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Submitted in fulfillment of the requirements of the degree of Master of Applied Science in Biotechnology, Durban University of Technology, 2015. / In light of the world’s declining fossil fuel reserves, the use of microalgal biodiesel has come to the forefront as a potentially viable alternative liquid fuel. The depleting freshwater reserves make the feasibility of this concept questionable. The use of wastewater reduces the requirement for depleting freshwater supplies. This project aimed to determine the viability of municipal domestic wastewater effluent as a substrate for microalgal growth, in order to generate an economical and environmentally friendly source of biofuel. Wastewater effluents from three domestic wastewater treatment plants were characterized in terms of known microalgal nutrients viz., ammonia, phosphate and nitrates. Phosphate concentrations varied throughout the year and were found to be low (< 3 mgL-1) whilst ammonia and nitrate concentrations ranged from 0 to 10 mgL-1 throughout the experimental period. These wastewaters were found to be suitable for cultivating microalgae. The study explored the cultivation of Chlorella sorokiniana on pre- and post-chlorinated domestic wastewater effluent to assess their potential as a medium for high microalgal culture density and lipid production. Post-chlorinated wastewater effluent was found to be superior to pre-chlorinated wastewater effluent, as evident by the higher biomass concentration. This wastewater stream did not contain high concentrations of bacteria when compared to pre-chlorinated wastewater effluent. Nitrogen is an essential nutrient required for regulating the growth and lipid accumulation in microalgae. Cultures growing in post-chlorinated effluent had a lifespan of 18 d. Residual nitrogen in wastewater effluent supported microalgal growth for limited periods. Supplementation using cheap, readily available nitrogen sources was required for optimal biomass and lipid production. Urea, potassium nitrate, sodium nitrate and ammonium nitrate were evaluated in terms of biomass and lipid production of C. sorokiniana. Urea showed the highest biomass yield of 0.216 gL-1 and was selected for further experimentation. Urea concentrations (0–10 gL-1) were assessed for their effect on growth and microalgal physiology using pulse amplitude modulated fluorometry. A concentration of 1.5 gL-1 urea produced 0.218 gL-1 biomass and 61.52 % lipid by relative fluorescence. Physiological stress was evident by the decrease in relative Electron Transport Rate from 10.45 to 6.77 and quantum efficiency of photosystem II charge separation from 0.665 to 0.131. Gas chromatography analysis revealed that C16:0, C18:0, C18:1, C18:2 and C18:3 were the major fatty acids produced by C. sorokiniana. Wastewater effluent has been considered an important resource for economical and sustainable microalgal biomass/lipid production. The study showed that C. sorokiniana was sufficiently robust to be cultivated on wastewater effluent supplemented with urea. The results indicate that supplemented wastewater effluent was an acceptable alternative to conventional media. Using a relatively cheap nitrogen source like urea can certainly improve the techno-economics of large scale biodiesel production.

