Nanofios semicondutores de óxido metálico apresentam enorme potencial em aplicações de nano-sensoriamento de diferentes gases e substâncias químicas e biológicas, bem como na aplicação a detectores UV-visível. Neste trabalho, desenvolvemos e aperfeiçoamos a síntese de nanofios de ZnO em substratos de safira (001), silício (111) e silício (100) sob diferentes concentrações de oxigênio usando o processo de transporte de vapor-liquido-sólido (VLS). No presente trabalho, investigamos a influência da concentração de oxigênio no crescimento de nanofios de ZnO por Espectroscopia de Fotoluminescência a temperatura variável com a finalidade de estudo da mudança na concentração de defeitos. Apresentamos, ainda, caracterizações elétricas (IxV e Ixt) de nanoestruturas de ZnO sob diferentes pressões com o objetivo de estudar os defeitos envolvidos nos processos de transportes eletrônicos. Por último, propomos o desenvolvimento de micro-contatos através da técnica de microfeixe iônico e através de nanolitografia por feixe de elétrons com a finalidade de aplicações a sensores químicos, gasosos e fotodetectores. / Metal oxide nanowires semiconductors have enormous potential in high-sensitive, fast and selective sensing applications. It may be used to selectively detect different gases, chemical and biological substances and also in UV-visible photodetectors. The described processes involve the synthesis as well as the characterization of ZnO nanowires grown on sapphire (001), silicon (100) e silicon (111) substrates by the Vapor-liquid-solid transport method. In the present work, we describe the influence of oxygen concentration introduced in the growth step measured by photoluminescence at variable temperature to demonstrate the change in defect levels emission (DLE). Furthermore, we have shown electrical characterization (IxV and Ixt) in order to study the ambient effect for transport mechanisms in ZnO nanowires. We also report the development of crucial steps in the fabrication for an upcoming ZnO nanowire sensor device (gas, chemical and photodetector) using lithography techniques such as ion micro-beam and electron beam with the purpose of fabricating metallic micro-pads.

Neste trabalho se realiza a síntese e caracterização de nanofios de óxido de zinco. Adicionalmente se apresenta o processo de montagem de um dispositivo para medidas elétricas deste material. Estuda-se complementarmente o efeito do tratamento de plasma sobre as propriedades de fotoluminescência do material. Nanofios foram sintetizados pelo mecanismo vapor-líquido-sólido (VLS), utilizando ouro como catalizador e safira c-plane como substrato. As amostras foram caracterizadas utilizando microscopia eletrônica de varredura, fotoluminescência a temperatura ambiente, difração de raios X, e microscopia eletrônica de transmissão. Os nanofios obtidos têm seção transversal com formato quase hexagonal, e larguras de aproximadamente 46 nm. O comprimento deles varia de 3 a 10 μm. Os resultados de difração de raios x e microscopia eletrônica de transmissão mostram que eles são monocristalinos com rede cristalina tipo wurtzita, e com direção de crescimento no eixo c. Foram estudados os efeitos da potência de plasma de oxigênio (O2) na fotoluminescência dos nanofios a temperatura ambiente. A diferença na fotoluminescência após diferentes tratamentos de plasma de O2 mostra que a razão entre a emissão da região do band gap e da banda do visível pode ser modificada pelo tratamento. Este efeito corrobora com a hipótese de que a banda verde de luminescência está relacionada às vacâncias de zinco. A variação percentual da razão entre as duas regiões apresenta uma dependência linear com a potência do plasma. / In this work, we performed the synthesis and characterization of zinc oxide nanowires. We also report an assembly process to measure the electrical properties of this material. We study the plasma treatment effect on the photoluminescence spectra of the nanowires. Nanowires were synthesized via vapor-liquid-solid mechanism, using gold as catalyst and c-plane sapphire as substrate. The samples were characterized using scanning electron microscopy, room temperature photoluminescence, x-rays diffraction and transmission electron microscopy. Our nanowires show a quasi-hexagonal cross section, with diameters of approximately 46 nm. Their lengths ranged from 3 to 10 μm. Our results show monocrystalline wurtzite crystal nanowires with c growth direction. We also study the plasma power effect of oxygen (O2) plasma treatment on the room temperature photoluminescence spectra of the nanowires. Our results show that the deep level emission to near band emission ratio decreases with the plasma treatment. This effect supports the hypothesis that claims the green band luminescence is related to the oxygen vacancies. Furthermore, the relative ratio change depends linearly on the plasma power.

