Made available in DSpace on 2014-12-17T14:57:40Z (GMT). No. of bitstreams: 1 OsvaldoCS.pdf: 1194235 bytes, checksum: da247435df103f473806af70be8f1c3e (MD5) Previous issue date: 2007-06-01 / The study of the physical and mechanic properties is an analysis of unquestioned importance on the production of the ceramic materials. In the region of the Rec?ncavo Baiano, there are ceramic and small brick factories, that still use rudimentary techniques, where the necessity of characterization of raw materials is denounced by the quality of the final product. The present work has for objective to study the behavior of the clay proceeding from the region of the Rec?ncavo, between the cities of Candeias and Cama?ari/Ba, with addition of 5, 10 and 15% by weight of brick scraps, trying to optimize the physic and mechanical properties of the final product, aiming a better possibility of being manufactured, mechanic resistance, low linear retraction and water absorption. The brick scraps and the clay were characterized by FRX, DRX, TG, ATD and the granulometric analysis. Samples for testing where prepared by uniaxial pressing at 25Mpa, in 60x20x5mm size. The evaluated technological properties were: linear retraction, water absorption, apparent porosity and flexural strength. The samples were burned in electric oven in the temperatures of 850?, 950? and 1050?C and compared its mechanical properties and the gresification. With addition of 15% by weight of brick scraps and burning at 900?-1000?C the samples showed properties superior to that clay / O estudo das propriedades f?sicas e mec?nicas ? uma an?lise de import?ncia inquestion?vel na produ??o dos materiais cer?micos. Na regi?o do Rec?ncavo Baiano, encontram-se cer?micas e pequenas olarias, que ainda utilizam t?cnicas rudimentares, onde a necessidade de caracteriza??o das mat?rias-primas ? denunciada pela qualidade do produto final. O presente trabalho tem por objetivo estudar o comportamento da argila proveniente da regi?o do Rec?ncavo Baiano, compreendida entre os munic?pios de Candeias e Cama?ari, com adi??o de 5, 10 e 15% em peso de rejeitos cer?micos, procurando otimizar as propriedades f?sico-mec?nicas do produto final, visando uma melhor trabalhabilidade, resist?ncia mec?nica e baixas retra??o linear e absor??o de ?gua. O rejeito cer?mico e a argila foram caracterizados por FRX, DRX, TG, ATD e analise granulom?trica. Foram preparados corpos-de-prova com dimens?es de 60x20x5mm, por prensagem uniaxial a 25MPa. As propriedades tecnol?gicas avaliadas foram: retra??o linear, absor??o de ?gua, porosidade aparente e resist?ncia mec?nica ? flex?o. Os corpos foram sinterizados em forno resistivo nas temperaturas de 850?, 950? e 1050?C e comparadas suas propriedades mec?nicas e a gresifica??o. Obteve-se para os corpos com incorpora??o de 15% em peso de rejeitos cer?micos, propriedades superiores as da argila, nas temperaturas entre 900? e 1000? C

Made available in DSpace on 2014-12-17T14:57:48Z (GMT). No. of bitstreams: 1 MaurilioML.pdf: 1402196 bytes, checksum: 5d957dc60dc4fcde085c9265b4ecfe9b (MD5) Previous issue date: 2008-10-15 / The red ceramics and structural ceramics, as they are known, include ceramic materials made by blocks of seals and structures, bricks, tiles, smail flagstones manacles, rustic floors and ornamental materials. Their fabrication uses raw material such as clay and clay sites, with some content of impurity. It has good durability and mechanical strength to compression, low cost, making it one of the mainly used materials in civil engineering. The incorporation of many industrial activities residue to ceramic products is a technological alternative for reducing the environmental impact caused by its carefree disposal. This incorporation can promote chemical change and inertness of metals from residue, by fixation in the glassy phase of ceramic during the burning stage. The main aim of this project is to study the technical feasibility of the addition of