Made available in DSpace on 2016-03-15T19:37:53Z (GMT). No. of bitstreams: 1 Marcio Ribeiro Gastaldi.pdf: 1118514 bytes, checksum: 0da632ad9d5d56b0c1ab1df75e83eee3 (MD5) Previous issue date: 2007-02-02 / We present the results of a 2-year project to monitor the spectral and temporal variability of Sagittarius A, Centaurus A, OV236 and the Einstein s Ring PKS1830-211 from 2004 to 2006. The observational data were obtained from the Itapetinga Radio Telescope at 22 and 43GHz. The data at 4,8, 8,0 and 14,5GHz for OV236 and PKS1830-211 were taken from the Michigan Radio Observatory. We also obtained previous observations of OV236 and PKS1830-211 at 100 and 230GHz from the Swedish-ESO Sub Millimeter Telescope (SEST), and VLA 23 and 43GHz data for Sgr A*. We estimated parameters such as period, angular size and brightness temperature and applied the Shock Wave Model (MARSHER; GEAR 1985) for OV236. The work we present here results from an international cooperation among Brazil (Itapetinga at 22 and 43GHz), EUA (Michigan at 4,8, 8,0 and 14,5GHz, and the VLA at 23 and 43GHz) and Finland (Metsähovi at 90GHz). / Este trabalho mostra o estudo da variabilidade temporal e espectral de Sagittarius A, Centaurus A, OV236 e do anel de Einstein PKS1830-211 em campanhas de observação mensais realizadas de janeiro de 2004 a outubro de 2006. Os dados observacionais foram obtidos através do Rádio-Observatório do Itapetinga nas freqüências de 22 e 43GHz. Os dados em 4,8, 8,0 e 14,5GHz para OV236 e PKS1830-211 foram obtidos do Rádio-Observatório de Michigan. Também foram utilizados dados do SEST para OV236 em 100 e 230GHz, e dados do VLA em 23 e 43GHz para Sgr A*. Foram feitas estimativas de período, variação angular e temperatura de brilhância. O modelo de Marscher e Gear (1985) foi aplicado a OV236. Este é um trabalho de cooperação internacional entre Brasil (Itapetinga em 22 e 43GHz), Estados Unidos (Michigan em 4,8, 8,0 e 14,5 GHz e VLA em 23 e 43GHz) e Finlândia (Metsähovi em 90GHz).

Este trabalho teve como objetivo principal analisar, em condições de campo, o efeito de lâminas de irrigação e de doses de nitrogênio sobre o comportamento espectral da cultura do feijão, a partir de medidas de reflectância hiperespectral, na faixa de 350 a 1150 nm, e da correlação entre os parâmetros biofísicos e as variáveis agronômicas da cultura, nessas condições. O experimento foi conduzido na área experimental de Agricultura Irrigada da Fazenda Areão, sob a responsabilidade do Departamento de Engenharia Rural da Escola Superior de Agricultura Luiz de Queiroz DER/ESALQ/USP, localizada no município de Piracicaba, SP, de setembro a dezembro de 2007. O delineamento experimental foi em blocos casualizados com parcelas subdivididas, alocando-se, nas parcelas, os tratamentos relacionados aos níveis de irrigação ((179,5; 256,5; 357,5 e 406,2 mm) e nas subparcelas os tratamentos relativos às doses de nitrogênio (0; 80 e 160 kg ha-1), totalizando doze tratamentos em cada bloco. Como os tratamentos foram dispostos em quatro blocos (repetições), o total de parcelas experimentais foi de 48. As medidas radiométricas de campo foram adquiridas por meio do espectrorradiômetro SPECTRON SE-590, em sete datas, durante o ciclo da cultura. Foram coletados, ainda, a altura das plantas, o índice de área foliar, a produtividade de grãos, o número de grãos por vagem e o número de vagens por planta. Os índices espectrais calculados foram o NDVI e o NB_NDVI. Foi aplicada a remoção do contínuo nos espectros de reflectância para analisar a profundidade da banda e a área da banda de absorção, centrada em 665 nm. O fator água influenciou as variáveis biofísicas (IAF, altura da planta, produtividade, número de vagens por planta e número de grãos por vagem), sendo maiores os valores encontrados nas plantas que receberam maiores quantidades de água. O aumento da dose de nitrogênio não influenciou as variações das variáveis biofísicas, devido, possivelmente, ao processo de lixiviação desse nutriente para as camadas abaixo do sistema radicular da cultura. As análises dos índices de vegetação e dos parâmetros da remoção do contínuo (área e profundidade da banda de absorção) mostraram que as lâminas de irrigação afetaram o comportamento espectral do feijão no comprimento de onda de 665 nm, e que esses parâmetros não foram