In this study eddy covariance was used to measure sensible heat, latent heat, and carbon dioxide fluxes for the months of August, September, and October of 2009 within the roughness sublayer (RSL) of the urban center of Portland, OR. Vehicle traffic and solar radiation were also measured for the month of October. Flux measurements were compared with measurements from other urban areas as a test of reasonableness. CO₂ fluxes were nearly always positive and were strongly correlated with the weekday diurnal traffic cycle. CO₂ fluxes averaged 6.6 μmol/m^²s, which is less than other published measurements in urban areas. Sensible and latent heat fluxes followed the expected diurnal profile associated with solar radiation. Average sensible heat flux decreased as the season changed from summer to fall, moving from an average of 39 W/m^² in August to 12 W/m^² in October. A corresponding increase in latent heat flux was observed during this period, changing from an average of 10 W/m^² in August to 17 W/m^² in October. Heat flux behavior and amplitude was consistent with other urban measurements, though amplitude varies considerably from city to city. Stationarity was shown to positively influence measured CO₂ fluxes, but to have little effect on measured heat fluxes. Preliminary comparisons of October sensible heat and CO₂ fluxes to an inventory-based estimate of vehicle emissions indicate that eddy covariance measurements underestimate the true fluxes by 50%.

No description available.

No description available.

The adhesion of coatings is of high importance in the coating industry and a more thorough understanding of adhesion behavior is required. In this thesis work, seven parameters affecting adhesion of silane-modified poly(urethane urea) (PUSi) coatings on pretreated steel and aluminum substrates were studied. These parameters include substrate type, dry film thickness (20-30 and 60-70 μm), solid content (40, 60, and 70 wt%), resin ratio between two different types of PUSi (PUSi-A: PUSi-B = 70:30, 50:50, and 30:70 wt ratio), crosslinking density, additive, and curing condition. The different pretreatments of substrates include solvent wiping, sandblasting, phosphating, and galvanizing. A commercial paint product (‘yellow topcoat’) was used as a reference for the study of substrates and additives. Several formulations of clearcoat, prepared from the same PUSi resins as the commercial paint product, were mainly used in every experiment. The obtained coatings were tested for their adhesion properties using cross hatch adhesion test, bending test, and humidity resistance test. The film hardness and thermo-mechanical properties were evaluated with König pendulum hardness test and Dynamic Mechanical Analysis (DMA), respectively. Surface energies of all substrates were analyzed with Contact Angle Measurement (CAM). The PUSi-A and PUSi-B resins used in the coating formulations were characterized with Differential Scanning Calorimetry (DSC), Size-Exclusion Chromatography (SEC), and Fourier Transform Infrared Spectroscopy (FT-IR). The results showed a correlation between poor adhesion properties and the relatively low surface energies of some substrates, namely cold-rolled steel (CRS), industrial ACE aluminum, and standard Q aluminum. The use of silane-functional crosslinking agent and silane adhesion promoters in the coatings has greatly enhanced adhesion. The increase in film hardness via increased crosslinking density also did not hinder the adhesion due to the presence of silane groups in the crosslinker. Additionally, increased time and temperature during curing showed positive effects. However, the variation of resin ratio, solid content, and film thickness did not offer significant adhesion improvement in this study. / Adhesionsegenskaperna hos ytbeläggningar är av stor betydelse i färg- och lackindustrin och en djupare förståelse av vidhäftning är av stor betydelse. I detta uppsatsarbete studerades sju parametrar som påverkar vidhäftning av silanmodifierad poly(uretan-urea) (PUSi)-beläggningar på stål- och aluminiumsubstrat. Dessa parametrar inkluderar substrattyp, torr filmtjocklek (20-30 och 60-70 μm), torrhalt (40, 60 och 70 viktprocent), mängdförhållandet mellan två olika typer av PUSi (PUSi-A: PUSi-B = 70:30, 50:50 och 30:70 viktprocent), tvärbindningsdensitet, tillsatsmedel och härdningsbetingelser. Förbehandlingen av substraten inkluderar lösningsmedelsavtorkning, sandblästring, fosfatering och galvanisering. En kommersiell ytbehandlingsprodukt innehållandes gula pigment (gul topplack) användes som referens. Flera formuleringar av klarlack, framställda av samma PUSi-hartser som den kommersiella produkten, användes i det experimentella arbetet. Beläggningarna testades med avseende på deras vidhäftningsegenskaper med ’cross-hatch’-test, böjningstest och fuktbeständighetstest. Filmhårdhet och termomekaniska egenskaper utvärderades med König pendelhårdhetstest respektive Dynamisk Mekanisk Analys (DMA). Ytenergier för alla substrat analyserades med kontaktvinkelmätning (CAM). PUSi-A- och PUSi-B-hartserna som användes i ytbeläggningarna karaktäriserades med Differential Scanning Calorimetry (DSC), Size-Exclusion Chromatography (SEC) och Fourier Transform Infrared Spectroscopy (FT-IR). Resultaten visade en korrelation mellan dålig vidhäftning och låga ytenergier för vissa underlag, främst kallvalsat stål (CRS), industriellt ACE-aluminium och standard Q-aluminium. Användningen av silan-funktionell tvärbindare och en silan-baserad primer förbättrade vidhäftningen avsevärt. Ökningen i filmhårdhet genom högre tvärbindningsdensitet resulterade inte i sämre vidhäftning eftersom tvärbindaren innehåller silan-grupper vilket bidrog till att upprätthålla vidhäftningen. Längre tid och högre temperatur vid härdning gav generellt bättre vidhäftning, liksom tillsats av urea. Att variera mängden bindemedel, torrhalt eller filmtjocklek gav inte någon signifikant påverkan på vidhäftning i denna studie.

