The thesis is devoted to the study of in-chain impurities in spin 1/2 antiferromagnetic Heisenberg chains (S=1/2 aHC's)---a model which accompanies the research on magnetism since the early days of quantum theory and which is one of the few integrable spin systems. With respect to impurities it is special insofar as an impurity perturbs the system strongly due to its topology: there is no way around the defect. To what extend the one-dimensional picture stays a good basis for the description of real materials even if the chains are disturbed by in-chain impurities is an interesting question which is addressed in this work. For this purpose, Cu Nuclear Magnetic Resonance (NMR) measurements on the cuprate spin chain compounds SrCuO2 and Sr2CuO3 intentionally doped with nickel (Ni), zinc (Zn) and palladium (Pd) are presented. These materials are well known to be among the best realizations of the S=1/2 aHC model and their large exchange coupling constants allow the investigation of the low-energy dynamics within experimentally easily feasible temperatures. NMR provides the unique ability to study the static and dynamic magnetic properties of the spin chains locally which is important since randomly placed impurities break the translational invariance. Because copper is the magnetically active ion in those materials and the copper nuclear spin is most directly coupled to its electron spin, the NMR measurements have been performed on the copper site. The measurements show in all cases that there are changes in the results of these measurements as compared to the pure compounds which indicate the opening of gaps in the excitation spectra of the spin chains and the emergence of oscillations of the local susceptibility close to the impurities. These experimental observations are compared to theoretical predictions to clarify if and to what extend the already proposed model for these doped systems---the finite spin chain---is suitable to predict the behavior of real materials. Thereby, each impurity shows peculiarities. While Zn and Pd are know to be spin 0 impurities, it is not clear if Ni carries spin 1. To shed some light on this issue is another scope of this work. For Zn impurities, there are indications that they avoid to occupy copper sites, other than in the layered cuprate compounds. Also this matter is considered.

By numerical methods, two models of anisotropic mixed quantum spin chains, consisting of spins of two different sizes, Sa = 1/2 and Sb = 1 as well as Sb = 3/2, are studied with respect to their critical properties at quantum phase transitions in a selected region of parameter space. The quantum spin chains are made up of basecells of four spins, according to the structure Sa − Sa − Sb − Sb. They are described by the XXZ Hamiltonian, that extends the quantum Heisenberg model by a variable anisotropic exchange interaction. As additional control parameter, an alternating exchange constant between nearest-neighbour spins is introduced. Insight gained by complementary application of exact diagonalization and quantum Monte Carlo simulations, as well as appropriate methods of analysis, is embedded in the broad existing knowledge on homogeneous quantum spin chains. In anisotropic homogeneous quantum spin chains, there exist phase boundaries with continuously varying critical exponents, the Gaussian critical lines, along which, in addition to standard scaling relations, further extended scaling relations hold. Reweighting methods, also applied to improved quantum Monte Carlo estimators, and finite-size scaling analysis of simulation data deliver a wealth of numerical results confirming the existence of a Gaussian critical line also in the mixed spin models considered. Extrapolation of exact data offers, apart from confirmation of simulation data, furthermore, insight into the conformal operator content of the model with Sb = 1. / Mittels numerischer Methoden werden zwei Modelle anisotroper gemischter Quantenspinketten, bestehend aus Spins zweier unterschiedlicher Größen, Sa = 1/2 und Sb = 1 sowie Sb = 3/2, hinsichtlich ihrer kritischen Eigenschaften an Quanten-Phasenübergängen in einem ausgewählten Parameterbereich untersucht. Die Quantenspinketten sind aus Basiszellen zu vier Spins, gemäß der Struktur Sa − Sa − Sb − Sb, aufgebaut. Sie werden durch den XXZ Hamiltonoperator beschrieben, der das isotrope Quanten-Heisenberg Modell um eine variable anistrope Austauschwechselwirkung erweitert. Als zusätzlicher Kontrollparameter wird eine alterniernde Kopplungskonstante zwischen unmittelbar benachbarten Spins eingeführt. Die durch komplementäre Anwendung exakter Diagonalisierung und Quanten-Monte-Carlo Simulationen, sowie entsprechender Analyseverfahren, gewonnenen Erkenntnisse werden in das umfangreiche existierende Wissen über homogene Quantenspinketten eingebettet. Im Speziellen treten in anisotropen homogenen Quantenspinketten Phasengrenzen mit kontinuierlich variierenden kritischen Exponenten auf, die Gaußschen kritischen Linien, auf denen neben den herkömmlichen auch erweiterte Skalenrelationen Gültigkeit besitzen. Umgewichtungsmethoden, speziell auch angewandt auf verbesserte Quanten-Monte-Carlo Schätzer, und Endlichkeitsskalenanalyse von Simulationsdaten liefern eine Fülle von numerischen Ergebnissen, die das Auftreten der Gaußschen kritischen Linie auch in den untersuchten gemischten Quantenspinketten bestätigen. Die Extrapolation exakter Daten bietet, neben der Bestätigung der Simulationsdaten, darüber hinaus Einblick in einen Teil des konformen Operatorinhalts des Modells mit Sb = 1.

