<p>The increased use of the diesel engine in the passenger car, truck and bus market is due to high efficiency and lower fuel costs. This growing market share has brought with it several environmental issues for instance soot particle emission. Different technologies to remove the soot have been developed and are normally based on some kind of soot trap. In particular for automobiles the use of diesel particulate traps or filters (DPF:s) based on ceramic monolithic honeycombs are becoming a standard. This new exhaust system component will affect the acoustics and also work as a muffler. To properly design exhaust systems acoustic models for diesel particulate traps are needed. The first part of this thesis considers the modelling of sound transmission and attenuation for traps that consist of narrow channels separated by porous walls. This work has resulted in two new models an approximate 1-D model and a more complete model based on the governing equations for a visco-thermal fluid. Both models are expressed as acoustic 2-ports which makes them suitable for implementation in acoustic software for exhaust systems analysis. The models have been validated by experiments on clean filters at room temperature with flow and the agreement is good. In addition the developed filter models have been used to set up a model for a complete After Treatment Device (ATD) for a passenger car. The unit consisted of a chamber which contained both a diesel trap and a Catalytic Converter (CC). This complete model was also validated by experiments at room temperature. The second part of the thesis focuses on experimental techniques for plane wave decomposition in ducts with flow. Measurements in ducts with flow are difficult since flow noise (turbulence) can strongly influence the data. The difficulties are also evident from the lack of good published in-duct measurement data, e.g., muffler transmission loss data, for Mach-numbers above 0.1-0.2. The first paper in this part of the thesis investigates the effect of different microphone mountings and signal processing techniques for suppressing flow noise. The second paper investigates in particular flow noise suppression techniques in connection with the measurement of acoustic 2-ports. Finally, the third paper suggests a general wave decomposition procedure using microphone arrays and over-determination. This procedure can be used to determine the full plane wave data, e.g., the wave amplitudes and complex wave numbers k+ and k-. The new procedure has been applied to accurately measure the sound radiation from an unflanged pipe with flow. This problem is of interest for correctly determining the radiated power from an engine exhaust outlet. The measured data for the reflection coefficient and end correction have been compared with the theory of Munt [33] and the agreement is excellent. The measurements also produced data for the damping value (imaginary part of the wavenumber) which were compared to a model suggested by Howe [13]. The agreement is good for a normalized boundary layer thickness less than 30-40</p>

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There is a strong competition among automotive manufacturers to reduce the radiated noise levels. One important source is the engine exhaust where the main noise control strategy is by using efficient mufflers. Stricter vehicle noise regulations combined with various exhaust gas cleaning devices, removing space for traditional mufflers, are also creating new challenges. Thus, it is crucial to have efficient models and tools to design vehicle exhaust systems. In addition the need to reduce CO2 emissions puts requirements on the losses and pressure drop in exhaust systems. In this thesis a number of problems relevant for the design of modern exhaust systems for vehicles are addressed. First the modelling of perforated mufflers is investigated. Fifteen different configurations were modeled and compared to measurements using 1D models. The limitations of using 1D models due to 3D or non-plane wave effects are investigated. It is found that for all the cases investigated the 1D model is valid at least up to half the plane wave region. But with flow present, i.e., as in the real application the 3D effects are much less important and then normally a 1D model works well. Another interesting area that is investigated is the acoustic performance of after treatment devices. Diesel engines produce harmful exhaust emissions and high exhaust noise levels. One way of mitigating both exhaust emissions and noise is via the use of after treatment devices such as Catalytic Converters (CC), Selective Catalytic Reducers (SCR), Diesel Oxidation Catalysts (DOC), and Diesel Particulate Filters (DPF). The objective of this investigation is to characterize and simulate the acoustic performance of different types of filters so that maximum benefit can be achieved. A number of after treatment device configurations for trucks were selected and investigated. Finally, addressing the muffler design constraints, i.e., concerning space and pressure drop, a muffler optimization problem is formulated achieving the optimum muffler design through calculating the acoustic properties using an optimization technique. A shape optimization approach is presented for different muffler configurations, and the acoustic results are compared against optimum designs from the literature obtained using different optimization methods as well as design targets. / <p>QC 20121016</p>

Ökad efterfråga på koppar har inneburit att man börjat prospektera områden där kopparhalten är låg. Ett sådant område är Laver i Älvsbyn kommun där Boliden vill etablera ett dagbrott i vad som förut var ett gruvsamhälle men nu står övergivet. Den planerade gruvan orsakar konflikter med närliggande rennäring, Natura 2000-områden samt har konsekvenser för miljön och samhället i Älvsbyn. Denna rapport undersöker effekterna av den tidigare och planerade gruvan i Laver med fokus på hur efterbehandling ska gå till och hur den påverkar olika aktörer. Materialet är hämtat från litteratur, intervjuer och ett fältarbete i Laver och har resulterat i en scenarioanalys där påverkan på miljön, rennäring och samhället värderats. Om en gruva etableras i Laver kan gruvavfallet tas hand om av Boliden och det finns idéer om hur en efterbehandling kan tillgodose kommunens behov men projektet riskerar att slå ut rennäringen. Det är därför viktigt att konsekvenserna vägs utifrån ett helhetsperspektiv där alla aktörers intressen tillgodoses. / An increasing demand for copper has led to the prospecting of areas with low copper content. One such area is Laver in Älvsbyn municipality where Boliden Mineral AB wants to establish an open pit mine in what was once an old mining settlement. The planned mine causes conflicts with nearby reindeer husbandry, Natura 2000-areas and has consequences for the environment as well as the society in Älvsbyn. This report examines the effects of both the old and planned mine in Laver, with a focus on the after-treatment and how the concerned agents become affected by a new mine. A scenario analysis was made by gathering information from literature, interviews and a field work at the mining site. This scenario analysis compares and values the impact on the local environment, reindeer herding and society. The planned mine will be on a larger scale than the old one and will therefore have to take more aspects of future impacts into account. If a mine is established in Laver, most of the waste can be taken care of by Boliden. There are some ideas on how the after-treatment can meet the needs of the municipality, but the reindeer husbandry is at great risk of vanishing from the area. Hence, it’s of importance that future consequences are weighed from a holistic perspective where the interests of all agents are met.

Particulate emissions from road transportation are known to have an adverse impact on human health as well the environment. As the effects become more palpable, stricter legislation have been proposed by regulating bodies. This puts forward a challenge for the automotive industry to develop after treatment technologies to fulfil the progressively stricter legislation. At present, the most common after-treatment technologies used for particulates are the diesel and gasoline particulate filters. The typical size distribution of the particles is such that the smallest particles in terms of size are in numbers the largest, although they are not influencing the total particle mass significantly. The most recent legislation have included restrictions on the particle number as well as particle mass. In this thesis numerical tools for studying the transport and interaction of particles in an exhaust flow are evaluated. The specific application is particle agglomeration as a mean to reduce the number of particles and manipulate the size distribution. As particles agglomerate the particle number distribution is shifted and larger sized agglomerates of particles are created reducing the number of ultra-fine particles. The particle agglomeration is obtained by forcing sudden acceleration and deceleration of the host gas carrying the particles by variations in the cross sectional areas of the geometry it is passing through. Initially, a simplified one dimensional model is utilized to assess the governing parameters of particle grouping. Grouping here means that the particles form and are transported in