influenciados pelas doses de N. Os índices de vegetação (NDVI e NB_NDVI) e os parâmetros da remoção do contínuo (a profundidade da banda e a área da banda de absorção) foram eficientes na estimativa do IAF, da altura de plantas e da produtividade de grãos. Durante todo o desenvolvimento da cultura, as melhores correlações entre as variáveis biofísicas e as variáveis espectrais foram observadas nos estádios V4 e R6 de acordo com a variável analisada, sendo, portanto, estes os melhores estádios para monitorar espectralmente a cultura. Diante das metodologias utilizadas, as variáveis biofísicas foram mais bem estimadas pelo índice NB_NDVI, nos estádios V4 e R6, quando comparado ao índice NDVI e aos parâmetros da remoção do contínuo (profundidade e área da banda de absorção). / The objective of this research was to analyze the effect of irrigation levels and nitrogen fertilization on the spectral behavior, in the wavelength range of 350 to 1150 nm, of bean crop and the correlation between biophysical parameters and agronomical variables. The experiment was carried on at the Fazenda Areão, located at the University of São Paulo (ESALQ/USP) campus, Piracicaba, São Paulo, Brazil, from September to December, 2007. The experimental design was the randomized blocks, with split plots, with 12 treatments, 4 irrigation levels (179,5; 256,5; 357,5 e 406,2 mm) and 3 nitrogen rates (0; 80 e 160 kg ha-1), and four blocks. The field radiometric data were acquired with the SPECTRON-SE 590 spectroradiometer for seven dates during the crop growing season. Plant height, leaf area index (LAI), grain yield, the pod number per plant and the grain number per pod were also acquired. The spectral indices used were NDVI and NB_NDVI. The continuum removal was applied for the reflectance spectrum, on visible region centered on 665 nm, to analyze the band area and band depth. The irrigation also influenced the biophysical variables, so the largest medium values were observed in the treatments that used the largest irrigation levels. The nitrogen fertilization did not interfere on the biophysical variables, probably due to the leaching process. The vegetation indices and continuum removal analysis showed that irrigation levels affected the spectral behavior of bean crop on 665 nm and this parameters had not been influenced by nitrogen levels. The vegetation indices (NDVI and NB_NDVI) and the continuum removal parameters (band area and band depth) were efficient in the estimate of IAF, plant height and grain yield. During all the crop development, the best correlations between biophysical variables and spectral variables were observed on V4 and R6 stages, according to the variable analized. In face of the methodologies used, the biophysical variables were better estimated by NB_NDVI, on V4 and R6 stages, when compared with NDVI and the continuum removal parameters.

M.Ing. / This dissertation deals with the structural integrity analysis of a low pressure (LP) turbine with transverse cracking. Cracks are initiated in the centre ring keyway of the shaft by a fretting mechanism and propagate during barring operation. The cracks arrest during normal operation when they are still relatively shallow. The aim of the calculations is to predict the transition where cracks start propagating by high cycle fatigue during normal operation of the shaft. Most influencing factors, including continuum mechanics, mathematical modelling, material behaviour, service loads and industry experience, are studied in detail as a precursor to the case study. The calculated results show that the case study is an example where the application of fracture mechanics on the crack-free stress field leads to erroneous results. There is a significant redistribution of stress in the presence of the crack so that the actual stress ratio, as calculated from three dimensional cracked models, varies significantly compared to the crack-free model. Calculated results, together with carefully researched material properties, confirm the postulated crack growth during barring operation and predict limiting crack sizes where high cycle fatigue would ensue during normal operation. The case study concludes that the shaft has a significant remaining life and that it can be returned to service with periodic non-destructive examinations.