On a compris ces dernières années que certaines mesures d'intrications sont un outil efficace pour la compréhension et la caractérisation de phases nouvelles et exotiques de la matière, en particulier lorsque les méthodes traditionnelles basées sur l'identification d'un paramètre d'ordre sont insuffisantes. Cette thèse porte sur l'étude de quelques systèmes quantiques à basse dimension où un telle approche s'avère fructueuse. Parmi ces mesures, l'entropie d'intrication, définie via une bipartition du système quantique, est probablement la plus populaire, surtout à une dimension. Celle-ci est habituellement très difficile à calculer en dimension supérieure, mais nous montrons ici que le calcul se simplifie drastiquement pour une classe particulière de fonctions d'ondes, nommées d'après Rokhsar et Kivelson. L'entropie d'intrication peut en effet s'exprimer comme une entropie de Shannon relative à la distribution de probabilité générée par les composantes de la fonction d'onde du fondamental d'un autre système quantique, cette fois-ci unidimensionnel. Cette réduction dimensionnelle nous permet d'étudier l'entropie aussi bien par des méthodes numériques (fermions libres, diagonalisations exactes, ...) qu'analytiques (théories conformes). Nous argumentons aussi que cette approche permet d'accéder facilement à certaines caractéristiques subtiles et universelles d'une fonction d'onde donnée en général.Une autre partie de cette thèse est consacrée aux trempes quantiques locales dans des systèmes critiques unidimensionnels. Nous insisterons particulièrement sur une quantité appelée écho de Loschmidt, qui est le recouvrement entre la fonction d'onde avant la trempe et la fonction d'onde à temps t après la trempe. En exploitant la commensurabilité du spectre de la théorie conforme, nous montrons que l'évolution temporelle doit être périodique, et peut même être souvent obtenue analytiquement. Inspiré par ces résultats, nous étudions aussi la contribution de fréquence nulle à l'écho de Loschmidt après la trempe. Celle-ci s'exprime comme un simple produit scalaire -- que nous nommons fidélité bipartie -- et est une quantité intéressante en elle-même. Malgré sa simplicité, son comportement se trouve être très similaire à celui de l'entropie d'intrication. Pour un système critique unidimensionnel en particulier, notre fidélité décroît algébriquement avec la taille du système, un comportement rappelant la célèbre catastrophe d'Anderson. L'exposant est universel et relié à la charge centrale de la théorie conforme sous-jacente. / In recent years, it has been understood that entanglement measures can be useful tools for the understanding and characterization of new and exotic phases of matter, especially when the study of order parameters alone proves insufficient. This thesis is devoted to the study of a few low-dimensional quantum systems where this is the case. Among these measures, the entanglement entropy, defined through a bipartition of the quantum system, has been perhaps one of the most heavily studied, especially in one dimension. Such a quantity is usually very difficult to compute in dimension larger than one, but we show that for a particular class of wave functions, named after Rokhsar and Kivelson, the entanglement entropy of an infinite cylinder cut into two parts simplifies considerably. It can be expressed as the Shannon entropy of the probability distribution resulting from the ground-state wave function of a one-dimensional quantum system. This dimensional reduction allows for a detailed numerical study (free fermion, exact diagonalizations, \ldots) as well as an analytic treatment, using conformal field theory (CFT) techniques. We also argue that this approach can give an easy access to some refined universal features of a given wave function in general.Another part of this thesis deals with the study of local quantum quenches in one-dimensional critical systems. The emphasis is put on the Loschmidt echo, the overlap between the wave function before the quench and the wave function at time t after the quench. Because of the commensurability of the CFT spectrum, the time evolution turns out to be periodic, and can be obtained analytically in various cases. Inspired by these results, we also study the zero-frequency contribution to the Loschmidt echo after such a quench. It can be expressed as a simple overlap -- which we name bipartite fidelity -- and can be studied in its own right. We show that despite its simple definition, it mimics the behavior of the entanglement entropy very well. In particular when the one-dimensional system is critical, this fidelity decays algebraically with the system size, reminiscent of Anderson's celebrated orthogonality catastrophe. The exponent is universal and related to the central charge of the underlying CFT.