Excess Fluoride in drinking water is a cause for concern in several countries in the world. Various techniques have been developed to mitigate the harmful effects of fluoride. In the present work, a combined alum and activated alumina (AA) process has been investigated. Tap water with sodium fluoride dissolved in it to produce a solution having a fluoride concentration of 5 mg/L was used as the feed. It was found that pretreatment with alum extends the time required for the regeneration of the AA column. The volume of water treated increased by 89% compared to AA process alone. Though the regeneration of the AA column has been well documented, subtle issues have ot been reported. The disposal of regeneration effluent is a concern in adsorption-based processes. This study aims to examine some of the issues involved in the regeneration of the AA column such as disposal of effluent, and the quantity of acid and alkali required. The regeneration effluent from the combined process, which had a fluoride concentration of 10-16 mg/L was treated in a solar still. The distillate from the still had a fluoride concentration of 2-3 mg/L, which is much lower than the concentration of the regeneration effluent. The cost of treatment decreased with each regeneration cycle and after four regenerations the cost was Rs 0.5/L of treated water. The volume of water treated after four regenerations was 307 L/Kg of AA. Studies were also done using field water from Banavara, Hassan district, Karnataka, which had a fluoride concentration of 3,0-3.5 mg/L. The combined process successfully produced treated water having an acceptable fluoride concentration. After one regeneration cycle, the operating cost was Rs. 1/L of treated water. Studies have also been conducted on a point-of-use water filter containing a bed of AA pellets. The filter was provided by an organization called TIDE. The present results appear to suggest that a column with a smaller diameter than the TIDE filter has a better removal capacity. Ceramic candles are widely used for water filtration as they are readily available and inexpensive. Hence they are suitable for household water treatment purposes. In the present work, ceramic candles have been impregnated with nano-size alumina and nano-size magnesium oxide and tested for their defluoridation capacity. The nanoparticles were generated in situ in the pores of the candle by solution combustion synthesis. It has been found the candle impregnated with nano-size magnesium oxide has a higher defluoridation capacity than nano-size alumina. Estimation of the particle size in the samples of treated water did not give conclusive evidence for the presence or absence of nanoparticles. The volume of water treated was low and the cost of treatment was high (Rs. 12/L for the candle impregnated with MgO). Hence such candles are unsuitable for defluoridation. Batch adsorption has been employed to measure the adsorption capacity of adsorbents. A model to capture the overall picture of the batch adsorption process, obtaining the kinetic and transport parameters involved has been developed. The mathematical model takes into account external mass transfer resistance, intraparticle diffusion, adsorption, and desorption. The equilibrium adsorption data was fitted using the Langmuir isotherm. The governing equations were solved using a finite difference technique known as the Laasonen method. The parameters were estimated by fitting two sets of data using a MATLAB function. The values estimated suggest that the adsorption process may not be diffusion-limited, in contrast to the assumption commonly used in the literature. The estimated parameter values were used to predict the concentration profiles for the other data sets. It was found that predicted and measured profiles agreed reasonably well.

Turkey has very different geomorphologic, hydrologic and climatic conditions, so the runoff coefficient should be different from one basin to another. But only one constant value, which is 0.37, is being used for all the basins in Turkey. In this thesis, monthly, seasonal and annual runoff coefficients of 48 sub-basins in western and southern part of Anatolia are determined by using synchronous and average rainfall, runoff data of 26 year record period. Their temporal and spatial distributions are investigated. The relationship between the basin parameters and the runoff coefficient are also examined. Some of the basins have unrealistic large runoff coefficients, therefore excluded from the analyses. The basin boundaries and parameters are determined by using Geograhic Information System (GIS), and areal average precipitations are found by a program written in visual basic language that uses ArcObjects. The Box-Cox transformed data are used in regression analysis. There are a number of dams in the region, which affect the natural flow. Such streams are found and their sub-basins are not used in the analyses. The results revealed that there is not a strong the relationship between the basin parameters and annual and seasonal runoff coefficients for the whole region, but there are significant relations between them for some basins.

Dissolved oxygen refers to the mass of oxygen that is contained in water. The concentration of dissolved oxygen is an important indicator of the environments water quality. The presence of oxygen in water is desirable therefore it is a positive sign; whereas the absence of oxygen is a sign of severe pollution. An adequate supply of dissolved oxygen is important for waste water treatment processes. Many naturally occurring biological and chemical processes use oxygen, thereby diminishing the dissolved oxygen concentration in the water. The physical process of oxygen transfer or oxygen absorption from the atmosphere acts to replenish the used oxygen. This process has been termed aeration. Aeration is the primary requirement of the biological treatment of water and wastewater treatment. As reported in the literature, the aeration process consumes as much as 60-80% of total power requirements in wastewater treatment plants. Therefore, it is necessary that the design and operation of aeration process should be economized in terms of their energy efficiency. The performance of surface aeration systems is rated in terms of their oxygen transfer rate; hence the