The continuum theory of large deformation elasto-plasticity is summarized as far as it is necessary for the numerical treatment with the Finite-Element-Method. Using the calculus of modern differential geometry and functional analysis, the fundamental equations are derived and the proof of most of them is shortly outlined. It was not our aim to give a contribution to the development of the theory, rather to show the theoretical background and the assumptions to be made in state of the art elasto-plasticity.

It has recently been discovered that some, if not all, classical novae emit GeV gamma-rays during outburst, but the mechanisms involved in the production ofgamma-rays are still not well understood. We present here a comprehensive multiwavelength data set-from radio to X-rays-for the most gamma-ray-luminous classical nova to date, V1324 Sco. Using this data set, we show that V1324 Sco is a canonical dusty Fe II-type nova, with a maximum ejecta velocity of 2600 km s(-1) and an ejecta mass of a few x 10(-5) M-circle dot. There is also evidence for complex shock interactions, including a double-peaked radio light curve which shows high brightness temperatures at early times. To explore why V1324. Sco was so gamma-ray luminous, we present a model of the nova ejecta featuring strong internal shocks and find that higher gamma-ray luminosities result from higher ejecta velocities and/or mass-loss rates. Comparison of V1324. Sco with other gamma-ray-detected novae does not show clear signatures of either, and we conclude that a larger sample of similarly well-observed novae is needed to understand the origin and variation of gamma-rays in novae.

The overarching goal of this thesis is to develop a diagnostic and predictive model to quantify the estuarine CO2 dynamics across scales – from catchment to the globe – using an approach that explicitly resolves the strong physical and biogeochemical gradients typically observed in these systems.Chapter 1 provides fundamental definitions and descriptions of estuaries, as well as an assessment of their role in the global carbon cycle. It also raises the specific objectives and research questions tackled in the present study. Chapter 2 presents the rationale behind the novel modelling approach (C-GEM, Carbon-Generic Estuary Model) developed in the framework of this thesis. First, the dominant processes that control the estuarine biogeochemistry in estuaries are discussed in detail. Then, the power of reactive-transport models (RTMs) in understanding and quantifying the estuarine biogeochemical functioning is illustrated on the basis of local modelling studies. Finally, trends in estuarine biogeochemical dynamics across different geometries and environmental scenarios are briefly explored with C-GEM and results are discussed in the context of improving the modelling of estuarine carbon dynamics at regional and global scales. In Chapter 3, a detailed description of C-GEM, both in terms of structure and set-up, is provided and model’s performance is successfully evaluated through comprehensive model-data and model-model comparisons in the macro-tidal Scheldt estuary (BE/NL). In Chapter 4, C-GEM is combined with a generic set of forcing conditions and parameter values to quantify the carbon dynamics (net ecosystem metabolism, CO2 exchange at the air-water interface, carbon filtering capacity) in three idealized estuaries subject to temperate climatic conditions. Their hydro-geometrical characteristics span the wide diversity of estuarine morphological characteristics. Model results are used to upscale the estuarine CO2 dynamics under present-day conditions and to quantify the response of the estuarine filter to future atmospheric CO2, land use and climate change scenarios. In Chapter 5, C-GEM is applied to derive estimations of carbon export and CO2 outgassing from all tidal estuaries discharging in the North Sea. Overall, our results suggest that the estuarine carbon filtering capacity and the contribution of these land-ocean transition systems to the atmospheric CO2 budget might not be as high as previously thought. Finally, a conclusive chapter (Chapter 6) provides a synthesis of the key findings and arguments projected by the present research work. Moreover, recommendations are given in the light of further applications of the modelling approach developed during this thesis. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