L’étude réalisée dans cette thèse porte sur les phénomènes critiques classiques et quantiques. En effet, les phénomènes critiques et les transitions de phases sont devenus des sujets fondamentaux en physique statistique moderne et en théorie des champs et nous proposons dans cette thèse d’étudier certains modèles qui présentent un comportement critique, à la fois à l’équilibre et hors de l’équilibre. Dans la première partie de la thèse, certaines propriétés du modèle de dimères à deux dimensions sont étudiées. Ce modèle a été largement étudié dans les communautés de physique statistique et de mathématiques et un grand nombre d’applications en physique de la matière condensée existent. Ici, nous proposons de mettre l’accent sur des solutions exactes du modèle et d’utiliser l’invariance conforme afin d’avoir une compréhension profonde de ce modèle en présence de monomères et/ou en présence de bords. Les mêmes types d’outils sont ensuite utilisés pour explorer un autre phénomène important apparaissant dans les modèles de dimères et de chaînes de spin : le cercle arctique. Le but étant de trouver une description adéquate en termes de théorie des champs de ce phénomène, en utilisant des calculs exacts ainsi que de l’analyse asymptotique. La deuxième partie de la thèse concerne les phénomènes critiques hors de l’équilibre dans le contexte des modèles de croissance d’interfaces. Ce domaine de recherche est très important de nos jours, principalement en raison de la découverte de l’équation Kardar-Parisi-Zhang et de ses relations avec les ensembles de matrices aléatoires. La phénoménologie de ces modèles en présence des bords est analysée via des solutions exactes et des simulations numériques, on montre alors que des comportements surprenants apparaissent proches des bords / The study carried in this thesis concerns classical and quantum critical phenomena. Indeed, critical behaviors and phase transitions are fundamental topics in modern statistical physics and field theory and we propose in this thesis to study some models which exhibit such behaviors both at equilibrium and out of equilibrium. In the first part of the thesis, some properties of the two-dimensional dimer model are studied. This model has been studied extensively in the statistical physics and mathematical communities and a lot of applications in condensed matter physics exist. Here we propose to focus on exact solutions of the model and conformal invariance in order to have a deep understanding of this model in presence of monomers, and/or boundaries. The same kind of tools are then used to explore another important phenomenon appearing in dimer models and spin chains: the arctic circle. The goal was to find a proper field theoretical description of this phenomenon using exact solutions and asymptotic analysis. The second part of the thesis concerns out of equilibrium critical phenomena in the context of interface growth models. This field of research is very important nowadays, mainly because of the Kardar-Parisi-Zhang equation and its relations with random matrix ensembles. The phenomenology of these models in presence of boundaries is studied via exact solutions and numerical simulations, we show that surprising behaviors appear close to the boundaries

Quantum simulations, where controllable quantum systems are used to simulate other quantum systems, originally proposed by Richard Feynman, are one of the most remarkable applications of quantum information science. Compared to computation, quantum simulations require much less number of qubits for the m to be practical. In the work described in this thesis, we have performed a few quantum simulations of small quantum systems using Nuclear Magnetic Resonance(NMR) techniques. These simulations have been used to experimentally demonstrate the underlying interesting quantum protocols. All the experiments presented have been carried out using liquid-state or liquid crystal NMR. Numerical pulse optimization techniques have been utilized in some of the experiments, to achieve better control over the spin systems. The first chapter contains “Introduction” to quantum information processing, NMR, and numerical pulse optimization techniques. In chapter 2, we describe quantum simulation of a 3-spin Heisenberg-XY spin chain having only nearest neighbour interactions. Recently, spin chains having pre-engineered short-range interactions have been proposed to efficiently transfer quantum information between different parts of a quantum information processor. Other important proposals involving these spin chains include generating entangled states and universal quantum computation. However, such engineered interactions do not occur naturally in any system. In such a scenario, the experimental viability of these proposals can be tested by simulating the spin chains in other controllable quantum systems. In this work, we first theoretically study the time evolution of bipartite and tripartite entanglement measures for a 3-spin open ended XY spin chain. Then, by simulating the XY interactions in a 3-spin nuclear spin system, we experimentally generate, (i)a bipartite maximally(pseudo-)entangled state(Bell state) between end qubits, and(ii) multipartite(pseudo-)entangled states(Wand GHZ states),starting from separable pseudo-pure states. Bell state has been