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Stable isotopes of oxygen (O18) and hydrogen (H2) are used as proxies of past climates when ice preserved in the polar icecaps. The main assumption when doing paleoclimatic reconstructions using these isotopes is that the isotopic composition of the snow that turned into ice reflect the present temperature of the planet during deposition. In this study, I investigate to what extent the composition of O18 and H2 varies as a function of precipitation. I tested the following hypotheses: i) δO18 and δH2 decreases due to fractionation during orographic fallout, and ii) the electric conductivity in the snow decreases with distance from sea due to fading marine inputs. The hypotheses were tested with field samples gathered along a precipitation gradient from the Norwegian coast to Kiruna, Northern Sweden. To support my first hypothesis, I found a decrease from -9.32% δO18 (-54.85% δH2) to -25.48% δO18 (-109.54 % δH2) due to orographic deposition over the Scandes with a drastic drop in Abisko caused by a rain shadow. Similarly, I found a considerable variation and decreasing trend of conductivity along the precipitation gradient. My study raises awareness that δO18 in snow is in fact dependent on precipitation regimes rather than temperature regimes in this area, which should be considered when interpreting environmental records of δO18 in a paleoclimatic context. Lastly, I suggest further studies targeting the effects of post-depositional processes (melting, sublimation, and anthropogenic influence) on the isotopic composition and conductivity, especially with a changing climate.

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With use of deuterium-labeled isotopes of RRR-and all-rac-α-tocopheryl acetate, the transport of vitamin E in pregnancy was evaluated to determine whether the placenta discriminates between these compounds. Fifteen pregnant subjects were recruited 5 d before delivery to receive 15, 30, 75, 150, or 300 mg vitamin E/d in capsules containing d3-RRR-α-tocopheryl acetate and d6-all-rac-α-tocopheryl acetate (1:1, by wt). Maternal blood was obtained before dosing, at hospital admission, and at parturition. Cord blood samples were obtained at parturition. Deuterium-labeled and unlabeled tocopherol contents were determined by gas chromatography-mass spectrometry in plasma and lipoproteins (chylomicrons, VLDL, LDL, and HDL). Maternal plasma and lipoproteins obtained at delivery had higher concentrations of d3-RRR-α- tocopherol than d6-all-rac-α-tocopherol regardless of the vitamin E dose administered (P < 0.05). Cord plasma at delivery also had higher concentrations of d3-RRR-α-tocopherol than d6-all-rac-α-tocopherol in plasma irrespective of the dose administered (P < 0.05). In lipoproteins isolated from cord blood, tocopherol concentrations were greatest in the HDL fraction (P < 0.05), whereas in maternal blood they were greatest in the LDL fraction (P < 0.05). We conclude that the placental-fetal unit, the fetal liver, or both further discriminate between RRR- and all-rac-α-tocopherol.

In many ore deposits throughout the world, brecciation often accompanies or occurs in association with mineralization (Sillitoe, 1985). Such is the case in the Tintic Mining District (Ag-Pb-Zn) of north-central Utah, where unique breccia features called pebble dikes occur alongside significant mineralization. Pebble dikes are tabular bodies of breccia, which consist of angular to rounded clasts of quartzite, shale, carbonate, and minor igneous rock cemented in a fine-grained clastic matrix. All clasts now lie above or adjacent to corresponding source rocks. Dikes are thin, typically less than 0.3 m wide to as much as 1 m, and can exceed 100 m in length. The average of the largest clast sizes is less than 3 cm but correlates positively with pebble dike width. Contacts are sharp and an envelope of fine breccia surrounds roughly half of the dikes. Pebble dikes are mostly hosted in an Eocene rhyolite lava flow, which displays argillic to silicic alteration when in contact with a pebble dike, but are also hosted in an assortment of folded Paleozoic sedimentary rocks. The dikes show a strong northeast trend in orientation, following a regional fabric of northeast-trending strike-slip and oblique-slip faults.The formation of pebble dikes has been historically attributed to the intrusion of the Silver City Stock, the Tintic District's main productive intrusion (Morris and Lovering, 1979; Hildreth and Hannah, 1996; Kim, 1997; Krahulec and Briggs, 2006). However, pebble dikes are spatially associated with a previously unrecognized porphyritic unit, informally named the porphyry of North Lily, which is texturally, mineralogically, and chemically distinct from the Silver City Stock, and like pebble dikes, is emplaced in northeast-trending plugs and dikes. Pebble dikes show a strong spatial correlation to outcrops of the porphyry of North Lily. Additionally, clasts of the porphyry of North Lily have been found in pebble dikes, while pebble dike quartzite clasts have been found as xenoliths in the porphyry of North Lily. These similarities and interactions suggest simultaneous formation. Low-grade alteration associated with pebble dikes indicates that they formed at elevated temperatures (<150°C). Stable isotope characteristics of rhyolite altered during the emplacement of pebble dikes suggests that the dikes formed in the presence of heated groundwater, with little to no magmatic water association. The overall physical, spatial, and chemical characteristics of pebble dikes of the Tintic Mining District suggest that they formed by the mobilization of breccia in the explosive escape of groundwater that had been heated by the porphyry of North Lily. This escape occurred along pre-existing northeast-trending faults and fractures. Pebble dikes then became pathways for later ore fluids, easing the creation of the district's abundant mineral resources.

Feral horse management has become a subject of significant controversy in the United States. This is because of differing opinions and minimal recent empirical data on feral horses. In recent years, numbers of feral horses have increased due to governmental horse removal restrictions (specifically the Wild Horse and Burro act of 1971). With increasing numbers of feral horses on rangelands, land managers are challenged with identifying the appropriate course of action for satisfying groups with differing opinions. The purpose of this study is to characterize diet consumption through the use of stable isotope dietary analysis (δ15N and δ13C). We did this in order to measure the impact of feral horse forage consumption on rangelands and to propose strategies for improving habitat management and conservation. We obtained tail hair isotopic values from tail hair removed while horses that were held in squeeze chutes following a roundup. Resulting isotopic values were compared to plant isotopic values using plant samples obtained from the geographical areas as the horses in order to characterize diet. Contribution of the various plant species to the tail hair mixture values was determined using the EPA program IsoSource©. Initial analysis of tail hair isotopes demonstrated seasonal variation. During summer months, shrubs (mostly Artemesia spp, and Purshia Tridentate), Elymus elymoides, Juncus balticus, and Festuca idahoensis were the predominantly consumed vegetative species. During fall months, Leymus cinereus and Juncus balticus played a more significant role in feral horse diet. In the winter, shrubs were more heavily consumed along with Poa secunda. Springtime showed a shift towards forb consumption. Changes in seasonal consumption of forages are most likely linked to forage availability as well as equine preference. We analyzed plant metrics (specifically biomass, abundance, and cover) to compare a site with horses present to a site where horses had been removed the previous year and found relatively few differences between the two sites. With nearly all differences we found higher plant production (forage availability) on the site where horses were still present. In riparian areas however, there was more vegetation (specifically Carex rossii, Juncus balticus, and Poa secunda) on the site where horses had been removed. Within riparian areas, only Bromus tectorum (a plant not typically found in riparian areas but characteristic of degraded areas) showed significantly greater amounts of biomass on the site with horses present. Knowledge of plant species consumption will allow land managers greater ability to make scientifically based decisions regarding feral horse population control which is important in determining appropriate management levels of populations.