choice of a particular surface aeration system depends on its performance and efficiency of oxygen transfer rates. Oxygen transfer rate and the corresponding power requirement to rotate the rotor are very vital parameters for the design and scale-up of surface aerators. Basically two types of operation are in use for surface aeration systems – batch operation and continuous operation. Batch operation involves a single vessel which is filled, aerated then completely emptied. Continuous operation method of operating a biological treatment plant is characterized by a steady input stream (in terms of chemical and biological composition and flow rate, when flow and concentration equalization is practiced), steady process conditions during the treatment steps and by a fairly consistent flow of treated material with only little variation in its composition. The work presented in this thesis consists of two parts. The first one deals with the experimental investigations on the three types of batch surface aeration tanks. A comprehensive design analysis has been worked out and presented on these types of surface aeration systems. In the second category, experimental investigations have been carried out extensively on continuous flow surface aeration systems of different sizes. Analysis has led to the formulation of optimal geometric dimension and the simulation criteria for the design purposes. As far as the first category of investigations is concerned, a substantial work has been reported on batch surface aerators on various issues, during the past several years. Still, a general methodology to scale up or scale down the process phenomena is lacking. In the present work, experiments were done on different shaped batch surface aeration system for generalizing or devising the scale up and scale down criteria for oxygen transfer coefficient and power consumption. Present work through experimental observations established that unbaffled circular tanks are more energy efficient than baffled when used as surface aerator. Power consumption in surface aeration systems is characterized by a fundamental non-dimensional parameter named power number. This number relates drag force to the inertial force in fluid flow system. Power number scaling up of unbaffled surface aerators of square, circular and rectangular shaped tanks is one of the most important contributions of the present work. Design charts have been developed for all the three shape of tanks for the installation as the batch surface aeration systems. Based on the experimental analyses in the present work, it was found that circular shape is the most efficient than any other shape and it is also established that generally a number of smaller sized tanks were more economic and efficient than using a single big tank while aerating the same volume of water. Based on the energy economy analysis, present work suggests the optimal speed range of batch systems of different shaped surface aeration tanks. Different sized rectangular aeration tanks with different aspect ratios (that is length to width ratio) were tested along with a series of square and circular tanks for comparing their relative performances. Present work by doing experiments answered this fact and found that square tank (aspect ratio =1) was more efficient than any other aspect ratio rectangular tanks. Vortexes are inherently present in any type of unbaffled tanks. Present work analyzed the vortex behavior of unbaffled surface aeration systems to determine the critical impeller speed in unbaffled batch surface aeration systems at which oxygen transfer rates are more. The second part of the present work establishes the optimal geometrical parameters of a continuous flow surface aeration systems. These types of operations were found to be least reported in the available literature and there appears to be of no report in the literature on optimal geometrical parameters. Extensive experimental work is reported in the present thesis on the establishment of the optimal geometrical parameters of continuous flow surface aeration systems. From there, simulation criteria are established by maintaining optimal geometrical similarity in different sized continuous flow surface aeration tanks; so that the scale up or scale down criteria can be applied to predict oxygen transfer rates and power number.

Shortage of drinking water in most parts of the world has been a growing concern in recent times. The situation has been getting worse in underdeveloped and developing countries due to sudden explosion in population growth and the growth in the industries. The natural resources for potable water are limited and unless a feasible solution is obtained in the near future, the ‘concern situation’ may turn into a ‘panic situation’. A possible solution for the shortage in drinking water is to use water from inexhaustible sources such as oceans and seas and make it potable using desalination process. However, the process of desalination is an energy intensive process which the poor countries can not afford. In recent times, the cost of fossil fuels has been skyrocketing. With the crude oil costing more than Rs.5200 (US$120) a barrel as on September 2008, even the rich countries like USA and the countries in the European Union are feeling the pinch of the energy cost. Alternate energy sources such as solar, wind, geo-thermal, hydrogen etc., have become the order of the day. These sources are renewable and are environmental friendly. More than one third of the populations of the world live in coastal areas. These areas get abundant amount of solar energy throughout the year. Utilization of this energy in desalination process would solve drinking water problem to a very great extent. However, construction of centralized desalination plants requires large amount of capital which the poor countries can ill-afford. An alternate solution would be to construct decentralized smaller plants that would require smaller capital to construct and easier to maintain. If the energy requirement is tapped from renewable sources such as solar, then the operational cost also becomes affordable for the poor countries. By taking care of the water requirement of the coastal areas through this process, one may save large amounts of money in transporting potable water from interior areas