Neste trabalho se realiza a síntese e caracterização de nanofios de óxido de zinco. Adicionalmente se apresenta o processo de montagem de um dispositivo para medidas elétricas deste material. Estuda-se complementarmente o efeito do tratamento de plasma sobre as propriedades de fotoluminescência do material. Nanofios foram sintetizados pelo mecanismo vapor-líquido-sólido (VLS), utilizando ouro como catalizador e safira c-plane como substrato. As amostras foram caracterizadas utilizando microscopia eletrônica de varredura, fotoluminescência a temperatura ambiente, difração de raios X, e microscopia eletrônica de transmissão. Os nanofios obtidos têm seção transversal com formato quase hexagonal, e larguras de aproximadamente 46 nm. O comprimento deles varia de 3 a 10 μm. Os resultados de difração de raios x e microscopia eletrônica de transmissão mostram que eles são monocristalinos com rede cristalina tipo wurtzita, e com direção de crescimento no eixo c. Foram estudados os efeitos da potência de plasma de oxigênio (O2) na fotoluminescência dos nanofios a temperatura ambiente. A diferença na fotoluminescência após diferentes tratamentos de plasma de O2 mostra que a razão entre a emissão da região do band gap e da banda do visível pode ser modificada pelo tratamento. Este efeito corrobora com a hipótese de que a banda verde de luminescência está relacionada às vacâncias de zinco. A variação percentual da razão entre as duas regiões apresenta uma dependência linear com a potência do plasma. / In this work, we performed the synthesis and characterization of zinc oxide nanowires. We also report an assembly process to measure the electrical properties of this material. We study the plasma treatment effect on the photoluminescence spectra of the nanowires. Nanowires were synthesized via vapor-liquid-solid mechanism, using gold as catalyst and c-plane sapphire as substrate. The samples were characterized using scanning electron microscopy, room temperature photoluminescence, x-rays diffraction and transmission electron microscopy. Our nanowires show a quasi-hexagonal cross section, with diameters of approximately 46 nm. Their lengths ranged from 3 to 10 μm. Our results show monocrystalline wurtzite crystal nanowires with c growth direction. We also study the plasma power effect of oxygen (O2) plasma treatment on the room temperature photoluminescence spectra of the nanowires. Our results show that the deep level emission to near band emission ratio decreases with the plasma treatment. This effect supports the hypothesis that claims the green band luminescence is related to the oxygen vacancies. Furthermore, the relative ratio change depends linearly on the plasma power.

Nanofios semicondutores de óxido metálico apresentam enorme potencial em aplicações de nano-sensoriamento de diferentes gases e substâncias químicas e biológicas, bem como na aplicação a detectores UV-visível. Neste trabalho, desenvolvemos e aperfeiçoamos a síntese de nanofios de ZnO em substratos de safira (001), silício (111) e silício (100) sob diferentes concentrações de oxigênio usando o processo de transporte de vapor-liquido-sólido (VLS). No presente trabalho, investigamos a influência da concentração de oxigênio no crescimento de nanofios de ZnO por Espectroscopia de Fotoluminescência a temperatura variável com a finalidade de estudo da mudança na concentração de defeitos. Apresentamos, ainda, caracterizações elétricas (IxV e Ixt) de nanoestruturas de ZnO sob diferentes pressões com o objetivo de estudar os defeitos envolvidos nos processos de transportes eletrônicos. Por último, propomos o desenvolvimento de micro-contatos através da técnica de microfeixe iônico e através de nanolitografia por feixe de elétrons com a finalidade de aplicações a sensores químicos, gasosos e fotodetectores. / Metal oxide nanowires semiconductors have enormous potential in high-sensitive, fast and selective sensing applications. It may be used to selectively detect different gases, chemical and biological substances and also in UV-visible photodetectors. The described processes involve the synthesis as well as the characterization of ZnO nanowires grown on sapphire (001), silicon (100) e silicon (111) substrates by the Vapor-liquid-solid transport method. In the present work, we describe the influence of oxygen concentration introduced in the growth step measured by photoluminescence at variable temperature to demonstrate the change in defect levels emission (DLE). Furthermore, we have shown electrical characterization (IxV and Ixt) in order to study the ambient effect for transport mechanisms in ZnO nanowires. We also report the development of crucial steps in the fabrication for an upcoming ZnO nanowire sensor device (gas, chemical and photodetector) using lithography techniques such as ion micro-beam and electron beam with the purpose of fabricating metallic micro-pads.