ceramic oven ash into formulations of mass for structural ceramics. In this project two kinds of clay (plastic and non-plastic) were used, as well as the ash from firewood used in the process of burning of structural ceramics. A group of experiments was outlined, which permitted the evaluation of the influence of the burning cycle in different temperatures of the ash content in formulations for ceramic blocks through technological properties, mechanical behavior and microstructure. Five samples were processed of each one of the masses of plastic and non-plastic clay without addition of ash and with addition of ash on the percentages of 10 % and 20 %, for temperatures of 850 ?C, 950 ?C, 1050 ?C and 1150 ?C, obtained through sinterization process. Among the studied compositions, the one which presented best performance was the mass of clay with 10 % of ash, at temperature of 1150 ?C, with the smallest absorption of water, the smallest apparent porosity, specific apparent mass a bit over the others and greatest mechanical resistance to flexion. The composition made confirmed the technical feasibility of the use of ash in the mass for structural ceramics with maintenance of its necessary characteristics for its purposes / A cer?mica vermelha ou estrutural, como ? conhecida, compreende os materiais cer?micos formados por blocos de veda??es e estruturais, tijolos, telhas, lajotas, manilhas, pisos r?sticos e materiais ornamentais. Sua fabrica??o utiliza mat?rias-primas como argilas e siltes argilosos, com certo teor de impurezas. Possui boa durabilidade e resist?ncia mec?nica ? compress?o, baixo custo, o que a torna um dos principais materiais utilizados na constru??o civil. A incorpora??o de res?duos de diversas atividades industriais em produtos de cer?mica estrutural ? uma alternativa tecnol?gica para reduzir o impacto ambiental causado por sua disposi??o indiscriminada. Esta incorpora??o pode promover a troca qu?mica e a inertiza??o de metais, provenientes do res?duo, por fixa??o na fase v?trea da cer?mica durante o est?gio de queima. O trabalho em quest?o tem como objetivo principal estudar a viabilidade t?cnica de adi??o de cinza de alto forno cer?mico em formula??es de massa para cer?mica estrutural. Neste trabalho foram utilizadas duas argilas (pl?stica e n?o-pl?stica), assim como a cinza provinda da lenha utilizada no processo de queima de cer?mica estrutural. Delineou-se um conjunto de experimentos que permitiram avaliar a influ?ncia do ciclo de temperatura de queima em temperaturas diferentes do teor de cinzas em formula??es para blocos cer?micos atrav?s das propriedades tecnol?gicas, comportamento mec?nico e microestrutura. Foram processadas cinco amostras de cada uma das massas de argila pl?stica e n?o pl?stica sem adi??o de cinza e com adi??o de cinza nos percentuais de 10 % e 20 %, para temperaturas de 850 0C, 950 0C, 1050 0C e 1150 0C, tendo sido obtidas atrav?s do processo de sinteriza??o. Das composi??es estudadas com cinza, a que apresentou melhor desempenho foi a massa de argilas com 10 % de cinza, na temperatura de 1150 ?C, com a menor absor??o de ?gua, menor porosidade aparente, massa espec?fica aparente pouco acima das outras e maior resist?ncia mec?nica ? flex?o. A composi??o efetuada comprovou a viabilidade t?cnica da utiliza??o de cinza na massa para cer?mica estrutural, com manuten??o das suas caracter?sticas necess?rias para os fins a que se destinam

