The petroleum industry is currently moving to meet the ever-rising demand for oil and gas production. As onshore fields become depleted and decline in production, exploration and production companies have started venturing further offshore. To support this activity, there is need for new subsea production technologies to develop deepwater and ultra deepwater fields.Woodside Hydrocarbon Research Facility (WHRF) at Curtin University of Technology is working on natural gas dehydration processing using gas hydrate technology. Through the studies, a novel gas dehydration process has been developed and now proposed for subsea application. Natural gas dehydration processes generate both a treated dry gas stream and a waste stream of condensate consisting of both hydrocarbons and water. This condensate can be reinjected to the reservoir formation but this is not always economic or practical. Availability of an alternative means of treatment and disposal of the condensate would be advantageous. This study aims to investigate and to provide a basis for the design of such an alternative scheme by constructing a floating separator for the treatment and disposal of waste condensate from subsea dehydration stage.A model was developed to simulate the process of evaporation of condensate from the proposed floating separator. The calculations were performed taken into account zero wind speed and an ambient temperature around 34 C. The simulation results showed that condensate skimming time was found to be 15 days for flowrate (Qin) of 100 bbd associated with specific separator diameter and total height dimensions. By considering the ratio of diameter to total height of 2.5, the floating separator was designed to enhance the evaporation rate and to get overall structure stability due to the mechanical restrictions that might be encountered in the sea.

When a disaster the magnitude of the Deepwater Horizon blowout and oil spill takes place, is it natural for the news media stories, investigative reports, and public deliberation to focus almost exclusively on finding the person or group responsible for such a horrendous scene. Rhetorically speaking, the discourse surrounding the event can be characterized as a reductive form of praise and blame rhetoric (epideixis). However, these efforts, while well-intentioned, are troublesome because searches for the one technical cause and the sole personal culpability are thwarted by the sheer complexity of the ecological, technological, scientific, institutional, and communicative network required for such a disaster to take place. Thus, to demonstrate the insufficiency of extant models of disaster in a variety of fields, which tend to privilege human-centered approaches, Dead Man's Switch: Disaster Rhetorics in a Posthuman Age explores the ontology, technical documentation, and rhetorical theory of disasters through a posthuman lens. To find a more critical approach to understanding the nature of disasters in the twenty-first century, I ask the following questions: How do rhetoricians and technical communicators account more fully for the human and nonhuman forces at work in the precipitation of disaster? How do rhetoricians and technical communicators find an approach to ecological catastrophe that goes beyond the mere "environmentalist rhetoric" characterizing the public response? Through the application of several posthumanist theories, my project develops an approach to disaster that complicates traditional ways of approaching causality and blame. I use accident reports, news media stories, and popular literature as data for this project. By examining these texts, my project has broad implications for technical communication, rhetorical theory, and philosophy of rhetoric.

Natural vents in the Gulf of Mexico are actively expelling water and hydrocarbons. They are ubiquitous along continental margins, and I characterize a single vent in the Ursa Basin at leaseblocks MC852/853. Seismic data reveal that the vent is elevated ~75 meters above the seafloor and is roughly circular with a ~1.2 km diameter. A transparent zone centered underneath the vent extends to ~1500 meters below seafloor; this zone is commonly interpreted to record the presence of gas. There is a strong negative polarity seismic reflection that rises rapidly at the vent’s boundaries and is horizontal within a few meters of the seafloor beneath the vent edifice. I interpret that this reflection records a negative impedance contrast, marking the boundary between hydrate and water above and free gas and water below: it is the bottom-simulating reflector. Salinities beneath the vent increase from seawater concentrations to >4x seawater salinity one meter below seafloor. Temperature gradients within the vent are ~15x the background geothermal gradient. I model the coexistence of high salinity fluids, elevated temperature gradients, and an uplifted bottom-simulating reflector with two approaches. First, I assume that high salinity fluids are generated by dissolution of salt bodies at depth and that these hot, saline fluids are expelled vertically. Second, I model the solidification of gas hydrate during upward flow of gas and water. In this model, free gas combines with water to form hydrate: salt is excluded and heat is released, resulting in the generation of a warm, saline brine. The two models result in predictable differences of salinity and temperature. A better understanding of the hydrogeological processes at vent zones is important for quantifying the fluxes of heat and mass from submarine vents and is important for understanding the conditions under which deep-sea biological vent communities exist. / text