Nanofios semicondutores de óxido metálico apresentam enorme potencial em aplicações de nano-sensoriamento de diferentes gases e substâncias químicas e biológicas, bem como na aplicação a detectores UV-visível. Neste trabalho, desenvolvemos e aperfeiçoamos a síntese de nanofios de ZnO em substratos de safira (001), silício (111) e silício (100) sob diferentes concentrações de oxigênio usando o processo de transporte de vapor-liquido-sólido (VLS). No presente trabalho, investigamos a influência da concentração de oxigênio no crescimento de nanofios de ZnO por Espectroscopia de Fotoluminescência a temperatura variável com a finalidade de estudo da mudança na concentração de defeitos. Apresentamos, ainda, caracterizações elétricas (IxV e Ixt) de nanoestruturas de ZnO sob diferentes pressões com o objetivo de estudar os defeitos envolvidos nos processos de transportes eletrônicos. Por último, propomos o desenvolvimento de micro-contatos através da técnica de microfeixe iônico e através de nanolitografia por feixe de elétrons com a finalidade de aplicações a sensores químicos, gasosos e fotodetectores. / Metal oxide nanowires semiconductors have enormous potential in high-sensitive, fast and selective sensing applications. It may be used to selectively detect different gases, chemical and biological substances and also in UV-visible photodetectors. The described processes involve the synthesis as well as the characterization of ZnO nanowires grown on sapphire (001), silicon (100) e silicon (111) substrates by the Vapor-liquid-solid transport method. In the present work, we describe the influence of oxygen concentration introduced in the growth step measured by photoluminescence at variable temperature to demonstrate the change in defect levels emission (DLE). Furthermore, we have shown electrical characterization (IxV and Ixt) in order to study the ambient effect for transport mechanisms in ZnO nanowires. We also report the development of crucial steps in the fabrication for an upcoming ZnO nanowire sensor device (gas, chemical and photodetector) using lithography techniques such as ion micro-beam and electron beam with the purpose of fabricating metallic micro-pads.

This work investigates the feasibility of developing a self-powered structural health monitoring (SHM) smart tire using piezoelectric materials. While this work is divided into two components: SHM and energy harvesting, the context of smart tire in this work is defined as the development of a SHM system that (i) has self-powering capabilities, and (ii) addresses the potential of embedding sensors. The use of impedance based SHM on a tire is severely limited due to the low stiffness and high damping characteristics of the tire. This work propose the use of a high voltage impedance analyzer, and the addition of electrical circuit to enhance the damage detection process. Experimental work was conducted on an aluminum beam and on a tire section with commercially available piezoelectric sensors. The use of a high voltage impedance analyzer was demonstrated to provide insight on damage type and damage location. Two sensors were connected in parallel as an effective sensory system, and was shown to reduce interrogation time, but reduce damage identification sensitivity. With added electrical circuits, a belt separation on the tire was successfully detected by the shift in electrical impedance signature. For the energy harvesting portion of this work, a bimorph piezoelectric energy harvester model was derived using extended Hamilton's principle and the linear constitutive relations of piezoelectric materials. Comparison of model with experimental data at increasing loading conditions demonstrated the monotonic increase in voltage output, with linear asymptotes at extreme loading conditions (short-circuit and open-circuit). It also demonstrated the existence of an optimal resistive load for maximum power output. To address the ability to embed sensors, an existing fabrication process to grow arrays of ZnO nanowires in carbon fiber reinforced polymer was used in this work. Comparison of power generation from a composite beam with ZnO nanowires with a composite beam without ZnO nanowires demonstrated the power generation capabilities of the nanowires. A maximum peak voltage of 8.91 mV and peak power of 33.3 pW was obtained. After the application of 10V DC, a maximum of 45 pW was obtained. However, subsequent application of 20V DC reduced the maximum peak power output to 2.5 pW. Several attempts to increase power generation including adding a tip mass and changing the geometry of the composite beam were conducted. Finally, the theoretical voltage frequency response function obtained from the theoretical piezoelectric constant and dielectric constant of a single ZnO nanowire were compared to the experimental voltage frequency response function. The discrepancies were discussed. / Master of Science