Made available in DSpace on 2014-12-17T14:58:06Z (GMT). No. of bitstreams: 1 RodrigoMS_DISSERT.pdf: 4460162 bytes, checksum: 823c9d3e0475b4431fb15b4de861b51b (MD5) Previous issue date: 2011-03-30 / In the State of Rio Grande do Norte potteries are distributed in several counties in the four meso, which are: West Potiguar, Center Potiguar, Agreste Potiguar and East Portiguar. The ceramics, mostly, are responsible for products used in construction as bricks, tiles and white brick and wood used as fuel. This paper had a primary focus in the region of Serid?. The furnaces in this region, used to manufacture bricks are configured Caieira and Valt, in most of them using principles rustic, usually operated in an empirical way, using principles of control rather primitive, predominantly visual control. The focus of this study was to analyze the differences in the thermophysical, mechanical and geometric characteristics of bricks produced by Caieira and vault furnaces, using the NBR 15720 and the evaluation of energy efficiency in both furnaces. Thermophysical characteristics were analyzed through tests to determine the water absorption obtained from the difference between dry mass and wet mass of the sample and analysis of the thermal gradient, the mechanical characteristics from determination of the compressive strength of ceramic brick popularly known as bricks and also analyzed the geometrical characteristics of the bricks in order to verify the homogeneity of manufacturing. The tests showed that the energy difference of the two furnaces is not considered responsible for a significant difference in the properties of the products / No estado do Rio Grande do Norte as olarias s?o distribu?das em diversos munic?pios, nas quatro mesorregi?es, que s?o: Oeste Potiguar, Centro Potiguar, Agreste Potiguar e Leste Potiguar. As cer?micas, em sua maioria, s?o respons?veis por produtos utilizados na constru??o civil como tijolos furados, tijolos brancos e telhas e utilizam como combust?vel a lenha. Este trabalho teve um enfoque principal na ind?stria cer?mica na regi?o do Serid?. Os fornos nessa regi?o, utilizados para a fabrica??o de tijolos furados possuem a configura??o caieira e ab?bada, geralmente operados de forma emp?rica, utilizando princ?pios de controle bastante primitivos, sendo predominante o controle visual. O objetivo deste trabalho foi analisar as diferen?as nas caracter?sticas termof?sicas, mec?nicas e geom?tricas dos tijolos produzidos pelos fornos caieira e ab?bada, utilizando a NBR 15720, que trata de blocos de alvenaria e a avalia??o do rendimento energ?tico de ambos os fornos. Foram analisadas as caracter?sticas termof?sicas por meio dos ensaios de determina??o da absor??o de ?gua obtido a partir da diferen?a entre a massa seca e a massa ?mida das amostras e da an?lise do gradiente t?rmico; as caracter?sticas mec?nicas a partir da determina??o da resist?ncia ? compress?o dos blocos cer?micos popularmente conhecidos como tijolos e tamb?m foram analisadas as caracter?sticas geom?tricas dos tijolos com o objetivo de verificar a homogeneidade da fabrica??o. Os ensaios realizados mostraram que a diferen?a energ?tica dos dois tipos de fornos analisados n?o ? respons?vel por uma diferen?a significativa nas propriedades dos produtos produzidos

Made available in DSpace on 2014-12-17T15:01:17Z (GMT). No. of bitstreams: 1 AnaPCC_Restricao_total.pdf: 752303 bytes, checksum: 654aeb93235755a52cbaf1212dfece64 (MD5) Previous issue date: 2009-02-19 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / In this work is the addition of a metallic ion, of the metal Manganese, in a clay of Rio Grande do Norte state for structural ceramics use, the objective this study was to assess the evolution of ceramic properties. The clay was characterized by Chemical and Thermal analysis and Xray difraction. The metallic ion was added in the clay as aqueous solutions at concentrations of 100, 150 and 200 mg / L. The molded by extrusion and the burned were temperatures at 850, 950, 1050 and 1150 ? C. Was made Chemical Analysis and investigated the following parameters environmental and ceramic: Solubility, Colour, Linear Retraction (%), Water Absorption (%), Gresification Curves, Apparent Porosity (%), Apparent Specific Mass (g/cm3) and Flexion Rupture Module (kgf/cm2). The results showed that increasing the concentration of metallic ion, properties such as Apparent Porosity (%), Water Absorption (%) decreases and the Flexion Rupture Module (kgf/cm2) increases with increasing temperature independent of the concentration of the ion. The gresification curves showed that the optimum firing temperatures were in the range between 950 and 1050 ? C. The evaluation of the properties showed that the ceramic material can be studied its use in solid brick and ceramic materials with structural function of filling. The results of solubility showed that the addition of ion offers no risk to the environment / Neste trabalho estudou-se a adi??o de um ?on met?lico, Mangan?s bivalente, em uma argila do Rio Grande do Norte para uso em cer?mica estrutural, tendo como objetivo avaliar a evolu??o das propriedades cer?micas e ambientais. A argila foi caracterizada por An?lise Qu?mica (FRX) e Difratograma de Raios X (DRX). O ?on met?lico foi adicionado ? argila na forma de solu??es aquosas nas concentra??es de 100, 150 e 200 mg/L. A moldagem foi por extrus?o e a queima foi realizada nas temperaturas de 850, 950, 1050 e 1150 ?C respectivamente. Fez-se a An?lise Qu?mica de corpos queimados, e os ensaios ambientais de Solubilidade e cer?micos de Cor, Retra??o Linear (%), Absor??o de ?gua (%), Curvas de Gresifica??o, Porosidade Aparente (%), Massa Espec?fica Aparente (g/cm3) e Tens?o de Ruptura ? Flex?o (Kgf/cm2) para os corpos queimados. Os resultados mostraram que aumentando a concentra??o do ?on met?lico, propriedades como Porosidade Aparente (%), Absor??o de ?gua (%) diminuem e a Tens?o de Ruptura ? Flex?o (Kgf/cm2) cresce com o aumento da temperatura independente da concentra??o do ?on. As curvas de gresifica??o mostraram que as temperaturas ?timas de queima ficaram no intervalo compreendido entre 950 e 1050 ?C. A avalia??o das propriedades cer?micas demonstrou que o material estudado ? poss?vel seu uso em tijolo maci?o cer?mico e materiais com fun??o de preenchimento estrutural. Os resultados de solubilidade revelaram que a adi??o do ?on n?o oferece risco ao meio ambiente

Made available in DSpace on 2014-12-17T15:14:53Z (GMT). No. of bitstreams: 1 ElcioCST_DISSERT.pdf: 3894330 bytes, checksum: 2a548c4a2bfaf88d5c10cfd9d56e3361 (MD5) Previous issue date: 1993-09-03 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / This work is part of an effort of consolidation of a daily search for powder technology at the Department of Physics of the Universidade Federal do Rio Grande do Norte. This work objective the study and development of new ceramic materials from raw materials abundant at the region. For this, were studied ceramic mixtures of powders from diatomite-titania to aiming at a new ceramic material from powder technology. The experimental work involved a characterization of ceramic powders from a diatomite-titania mixture. The powders obtained were pressed and then parameters like variation of mass, linear shrinkage, activation energy and the mechanism of sintering are studied in function of the time and temperature of sintering, beyond microstructural analysis. The obtained results allow us estimate the optimizing of sintering conditions of this material / Este trabalho ? parte do esfor?o para consolida??o de uma rotina de pesquisa em tecnologia do p? no Departamento de F?sica Te?rica e Experimental da Universidade Federal do Rio Grande do Norte. 0 trabalho objetiva o estudo e desenvolvimento de novos materiais cer?micos a partir de mat?rias primas abundantes na regi?o. Neste sentido foram estudadas misturas cer?micas de p?s de diatomita-tit?nia visando a obten??o de um novo material cer?mico a partir do processamento pela tecnologia do p?. O trabalho experimental envolveu a caracteriza??o de p?s cer?micos obtidos da mistura de di?xido de tit?nio (tit?nia) com diatomita. Os p?s assim obtidos s?o compactados e ? feito um estudo relacionando a varia??o de massa, a contra??o linear, a energia de ativa??o e o mecanismo de sinteriza??o predominante em fun??o da temperatura e do tempo de sinteriza??o, al?m da an?lise microestrutural. Os dados obtidos fornecem subs?dios para a otimiza??o dos par?metros de sinteriza??o do material