groups, thus increasing the probability for agglomeration. The lessons learned from the 1D-model are also used to design the three dimensional geometry: an axisymmetric corrugated pipe. Two different geometries are studied, they both have the same main pipe diameter but different diameter on the corrugations. The purpose is to find the potential onset of flow instabilities and the influence of 3D-effects such as recirculation on the agglomeration. The CFD simulations are performed using DES methodology. First the simulations are run without particles in a non pulsatile flow scenario. Later particles are added to the setup in a one way coupled approach (no particle-particle interaction). The main results were: 1) An additional criterion for grouping to the ones given in previous work on the 1D model is proposed. It is found that grouping is more likely if the combination of the pulse frequency and geometric wavelength is large. Furthermore, smooth pulse forms (modelling the modulation in the flow due to the geometry) yielded more grouping than other more abrupt pulse shapes. However, idealised inlet pulses underestimate the extent of grouping compared to actual engine pulses. 2) For the geometry with larger maximum cross sectional area stronger flow separation was observed along with higher turbulent kinetic energy. 3) Particles were added in the flow field and a reduction in the particle count was observed in the initial simulations for particles going from the first corrugated segment to the last. Natural extensions of the present work would be to consider pulsatile flow scenarios, particle-particle interaction and a polydisperse setup for the particles / <p>QC 20181008</p>

During this master thesis, the possibility of ammonia removal from digestate in combination with after hygienization has been investigated. The aim of the work was to see how much ammonia that could be removed but also the properties of other process parameters such as TS/VS content, pH and alkalinity of the digestate. It was also of interest to study the energy balances for a process that combines ammonia stripping with after hygienization. The purpose of hygienization in a biogas plant is to kill pathogens. To study ammonia stripping combined with after hygienization, a prototype of an ammonia stripper was built in a laboratory. The digestate was heated to the hygienization temperature of 70 °C and air was led through with the help of a peristaltic pump by the end of the system. Condensate was trapped in a bottle by cooling the tube and the gases were brought to another bottle containing 1 M sulfuric acid. Ammonia and sulfuric acid reacted and formed ammonium sulfate. The process was also tested with closed system using vacuum to decrease the boiling point and thereby create more condensate. The results from the experiments showed that with an air stripping process most of the ammonium was trapped in the sulfuric acid while with a vacuum process more ammonium was trapped in the condensate. The most important parameters to achieve a good ammonia removal were air flow and time. With the vacuum system, more condensate was removed. The removal of condensate could make it possible to recirculate process fluid from the stripping process and thereby save energy in the centrifugation part which is used to create a solid part of the bio digestate. It was concluded from the experiments that air stripping is more effective when it comes to ammonium recovery. The process could be improved by using higher air flow which could decrease the time to less than one hour, which is the desired hygienization time. However, it is desired to keep the pump flow as low as possible since it is energy consuming. A chemical increase of the pH would also be of interest to try since previous tests showed a strong correlation between high pH-value and good ammonia stripping. More tests overall are of interest to ensure a reliable result. Still, the combination of after-hygienization and ammonia stripping would contribute to a better environment and a sustainable agriculture with a natural and nutritious digestate.