The goal of this work is to investigate the piezoelectricity of composite laminates embedded with layers of zinc oxide (ZnO) nanowires. ZnO nanowire embedded composites have the potential to sense and actuate giving the potential for these smart composites to serve the function of being load bearing structures and monitoring the integrity of the structure. This work examines the piezoelectric characteristics of composite beams by investigating their electromechanical coupling in the form of vibration under the presence of electrical excitation. With the help of a mathematical model, piezoelectric constants are estimated for these samples. A layer of ZnO nanowires were grown on plane woven fiberglass fabric that was incorporated into a carbon fiber epoxy composite. The beam deflection velocity was measured as a varying voltage was applied to the composite. Using Hamilton's Principle and Galerkin's method of weighted residuals, a mathematical model was derived to estimate piezoelectric constants for the composites from the experimental data. Piezoelectric properties were determined using vibrational testing and a mathematical model. Piezoelectric constants h31, g31, and d31 were estimated to be 9.138 E7 V/m, 6.092 E-4 Vm/N, and 2.46 E-14 respectively. To demonstrate the electromechanical coupling, ZnO nanowire composites were bonded to Al beams that were progressively damaged to determine if a change in electrical impedance could be observed to correspond to the change in structural impedance of the host beam. Changes in impedance were detected by a change in root mean squared deviation damage metric M. A significant correlation was shown between increasing damage in the host beam and an increase in damage metric M. / Master of Science

Thesis (PhD)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: This study developed and optimised zinc oxide (ZnO) nanowire-based nanogenerator. The nanogenerator works on the piezoelectric effect that is, a mechanical force is converted to an electrical voltage. The ZnO nanowires are piezoelectric and when any force is applied to the nanowires an output voltage is generated. This ZnO nanowire-based nanogenerator can be used to power small electronic devices, such as pacemakers. The nanogenerator can also be incorporated into clothes and shoes to generate electricity to charge a cell phone for example. The problem experienced currently is that the nanogenerator does not generate enough electricity to be of practical use and needs to be further optimised. Simulations and mathematical models were used to identify areas where the nanogenerator could be optimised in order to increase the output voltage. It is shown that the morphology of the nanowires can have a considerable effect on the output voltage. For this reason the growth of the nanowires was investigated first. Different methods were used to propagate the nanowires in order to select the method that, on average, has the highest output voltage. Accordingly, one parameter at a time and design of experiments were used to optimise the nanowire growth. Consequently, these two methods were used to optimise the growth parameters with the respect to the output voltage. The aqueous solution method was found to yield nanowires that give the highest generated output voltage. After growing over 600 nanowire samples, optimal growth parameters for this method were found. These optimal growth parameters were subsequently used to grow nanowires that were used to manufacture the nanogenerator. The nanowires were grown on a solid substrate and hence the nanogenerator was also manufactured on the solid substrate. Through various optimisations of the manufacturing process the maximum output voltage achieved was about 500 mV. However, this output voltage is too low to be of practical use, even though the output has been raised considerably. The main problem was found to be the fact that the contact between the nanowires and the electrode was weak due to contamination. A new method was therefore required where the electrode and the nanowires would be in proper contact to ensure that higher output voltages were achieved. Subsequently, a flexible nanogenerator was manufactured in order to solve this problem. Accordingly, the nanowires were grown on the flexible polyimide film and a buffer layer was then spun onto the