In this dissertation physical phenomena relevant to (i) an interface formed between two fluids and a solid phase (wetting line) and (ii) an interface between three fluids (triple contact line) were investigated. In the former case, the wetting line (WL) phenomena which encompass the wetting line energy (WLE) or pinning, the wetting line velocity (WLV), and the contact angle hysteresis, were studied using a micropump based on electrowetting on dielectric (EWOD). In the latter case, the interfacial phenomena such as the air film lubrication effect and the liquid free surface deformation were taken into account to explain the dual equilibrium states of water droplets on liquid free surfaces. EWOD was implemented to devise a pumping method for a continuous flow in a microchannel. An active micropump with a simple layout and no moving parts is designed and fabricated which has on demand flow on/off capability. The micropump is based on droplet/meniscus pressure gradient generated by EWOD. By altering the contact angle between liquid and solid using an electric field a pressure gradient was induced and a small droplet was pumped into the channel via a uniform flow rate. A surface tension based propellant method was introduced as a low power consumption actuation method in microfluidic devices. For an initial droplet volume of 0.3µL and a power of 12nW a constant flow rate of 0.02µL/sec was demonstrated. Sample loading on-demand could be achieved by regulating an electric potential. Unexpectedly, the flow rate of the pump was found to be constant in spite of the changes in the droplet’s radius, which directly affects the pump’s driving pressure. iv The WL phenomena were studied in details to unravel the physical concept behind the micropump constant flow rate during the operation. An interesting observation was that the shrinking input droplet changes its shape in two modes in time sequence: (i) in the first mode its contact angle decreases while its wetting area remains constant due to the pinning, (ii) in the second mode the droplet’s WL starts to move while its contact angle changes as a function of its velocity. Contact angles were measured for the droplet advancing and receding WLs at different velocities to capture a full picture of contact angle behavior due to pinning and WLV effects. These results are also relevant to the meniscus inside the channel. The changes on the contact angle caused by the presence of EWOD at the bottom of the channel were studied in detail. The EWOD based micropump was used as a platform to study the contribution of the pinning and WLV effects on its constant flow rate. The effects of the WLE on the static contact angle and the WLV on the dynamic contact angle in the pump operation were investigated. Also the effect of EWOD voltage on the magnitude and uniformity of the micropump flow rate was studied. Dynamic contact angles (as a function of pinning and WLV) were used to accurately calculate the pressure gradient between the droplet and the meniscus and estimate the flow rate. It was shown that neglecting either of these effects not only results in a considerable gap between the predicted and the measured flow rates but also in an unphysical instability in the flow rate analysis. However, when the WLE and WLV effects were fully taken into account, an excellent agreement between the predicted and the measured flow rates was obtained. v For the study of the TCL between three fluids, aqueous droplets were formed at oil-air interface and two stable configurations of (i) non-coalescent droplet and (ii) cap/bead droplet were observed. General solutions for energy and force analysis were obtained and were shown to be in good agreement with the experimental observations. Further the energy barrier obtained for transition from configuration (i) to (ii), was correlated to the droplet release height and the probability of non-coalescent droplet formation. Droplets formed on the solid surfaces and on the free surface of immiscible liquids have various applications in droplet-based microfluidic devices. This research provides an insight into their formation and manipulation.