[ES] Esta tesis doctoral abarca el desarrollo de algoritmos orientados a mejorar el sistema de control de emisiones en motores Diesel. Para este propósito, la inclusión en el vehículo de sensores embarcados como los de temperatura, los de NOx o el de NH3 permite realizar diagnóstico a bordo de los sistemas de post-tratamiento foco de este trabajo, los cuales son el DOC y el SCR. Así pues, el objetivo es el de satisfacer las normativas de diagnóstico a bordo para mantener las emisiones por debajo del umbral permitido por la normativa a lo largo del tiempo. Los tests experimentales, incluyendo las medidas con analizador de gases, permiten tener una visión más amplia de las especies en la línea de escape. Complementariamente, se utilizan unidades nuevas y envejecidas para tener el efecto experimental del envejecimiento en los catalizadores. De esta manera, se analiza el efecto de la temperatura, el gasto de escape, las concentraciones de las especies y el envejecimiento en el DOC y en el SCR, así como la evaluación de algunas de las medidas relevantes realizadas por los sensores. Las temperaturas tienen una influencia destacada en el funcionamiento de los catalizadores, por lo que se requiere la evaluación de las medidas de los sensores de temperatura, junto con el desarrollo de modelos de transmisión de calor, para alimentar las funciones a continuación desarrolladas. En este sentido, la medida lenta del sensor aguas arriba del DOC se mejora en condiciones transitorias mediante una técnica de fusión de la información basada en un filtro de Kalman. Luego, se presenta un modelo de transmisión de calor 1D y un modelo agrupado 0D, en los cuales se evalúan las entradas aguas arriba según el uso del modelo. Por otra parte, se presenta una técnica para estimar el incremento de temperatura debido a la oxidación de los pulsos de post-inyección en el DOC. Se proponen modelos para ambos DOC y SCR para estimar el efecto del envejecimiento en las emisiones, en los cuales el factor de envejecimiento es modelado como un parámetro sintonizable que permite variar desde estados nuevos a envejecidos. Por una parte, un modelo agrupado 0D es desarrollado para el DOC con el propósito de estimar el desliz de HC y CO, el cual es validado en un WLTC para después ser usado en simulación. Por otra parte, un modelo 1D y un modelo 0D se desarrollan para el SCR, los cuales se usan a continuación para alimentar la estrategia de diagnóstico y para simulación. Finalmente, las estrategias de diagnóstico se presentan para fallo total o retirada de DOC, así como para la estimación de la eficiencia en DOC y SCR. Por una parte, la primera estrategia se divide en pasiva y activa, en la que se usan post-inyecciones en la activa para excitar el sistema y confirmar el fallo total si es el caso. A continuación, la eficiencia del DOC se estima a través de una técnica indirecta en la que la temperatura de activación se detecta y se relaciona con el incremento de emisiones a través del modelo. Por otra parte, se desarrolla un observador para estimar el estado de envejecimiento del SCR, el cual está basado en un filtro de Kalman extendido. Sin embargo, para evitar asociar baja eficiencia del catalizador debido a pobre calidad de la urea inyectada, a envejecimiento del SCR, un indicador de la calidad de la urea se ejecuta en paralelo. / [CA] Esta tesi doctoral abasta el desenvolupament d'algoritmes orientats a millor el sistema de control d'emissions en motors Diesel. Per a este propòsit, la inclusió en el vehicle de sensor embarcats com els de temperatura, els de NOx o el d'NH3 permet realitzar el diagnòstic a bord dels sistemes de post-tractament focus d'este treball, els quals són el DOC i el SCR. Així doncs, l'objectiu és el de satisfer les normatives de diagnòstic a bord per a mantindre les emissions per baix de l'umbral permés per la normativa al llarg del temps. Els tests experimentals, incloent les mesures amb analitzador de gasos, permeten obtindre una visió més àmplia de les espècies en la línia d'escapament. Complementàriament, s'utilitzen unitats noves i envellides per tal de tindre l'efecte experimental de l'envelliment en els catalitzadors. D'aquesta manera, s'analitza l'efecte de la temperatura, la despesa d'escapament, les concentracions de les espècies i l'envelliment en el DOC i en el SCR, així com l'avaluació d'algunes mesures rellevants realitzades pels sensors. Les temperatures tenen una influència destacada en el funcionament dels catalitzadors, pel que es requerix l'avaluació de les mesures dels sensors de temperatura, junt amb el desenvolupament de models de transmissió de calor, per a alimentar les funcions a continuació desenvolupades. En este sentit, la mesura lenta del sensor a l'entrada del DOC es millora en condicions transitòries mitjançant una tècnica de fusió de la informació basada en un filtre de Kalman. Després, es presenta un model de transmissió de calor 1D i un model agrupat 0D, en els quals s'avaluen les entrades a l'entrada segons l'ús del model. Per altra banda, es presenta una tècnica per a estimar l'increment de temperatura degut a l'oxidació dels polsos de post-injecció en el DOC. Es proposen models per a DOC i SCR per a estimar l'efecte de l'envelliment en les emissions, en els quals es modela el factor d'envelliment com un paràmetre sintonitzable, que permet variar des d'estats