The means of communication in oceanic environments is currently dominated by sonar. Although it is reliable for long-distance transmission, the vision of internet of underwater things (IoUT) requires an alternate means for high-data-rate transmission. It is also envisaged that a networked underwater and above-water objects, such as sensor nodes, and autonomous underwater vehicles will benefit seafloor exploration. The use of laser-based optical communication is poised to realize this dream while working hand-in-hand with acoustic and radio-frequency technologies from the littoral zone to deep blue sea. While blue and green lasers are typically utilized depending on the optical properties of the water, laser-based white light is attractive in a number of aspects. In this thesis, we proposed and realized the use of white light to model the channel and to provide the immediate decision for the preferred system configuration, which is critical for developing reliable communication links, particularly, in the presence of turbulence, which makes the alignment of underwater wireless optical communication (UWOC) links challenging. Temperature and salinity changes are among factors that change the refraction index, giving rise to beam wander. This thesis explores the dependence of underwater turbulence on the wavelength. After comparing the performance of red, green, and blue lasers, an ultra-fast comprehensive method that utilizes a white-light source that can produce a wide range of wavelengths is implemented. Experimental results show an 80%-decrease in the scintillation index as the wavelength is increased from 480 to 680 nm in weak turbulence caused by a 0.02-℃/cm temperature gradient with a 40-ppt salt concentration, which emulates conditions found in the Red Sea. The effect of turbulence on the bit error ratio (BER) is also investigated experimentally. Temperature gradients increased the BER especially for shorter wavelengths. The results along long-transmission distances were verified using Monte Carlo simulations. The correlation matrix between wavelengths was studied, which is important for designing multiple-input multiple-output systems. The results obtained show that as the difference in the wavelengths increases, the correlation decreases. Based on the interplay among scintillations, scattering, absorption, and the correlation between different wavelengths, it is possible to design a more reliable UWOC link.

This thesis describes and documents the design and construction of a light source which is tunable and has the ability to mimic the spectral output of the sun in the photosynthetic active radiation range (400 - 700 nm). To adjust the spectral output at different wavelengths different types of LEDs were chosen and combined. This thesis describes the design, construction, testing, and suggestions for further improvements to this light source. The light source is comprised of 900 LEDs with 26 different peak wavelengths within the photosynthetically active radiation range. The light source is made tunable through the use of a control system utilizing pulse width modulation. This unique light source will allow studies to be performed to understand spectral influences on microalgae and lipid production as well as other photosynthetic organisms.

The main goal of this dissertation is to introduce and demonstrate a new method for the rapid determination of the nonlinear absorption spectra and the dispersion of the nonlinear refraction of optical materials in the visible and near IR spectral regions. However, conventional methods like, white-light continuum pump-probe and Z-scan techniques were used to measure the peak 2PA cross-sections for a number of commercially available photoinitiators. In the new method mentioned above, a high energy, broadband femtosecond white-light continuum is used to replace the single wavelength source conventionally used in a Z-scan experiment. In a Z-scan experiment, the transmittance of a focused beam through a sample is monitored as the sample travels through the focus, in the Z direction, along the focused beam. Providing the sample exhibits nonlinear absorption and/or refraction, the detector monitors a change in transmittance and/or a change in the beam divergence (if the energy is partially collected through an aperture in front of the detector). Replacing the single wavelength source with a white-light continuum allows for a much faster way of measuring nonlinear absorption/refraction spectra. This could eliminate the need for using other tunable sources (e.g. Optical Parameter Generators/Amplifiers) for nonlinear measurements. These sources made nonlinear spectroscopy using Z-scan experiments a time consuming task. This new source/method allows for rapid and simultaneous measurement of the nonlinear absorption spectrum and the dispersion of the nonlinear refraction. We have confirmed the functionality of the continuum as a source for nonlinear optical characterization of materials by using it to perform Z-scans on the well characterized semiconductors ZnSe and ZnS and on solutions of organic dyes.