Du fait de leurs bonnes propriétés physiques et thermiques et de leur faible coût, les aciers ferrito-martensitiques à 9%Cr sont envisagés comme matériaux de circuits et comme tubes des échangeurs et des générateurs de vapeur pour le prototype de Réacteur Rapide au sodium (RNR-Na) ASTRID. Plusieurs mécanismes existent dans la littérature pour expliquer la formation de la couche d’oxyde duplexe spinelle Fe-Cr/magnétite formée lors de l’oxydation des aciers Fe-9Cr dans différents environnements. Par ailleurs, un endommagement partiel ou total de la couche d’oxyde apparait systématiquement en environnement eau ou vapeur d’eau. Aussi, afin d’apporter des éléments pour une évaluation robuste de ces alliages sur de longues durées, ce travail a eu pour but d’une part d’étudier les cinétiques d’oxydation et d’autre part de comprendre l’ensemble des mécanismes conduisant à l’écaillage de la couche d’oxyde. La première partie de l’étude a consisté à mener des essais d’oxydation à 550°C en milieu vapeur d’eau pure et sous Ar/D2O/H2, avec différentes teneurs en hydrogène et vapeur d’eau. Une simulation, basée sur une résolution analytique, a permis de montrer que le modèle de l’espace disponible proposé dans la littérature pour la croissance de la couche duplexe permet de représenter quantitativement les résultats expérimentaux (cinétique, stœchiométrie, proportion des phases). Le deuxième volet de cette étude a été consacré à l’étude de l’endommagement de la couche d’oxyde lors de sa croissance en milieu vapeur d’eau pure. La rupture de la couche d’oxyde par cloquage puis écaillage a systématiquement lieu au sein de la couche de magnétite. Les pores observés au sein de cette couche apparaissent être des sites d’initiation du phénomène de décohésion. Un modèle en cohérence avec le modèle cinétique a été proposé pour anticiper le lieu de formation des pores. Il repose sur le calcul du flux de fer au sein de la couche d’oxyde en croissance. Il permet d’expliquer quantitativement le lieu de formation des pores par l’accumulation de lacunes de fer au sein de la couche de magnétite dans une zone de plus fort gradient de potentiel chimique. Pour évaluer les contraintes présentes au sein de la couche d’oxyde et impliquées dans l’endommagement de celle-ci, des essais de déflexion d’une lame mince asymétrique ont été réalisés sous différents environnements oxydants à 550°C. Les essais réalisés en milieu humide sous Ar/H2O/(H2) et sous CO2 ont mis en évidence la présence de contraintes de croissance en compression de l’ordre de -150 MPa au sein de la couche d’oxyde lors de l’isotherme. Par ailleurs, la présence d’hydrogène dans le milieu oxydant apparait favoriser la fragilisation de la couche d’oxyde. Une approche numérique a été développée pour simuler les essais de déflexion, en prenant en compte les phénomènes de relaxation par fluage et le caractère multi-strates de la couche d’oxyde. Les principales formes de relaxation des contraintes, viscoplasticité de la couche, signes d’endommagement macroscopique (fissurations), ont ainsi été quantifiées. / In the framework of the development of Generation IV reactors and specifically in the new Sodium Fast Reactor (SFR) project, Fe-9Cr ferritic-martensitic steels are candidates as structural materials for steam generators. Indeed, Fe-9Cr steels are already widely used in high temperature steam environments – like boilers and steam turbines- for their combination of creep strength and high thermal properties. Many studies have been focused on Fe-9Cr steels oxidation behavior between 550°C-700°C.Depending on the oxidizing environment, formation of a triplex (Fe-Cr spinel/magnetite/hematite) or duplex (Fe-Cr spinel/magnetite) oxide scales are reported.. Besides, for long time exposure in steam, the exfoliation of oxide