generated by using only the natural unitary evolution of the XY spin chain. W-state and GHZ-state have been generated by applying a single-qubit rotation to the second qubit, and a global rotation of all the three qubits respectively after the unitary evolution of the spin chain. In chapter 3, we simulate a 3-spin quantum transverse Ising spin system in a triangular configuration, and show that multipartite quantum correlations can be used to distinguish between the frustrated and non-frustrated regimes in the ground state of this spin system. The ground state of the spin system has been prepared by using adiabatic state preparation method. Gradient ascent pulse engineering technique has been utilized to efficiently realize the adiabatic evolution of the spin system. To analyse the experimental ground state of the system, we employ two different multipartite quantum correlation measures, generated from monogamy studies of bipartite quantum correlations. Chapter 4 contains a digital quantum simulation of the mirror inversion propagator corresponding to the time evolution of an XY spin chain. This simulation has been used to experimentally demonstrate the mirror inversion of quantum states, proposed by Albanese et al.[Phys.Rev.Lett.93,230502(2004)], by which entangled states can be transferred from one end of the chain to the other end. The experiments have been performed in a 5-qubit dipolar coupled nuclear spin system. For simulation, we make use of the recently proposed unitary operator decomposition algorithm along with the numerical pulse optimization techniques, which assisted in achieving high experimental fidelities. Chapter 5 contains a digital quantum simulation of the unitary propagator of a transverse Ising spin chain, which has been used to experimentally demonstrate the perfect state transfer protocol of Di Franco et al. [Phys.Rev.Lett.101,230502(2008)]. The importance of this protocol arises due to the fact that it achieves perfect state transfer from one end of the chain to the other end without the necessity of initializing the intermediate spins of the chain, whereas most of the previously proposed protocols require initialization. The experiments have been performed in a 3-spin nuclear spin system. The simulation has also been used to demonstrate the generation of a GHZ state.

Cette thèse s’inscrit dans le cadre général de la théorie des systèmes intégrables avec bords et le développement des structures algébriques associées.D’une part, nous nous attaquons au problème de la diagonalisation de l’hamiltonien du modèle XXZ avec bords non diagonaux. Nous exhibons les deux ensembles d’états propres et valeurs propres du modèle si les paramètres de bords satisfont deux conditions.D’autre part, nous introduisons un modèle de physique statistique que nous appelons le modèle face avec un bord réfléchissant. Nous calculons exactement sa fonction de partition et nous montrons que cette dernière se représente simplement sous la forme d’un unique déterminant matriciel.Nous montrons que ces deux problèmes sont reliés par la transformation vertex-face et exhibent une structure algébrique commune, l’algèbre de réflexion dynamique. Nous nous intéressons aux aspects mathématiques de cette algèbre dans le cas elliptique général,et nous introduisons deux classes de ces représentations, la représentation de co-module d’évaluation et sa duale. Nous pensons que cette algèbre est la structure clef pour l’analyse des modèles faces avec bords. En particulier, nous montrons à l’aide de twists de Drinfel’d que leur fonction de partition se représente simplement dans le cas général. Enfin, nous tentons une ’dynamisation’ du modèle à vertex ’Half-Turn-Symmetric’,et nous décrivons sa fonction de partition en termes de représentation d’évaluation de l’algèbre de Yang-Baxter dynamique, et trouvons un ensemble de conditions la déterminantunivoquement. / This thesis is embedded in the general theory of quantum integrable models withboundaries, and the development of associated algebraic structures.We first consider the question of the diagonalization of the XXZ hamiltonian with nondiagonalboundaries. We succeed to find the two sets of eigenstates and eigenvalues of themodel if the boundaries parameters satisfy two conditions.We introduce then a statistical physics model which we refer to be the face model witha reflecting end. Moreover, we compute exactly its partition function and show that it takesthe form of a simple single matrix determinant.We show that these two problems are related through the vertex-face transformationand are solved using a common algebraic structure, the dynamical reflection algebra andits dual. We focus from a mathematical perspective on this algebra in the general ellipticcase. Both the co-module evaluation representation and its dual are introduced. We believethat these structures are the key ingredients for the analysis of face models with boundaries.In particular, using the concept of Drinfel’d twists, we show that the partition function ofthese models has a simple representation in the general case.Finally, we attempt on a ’dynamization’ of the Half-Turn-Symmetric vertexmodel. Wedescribe its partition function in terms of the evaluation representation of the dynamicalYang-Baxter algebra, and find a set of conditions that uniquely determine it.