flexible substrate, leaving only the nanowire tips exposed. The electrode was then sputtered on top of this buffer layer, covering the nanowire tips. This ensured proper contact between the nanowires and the electrode. The nanogenerator, which was manufactured with non-optimal growth parameters, gives a maximum voltage output of 1 V, double the maximum achieved with the solid nanogenerator. When the optimal growth parameters were used the output voltage was raised to 2 V. Various optimisation techniques were performed on the nanogenerator, including plasma treatment and annealing and the use of various materials in the buffer layer. Combining these optimisation methods subsequently led to an optimised nanogenerator that can generate an output voltage of over 5 V. This was achieved after over 1200 nanogenerators had been manufactured. However, the output voltage was not in a usable form. Circuitry was therefore developed to transform the voltage generated by the nanogenerator to a useable form. The best circuit, the LTC3588, was used to power an LED for 10 seconds. The completed device was found to achieve a power output of 0.3 mW, enough for small electronic devices. / AFRIKAANSE OPSOMMING: ‘n Sink-oksied (ZnO) nanodraad gebaseerde nanogenerator is ontwikkeld en geöptimeer. Die nanogenerator werk met behulp van die piezoelektriese effek - meganiese krag work omgesit in ‘n elektriese spanning. Die ZnO nanodrade is piezoelektries en wanneer ‘n krag op die drade aangewend word, word ‘n uittree spanning gegenereer. Die nanogenerator kan gebruik word om klein elektroniese toestelle, soos ‘n pasaangeër, van krag te voorsien. Die nanogenerator kan in klere en skoene geïnkorporeer word om elektrisiteit op te wek vir die laai van ‘n selfoon. Die probleem is egter dat die nanogenerator tans nie genoeg krag opwek om prakties van nut te wees nie en verdere optimasie word benodig. Simulasies en wikundige modelle work gebruik om areas te identifiseer waar die nanogenerator geöptimeer kan word, met die doel om die uittreespanning te verhoog. Dit word bewys dat die morfologie van die nanodrade ‘n groot effek het op die uittreespanning. Dus word die groei van die nanodrade eerste ondersoek. Verskillende metodes word gebruik om die nanodrade te groei en die beste metode, wat die hoogste uittreespanning op gemiddeld verskaf, word gekies. Een parameter op ‘n slag en ontwerp van eksperimente word gebruik om die nanodraad groei te optimeer. Die groei parameters word geöptimeer deur van die twee metodes gebruik te maak, en die optimeering word gedoen in terme van die uittreespanning. Die oplossing groei metode lei tot nanodrade wat die hoogste uittreespanning verskaf. Na oor die 600 nanodraad monsters gegroei is, is die optimale parameters gevind. Hierdie optimale parameters word uitsluitlik gebruik om die nanogenerator te vervaardig. Die nanodrade word op ‘n soliede substraat gegroei en dus word die nanogenerator op dieselfde soliede substraat vervaardig. Verskeie metodes is gebruik om die vervaardiging te optimeer en die hoogste uittreespanning wat bereik is, is 500 mV. Die uittreespanning is te laag om van praktiese nut te wees alhoewel dit heelwat verhoog is. Die grootste probleem is die swak kontak tussen die nanodrade en die elektrode, wat veroorsaak word deur kontaminasie. ‘n Nuwe metode word verlang wat beter kontak tussen die nanodrade en elektrode sal verseker. ‘n Buigbare nanogenerator is vervaardig om die probleem op te los. Die nanodrade word nou op ‘n buigbare film gegroei. ‘n Bufferlaag word tussen die nanodrade in gedraai, tot net die punte van die nanodrade nog sigbaar is. Die elektrode word bo-op die bufferlaag gedeponeer, wat behoorlike kontak tussen die nanodrade en elektrode verseker. Die nanogenerator wat met nie-optimale groei parameters vervaardig is, bereik ‘n uittreespanning van 1 V, dubbel die soliede nanogenerator. Met optimale groei parameters word die uittreespanning tot 2 V verhoog. Verskeie optimasie tegnieke word op die nanogenerator toegepas. Die metodes sluit in suurstof plasma behandeling, verhitting en die inkorporasie van verskillende materiale in die bufferlaag. ‘n Kombinasie van die metodes geïnkorporeer in een nanogenerator lei tot ‘n uittreespanning van 5 V. Die uittreespanning is bereik na oor die 1200 nanogenerators vervaardig is. The uittreespanning is nog nie in ‘n bruikbare vorm nie. Spesiale stroombane is ontwikkel wat die nanogenerator spanning omskakel na ‘n bruikbare vorm. Die beste stroombaan, die LTC3588, kan ‘n LED aanskakel vir 10 sekondes. The toestel kan ook 0.3mWuittreekrag voorsien, genoeg vir klein elektroniese toestelle om te werk.