scales can cause serious problems such as tube obstruction and steam turbine erosion. Consequently, this work has been dedicated to study, on the one hand the oxidation kinetics of T91 steel in water vapor environments, and on the other hand, the mechanisms leading to the spallation of the oxide scale. Oxidation tests have been carried out at 550°C in pure water vapor and in Ar/D2O/H2 environments with different hydrogen contents. Based on an analytical resolution, a quantitative modeling has shown that the “available space model” proposed in the literature for duplex oxide scale formation well reproduces both scales growth kinetics and spinel oxide stoichiometry. Then, oxidized samples have been precisely characterized and it turns out that buckling then spalling of the oxide scale is always located in the magnetite layer. Voids observed in the magnetite layer are major initiation sites of decohesion of the outer oxide scale. A mechanism of formation of these voids has been proposed, in accordance with the mechanism of duplex scale formation. The derived model based on the assumption that vacancies accumulate where the iron vacancies flux divergence is maximal gives a good estimation of the location of pores inside the magnetite layer. Then, in order to evaluate stresses involved in the spallation of the oxide scale, deflection tests have been performed in different oxidizing environments at 550°C. Tests carried out in Ar/H2O/(H2) and in CO2 have highlighted the presence of compressive growth strains (around -150 MPa) during isothermal oxidation. Moreover, hydrogen seems to promote the oxide scale embrittlement. A numerical approach has also been developed in order to simulate the deflection test experiment, taking into account different relaxation phenomenon and considering a triplex oxide scale. Hence, stress relaxation by oxide scale viscoplasticity and microfissuration have been quantified.

This dissertation describes efforts to evaluate a recently proposed continuum model for the dense flow of dry granular materials (Jop, Forterre & Pouliquen, 2006, Nature, 441, 167-192). The model, based upon a generalisation of Coulomb sliding friction, is known to perform well when modelling certain simple free surface flows. We extend the application of this model to a wide range of flow configurations, beginning with six simple flows studied in detailed experiments (GDR MiDi, 2004, Eur. Phys. J. E, 14, 341-366). Two-dimensional shearing flows and problems of linear stability are also addressed. These examples are used to underpin a thorough discussion of the strengths and weaknesses of the model. In order to calculate the behaviour of granular material in more complicated configurations, it is necessary to undertake a numerical solution. We discuss several computational techniques appropriate to the model, with careful attention paid to the evolution of any shear-free regions that may arise. In addition, we develop a numerical scheme, based upon a marker-and-cell method, that is capable of modelling two-dimensional granular flow with a moving free surface. A detailed discussion of our unsuccessful attempt to construct a scheme based upon Lagrangian finite elements is presented in an appendix. We apply the marker-and-cell code to the key problem of granular slumping (Balmforth & Kerswell, 2005, J. Fluid Mech., 538, 399-428), which has hitherto resisted explanation by modelling approaches based on various reduced (shallow water) models. With our numerical scheme, we are able to lift the assumptions required for other models, and make predictions in good qualitative agreement with the experimental data. An additional chapter describes the largely unrelated problem of contact between two objects separated by a viscous fluid. Although classical lubrication theory suggests that two locally smooth objects converging under gravity will make contact only after infinite time, we discuss several physical effects that may promote contact in finite time. Detailed calculations are presented to illustrate how the presence of a sharp asperity can modify the approach to contact.