nous a envellits. Per altra banda, un model agrupat 0D _es desenvolupat per al DOC amb el propòsit d'estimar la relliscada de HC i CO, el qual és validat en un WLTC per a després ser usat en simulació. Per altra banda, un model 1D i un model 0D es desenvolupen per al SCR, els quals s'usen a continuació per a alimentar l'estratègia de diagnòstic i per a simulació. Finalment, les estratègies de diagnòstic es presenten per a la fallada total o retirada del DOC, així com per a l'estimació de l'eficiència en DOC i SCR. Per altra banda, la primera estratègia es divideix en passiva i activa, en la que s'utilitzen post-injeccions en la activa per a excitar el sistema i confirmar la fallada total si es dona el cas. A continuació, l'eficiència del DOC s'estima a través d'una tècnica indirecta en la que la temperatura d'activació es detecta i es relaciona amb l'increment d'emissions a través del model. Per altra banda, es desenvolupa un observador per a estimar l'estat d'envelliment del SCR, el qual està basat en un filtre de Kalman extés. No obstant això, per a evitar associar baixa eficiència degut a pobre qualitat de l'urea injectada a l'envelliment del SCR, un indicador de la qualitat de l'urea s'executa en paral·lel. / [EN] This dissertation covers the development of algorithms oriented to improve the emission control system of Diesel engines. For this purpose, the inclusion of on-board sensors like temperature, NOx and NH3 sensors allows performing on-board diagnostics to the after-treatment systems focus of this work, which are the DOC and the SCR system. Then, the target is to meet on-board diagnostics regulations in order to keep emissions below a regulation threshold over time. Experimental tests, including gas analyzer measurements, allow having a wider view of the species in the exhaust line. Complementary, new and aged units are used in order to have the experimental effect of ageing on the catalysts. Then, the effect of temperature, exhaust mass flow, species concentrations and ageing is analyzed for DOC and SCR, in combination with the assessment of some relevant sensors measurements. As a result, the characteristics, opportunities and limitations extracted from experimental data are used as the basis for the development of models and diagnostics techniques. The assessment of temperature sensors measurements, along with the development of heat transfer models is required to feed temperature dependent functions. In this sense, the slow measurement of the DOC upstream temperature sensor is improved in transient conditions by means of a data fusion technique, based on a fast model and a Kalman filter. Then, a 1D and a 0D lumped heat transfer models are presented, in which the upstream inputs are assessed in relation to its use. On the other hand, a technique to estimate the temperature increase due to post-injection pulses oxidation is also presented. Both DOC and SCR models are proposed in order to estimate the effect of ageing on emissions, in which an ageing factor is modelled as a tunable parameter that allows varying from new to aged states. On the one hand, a 0D lumped model is developed for DOC in order to estimate the HC and CO species slip, which is validated in a WLTC and is then used for simulation. On the other hand, a 1D and a 0D models are developed for SCR, which are then used to feed the diagnostics strategy and for simulation. Finally, diagnostics strategies are presented for total failure or removal of DOC, as well as for efficiency estimation of DOC and SCR. On the one hand, the former strategy is separated into passive and active diagnostics, in which post-injections are used in active diagnostics in order to excite the system and confirm a total failure, in case. Then, the DOC efficiency estimation is done by means of an indirect technique in which the light-off temperature is detected and an emissions increase is related by means of the DOC ageing model. On the other hand, an observer to estimate the SCR ageing state is developed, which is based on an extended Kalman filter. However, in order to avoid associating low SCR efficiency to ageing, an indicator of the injected urea quality is developed to run in parallel. / Mora Pérez, J. (2018). Control-oriented modelling and diagnostics of diesel after-treatment catalysts [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/115937