Because of its excellent and unique physical properties, ZnO nanowires have been widely used in numerous scientific fields such as sensors, solar cells, nanogenerators, etc. Although it is believed that single crystal ZnO has a much higher electron transfer rate than TiO₂, it was found that ZnO nanowire-based dye-sensitized solar cells (DSSCs) have lower efficiencies than TiO₂ nanoparticle-based DSSCs because the density and surface area of ZnO nanowires are usually lower than that of TiO₂ nanoparticles, limiting the cell's light absorption, and because the open-root structure of ZnO nanowires results in electron back transfer that causes charge shortage of the cell. Here, experimental studies were performed that utilize strategic manipulations of the design of the ZnO nanowire based DSSCs in efforts to address and solve its key challenges. It was shown that by incorporating various blocking layers into the design of the cell, the performance of the DSSC can be improved. Specifically, by placing a hybrid blocking layer of TiO₂-P4VP polymer between the substrate and the ZnO nanowires, the conversion efficiency of the cell was 43 times higher than that of a cell without this blocking layer due to the reduction of electron back transfer. Furthermore, in efforts to improve the surface area of the ZnO nanowire array, unique three dimensional structures of ZnO nanowires were fabricated. It was found that by significantly improving the overall density and surface area of the ZnO nanowire array through distinctive hierarchal nanowire structures, the light harvesting efficiency and electron transport were enhanced allowing the DSSC to reach 5.20%, the highest reported value for 3D ZnO NW based DSSCs. Additionally, the development of a theoretical model was explored in efforts to investigate how the geometry of ZnO nanowires affects the incident photon-to-current conversion efficiency of 1D ZnO nanowire-based N719-sensitized solar cells at the maximum absorption wavelength of 543 nm.

Despite the many attractive features of carbon fiber reinforced polymers (FRPs) composites, they are prone to failure due to delamination. The ability to tailor the fiber/matrix interface FRPs is crucial to the development of composite materials with enhanced structural performance. In this dissertation, ZnO nanowires (NWs) were grown on the surface of carbon fibers utilizing low temperature hydrothermal synthesis technique prior to the hybrid composite fabrication. The scanning electron microscopy revealed that the ZnO nanowires were grown uniformly on the surface of the carbon fabric. The surface grown ZnO NWs functionally-graded the composite material properties and ensured effective load transfer across the interface. To assess the influence of the ZnO NWs growth, reference samples were also prepared by exposing the carbon fabric to the hydrothermal conditions. The damping properties of the hybrid ZnO NWs-CFRP composite were examined using the dynamic mechanical analysis (DMA) technique. The results showed enhanced energy dissipation within the hybrid composite. Quasi-static tensile testing revealed that the in-plane and out-of-plane strengths and moduli of the hybrid FRP composite were also boosted. The interlaminar shear strength (ILSS) measurements suggested the improvement in the mechanical properties of the composite to the enhanced adhesion between the ZnO nanowires and the other constituents (carbon fiber and epoxy). It was necessary thus, to utilize the molecular dynamics simulations (MD) to investigate the adhesion within the CFRP structure upon growing the ZnO nanowires on the surface of the carbon fibers. Molecular models of the carbon fibers, the epoxy matrix and the ZnO nanowires were built. The resulting molecular structures were minimized and placed within a simulation box with periodic boundary conditions. The MD simulations were performed using the force field COMPASS to account for the empirical energy interactions between the different toms in the simulation box. Proper statistical thermodynamics were employed to relate the dynamics of the molecular model to the macroscale thermodynamic states (pressure, temperature and volume). Per the computed potential energies of the different components of the composite, it was found that the polar surfaces in the ZnO structures facilitates good adhesion properties in the graphite-epoxy composite. Besides the attractive mechanical properties of the ZnO nanowires, their piezoelectric and semiconductor properties were sought to design an energy harvesting device. To ensure sufficient charges collection from the mechanically stressed individual ZnO nanowires, a copper layer was sputtered on top of the ZnO nanowires which introduced also a Schottky effect. The mechanical excitation was provided by exposing the device to different vibration environment. The output voltage and currents were measured at the conditions (in terms of frequency and resistive load). It was demonstrated that the electrical output could be enhanced by stacking up similar devices in series or in parallel. Finally, in an attempt to exploit the reversibility of the electromechanical coupling of the energy harvesting device, the constitutive properties of the hybrid ZnO nanowires-CFRP composite were estimated using the Mori-Tanaka approach. This approach was validated by a finite element model (FEM). The FEM simulations were performed on a representative volume element (RVE) to reduce the computational time. The results demonstrated that the mechanical properties of the hybrid ZnO NWs-CFRP composite were better than those for the baseline CFRP composite with identical carbon fiber volume fraction (but with no ZnO NWs) which confirmed the experimental findings. Furthermore, the electro-elastic properties of the hybrid composite were determined by applying proper boundary conditions to the FE RVE. The work outlined in this dissertation will enable significant advancement in the next generation of hybrid composites with improved structural and energy harvesting multifunctionalties. / Ph. D.