Aims. The aim of this work is to constrain properties of the disk around the archetype FU Orionis object, FU Ori, with as good as similar to 25 au resolution. Methods. We resolved FU Ori at 29-37 GHz using the Karl G. Jansky Very Large Array (JVLA) in the A-array configuration, which provided the highest possible angular resolution to date at this frequency band (similar to 0 ''.07). We also performed complementary JVLA 8-10 GHz observations, Submillimeter Array (SMA) 224 GHz and 272 GHz observations, and compared these with archival Atacama Large Millimeter Array (ALMA) 346 GHz observations to obtain the spectral energy distributions (SEDs). Results. Our 8-10 GHz observations do not find evidence for the presence of thermal radio jets, and constrain the radio jet/wind flux to at least 90 times lower than the expected value from the previously reported bolometric luminosity-radio luminosity correlation. The emission at frequencies higher than 29 GHz may be dominated by the two spatially unresolved sources, which are located immediately around FU Ori and its companion FU Ori S, respectively. Their deconvolved radii at 33 GHz are only a few au, which is two orders of magnitude smaller in linear scale than the gaseous disk revealed by the previous Subaru-HiCIAO 1.6 mu m coronagraphic polarization imaging observations. We are struck by the fact that these two spatially compact sources contribute to over 50% of the observed fluxes at 224 GHz, 272 GHz, and 346 GHz. The 8-346 GHz SEDs of FU Ori and FU Ori S cannot be fit by constant spectral indices (over frequency), although we cannot rule out that it is due to the time variability of their (sub)millimeter fluxes. Conclusions. The more sophisticated models for SEDs considering the details of the observed spectral indices in the millimeter bands suggest that the >29 GHz emission is contributed by a combination of free-free emission from ionized gas and thermal emission from optically thick and optically thin dust components. We hypothesize that dust in the innermost parts of the disks (less than or similar to 0.1 au) has been sublimated, and thus the disks are no longer well shielded against the ionizing photons. The estimated overall gas and dust mass based on SED modeling, can be as high as a fraction of a solar mass, which is adequate for developing disk gravitational instability. Our present explanation for the observational data is that the massive inflow of gas and dust due to disk gravitational instability or interaction with a companion/intruder, was piled up at the few-au scale due to the development of a deadzone with negligible ionization. The piled up material subsequently triggered the thermal instability and the magnetorotational instability when the ionization fraction in the inner sub-au scale region exceeded a threshold value, leading to the high protostellar accretion rate.

Shape memory alloys (SMAs) are materials that show reversible, thermo-elastic, diffusionless, displacive (solid to solid) phase transformation, due to the application of temperature and/ or stress (/strain). Among different SMAs, NiTi is a popular one. NiTi shows reversible phase transformation, the shape memory effect (SME), where irreversible deformations are recovered upon heating, and superelasticity (SE), where large strains imposed at high enough temperatures are fully recovered. Phase transformation process in NiTi SMA is a very complex process that involves the competition between developed internal strain and phonon dispersion instability. In NiTi SMA, phase transformation occurs over a wide range of temperature and/ or stress (strain) which involves, evolution of different crystalline phases (cubic austenite i.e. B2, different monoclinic variant of martensite i.e. B19', and orthorhombic B19 or BCO structures). Further, it is observed from experimental and computational studies that the evolution kinetics and growth rate of different phases in NiTi SMA vary significantly over a wide spectrum of spatio-temporal scales, especially with length scales. At nano-meter length scale, phase transformation temperatures, critical transformation stress (or strain) and phase fraction evolution change significantly with sample or simulation cell size and grain size. Even, below a critical length scale, the phase transformation process stops. All these aspects make NiTi SMA very interesting to the science and engineering research community and in this context, the present focuses on the following aspects. At first this study address the stability, evolution and growth kinetics of different phases (B2 and variants of B19'), at different length scales, starting from the atomic level and ending at the continuum macroscopic level. The effects of simulation cell size, grain size, and presence of free surface and grain boundary on the phase transformation process (transformation temperature, phase fraction evolution kinetics due to temperature) are also demonstrated herein. Next, to couple and transfer the statistical information of length scale dependent phase transformation process, multiscale/ multiphysics methods are used. Here, the computational difficulty from the fact that the representative governing equations (i.e. different sub-methods such as molecular dynamics simulations, phase field simulations and continuum level constitutive/ material models) are only valid or can be implemented over a range of spatiotemporal scales. Therefore, in the present study, a wavelet based multiscale coupling method is used, where simulation results (phase fraction evolution kinetics) from different sub-methods are linked via concurrent multiscale coupling fashion. Finally, these multiscale/ multiphysics simulation results are used to develop/ modify the macro/ continuum scale thermo-mechanical constitutive relations for NiTi SMA. Finally, the improved material model is used to model new devices, such as thermal diodes and smart dampers.