Made available in DSpace on 2014-12-17T15:14:54Z (GMT). No. of bitstreams: 1 FabioHSS_DISSERT.pdf: 2027272 bytes, checksum: 919f3e2ba610b0903c6a4bfaa7fcdd5d (MD5) Previous issue date: 1997-09-12 / Este trabalho tem como objetivo estudar a influ?ncia da adi??o de diversos aditivos tais como ?xido de sil?cio (SiO2), ?xido de bismuto (BiO2), ?xido de c?rio (CeO2) e ?xido de lant?nio (La2O3) nas propriedades el?tricas e diel?tricas do titanato de b?rio (BaTiO3) policristalino. As amostras de titanato de b?rio foram compactadas e sinterizadas no Laborat?rio de Tecnologia dos P?s, do Departamento de F?sica da Universidade Federal do Rio Grande do Norte. Foram realizadas medidas de resistividade el?trica e constante diel?trica em fun??o da temperatura, bem como ensaios de difra??o de raios-X e an?lise microestrutural atrav?s da microscopia eletr?nica de varredura. A an?lise dos resultados permitiu avaliar a influ?ncia dos aditivos nas propriedades el?tricas e diel?tricas, e propor a utiliza??o de cer?micas eletr?nicas a base de titanato de b?rio com propriedades superiores as do material existente atualmente

Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2017-01-12T13:22:33Z No. of bitstreams: 1 KarineFonsecaSoares_DISSERT.pdf: 2976075 bytes, checksum: b560a351beeba6e2e2f1180927badcfb (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2017-01-16T14:24:12Z (GMT) No. of bitstreams: 1 KarineFonsecaSoares_DISSERT.pdf: 2976075 bytes, checksum: b560a351beeba6e2e2f1180927badcfb (MD5) / Made available in DSpace on 2017-01-16T14:24:12Z (GMT). No. of bitstreams: 1 KarineFonsecaSoares_DISSERT.pdf: 2976075 bytes, checksum: b560a351beeba6e2e2f1180927badcfb (MD5) Previous issue date: 2016-01-29 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / A ind?stria de processamento t?xtil agrega benef?cios econ?micos e sociais ao estado do Rio Grande do Norte desde 1949. Entretanto, ao longo da cadeia produtiva deste segmento diversas opera??es levam a gera??o de res?duos s?lidos, l?quidos e gasosos, os quais apresentam grande potencial poluidor tornando essencialmente necess?rio o tratamento dos efluentes oriundo desse setor. Ao final dos processos de tratamento dos efluentes t?xteis ? obtido um res?duo s?lido denominado lodo, que ? constitu?do basicamente por mat?ria org?nica e metais pesados. Nas ?ltimas d?cadas, a preocupa??o acerca do destino final, tratamento e reciclagem desse res?duo tem instigado as empresas geradoras a contribuir para a diminui??o do impacto que este material vem provocando ao meio ambiente. Neste contexto, este trabalho teve como objetivo estudar uma alternativa vi?vel para a reciclagem do lodo gerado na esta??o de tratamento de efluentes de uma ind?stria t?xtil por meio da incorpora??o ? argila para a fabrica??o de tijolos utilizados na constru??o civil. As mat?rias primas, lodo e argila, foram caracterizadas por fluoresc?ncia de raios X (FRX), difratometria de raios X (DRX), termogravimetria (TG) e an?lise t?rmica diferencial (ATD). Posteriormente, o lodo foi incorporado ? argila para a fabrica??o de barras cer?micas e tijolos em escala reduzida, nos percentuais de 0%, 10%, 20% e 30% em peso ?mido. Os corpos de prova foram sinterizados nas temperaturas de: 850, 900 e 950 ?C. As barras cer?micas e os tijolos foram avaliadas por meio dos testes de absor??o de ?gua, retra??o linear de secagem, retra??o linear de queima e resist?ncia mec?nica. Tanto para as barras quanto para os tijolos, a incorpora??o m?xima, em temperaturas de queima de 850 e 900?C, ? de 10%, sem comprometer as propriedades t?cnicas do produto. Em seguida foi realizada uma an?lise estat?stica das propriedades t?cnicas obtidas para identificar qual par?metro operacional contribuiu significativamente para o processo. Diante do exposto, pode-se concluir que ? poss?vel o reaproveitamento do lodo gerado na esta??o de tratamento da ind?stria t?xtil para a produ??o de tijolos utilizados na constru??o civil, sendo necess?rio