Recent drilling of deep stratigraphy in subsalt offshore Gulf of Mexico has revealed the presence of thick, amalgamated, Cretaceous siliciclastic reservoirs with the potential to become valid exploration targets. Similar to the Lower Tertiary deepwater play, the significant down-dip distance (> 400 km) from the source deltaics, the data gap across the modern structurally complex salt-tectonics-dominated slope and the difficulties of imaging subsalt stratigraphy pose challenges for the construction of meaningful deepwater system models to aid in exploration and appraisal efforts. A 3D seismic dataset in the Mad Dog field at the basinward end of the modern allochthonous salt canopy and outboard of the Sigsbee Escarpment offers the opportunity to study the nature of the deep stratigraphy at central positions in the basin. The nature of the Cretaceous sedimentary system has been investigated through detailed structural and seismic geomorphologic mapping. An early syndepositional contractional event has been identified and temporally associated with Mesozoic emplacement of a deep salt sheet. These events are masked by the major Neogene-age phase of fold amplification that dominates the present-day subsalt structural framework. Ponded-basin deepwater sedimentation processes control early phases of deposition in the Cretaceous Mad Dog area and sediment-gravity flows are deposited as complexes of low sinuosity amalgamated channelized deposits in roughly-confined sediment pathways. Ponded fills show internal lateral accretion architectures that grow sigmoid in nature as the migrating systems interact with the approaching minibasin margins making evident the structural control on sediment architecture. Later phases of deposition are characterized by slightly sinuous feeder channels with multiple lobe development at their terminus. Variable directions of sediment source pathways indicate a linear-sourced slope apron depositional model for these systems. In addition to the more structured morphologic elements, there were also pervasive mass-transport processes active, presumably triggered by Mesozoic halokinesis. Data in sparse deep wells in the GoM that penetrate the Cretaceous suggest that the Late Cretaceous deepwater depositional system was composed of coarse-grained high density gravity flows. The geometries seen in seismic beneath the Mad Dog area support the existence of such a basinwardly extensive deepwater fan systems developed during the Cretaceous, and the low sinuosity channel geometries and small length:width ratio and amalgamated nature of fan lobes suggest that these systems may have indeed been high-density in nature. / text

Green marketing has been a main topic of discussion for several years. Most studies conducted in this area have focused on the benefits of green marketing for a normal company. However, no studies have considered the effectiveness of green marketing by a negative brand like BP. This study aims to reveal the effectiveness of green marketing after pollution. An experiment was conducted to evaluate participants’ attitudes toward the marketing strategy. Although the results were not significant, some interesting findings were revealed and are addressed at the end of the paper. They imply that individuals with green awareness are less influenced by both green marketing and an economic-assistance strategy in BP’s case, compared to individuals with lower green awareness. Overall, all participants in this study preferred the economic-assistance strategy, which means that green marketing is not effective for a corporation involved in pollution issues. / text

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide 234Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using 210Pb, with verification from 137Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon concentrations of up to 21,913 ppb. This is far above the level at which adverse biological effects occur (4,022 ppb). Benthic foraminifera responded to the heavy oiling by decreases to standing stock and depth of habitation relative to unoiled sites, as well as exhibiting deformities. These data clearly show that oil can be quickly mixed into salt marsh sediments, with demonstrable impacts on indigenous benthos. Further, radioisotope inventories indicated that most of the sampled sites are in a net erosional state. Should marshes containing trapped DWH oil be submerged by rising sea level, there is a great potential for the remobilization of oil.

The long-term fate of hydrocarbons in the Gulf of Mexico (GOMx) following the 2010 Deepwater Horizon oil spill has yet to be fully characterized. Elemental (% C and % N), stable isotopes (δ13Corganic), and polycyclic aromatic hydrocarbon (PAH) molecular signatures were investigated in shelf and slope sediments collected in October 2010 and 2011 to gain insight into processes affecting the distribution and fate of spilled Macondo oil. Particulate organic carbon (POC) ranged between 1.55 and 2.22 wt. % in 2010 and 0.55 and 2.06 % in 2011 while the corresponding δ13Corganic ranges were from -23.37 to -20.77 ‰ (vs. PDB) in 2010, and -22.68 to -20.75 ‰ (vs. PDB) in 2011. Ranges of total polycyclic aromatic hydrocarbon (TPAH) concentrations were from 72.57 to 7,543.53 ng/g in 2010 and 25.55 to 16,582.77 ng/g in 2011. The range of measured values represented significant deviations from previous background measurements. This provided the basis for concluding that the Macondo spill altered the “background” organic carbon and hydrocarbon signature, that Macondo oil has weathered and/or biodegraded in the year following the spill, and that a significant spatial trend of hydrocarbons extended from the Macondo well across the northern GOMx in October 2010 and 2011.

In April 2010, approximately 4.9 million barrels of oil were accidentally released into the Gulf of Mexico during the Deepwater Horizon Macondo Mc252 Oil Spill. Some of the surface oil was carried by prevailing winds and currents and reached the coast of Louisiana impacting marsh and marine ecosystems. One and a half years after this incident, a set of oiled marsh samples (2 grab samples) coupled with nearby subtidal and intertidal cores (12 cores) were collected from Barataria Bay, Louisiana to determine the probable source of petroleum residues present and to characterize the chemical composition of the oil. Plus, pre-spill core which was collected from Barataria Bay in 2007 was analyzed to identify the background hydrocarbon composition of the area. Polycyclic aromatic hydrocarbons (PAH), total petroleum hydrocarbons (TPH), biomarker, and stable carbon isotope compositions of selected samples were detected using a GC-MS and an elemental analyzer Conflo system coupled to a DeltaPlusXP isotope ratio mass spectrometer. The comprehensive chemical data allowed us to classify the pre and post-spill samples into 4 Groups. According to this classification, Group 1 and Group 2 samples had the highest concentrations of petroleum-derived hydrocarbons. Group 3 and background samples, on the other hand, was dominated by biogenic signatures. Although a direct connection between the detected and spilled Macondo oils results are complicated due to confounding factors (e.g., already present hydrocarbons and weathering processes), our biomarker data indicates that both oils have similar signatures. This close genetic relationship was also identified by stable carbon isotope analysis. The impact of the Macondo Mc252 Oil Spill in Barataria Bay appears to be limited to areas closer to the source. The oil has undergone moderate weathering and has penetrated into, the at least, the top 9 cm sediments. Additionally, to examine the decadal-scale history of sedimentation in these marshes, a sediment core was analyzed for the radioisotope 137Cs. The observed sedimentation rate of 0.39 cm/yr shows that oil pollutant input into Barataria Bay has been ongoing for at least 50-60 years.

Suction caissons are a cost-effective alternative to traditional piles in deep to ultradeep waters. No design rule has been available on the axial capacity of suction caissons as part of the mooring system in soft sediments. In this research, a series of centrifuge tests were performed using instrumented model caissons, to investigate the axial capacity and radial stress changes around caissons during installation, consolidation and vertical pullout in normally consolidated, lightly overconsolidated and sensitive clays. Total pressure transducers instrumented on the caisson wall were calibrated for various conditions. The radial total stress acting on the external wall varied almost linearly during penetration and extraction of the caisson, with smaller gradients observed during post-consolidation pullout. Minimum difference was found in the penetration resistance and the radial total stress for caissons installed by jacking or by suction, suggesting that the mode of soil flow at the caisson tip is similar under these two types of installation. Observed soil heave showed that the soil particles at the caisson tip flow about evenly outside and inside the caisson during suction installation. Comparison was made between measurements and various theoretical predictions, on both the radial stress changes during caisson installation, and the radial effective stress after consolidation. Significant under-predictions on excess pore pressure changes, consolidation times and external shaft friction ratios were found for the NGI Method, based on the assumption that the caisson wall is accommodated entirely by inward motion of the clay during suction installation. Obvious over-predictions by the MTD approach were found in both stress changes and shaft capacity of the caissons. A simple form of cavity expansion method was found to give reasonable estimations of stress changes and post-consolidation external shaft friction. A model for predicting the penetration resistance of suction caissons in clay was evaluated. Upper and lower bound values of external shaft friction ratio during uplift loading after consolidation were derived. Uplift capacity of caissons under sustained loading and cyclic loading were investigated, revealing approximately 15 to 30% reduction of the capacity compared to that under monotonic loading. External shaft friction ratios and reverse end-bearing capacity factors were both found to be significantly lower than those under monotonic loading

Thesis (M.Sc. (Natural Resources Management))--Mahidol University, 2005.