A thesis submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy, Johannesburg, 2017 / Many reinforced concrete (RC) structures in inland environment deteriorate early due to carbonation-induced corrosion of their reinforcement. In some cases, the deterioration is visible within a few years of construction in the form of cover concrete cracking. This is widely accepted as one of the limit state indicators in defining the end of functional service life for existing RC structures undergoing corrosion. Many of the currently available service life prediction models are incapable of providing realistic service life estimates of RC structures beyond the corrosion initiation stage. Therefore, the need to incorporate the corrosion initiation and propagation stages in a comprehensive durability prediction approach has been receiving much research attention. In this research, empirical models were developed for predicting carbonation rate and the amount of steel radius loss required to initiate a first visible crack in concretes exposed to Johannesburg environment. The experimental data for the models were obtained from investigations of carbonation-induced reinforcement corrosion, which were explored in three phases; (i) concrete early-age durability and strength characteristics (ii) carbonation rate of different concrete mixes exposed to the natural inland environment (iii) amount of steel radius loss required to initiate the first visible crack on the pre-carbonated cover concretes exposed to an unsheltered environment. The experimental variables for the earlyage durability and strength tests were; water/binder ratio (w/b) and binder type; w/b, binder type, initial moist curing duration and exposure conditions are the experimental variables for the carbonation rate test. Cover depth, reinforcement diameter, binder type and w/b variables were considered for the corrosion cracking test. The results showed that an improvement in concrete quality (binder type, w/b ratio and extending the initial moist curing duration) and increment in cover thickness improved the durability of the RC structures exposed to the natural inland environment. Based on the trends in the observed experimental results, models to predict carbonation rate and the amount of steel radius loss required to initiate cover cracking in concrete were developed. The proposed models’ predictions are more closer to the measured values and compared well with the predictions of some previous models which indicate their respective predictive applications. They provide a general basis for durability analysis of RC structures in inland environment and can serve as basis for condition assessment of existing structures in the inland environment. Engineers can appreciate the consequences of design options on the service life of RC structures, while owners of RC structures can have information about how long their RC structures may last before any repair is envisaged / XL2018

Weathering steel has been a primary construction material for bridges in the United States. Notches caused by corrosion are observed on the flange of steel I-beams. These notches reduce the cross section area of the structure and are threats to bridge safety. A606-04 Type 4 cold rolled weathering steel samples were studied in this thesis to understand the effect of notches that caused by corrosion. Weathering steel samples were in the shape of plates, which simulated flange of I-beams. The plate samples were notched across their surfaces by applying electrical current through an electrochemical circuit composed of an anode, a cathode and electrolyte. Sixteen samples were notched and cut into appropriate shape for fatigue testing. S-N (Stress-Number of cycles to failure) diagram established from fatigue data indicated that the fatigue strength decreased below AASHTO category B. Weibull analysis was also performed to understand the reliability distribution. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection

The objective of this research is to determine if the deflection equations currently adopted in ACI 440.1r-15 and previously ACI 440.1r-06 accurately reflect the flexural behavior of an overreinforced Basalt Fiber Reinforced Polymer (BFRP) concrete beam. This was accomplished with experimental, analytical and numerical models. The experiment consisted of two beams doublyreinforced with BFRP rebar. A three-point flexural test on beams with a 30 in. clear span was performed and the deflections were recorded with a dial gauge and LVDT system. This data was compared to the equations from ACI 440.1r-06, ACI 440.1r-15, Branson’s equation and a numerical model created in ANSYS Mechanical APDL. Experimental results show a stiffer beam than expected when compared to the four predictive models for deflection. This can be due to the level of over-reinforcement and the small clear-span to depth ratio. Further research should be conducted to determine the cause for the additional stiffness. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2017. / FAU Electronic Theses and Dissertations Collection

This study presents and illustrates a methodology to calculate the capacity of an existing reinforced concrete bridge under a non-conventional blast load due to low and intermediate pressures. ATBlast program is used to calculate the blast loads for known values of charge weight and stand off distance. An excel spreadsheet is generated to calculate ultimate resistance, equivalent elastic stiffness, equivalent elastic deflection, natural period of the beam, the maximum deflection, and the maximum rotation in the support for a simple span solid slab and T-Beam bridges. The allowable rotation could be taken as to two degrees. Naval Facility Engineering Command (NAVFAC) approach was adopted, where the inputs were material properties, span length, and area of reinforcement. The use of the Fiber Reinforced Polymer for increasing the capacity of an existing bridge is also presented in this study. Parametric studies were carried out to evaluate the performance of the solid slab and T-Beam bridges under the assumed blast load. / by Firas A. Abdelahad. / Thesis (M.S.)--Florida Atlantic University, 2008. / Includes bibliography. / Electronic reproduction. Boca Raton, FL : 2008 Mode of access: World Wide Web.