This work establishes a solid foundation for the use of indirect band gap semiconductors for light emitting application and presents the work on development of white light emitting diodes (LEDs) in silicon carbide (SiC). Novel laser doping has been utilized to fabricate white light emitting diodes in 6H-SiC (n-type N) and 4H-SiC (p-type Al) wafers. The emission of different colors to ultimately generate white light is tailored on the basis of donor acceptor pair (DAP) recombination mechanism for luminescence. A Q-switched Nd:YAG pulse laser (1064 nm wavelength) was used to carry out the doping experiments. The p and n regions of the white SiC LED were fabricated by laser doping an n-type 6H-SiC and p-type 4H-SiC wafer substrates with respective dopants. Cr, B and Al were used as p-type dopants (acceptors) while N and Se were used as n-type dopants (donors). Deep and shallow donor and acceptor impurity level states formed by these dopants tailor the color properties for pure white light emission. The electromagnetic field of lasers and non-equilibrium doping conditions enable laser doping of SiC with increased dopant diffusivity and enhanced solid solubility. A thermal model is utilized to determine the laser doping parameters for temperature distribution at various depths of the wafer and a diffusion model is presented including the effects of Fick's diffusion, laser electromagnetic field and thermal stresses due to localized laser heating on the mass flux of dopant atoms. The dopant diffusivity is calculated as a function of temperature at different depths of the wafer based on measured dopant concentration profile. The maximum diffusivities achieved in this study are 4.61x10-10 cm2/s at 2898 K and 6.92x10-12 cm2/s at 3046 K for Cr in 6H-SiC and 4H-SiC respectively. Secondary ion mass spectrometric (SIMS) analysis showed the concentration profile of Cr in SiC having a penetration depth ranging from 80 nm in p-type 4H-SiC to 1.5 [micro]m in n-type 6H-SiC substrates respectively. The SIMS data revealed enhanced solid solubility (2.29x1019 cm-3 in 6H-SiC and 1.42x1919 cm-3 in 4H-SiC) beyond the equilibrium limit (3x1017 cm-3 in 6H-SiC above 2500 [degrees]C) for Cr in SiC. It also revealed similar effects for Al and N. The roughness, surface chemistry and crystalline integrity of the doped sample were examined by optical interferometer, energy dispersive X-ray spectrometry (EDS) and transmission electron microscopy (TEM) respectively. Inspite of the larger atomic size of Cr compared to Si and C, the non-equilibrium conditions during laser doping allow effective incorporation of dopant atoms into the SiC lattice without causing any damage to the surface or crystal lattice. Deep Level Transient Spectroscopy (DLTS) confirmed the deep level acceptor state of Cr with activation energies of Ev+0.80 eV in 4H-SiC and Ev+0.45 eV in 6H-SiC. The Hall Effect measurements showed the hole concentration to be 1.98x1019 cm-3 which is almost twice the average Cr concentration (1x1019 cm-3) obtained from the SIMS data. These data confirmed that almost all of the Cr atoms were completely activated to the double acceptor state by the laser doping process without requiring any subsequent annealing step. Electroluminescence studies showed blue (460-498 nm), blue-green (500-520 nm) green (521-575 nm), and orange (650-690 nm) wavelengths due to radiative recombination transitions between donor-acceptors pairs of N-Al, N-B, N-Cr and Cr-Al respectively, while a prominent violet (408 nm) wavelength was observed due to transitions from the nitrogen level to the valence band level. The red (698-738 nm) luminescence was mainly due to metastable mid-bandgap states, however under high injection current it was due to the quantum mechanical phenomenon pertaining to band broadening and overlapping. This RGB combination produced a broadband white light spectrum extending from 380 to 900 nm. The color space tri-stimulus values for 4H-SiC doped with Cr and N were X = 0.3322, Y = 0.3320 and Z = 0.3358 as per 1931 CIE (International Commission on Illumination) corresponding to a color rendering index of 96.56 and the color temperature of 5510 K. And for 6H-SiC n-type doped with Cr and Al, the color space tri-stimulus values are X = 0.3322, Y = 0.3320 and Z = 0.3358. The CCT was 5338 K, which is very close to the incandescent lamp (or black body) and lies between bright midday sun (5200 K) and average daylight (5500 K) while CRI was 98.32. Similar white LED's were also fabricated using Cr, Al, Se as one set of dopants and B, Al, N as another.

No description available.

Measurement of physical parameters in harsh environments (high pressure, high temperature, highly corrosive, high electromagnetic interference) is often desired in a variety of areas, such as aerospace, automobile, energy, military systems, and industrial processes. Pressure and temperature are among the most important of these parameters. A typical example is pressure monitoring in jet engine compressors to help detect and control undesirable air flow instabilities, namely rotating stall and surge. However, the temperatures inside a compressor could reach beyond 600°C for today's large engines. Current fiber-optic sensor can operate up to about 300°C and even the most widely employed semiconductor sensors are limited below 500°C. The objective of this research is to push the limit of fiber-optic sensing technology in harsh environment applications for both pressure and temperature measurements by developing novel sensing structures, fabrication techniques, and signal processing algorithms. An all-fused-silica pressure sensor has been demonstrated which is fabricated on the tip of a fiber with a diameter no larger than 125μm. The sensor was able to function beyond the current limit and operate into the 600~700°C range. Also a temperature sensor has been developed using sapphire fibers and wafers for ultra-high temperature measurement as high as 1600°C. This effort will generate more understanding regarding sapphire fiber's high temperature properties and could possibly lead to novel designs of pressure sensor for beyond 1000°C. Both sensors have been field tested in real-world harsh environments and demonstrated to be reliably and robust. In this dissertation, the design, fabrication, and testing of the sensors are discussed in detail. The system and signal processing techniques are presented. The plan and direction for future work are also suggested with an aim of further pushing the operating limit of fiber-optic sensors. / Ph. D.