to the coastal areas. There would be enough water for the people living in the interior areas. The water bed level in the interior areas would gradually increase, thereby reducing the drinking water concerns significantly. In this thesis, a small scale stand alone power generation system for the desalination process is proposed that is suitable to provide clean potable water from sources such as sea water or brackish water. Solar energy is proposed as a source of energy for the proposed desalination system. This source is available in plenty in arid and semi-arid areas. It is free and is also friendlier to the environment. It is proposed to use solar energy in thermal form to obtain energy equivalent of ‘latent heat of vaporization’ for the vaporization process and in electrical form for operating the dc machines and electronic control units that are integral parts of the desalination system. The proposed desalination unit can be built as small as possible even to feed a single household’s requirement and hence can be conceptualized as decentralized units. These units would require considerably less capital to build, and would require minimum maintenance. The desalination process is based on flash evaporation wherein a heated liquid is subjected to a pressure reduction by passing through a throttling device resulting in an initially superheated state. In the proposed desalination process, the traditional flash evaporator is extended to include continuous dynamic pressure modulation to obtain an optimal flow rate for a specified energy input. The cost function or the performance index for optimization is defined as the ratio of flow rate to the energy spent. The optimal flow rate occurs at a specific chamber pressure for a given inlet water temperature. By operating at optimal pressure, significant energy is saved for a specific flow rate. This principle is validated experimentally and the results are presented and discussed in the thesis. This proposed scheme along with hybrid energy input will prove to be an attractive solution for community drinking water problem. A system needs to have a mathematical representation in order to predict the dynamic behavior of the system. This thesis proposes the bond graph method of modeling the physical system wherein the energy flow across the electrical, thermal and the hydraulic domains are included. A system may comprise of several subsystems and the energy flow in each subsystem may be in a different domain. A desalination system is such a system wherein the energy flow in subsystems is in different domains such as electrical, thermal and hydraulics. The bond graph approach is best suited for modeling of such systems where the power/energy flow across domains can be easily and seamlessly integrated. The thesis proposes a fifth order dynamic model of a single stage flash evaporation with pressure modulation using the bond graph approach. The proposed model incorporates the effects of chamber pressure variation, the entropy flow from the chamber due to conduction, convection, radiation and also the thermal dynamics of the water bodies in the evaporation, condensation and collection chambers. The proposed model is simulated in MATLAB/Simulink environment. The simulation results are compared with the experimental results to validate the model. This proposed model can be used for both analysis and synthesis of a desalination system. The desalination system is a complex system wherein multiple energy domains are involved. The thesis presents a systematic process for the design of the desalination system. Design of the desalination system involves design of multi domain subsystems. The design becomes much more complex if the energy source to run the system is solar/ hybrid solar based. The energy budget has to be carefully evaluated considering the worst case conditions for the availability of solar energy. Hence, the information on the quantum of solar energy available at any location is a critical parameter needed for design of the desalination system. A generic method of developing a solar insolation model for a specific region such as the Indian sub-continent is proposed in this thesis along with the validation of the model by comparing measured value with the values that are obtained from the model. As the insolation model is dependent on the water vapor content in the vertical column at the location, the methodology is further applied to develop a model for estimating the precipitated water vapor content in a vertical column for any location. The model is validated by comparing the computed values to the measured values. The thesis further presents the design and selection of the balance of the system. The selection of the balance of the system includes sizing of solar thermal plate collectors such as flat plate for pre-heating and paraboloid for vaporization, solar PV panels for operating pumps, actuator and control units, and battery for backup source for night loads and during ‘no-sun days’, criteria of selecting centrifugal pump for circulating condensation water, vacuum pump for dynamic pressure modulation and selecting linear actuator for Sun tracking of the paraboloid concentrator. A discussion on the electronic circuits used in the control scheme is presented in this thesis. This includes the circuit for maximum power point tracking, circuit for DC-DC conversion, circuit for pressure modulation, circuit for speed control of linear actuator, and finally the circuit for water level limiter. A discussion on the life cycle costing is also presented in this thesis. This is an important parameter that refers to the accumulated worth of all the costs related to building and operating the desalination plant during its life span. It is emphasized that the objective of the design process is to minimize the life cycle cost while meeting other performance requirements. Thus, life cycle costing is an essential part of the design cycle. The design methodology and the approach used to design the desalination system are implemented in the form of a toolbox in the MATLAB environment. The various functions of the toolbox are highlighted by a detailed step by step presentation of the design modules in the thesis. The modules form the components of the design toolbox for designing the proposed desalination system.