The thesis is devoted to the study of in-chain impurities in spin 1/2 antiferromagnetic Heisenberg chains (S=1/2 aHC's)---a model which accompanies the research on magnetism since the early days of quantum theory and which is one of the few integrable spin systems. With respect to impurities it is special insofar as an impurity perturbs the system strongly due to its topology: there is no way around the defect. To what extend the one-dimensional picture stays a good basis for the description of real materials even if the chains are disturbed by in-chain impurities is an interesting question which is addressed in this work. For this purpose, Cu Nuclear Magnetic Resonance (NMR) measurements on the cuprate spin chain compounds SrCuO2 and Sr2CuO3 intentionally doped with nickel (Ni), zinc (Zn) and palladium (Pd) are presented. These materials are well known to be among the best realizations of the S=1/2 aHC model and their large exchange coupling constants allow the investigation of the low-energy dynamics within experimentally easily feasible temperatures. NMR provides the unique ability to study the static and dynamic magnetic properties of the spin chains locally which is important since randomly placed impurities break the translational invariance. Because copper is the magnetically active ion in those materials and the copper nuclear spin is most directly coupled to its electron spin, the NMR measurements have been performed on the copper site. The measurements show in all cases that there are changes in the results of these measurements as compared to the pure compounds which indicate the opening of gaps in the excitation spectra of the spin chains and the emergence of oscillations of the local susceptibility close to the impurities. These experimental observations are compared to theoretical predictions to clarify if and to what extend the already proposed model for these doped systems---the finite spin chain---is suitable to predict the behavior of real materials. Thereby, each impurity shows peculiarities. While Zn and Pd are know to be spin 0 impurities, it is not clear if Ni carries spin 1. To shed some light on this issue is another scope of this work. For Zn impurities, there are indications that they avoid to occupy copper sites, other than in the layered cuprate compounds. Also this matter is considered.

We consider integrable boundary states in the Heisenberg model. We begin by reviewing the algebraic Bethe Ansatz as well as integrable boundary states in spin chains. Then a new class of integrable states that was introduced last year by Caetano and Komatsu is described and expanded. We call these states the crosscap states. In these states each spin is entangled with its antipodal spin. We present a novel proof of the integrability of both a crosscap state that is known in the literature and one that is not previously known. We then use the machinery of the algebraic Bethe Ansatz to derive the overlaps between the crosscap states and off-shell Bethe states in terms of scalar products and other known overlaps. / Vi undersöker integrable gränstillstånd i Heisenbergmodellen. Vi börjar med att gå igenom den algebraiska Betheansatsen och integrabla gränstillstånd i spinnkedjor. Sedan beskrivs och expanderas en ny klass av integrabla tillstånd som introducerades förra året av Caetano och Komatsu. Vi kallar dessa tillstånd crosscap-tillstånd. I dessa tillstånd är varje spinn intrasslat med sin antipodala motsvarighet. Vidare presenterar vi ett nytt bevis av integrerbarheten hos både ett tidigare känt och ett nytt crosscap-tillstånd. Sedan använder vi den algebraiska Betheansatsens maskineri för att härleda överlappen mellan crosscap-tillstånden och off-shell Bethe tillstånd i termer av skalärprodukter och andra kända överlapp.