Les normes plus restrictives visent à réduire les émissions de polluants, en particulier le CO2, favorisant l'usage des biocarburants. Cependant, le biodiesel contient des éléments inorganiques (Na, K, Ca et P) qui réduisent la durabilité des systèmes de post-traitement. Dans ce travail sont évalués les performances des catalyseurs d'oxydation diesel (DOCs, catalyseur de référence PtPd/CeZrO2/La-Al2O3). Les résultats de caractérisation ont montré l’influence de ces impuretés sur les propriétés physico-chimiques et catalytiques. Bien que la structure cristalline du catalyseur de référence ne change pas après l'incorporation des impuretés, la surface spécifique diminue. La capacité redox a diminué lorsque les impuretés Na, K et Ca sont présents du à leur faible électronégativité, ce qui augmente l'interaction avec l'oxygène. Cette interaction semble être responsable de l’augmentation de la vitesse de réaction de C3H6. Les résultats NO-TPD ont montré que la forte basicité ces impuretés entraînait une plus forte adsorption du NO. Par DRIFT il a été aussi montré que l’adsorption des intermédiaires du NO, associée au champ électrostatique créé par ces cations, empêche l'oxydation de NO. L'adsorption de CO a été favorisée, améliorant la conversion du CO. La formation de phosphate de cérium observée pourrait stabiliser l'état d'oxydation de Ce3+ (vérifié par XPS), en diminuant l'oxydation de NO due au blocage des sites catalytiques. Néanmoins, les co-oxydations de CO et de C3H6 ont été améliorées en évitant l'auto-empoisonnement. Après vieillissement hydrothermal, l'effet des impuretés a été masqué par le frittage de Pt/Pd, ce qui diminue les performances catalytiques / The more restrictive regulations to reduce pollutants emissions, especially CO2, promote the use of biofuels. However, biodiesel contains inorganic elements (Na, K, Ca and P) that reduce the durability of the after-treatment catalysts. This work aims to evaluate the performance of Diesel Oxidation Catalysts (DOCs, PtPd/CeZrO2/La-Al2O3 reference catalyst). The characterization results have shown that the above-mentioned impurities affect the physico-chemical, redox, surface and catalytic properties. Although the catalyst crystalline structure of reference catalyst did not change after impurities incorporation, the specific surface area decreased. The redox ability was also decreased when Na, K and Ca impurities are present due to their low electronegativity, which increased the oxygen interaction. This high interaction seems to be responsible of the enhanced C3H6 reaction rate. NO-TPD results evidenced that the high basicity of Na, K and Ca impurities resulted in an increase of NO adsorption strength. Accordingly, DRIFT results showed the presence of NO intermediates adsorption associated to the electrostatic field created by these cations, hindering NO oxidation. CO adsorption was also promoted, enhancing CO reaction rate. The formation of cerium phosphate was also observed, which could stabilize the Ce3+ oxidation state (checked by XPS), decreasing NO oxidation due to the blockage of catalytic sites. Nevertheless, CO and C3H6 co-oxidations were enhanced by avoiding self-poisoning. After catalyst hydrothermal aging, the effect of impurities was masked by the sintering of Pt/Pd active sites, which decreases the DOC catalytic performances

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[ES] Para cumplir los límites de emisiones impuestos por los gobiernos y reducir el impacto negativo en el medio ambiente, el uso de sistemas de postratamiento (ATS) se ha convertido en algo esencial para los motores de combustión interna. Los ATS en los trenes motrices están planteados para lograr una alta eficiencia de reducción de contaminantes en las condiciones de funcionamiento diseñadas, para lo cual el sistema de control necesita conocer el nivel de desgaste del catalizador, así como confiar en la información de retroalimentación de los subsistemas de los ATS. Además, es posible aumentar la capacidad de reducción de contaminantes de los catalizadores mediante estrategias de control inteligentes. Ante este escenario, esta tesis pretende aplicar técnicas de monitorización y diagnóstico para garantizar el pleno funcionamiento del ATS, y estrategias de control óptimo para mejorar la reducción de las emisiones de NOx con bajo consumo y deslizamiento de NH3. Para lograr este objetivo, se han planteado dos caminos: ¿ Desarrollo de modelos de alta precisión para la predicción de las emisiones de NOx y NH3 acoplados a un algoritmo de fusión de datos, siendo aplicados para diagnosticar el sistema en dos enfoques específicos: detección del nivel de fallo de inyección de amoníaco en el ATS y estimación del estado de envejecimiento del catalizador del ASC. ¿ Uso de modelos físicos orientados al control para mejorar la estrategia de inyección de amoníaco. Se optimizaron dos escenarios, primero, un enfoque de referencia para la optimización off-line conociendo de antemano el ciclo de conducción, logrando así la máxima capacidad del sistema para reducir los NOx con el mínimo consumo de NH3. En