or pharmacosiderite and their stability is mainly controlled by pH, sulphur concentrations and moisture prevalence. Empirical evidence indicates that the sulphur-containing minerals zykaite and bukovskyite have a similar pH dependence to scorodite with solubilities slightly lower than scorodite and kankite. If dissolved As concentrations decline, iron arsenates potentially become unstable. Their dissolution maintains a pH between 2.5 and 3.5. This acidification process is pivotal with respect to As mobility, especially in the absence of other acidification processes, because iron arsenates are several orders of magnitude more soluble in circum-neutral pH regimes (~100 mg/L). From this, it becomes apparent that external pH modifications, for example as part of a remediation scheme, can significantly increase iron arsenate solubility and resultant As mobility. In contrast to As, the precipitation of secondary Sb and B minerals is limited by their high solubilities, which are several orders of magnitude higher than for iron arsenates. Thus, secondary Sb and B minerals are restricted to evaporative waters, from which they can easily re-mobilised during rain events. Metalloid adsorption to HFO is mainly controlled or limited by the extent of HFO formation, which in turn is governed by the availability of Fe and prevailing Eh-pH conditions. Thus, mineralisation styles and associated geochemical gradients, in particular pyrite abundance, can control the amount of HFO and consequent metalloid attenuation, and these can vary even within the same goldfleld. Furthermore, it was found that there is a mineralogical gradation between ferrihydrite with varying amounts of adsorbed As, amorphous iron arsenates and crystalline iron arsenates, suggesting that the maturity of mine waste is an important factor in As mineralogy. Once dissolved metalloids enter the hydrosphere, dilution is the main control on metalloid attenuation, which is especially pronounced at the inflow of tributaries. Dilution is, therefore, closely related to the size and frequency of these tributaries, which in turn are controlled by the regional topography and climate. Dilution is a considerably less effective attenuation mechanism and anomalous metalloid concentrations from mining related sites can persist for over 10 km downstream. The complex and often inter-dependent controls on metalloid mobility mean that management decisions should carefully consider the specific site geochemistry to minimize economic, health and environmental risks that can not be afforded. On a regional scale, background metalloid flux determines the downstream impact of an anomalous metalloid source upstream. For example, the Bullendale mine is located in a mountainous region, where rapidly eroding slopes expose fresh rock and limit the extent of soil cover and chemical weathering. Consequently, the background As flux is relatively low and As point sources, such as the Bullendale mine, present a significant contribution to the downstream As flux. In contrast, the bedrock at the Blackwater mine has undergone deep chemical weathering, resulting in an increased background mobilisation of As. Thus, the Prohibition mill site discharge, for example, contributes only about 10% to the downstream As flux. This information is relevant to site management decisions because the amount of natural background metalloid mobilisation determines whether site remediation will influence downstream metalloid chemistry on a regional scale.

Hector�s dolphin (Cephalorhynchus hectori) is an endangered coastal species endemic to New Zealand. Their distribution, like other marine organisms, is intertwined with the dynamics of their local habitats, and at a larger scale, the coastal waters around New Zealand. The main purpose of this thesis was to identify specific habitat requirements of this rare dolphin. Hector�s dolphin distribution around the South Island was quantified along several temporal and spatial scales. Large-scale density analyses of abundance surveys found over half of the South Island�s current population occurred within only three main regions. Two of these strongholds are along the west coast and the third is located around Banks Peninsula on the east coast. Smaller-scale analyses at Banks Peninsula found the majority of the dolphin community was preferentially using core regions within the marine mammal sanctuary. Monthly surveys showed that in summer and autumn statistically more dolphins occurred within inshore regions ([less than or equal to]one kilometre), spread throughout the surveyed coastline. From May through winter, dolphin densities rapidly declined. Remaining dolphins were significantly clumped in more offshore waters of eastern regions. The lowest encounter rates occurred between August and September. Certain 'hotspots' consistently had higher dolphin densities throughout the study period while others were preferred seasonally. To address habitat preferences, surveys simultaneously collected oceanographic samples using a CTD profiler. In general, physical variables of the Peninsula�s eastern and southeastern waters varied less, despite being regularly exposed to upwellings and the varied presence of sub-tropical waters. Semi-sheltered bays and shallow inshore waters were highly variable and more susceptible to spatially discrete influences, such as localised river outflows and exchange events. Several hydrographic features were seasonally predictable due to their dependence on climate. The stratification and location of the two dominant water masses (neritic and sub-tropical) accounted for over half of the temporal and spatial variability observed in oceanographic data. Possible relationships between oceanographic features and aggregations of dolphins within Banks Peninsula were examined using global regression and a spatial technique known as geographical weighted regression (GWR). GWR models out-performed corresponding global models, despite differences in degrees of freedom and increased model complexity. GWR results found relationships varied over localised scales that were concealed by global methods. Monthly GWR models suggested the seasonal presence and strength of local oceanographic fronts influenced dolphin distribution. Dolphin aggregations coincided with the steepest gradients between water masses along eastern regions of the Peninsula, and strong exchange events along the edges of the study area. The continued survival of this endangered species is contingent on its protection. Long-term monitoring programmes are needed for the three main strongholds identified in this study. The occurrence of Hector�s dolphin 'hotspots' along frontal zones within Banks Peninsula also suggests alternative and increased protection strategies are needed for this sanctuary to be effective. In light of this thesis� findings and based on marine protection research, future sanctuaries need to consider why Hector�s dolphins are preferentially using particular regions and how their association with certain oceanographic features can help make informed decisions on more appropriate protected areas.