Computerized data visualization and analysis tools, especially Geographic Information Systems (GIS), constitute an important part of today&amp / #65533 / s water resources development and management studies. In order to obtain satisfactory results from such tools, accurate and comprehensive hydrography datasets are needed that include both spatial and hydrologic information on surface water resources and watersheds. If present, such datasets may support many applications, such as hydrologic and environmental modeling, impact assessment, and construction planning. The primary purposes of this study are production of prototype national hydrography and watershed datasets for Turkey, and development of GIS-based tools for the analysis of local water quality and quantity data. For these purposes national hydrography datasets and analysis systems of several counties are reviewed, and based on gained experience / 1) Sub-watershed boundaries of 26 major national basins are derived from digital elevation model of the country by using raster-based analysis methods and these watersheds are named according to coding system of the European Union, 2) A prototype hydrography dataset with built-in connectivity and water flow direction information is produced from publicly available data sources, 3) GIS based spatial tools are developed to facilitate navigation through streams and watersheds in the hydrography dataset, and 4) A state-of-the art GIS-based stream flow and water quality data analysis system is developed, which is based on the structure of nationally available data and includes advanced statistical and spatial analysis capabilities. All datasets and developed tools are gathered in a single graphical user-interface within GIS and made available to the end-users.

In this thesis the impact of the Atat&uuml / rk Dam on social and environmental aspects of the Southeastern Anatolia Project has been discussed in terms of planning and policy making, institutional arrangements, infrastuctural development and human resources development. In order to analyse the impacts of Atat&uuml / rk Dam data related to several components are collected. These components can be listed as resettlement, land acquisition and land consolidation, education, health, gender issues. The results show that the Atat&uuml / rk Resettlement has been done involuntarily. The people mostly have their compensation. However the management abilities of the resettlers for the compensations were poor. Generally the Southeastern Anatolia Project as a large scale multi sectoral projects have positive impacts on the literacy ratio and health standards. Actually the social and environmental aspects of this kind of large scale projects are difficult to predict and measure. Therefore reasonable studies on prediciting the problems related to the environemental and social issues and producing sufficient solutions become more and more important day by day. The Southeastern Anatolia Project becomes an important example for similar projects by considering its both positive and negative impacts

This study is part of an NRF sponsored research project entitled “Neotectonics and its applications for the exploration of groundwater in the fractured Karoo aquifers in the Eastern Cape” under the NRF Niche area of Water Resources Management and Sustainable Development in the Eastern Cape Province. The identification of relatively highly productive wells in the Karoo fractured aquifers is extremely difficult. This study aims to identify neotectonic zones and lower stress fields, and apply the results to groundwater exploration in the Eastern Cape Province. The methodologies adopted in this study include: a comprehensive literature review, extensive field mapping and investigation such as road cuts, sampling for laboratory studies, examination of seismic data, study of hot and ordinary springs, and interpretation of aerial photography and satellite images. Three main neotectonic belts were identified in the Eastern Cape (southern neotectonic belt, northern neotectonic belt and eastern neotectonic belt) based on literature review and field interpretations. The southern neotectonic belt (from the Cape Fold Belt to the lower Beaufort Group boundary) is characterized by the reactivation of the Coega-Bavianskloof and Sauer faults, the presence of a hot spring near Fort Beaufort, the slickenlines and discrete slickenlines and specifically the seismic events that were recorded in the Eastern Cape from 1850 to 2007. In this southern neotectonic belt the remote sensing has also revealed the presence of the Fort Beaufort fracture, the quartz veins seen in some dolerites and the different vegetation types along it may indicate that this fracture is possibly a fault; moreover the Quaternary sediments and weathered dolerites indicate that the Fort iii Beaufort fracture is characterized by groundwater circulation and accordingly is a good target for groundwater exploration, this fracture is a post-Karoo