segundo lugar, la optimización on-line mediante la técnica de control predictivo de modelos (MPC) con el objetivo de conseguir la máxima reducción de NOx con un deslizamiento de NH3 aguas abajo del catalizador ASC inferior a un límite preestablecido. Todos los modelos desarrollados y los enfoques propuestos se implementaron en un banco de pruebas totalmente instrumentado y se validaron experimentalmente, alcanzando resultados satisfactorios en ambos enfoques, diagnóstico y control. / [CAT] Per a complir els límits d'emissions imposats pels governs i reduir l'impacte negatiu en el medi ambient, l'ús de sistemes de posttractament (ATS) s'ha convertit en una cosa essencial per als motors de combustió interna. Els ATS als trens motrius estan plantejats per a aconseguir una alta eficiència de reducció de contaminants en les condicions de funcionament dissenyades, per a això el sistema de control necessita conéixer el nivell de desgast del catalitzador, així com confiar en la informació de retroalimentació dels subsistemes dels ATS. A més, és possible augmentar la capacitat de reducció de contaminants dels catalitzadors mitjançant estratègies de control intel·ligents. Davant aquest escenari, aquesta tesi pretén aplicar tècniques de monitoratge i diagnòstic per a garantir el ple funcionament de l'ATS, i estratègies de control òptim per a millorar la reducció de les emissions de NOx amb baix consum i lliscament de NH3. Per a aconseguir aquest objectiu, s'han plantejat dos camins: ¿ Desenvolupament de models d'alta precisió per a la predicció de les emissions de NOx i NH3 acoblats a un algorisme de fusió de dades, sent aplicats per a diagnosticar el sistema en dos enfocaments específics: detecció del nivell de fallada d'injecció d'amoníac en l'ATS i estimació de l'estat d'envelliment del catalitzador del ASC. ¿ Ús de models físics orientats al control per a millorar l'estratègia d'injecció d'amoníac. Es van optimitzar dos escenaris, primer, un enfocament de referència per a l'optimització off-line coneixent per endavant el cicle de conducció, aconseguint així la màxima capacitat del sistema per a reduir els NOx amb el mínim consum de NH3. En segon lloc, l'optimització en línia mitjançant la tècnica de control predictiu de models (MPC) amb l'objectiu d'aconseguir la màxima reducció de NOx amb un lliscament de NH3 aigües avall del catalitzador ASC inferior a un límit preestablit. Tots els models desenvolupats i els enfocaments proposats es van implementar en un banc de proves totalment instrumentat i es van validar experimentalment, aconseguint resultats satisfactoris en tots dos enfocaments, diagnòstic i control. / [EN] To meet the emission limits imposed by governments and reduce the negative outcome on the environment, the use of after-treatment systems (ATS) has become essential for internal combustion engines. The ATS in powertrains are devised to achieve high pollutant abatement efficiency under the design operating conditions, for which the control system needs to know the catalyst wear level as well as to rely on feedback information from the ATS subsystems. Furthermore, it is possible to increase the pollutant reduction capacity of catalysts through intelligent control strategies. Looking at this scenario, this thesis intends to apply techniques of monitoring and diagnosis to guarantee the full operation of the ATS, and optimal control strategies to improve the reduction of NOx emissions with low NH3 consumption and slip. To this aim, two paths were outlined: ¿ Development of high accuracy models for the prediction of NOx and NH3 emissions coupled with a data fusion algorithm, being applied to diagnose the system in two specific approaches: detection of the ammonia injection failure level in the ATS and estimation of the ASC catalyst ageing state. ¿ Use of physical control-oriented models to improve the ammonia injection strategy. Two scenarios were optimized, firstly a benchmark approach for off-line optimization knowing in advance the driving cycle, thus achieving the maximum capacity of the system to reduce NOx with minimum NH3 consumption. Secondly, on-line optimization through the model predictive control (MPC) technique aiming the maximum NOx abatement with NH3 slip downstream the ASC catalyst below a pre-established threshold. All developed models and proposed approaches were implemented in a fully instrumented test bench and experimentally validated, reaching satisfactory results in both approaches, diagnosis and control. / Nakaema Aronis, A. (2023). Control and Diagnosis of a SCR-ASC After-Treatment System for NOx and NH3 Emission Reduction Under Real Driving Conditions and Potential System Failure [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/192476