The electrostatic self-assembly (ESA) method presents an effective application in the field of biosensing due to the uniform nanoscale structure. In previous research, a single mode fiber (SMF) sensor system had been investigated for the thin-film measurement due to the high fringe visibility. However, compared with a SMF sensor system, a multimode fiber (MMF) sensor system is lower-cost and has larger sensing area (the fiber core), providing the potential for higher sensing efficiency. In this thesis, a multimode fiber-optic sensor has been developed based on extrinsic Fabry-Perot interferometry (EFPI) for the measurement of optical thickness in self-assembled thin film layers as well as for the immunosensing test. The sensor was fabricated by connecting a multimode fiber (MMF) and a silica wafer. A Fabry-Perot cavity was formed by the reflections from the two interfaces of the wafer. The negatively charged silica wafer could be used as the substrate for the thin film immobilization scheme. The sensor is incorporated into the white-light interferometric system. By monitoring the optical cavity length increment, the self-assembled thin film thickness was measured; the immunoreaction between immunoglobulin G (IgG) and anti-IgG was investigated. / Master of Science

Since the invention of Laser (in 1960) and low loss optical fiber (in 1966) [1], extensive research in fiber-optic sensing technology has made it a well-defined and matured field [1]. The measurement of physical parameters (such as temperature and pressure) in extremely harsh environment is one of the most intriguing challenges of this field, and is highly valued in the automobile industry, aerospace research, industrial process monitoring, etc. [2]. Although the semiconductor based sensors can operate at around 500oC, sapphire fiber sensors were demonstrated at even higher temperatures [3]. In this research, a novel sensor structure is proposed that can measure both pressure and temperature simultaneously. This work effort consists of design, fabrication, calibration, and laboratory testing of a novel structured temperature compensated pressure sensor. The aim of this research is to demonstrate an accurate temperature measurement, and pressure measurement using a composite Fabry-Perot interferometer. One interferometer measures the temperature and the other accurately measures pressure after temperature compensation using the temperature data from the first sensor. / Master of Science

The use of optical fiber sensors is increasing widely in industry, civil, medicine, defense and research. Among different categories of these sensors is the Extrinsic Fabry-Perot interferometer (EFPI) sensor which is inherently simple and requires only modest amount of interface electronics. These advantages make it suitable for many practical applications. Investigating a cost-effective, reliable and repeatable method for optical fiber sensor fabrication is challenging work. In this thesis, a system for controlled fabrication of Fabry-Perot optical fiber sensors is developed and presented as the first attempt for the long-term goal of automated EFPI sensor fabrication. The sensor fabrication control system presented here implements a real-time control of a carbon dioxide (CO₂) laser as sensor bonding power, an optical fiber white light interferometric subsystem for real-time monitoring and measurement of the air gap separation in the Fabry-Perot sensor probe, and real-time control of a piezoelectric (PZT) motion subsystem for sensor alignment. The design of optoelectronic hardware and computer software is included. A large number of sensors are fabricated using this system and are tested under high temperature and high pressure. This system as a prototype system shows the potential in automated sensor fabrication. / Master of Science

In this thesis an investigation into novel beams and optical manipulation is presented. Sculpting the phase profile of a Gaussian beam can result in the generation of a beam with unusual properties. Described in this thesis are optical vortices, Bessel beams and Airy beams. Additionally, optical manipulation was investigated using both novel beams and Gaussian beams with an emphasis on the use of a broad bandwidth laser source. The generation of multiple broadband optical trap sites was explored, and the transfer of orbital angular momentum from a broadband optical vortex to trapped microspheres was demonstrated. An introduction to the thesis and an overview of laser sources used for optical manipulation is presented in Chapters 1 and 2. Chapters 3 and 4 detail the background of optical manipulation and novel beam shaping. In Chapter 5, an investigation into the generation of multiple broadband optical trap sites is presented. Chapter 6 details the use of a ‘white light’ optical vortex to transfer orbital angular momentum to trapped microspheres. Chapter 7 presents the results of an investigation carried out using a supercontinuum source to characterise the wavelength and spatial coherence dependence of the properties of an optical Airy beam. The use of a monochromatic laser to generate Bessel beams that propagate along curved trajectories is detailed in Chapter 8. Chapter 9 summarises the thesis and suggests future work.