By numerical methods, two models of anisotropic mixed quantum spin chains, consisting of spins of two different sizes, Sa = 1/2 and Sb = 1 as well as Sb = 3/2, are studied with respect to their critical properties at quantum phase transitions in a selected region of parameter space. The quantum spin chains are made up of basecells of four spins, according to the structure Sa − Sa − Sb − Sb. They are described by the XXZ Hamiltonian, that extends the quantum Heisenberg model by a variable anisotropic exchange interaction. As additional control parameter, an alternating exchange constant between nearest-neighbour spins is introduced. Insight gained by complementary application of exact diagonalization and quantum Monte Carlo simulations, as well as appropriate methods of analysis, is embedded in the broad existing knowledge on homogeneous quantum spin chains. In anisotropic homogeneous quantum spin chains, there exist phase boundaries with continuously varying critical exponents, the Gaussian critical lines, along which, in addition to standard scaling relations, further extended scaling relations hold. Reweighting methods, also applied to improved quantum Monte Carlo estimators, and finite-size scaling analysis of simulation data deliver a wealth of numerical results confirming the existence of a Gaussian critical line also in the mixed spin models considered. Extrapolation of exact data offers, apart from confirmation of simulation data, furthermore, insight into the conformal operator content of the model with Sb = 1. / Mittels numerischer Methoden werden zwei Modelle anisotroper gemischter Quantenspinketten, bestehend aus Spins zweier unterschiedlicher Größen, Sa = 1/2 und Sb = 1 sowie Sb = 3/2, hinsichtlich ihrer kritischen Eigenschaften an Quanten-Phasenübergängen in einem ausgewählten Parameterbereich untersucht. Die Quantenspinketten sind aus Basiszellen zu vier Spins, gemäß der Struktur Sa − Sa − Sb − Sb, aufgebaut. Sie werden durch den XXZ Hamiltonoperator beschrieben, der das isotrope Quanten-Heisenberg Modell um eine variable anistrope Austauschwechselwirkung erweitert. Als zusätzlicher Kontrollparameter wird eine alterniernde Kopplungskonstante zwischen unmittelbar benachbarten Spins eingeführt. Die durch komplementäre Anwendung exakter Diagonalisierung und Quanten-Monte-Carlo Simulationen, sowie entsprechender Analyseverfahren, gewonnenen Erkenntnisse werden in das umfangreiche existierende Wissen über homogene Quantenspinketten eingebettet. Im Speziellen treten in anisotropen homogenen Quantenspinketten Phasengrenzen mit kontinuierlich variierenden kritischen Exponenten auf, die Gaußschen kritischen Linien, auf denen neben den herkömmlichen auch erweiterte Skalenrelationen Gültigkeit besitzen. Umgewichtungsmethoden, speziell auch angewandt auf verbesserte Quanten-Monte-Carlo Schätzer, und Endlichkeitsskalenanalyse von Simulationsdaten liefern eine Fülle von numerischen Ergebnissen, die das Auftreten der Gaußschen kritischen Linie auch in den untersuchten gemischten Quantenspinketten bestätigen. Die Extrapolation exakter Daten bietet, neben der Bestätigung der Simulationsdaten, darüber hinaus Einblick in einen Teil des konformen Operatorinhalts des Modells mit Sb = 1.

Ce mémoire étudie le modèle quantique d’Ising-Kawasaki en une dimension. Cette chaîne quantique de spin-1/2 décrit la dynamique de Kawasaki hors d’équilibre d’une chaîne d’Ising classique couplée à un bain thermique. L’Hamiltonien est obtenu pour le cas général désor- donné avec des couplages d’Ising et champs magnétiques non-uniformes. Quand les champs magnétiques sont nuls, la chaîne de spin quantique est stochastique, et dépend des couplages d’Ising normalisés par la température du bain de chaleur. Dans le cas de couplages uniformes, nous donnons les états fondamentaux exacts de la chaîne de spin, ainsi que ses excitations à 1-magnon. Les solutions pour les spectres à deux magnons sont dérivées via une variante de l’Ansatz de Bethe. Dans le régime antiferromagnétique, les états de branche à deux magnons présentent un comportement complexe, notamment en ce qui concerne l’hybridation avec le continuum. L’analyse faite dans ce mémoire, combinée aux études précédentes, suggère que le système manifeste des dynamiques multiples à basse énergie, comme le montre la présence de plusieurs exposants critiques dynamiques. La distribution de l’espacement de l’ensemble des niveaux d’énergie est évaluée en fonction du couplage d’Ising. On conclut que le sys- tème est non-intégrable pour des paramètres génériques, ou de manière équivalente, que la dynamique classique hors équilibre correspondante est ergodique. / We study a quantum spin-1/2 chain that is dual to the non-equilibrium Kawasaki dynamics of a classical Ising chain coupled to a thermal bath. The Hamiltonian is obtained for the general disordered case with non-uniform Ising couplings. The quantum spin chain is stoquastic, and depends on the Ising couplings normalized by the bath’s temperature. Proceeding with uniform couplings, we give the exact groundstates of the gapless spin chain, as well as its single-magnon excitations. Solutions for the two-magnon spectra are derived via a Bethe Ansatz scheme. In the antiferromagnetic regime, the two-magnon branch states show intricate behavior, especially regarding hybridization with the continuum. Our analysis, when combined with previous studies, suggests that the system hosts multiple dynamics at low energy as seen via the presence of multiple dynamical critical exponents. Finally, we analyze the full energy level spacing distribution as a function of the Ising coupling. We conclude that the system is non-integrable for generic parameters, or equivalently, that the corresponding non-equilibrium classical dynamics are ergodic.