realiza??o pr?via dos testes, uma vez que as propriedades t?cnicas variam de acordo com o processamento. / The process textile industry brings benefits economic and social to Rio Grande do Norte since 1949. However, throughout productive chain this segment, several operations lead to generation of wastes solid, liquid and gaseous, which they have great potential polluter essentially making necessary treatment of effluent coming from this sector. In the wastewater treatment processes is obtained a solid residue called sludge, consisting primarily of organic matter and heavy metals. In recent decades, concern about the final destination, treatment and recycling of this waste has instigated generating companies to contribute to reducing the impact that this material has caused to the environment. In this context, the purpose was to study a viable alternative to recycling the sludge from the treatment effluent plant by incorporating the clay to make bricks. the raw materials, sludge and clay, were characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), thermogravimetry (TG) and differential thermal analysis (DTA). Then, sludge was incorporated into the clay for the manufacture of ceramic bars and bricks scaled-down, in percentages of 0%, 10%, 20% and 30% wet weight sludge. The specimens were sintered at temperatures of: 850, 900 and 950 ? C. The ceramic bars and bricks were evaluated by tests of water absorption, linear drying shrinkage, linear firing shrinkage and mechanical strength. Both for the bars and for the bricks, maximum amount, could be 10% of sludge, at firing temperature of 850 e 900?C, without compromising the properties of the product. Then a statistical analysis was made of the mechanical properties to identify which operating parameter significantly contributed to the process. The use of textiles waste can increase the efficiency of the industries involved in the manufacture of ceramic blocks, promoting a reduction in extraction of the natural resource used, as well as provide a sustainable destination of the pollutant waste textile industry. It is necessary prior to testing, since the technical properties vary with processing.

This diploma thesis deals with cerium-based conversion coatings for aluminium alloys. At first the mechanism of protection of metals by inhibitory substances is described in the theoretical section. The next chapter is devoted to application of lanthanide salts as cathodic corrosion inhibitors. Then the characterization of alloy AA 2024 follows. The main part is dedicated to the growth mechanism of the cerium-based mixed conversion coating on the alloy AA 2024. Finally, the factors affecting the character and the quality of obtained coatings are commented. In the experimental part an influence of the thermal activation together with the activation by a hydrogen peroxide was observed. The created film was characterized using SEM and EDS. The level of corrosion protection was evaluated by the polarization resistance measurement. erized using SEM and EDS. The level of corrosion protection was evaluated by the polarization resistance measurement.

This work contains a study of CeRuSn, which undergoes two structural transitions at 290 K and 256 K both connected with large temperature hysteresis. During the transitions the lattice shrinks along the c axis. At low temperatures the compound orders antiferromagnetically below 2.8(1) K. A strong magnetocrystalline anisotropy is caused by very shortened Ce-Ru separations pointing approximately along the c axis. Due to a strong hybridization, two thirds of Cerium atoms are in a non integer valence state. For the first time synthesized single-crystals of YbPt2Si2 a Yb2Pt3Si5 show no magnetic ordering. A maximum, which is visible in the temperature dependences of magnetic susceptibility originate in thermal population of the magnetic Yb3+ state. Powered by TCPDF (www.tcpdf.org)

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