This research is aimed at investigating the corrosion durability of polyolefin fiber-reinforced fly ash-based geopolymer structural concrete (hereafter referred to as GPC, in contradistinction to unreinforced geopolymer concrete referred to as simply geopolymer concrete), where cement is completely replaced by fly ash, that is activated by alkalis, sodium hydroxide and sodium silicate. The durability in a marine environment is tested through an electrochemical method for accelerated corrosion. The GPC achieved compressive strengths in excess of 6,000 psi. Fiber reinforced beams contained polyolefin fibers in the amounts of 0.1%, 0.3%, and 0.5% by volume. After being subjected to corrosion damage, the GPC beams were analyzed through a method of crack scoring, steel mass loss, and residual flexural strength testing. Fiber reinforced GPC beams showed greater resistance to corrosion damage with higher residual flexural strength. This makes GPC an attractive material for use in submerged marine structures. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2013.

Two duplex stainless steels rebars: UNS32304SS and UNS32101SS, were selected to investigate the corrosion initiation and propagation in reinforced concrete specimens. The investigation is divided in two phases with two different methods to accelerate the transport of chlorides through the concrete and initiate corrosion in a short period of time. After corrosion had initiated and propagated for some time; selected specimens were terminated for visual examination. On specimens selected for autopsy, the rebars in the top row showed corrosion to various degrees. Corrosion had propagated to such extent on the terminated specimens that the specimen showed cracks. Stray current might have caused accelerated corrosion on rebars where corrosion had initiated. Based on chloride concentrations measured at the rebar trace, corrosion initiated: on S32101 rebars on average at 7.9 kg/m3, and S32101 rebars on average at 6.0 kg/m3. The findings suggest that S32304 rebars corroded at a slower than S32101. / by Francisco Gutierrez Tellez. / Thesis (M.S.C.S.)--Florida Atlantic University, 2013. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

This study investigates corrosion initiation and propagation in instrumented specimens obtained from segments of dry-cast reinforced concrete pipes. Potential, LPR and EIS measurements were carried out. During the propagation stage in different exposures, reinforcement eventually reached negative potentials values, which suggest mass transfer limitations. So far these specimens show no visual signs of corrosion such as cracks or corrosion products with one exception; where corrosion products have reached the surface. Moreover, the apparent corrosion rate values obtained suggest high corrosion rate. No crack appearance so far, could be explained by the high porosity of the specimens; the corrosion products are filling these pores. It is speculated that although, there might be mass transfer limitations present, the current demanded by the anode is being balanced by a larger cathode area due to macrocell effects, since the high moisture conditions likely reduced the concrete resistivity and increased the throwing power. / by Hariharan Balasubramanian. / Thesis (M.S.C.S.)--Florida Atlantic University, 2013. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

With the need to improve corrosion resistance in columns and piles, the innovative idea of Centrally Prestressed Fiber Reinforced Concrete (CPFRC) columns is a promising solution. The first step is to compare if the compressive strength of any mix is affected by the size, geometry, or even the inclusion of polyolefin fibers in a specimen. The results showed that the cylinder size of 4 in. x 8 in., which is the most common size used by the testing labs, has the highest compressive strength. There was no sign on compressive strength improvement with the use of polyolefin fibers, except for reduction in cracking size and concrete spalling. The second step compared the ultimate strength, ductility characteristics and failure mode of CPFRC columns to conventional columns. CPFRC showed adequate axial and flexural resistance, in addition to ductile behavior similar to regular reinforced concrete columns. / by Daniel A. Grijalba. / Thesis (M.S.C.S.)--Florida Atlantic University, 2011. / Includes bibliography. / Electronic reproduction. Boca Raton, Fla., 2011. Mode of access: World Wide Web.

Chloride ions present in the marine atmosphere contained in marine aerosols is investigated for a relationship with chloride that accumulated into concrete. Chloride profiles are conducted on several concrete mixes containing fly ash, silica fume, and slag, with water to cementitious ratios of 0.35, 0.41, and 0.47. The chloride accumulation in concrete samples exposed to the environment is investigated with relation to the chloride deposition from the marine atmosphere measured via the wet candle test. Results indicate a possible relationship for the total accumulated chloride in the concrete with the accumulated chloride deposition (wet candle). Over the exposure periods, concrete specimens with 50% slag addition and 0.47 w/cm had the lowest average rates of chloride accumulation for deposition under 100 g/m2day. Chloride accumulation was lower in concrete containing 20% fly ash and 8% silica fume with 0.35 w/cm for chloride deposition rates over 200 g/m2day. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection

The corrosion propagation stage of D-CRP (types F and C) was tested under immersion in water, high humidity, and covered with wet sand. The half-cell potential, linear polarization test, and electrochemical impedance spectroscopy measurements were performed. Selected specimens were terminated after 300 days of exposure and visually inspected. Based on corrosion potential measurements obtained during the corrosion propagation observation, and calculated corrosion rate based on LPR measurements: all specimens were actively corroding. Additionally, EIS-Rc values were calculated for FS, CS and CH specimens. The Rc_EIS were generally greater than Rc_LPR values. EIS spectra for CI and FI specimens usually included mass transport limitations, as these specimens were immersed. Both type of specimens immersed in water (FI and CI), appeared to have higher corrosion rate based on LPR-Rc. However, upon autopsy it was revealed that a more modest amount of corrosion occurred on the reinforcing steel of FI and CI terminated specimens. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection