Migration and exile due to human rights violations have long been key topics in Latin American studies. In the Colombian context, a compelling corpus of texts has surfaced that deals specifically with the phenomenon of forced internal displacement. Colombia is second only to Sudan in terms of the number of victims––some four million people––who have had to leave their homes and communities because of civil unrest. In this dissertation, I consider the socio-political construct of the displaced to be a homogenizing term used by the media and official discourse to refer to those affected by internal exile. This study centres on the uses and impacts of this identity marker at individual and collective levels within a cultural studies approach. In Chapter 1, I discuss three different genres: a novel, which references testimonio accounts, and a play that is partly based on both. The sheer diversity of characters that become part of the displaced category exposes relevant racial, ethnic, and ideological alliances that emphasize us-them relations. An analysis of Luis Alberto Restrepo’s film La primera noche, Chapter 2 deals with the juxtaposition of the rural and urban so as to expose the ramifications of dispossession at multiple degrees of individual and collective identification and examines effects of marginality by contrasting the conditions of the displaced against those of other marginalized populations. In Chapter 3, I argue that music is a tool of both denunciation and declaration through an analysis of a collection of songs written and performed by members of Afro-Colombian displaced communities. I study these vallenato and rap songs, fused with unconventional lyrics and musical elements, as testimonial texts that contest issues of land rights vis-à-vis collective identity and agency. Finally, Chapter 4 is a cross-examination of the shelter within a series of photographs. I first read the refugee centre as a bio-political space where residents are subject to extreme inhumane conditions, and I then show the shelter to be a space that elicits movements of solidarity and resistance, and counters the notion of the displaced as a homogeneous group.

In this thesis Direct Numerical Simulation (DNS) is used to investigate the development of turbulent premixed flame kernels during the early stages of growth typical of the period following spark ignition. Two distinct aspects of this phase are considered: the interaction of the expanding kernel with a field of decaying turbulence, and the chemical and thermo-diffusive response of the flame for different fresh-gas compositions. In the first part of the study, three-dimensional, repeated simulations with single-step chemistry are used to generate ensemble statistics of global flame growth. The surface-conditioned mean fluid-velocity magnitude is found to vary significantly across different isosurfaces of the reaction progress variable, and this is shown to lead to a bias in the distribution of the Surface Density Function (SDF) around the developing flame. Two-dimensional simulations in an extended domain indicate that this effect translates into a similar directional bias in the Flame Surface Density (FSD) at later stages in the kernel development. Properties of the fresh gas turbulence decay are assessed from an independent, non-reacting simulation database. In the second part of this study, two-dimensional simulations with a detailed 68-step reaction mechanism are used to investigate the thermo-diffusive response of pure methane-air, and hydrogen-enriched methane-air flames. The changes in local and global behaviour due to the different laminar flame characteristics, and the response of the flames to strain and curvature are examined at different equivalence ratios and turbulence intensities. Mechanisms leading to flame quenching are discussed and the effect of mean flame curvature is assessed through comparison with an equivalent planar flame. The effects of hydrogen addition are found to be particularly pronounced in flame kernels due to the higher positive stretch rates and reduced thermo-diffusive stability of hydrogen-enriched flames.

Migration and exile due to human rights violations have long been key topics in Latin American studies. In the Colombian context, a compelling corpus of texts has surfaced that deals specifically with the phenomenon of forced internal displacement. Colombia is second only to Sudan in terms of the number of victims––some four million people––who have had to leave their homes and communities because of civil unrest. In this dissertation, I consider the socio-political construct of the displaced to be a homogenizing term used by the media and official discourse to refer to those affected by internal exile. This study centres on the uses and impacts of this identity marker at individual and collective levels within a cultural studies approach. In Chapter 1, I discuss three different genres: a novel, which references testimonio accounts, and a play that is partly based on both. The sheer diversity of characters that become part of the displaced category exposes relevant racial, ethnic, and ideological alliances that emphasize us-them relations. An analysis of Luis Alberto Restrepo’s film La primera noche, Chapter 2 deals with the juxtaposition of the rural and urban so as to expose the ramifications of dispossession at multiple degrees of individual and collective identification and examines effects of marginality by contrasting the conditions of the displaced against those of other marginalized populations. In Chapter 3, I argue that music is a tool of both denunciation and declaration through an analysis of a collection of songs written and performed by members of Afro-Colombian displaced communities. I study these vallenato and rap songs, fused with unconventional lyrics and musical elements, as testimonial texts that contest issues of land rights vis-à-vis collective identity and agency. Finally, Chapter 4 is a cross-examination of the shelter within a series of photographs. I first read the refugee centre as a bio-political space where residents are subject to extreme inhumane conditions, and I then show the shelter to be a space that elicits movements of solidarity and resistance, and counters the notion of the displaced as a homogeneous group.

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Development of displacement El objetivo de este trabajo es explorar y explotar los principios de funcionamiento de un Inmunosensor Electroquímico de Desplazamiento [(Displacement Electrochemical Immunosensor (DEI)] y también del ELISA Indirecto Competitivo [(Indirect Competitive ELISA (ICE)] para la detección de 2,4,6-tricloroanisol (TCA). Para tal fin, se lleva a cabo el desarrollo racional de un ELISA Indirecto Competitivo. El ensayo desarrollado resulta capaz de detectar TCA en concentraciones 1ppt a 1 ppm, con un limite de detección de 4.2 ppt. El ensayo desarrollado puede tener un particular interés comercial en situaciones donde el tiempo experimental requerido es de menos de 80 minutos.Se desarrolla también un modelo matemático (MM) cuyo principal objetivo es permitir el desarrollo racional de un Inmunosensor Electroquímico de Desplazamiento (DEI). A pesar de las bajas constantes de afinidad observadas en los anticuerpos obtenidos para este trabajo, se logra desarrollar un DEI funcional cuyo limite de detección de TCA (0.2 ppm) se corresponde con los valores obtenidos a través del MM.La adsorción inespecífica (NSA) de proteínas es identificada como uno de los problemas críticos que impidieron alcanzar limites de detección más bajos. El uso del electroquímicamente compatible Cu UPD como barrera/control de la NSA, junto con la detección amperométrica del desplazamiento son propuestos en este trabajo como base o punto de partida para el desarrollo de inmunosensores que puedan ser operados sin necesidad de marcaje (labelling) o la adición de otros componentes diferentes de la muestra de interés (reagentless and labelless immunosensors). / The purpose of this work is to explore and exploit the principles of Displacement Electrochemical Immunosensing (DEI) and Indirect Competitive ELISA (ICE) to detect 2,4,6-trichloroanisole (TCA). The rational design of indirect competitive ELISA for TCA detection is attempted. The developed assay detects TCA at concentrations from 1ppt to 1 ppm, with a limit of detection of 4.2 ppt. The assay can be commercially useful in situations where less than 80 minutes total assay time is required. A mathematical model (MM) is developed for the rational design of an electrochemical displacement immunosensor (DEI). Despite the low affinity constants of the antibodies obtained for this work a functional DEI is developed with the predicted by the MM high limit of detection for TCA (0.2 ppm). The non-specific adsorption (NSA) of proteins is identified as a critical problem inhibiting further optimization of the DEI. The use non-insulating Cu UPD as NSA controller or electrochemically compatible blocking, together with amperometric displacement detection are proposed as a platform that could permit further development of reagentless and labelless immunosensors.

Supersaturated water injection (SWI) is a novel remediation technology which is able to remove entrapped residual NAPLs from saturated porous media by both volatilization (partitioning of volatile contaminants into the gas phase) and mobilization (displacement of isolated NAPL residuals by gas clusters). The character of gas saturation evolution in-situ in saturated porous media during SWI results in high sweep efficiency. This work focuses on studying the recovery of entrapped residual NAPL by the mobilization mechanism during SWI, thus low-volatility NAPL residuals, kerosene and a kerosene-hexadecane mixture, are used as contaminants. A series of SWI recovery experiments are conducted to investigate the influence of grain size, low-permeability layering, and physical properties of the contaminants on the recovery behavior. For columns contaminated with kerosene, the residual saturation can be reduced to around 4% from an initial value of 16%, and over 70% of the residual kerosene is recovered by a combination of mobilization and volatilization in homogeneous sand packs. For columns contaminated with a kerosene-hexadecane mixture, the final residual saturation is 7.4% and the final NAPL recovery is lower than that in kerosene columns. Grain size has little influence on NAPL recovery, but low permeability layering has a significantly negative influence. Experiments designed to compare SWI to sparging, and water-gas co-injection showed that water-gas co-injection was able to effectively recovery residual NAPLs albeit not as efficiently as SWI, while steady gas sparging is completely ineffective at recovering residual NAPL by mobilization. Based on these experimental observations, a conceptual model, involving double displacements and NAPL bank formation, is purposed to explain the experimental observations.

Supersaturated water injection (SWI) is a novel remediation technology which is able to remove entrapped residual NAPLs from saturated porous media by both volatilization (partitioning of volatile contaminants into the gas phase) and mobilization (displacement of isolated NAPL residuals by gas clusters). The character of gas saturation evolution in-situ in saturated porous media during SWI results in high sweep efficiency. This work focuses on studying the recovery of entrapped residual NAPL by the mobilization mechanism during SWI, thus low-volatility NAPL residuals, kerosene and a kerosene-hexadecane mixture, are used as contaminants. A series of SWI recovery experiments are conducted to investigate the influence of grain size, low-permeability layering, and physical properties of the contaminants on the recovery behavior. For columns contaminated with kerosene, the residual saturation can be reduced to around 4% from an initial value of 16%, and over 70% of the residual kerosene is recovered by a combination of mobilization and volatilization in homogeneous sand packs. For columns contaminated with a kerosene-hexadecane mixture, the final residual saturation is 7.4% and the final NAPL recovery is lower than that in kerosene columns. Grain size has little influence on NAPL recovery, but low permeability layering has a significantly negative influence. Experiments designed to compare SWI to sparging, and water-gas co-injection showed that water-gas co-injection was able to effectively recovery residual NAPLs albeit not as efficiently as SWI, while steady gas sparging is completely ineffective at recovering residual NAPL by mobilization. Based on these experimental observations, a conceptual model, involving double displacements and NAPL bank formation, is purposed to explain the experimental observations.

Fluid dispensing is a method by which fluid materials are delivered to the targeted boards in a controlled manner and has been extensively applied in various packaging processes in the electronics assembly industry. In these processes, the flow rate of the fluid dispensed and/or the fluid amount transferred onto a board are two important performance indexes. Due to the involvement of the compressibility and non-Newtonian behaviour of the fluid being dispensed, modeling the fluid dispensing process has proven to be a challenging task. This thesis presents a study on the modeling of the positive displacement dispensing process, in which the linear displacement of a piston is used to dispense fluid. Also, this thesis presents an evaluation of different designs of the fluid dispensing system based on the axiomatic design principles. <p>At first, the characterization of the flow behaviour of fluids used in the electronic packaging industry is addressed. Based on the previous experiments conducted in the authors lab, a 3-parameter Carreau model for the fluid Hysol FP4451 is derived for use in the present study. Then, taking into account fluid compressibility and flow behaviour, a model is developed to represent the dynamics of the flow rate of the fluid dispensed. The resulting model suggests that the dynamics of the flow rate in the positive displacement dispensing process is equivalent to that of a second order system. Based on the model developed, the influences of the fluid compressibility and the process parameters such as the dispensing time and needle temperature are investigated by simulations. <p>In the positive dispensing process, it is noticed that the fluid amount dispensed out of needle is different from the fluid amount finally transferred to the board, if the fluid amount dispensed is very small. This difference is considered one major problem affecting dispensing performance. In order to determine the fluid amount transferred to the board, a 3-step method is developed in the present study, based on existing theories of liquid bridges and Laplaces equation. Simulations are conducted based on the developed method to study the influence of surface tension and initial fluid amount on the final fluid amount transferred onto the board. <p> Finally, this thesis presents a new approach to evaluate and compare different designs of the fluid dispensing system, namely air-pressure, rotary-crew, and positive- displacement. In this approach, the axiomatic design principles, i.e., the Independence Axiom and the Information Axiom, are employed. This approach can be used not only to evaluate existing dispensing systems, but also to design new dispensing systems.

Micromachined microphones with diffraction-based optical displacement detection are presented. A compliant membrane is made part of a phase sensitive diffraction grating, and the deflection resulting from external acoustic pressure alters the intensities of the diffracted orders which are monitored with integrated photodiodes. The scheme provides the displacement sensitivity of a Michelson interferometer and can be integrated without beam splitters or critical alignment problems into volumes on the order of 1mm³. The method is implemented and characterized using microphone membranes with integrated diffraction grating back electrodes fabricated on silicon using Sandia National Laboratories' dedicated processing platform. Detailed response characterization in both air and vacuum environments is performed to extract the diaphragm properties and high frequency cutoff frequencies of the microphone. Results from a finite element model of the microphone structure are in good agreement with measured data. The sensor's internal noise is characterized with measurements performed in the anechoic acoustic test facility at Georgia Tech. While utilizing 2.4mW of laser power, an (A) weighted displacement resolution of 6×10⁻⁴Å/√Hz is measured which is limited by thermal acoustic noise caused by the microphone's back-plate flow resistance.

In-process turbine monitoring has been a subject of research since the advent of gas turbines; however, it is difficult because it requires precision measurements to be made at high speeds and temperatures. The measurement of turbine blade tips is especially intriguing because of the potential it holds to greatly increase the efficiency of engine operation and maintenance. Tip-to-casing clearance is one of the major sources of inefficiency in a turbine and monitoring of this clearance would allow active tip-clearance control systems to be implemented. Also, analysis of engine wear through vibration monitoring may increase the effectiveness of engine maintenance and repair. A sensor recently developed at Georgia Tech could answer this challenge. The sensor operates by measuring the phase change of reflected microwaves to measure blade tip displacement. It is robust even in the harsh turbine environment. However, in sensor measurements, the microwave beam pattern causes a phenomenon called spatial filtering to occur, which may compromise the precision of measurements. Since the beam is not a thin line reflecting off a single point on the turbine blade, measurements are a weighted average of measurements along the entire surface within the field-of-view of the sensor. The net effect is a blurred measurement. In measuring turbine blades, only the tip is vital, so the blurring in between blades is not extremely detrimental. However, changing measurement geometry affects the amount of spatial filtering and hence the accuracy of the measurement. This thesis presents a detailed analysis of this phenomenon and especially its effect on turbine blade tip clearance measurements. A design of experiments is presented to qualitatively understand the effect of geometric factors on tip measurements. Along with experimentation, a robust, three-dimensional, ray-tracing, electromagnetic model is presented which was developed to further understand spatial filtering and to analyze specific geometric factors in the measurement of turbine blades. The research shows that microwave measurements may still be made to sufficient accuracy even considering the effect of spatial filtering, and by quantifying spatial filtering in measurements, it may be possible in to glean additional useful data from measurements.