No description available.

Surface energetics play a key role in the delivery of a dry powder inhaler formulation into the lungs, as there must be a sufficient balance of adhesive and cohesive forces to allow optimal lung delivery. In this study, measuring the surface energies of a set of single drug and carrier (budesonide or theophylline with either mannitol or lactose) with different levels of surfactant using Inverse Gas Chromatography, and comparing them to their lung deposition performance using a Next Generation Impactor established a relationship between the two. A 1:10 mixing ratio of budesonide with either carrier was found to have the highest FPF. Coating the carriers with 0.05% sodium lauryl sulphate resulted in a further increase in the FPF when using either budesonide or theophylline as the API, and the same results were seen when a sonocrystallised version of the API was substituted for the micronised form. The calculated IGC values then showed that the highest performing formulations had the lowest dispersive energy and total free surface energy. Furthermore, a trend was observed in the work of adhesion (Wa) and work of cohesion (Wc) for each set of formulations depending on which API was chosen, where for the less polar drug (budesonide) a higher Wa/Wc ratio was associated with the highest formulation performance, and for the more polar drug (theophylline) a smaller Wa/Wc ratio was associated with the highest formulation performance, enabling the estimation of lung performance for a set of single drug and carrier using their surface energy data. / Kuwait’s government and the Ministry of Health of Kuwait

No / The surface energetic parameters of carbamazepine and paracetamol have been studied using inverse gas chromatography modified to produce dry and ambient conditions within the column. The values of the dispersive component of the surface free energy (¿DS) do not change significantly at the increased relative humidity. In contrast the specific component of the free energy of adsorption (-¿GSPA) as measured by polar probes, can either remain constant or decrease by up to 10%, depending on the material and the probe. This indicates that an increase in the relative humidity causes a decrease in the surface energetics of the powder surface. It is proposed that where the water molecules are adsorbing to the same sites as the polar probes, the interaction of these probes with the surface is decreased. To identify these sites, the preferential interaction of each probe, including water, with the drug molecule has been modelled.

No / This article describes how an insight into the chemical and physical cues that affect bacterial adhesion and biofilm formation can provide ideas for creating successful antifouling or antimicrobial surfaces. To facilitate the design of new materials, the role of physical and chemical properties on bacterial adhesion is reviewed. The current approaches to reduce bacterial adhesion to various polymeric surfaces are discussed, as well as how multidisciplinary research on surface design and engineering may have an impact on both fundamental and applied microbiological science and technology.

No / This chapter describes the current approaches to reduce bacterial adhesion to various biomaterial surfaces, focusing on nonfouling surfaces through patterning and hydrophobicity plasma-assisted surface treatment and deposition; incorporation of antimicrobials, antibiotics, antibiofilms, and natural extracts that are either immobilized or released; dual function antimicrobial surfaces; incorporation of nonpathogenic bacteria, bacteriophages, and biofilm dispersal agents but also reduced bacterial adhesion through tissue integration. To facilitate the design of new materials, the role of physical, chemical, and biological surface properties on bacterial adhesion is reviewed in each case, as an insight into the chemical and physical cues that affect bacterial adhesion and biofilm formation can provide ideas for creating successful antifouling or antimicrobial surfaces. The application of these surfaces is explored based on the clinical needs and the market gaps. How multidisciplinary research on surface design and engineering may have an impact on both fundamental understanding of bacterial adhesion to biomaterials and applied biomaterial science and technology is finally discussed.