structure and possibly a neotectonic feature. In addition, the kaolin deposit, chiefly developed in the Dwyka tillite near Grahamstown is clearly controlled by neotectonic fracture zones. The northern neotectonic belt near the country of Lesotho is marked by the presence of the Senqu seismotectonic regime and hot springs. The Quaternary Amatole-Swaziland (formerly Ciskei-Swaziland) axis of uplift makes the eastern part of the province the third neotectonic zone, the asymmetric meanders of the Mbashe river in the vicinity of Qunu near Mthatha derived possibly from this Quaternary uplift; this asymmetric feature of meanders implies that the river has tried to maintain stability of its valley where tilting occurred. Within these neotectonic belts the central part of the Eastern Cape may be considered a static and inactive belt. A northwesterly trend for the maximum principal compresssional stress predominates in the Eastern Cape and is correlated with the present major structural control of the province. The current stress regime determination was derived from faults, joints and quartz veins only on kaolin deposits. Systematic joints reflect regional tectonic stress trajectories at the time of fracturing. Discharge rates of groundwater from boreholes as provided by the Department of Water and Forestry were used to confirm and predict water exploration targets. The region of Tabankulu (near Kwazulu Natal) in the northern neotectonic belt has remarkable discharge rates of groundwater (11.1 l/s, 4.65 l/s, 6.49 l/s, 42 l/s). The region of Mthatha, nearly surrounding the Amatole-Swaziland axis (former Ciskei-Swaziland iv axis) of uplift which might have generated some new faults, has a number of springs. These two regions should serve as case studies for future research. Apart from these two regions, two others regions can be considered as case studies for future groundwater exploration targets: the Bath Farm hot spring near the Fort Beaufort neotectonic fault and the vicinity of what is known as the Fort Beaufort fracture near Teba and Cimezile villages 20km north west of Fort Beaufort. It is concluded that the study of neotectonics and stress fields may be a useful tool for groundwater exploration in the Karoo fractured aquifers in the Eastern Cape, and in similar regions elsewhere in South Africa and in Africa.

This dissertation reflects on both the analysis of quality indicators for the identification of competencies and on the classification tools used to place German further vocational training courses into existing qualification frameworks, using the example of the field of engineering and study path “Supply Engineering”. The objective of this dissertation is to develop a competence model for “planning competence” that allows evaluation and classification of a range of competencies. This planning competence is determined by the categories “complexity”, “cross-linkage”, and “quality” of the process followed in the creation of certain planning documents. Of special focus in this dissertation is the planning competence and its (sub-)competencies exhibited by the college graduates in the study path “Supply Engineering” at the State College for Construction, Business and Logistics (State College) in Gotha / Thuringia. This planning competence ought to be evaluated, classified and placed into a qualification frame such as the European Qualification Frame (EQF). In order to do this, quality indicators are developed and applied to tender documents for a drinking water supply system in a kindergarten, which were presented by the college graduates as their final project. Using these indicators it is possible to identify the quality of these documents and consequently identify the planning competence of the future planning engineer. The quality of the plans is evaluated as a category and they are also looked at to see if they have a certain complexity. This category of complexity is defined as interconnected layers within a system, for example, regarding hot and cold water systems or the circulation water system. Cross-linkage is the third category, which determines both the planning of the project and the resulting planning competence. This cross-linkage is defined as the connection of the drinking water system to third parties, for instance to other planning projects, planning partners, or other technical systems such as heating or electrical systems. In addition, surveys among college graduates from the State College Gotha, their employers, and college alumni, shall indicate and bring to light certain competencies necessary for the planning of above mentioned systems and work as a planning engineer. Combining both the identified competencies of the exploration process using the above mentioned quality indicators and the results of the surveys, the author makes suggestions on how to classify and place the study path “Supply Engineering” at the State College Gotha / Thuringia and other German further vocational training courses into the EQF.