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Nederbördsmätning är viktigt inom många områden och en relativt ny teknik är enoptisk distrometer som med hjälp av laserteknik mäter nederbördspartiklarnasdroppstorlek och fallhastighet. Syftet med detta arbete var att undersöka hur välThies distrometer stämmer överens med nederbördsmätning från ett vippkärl ochmanuella mätningar från institutionen för geovetenskaper vid Uppsala universitet.Institutionen för geovetenskaper överväger att gå över till denna teknik och därmedbehövdes distrometern utvärderas för olika faktorer som kan påverka instrumentet.Vid jämförelse mellan instrumenten visade det sig att distrometern totalt sett samladein mer nederbörd än de andra mätarna. Det är svårt att avgöra vad skillnaden mellaninstrumenten kan bero på men felkällor så som avdunstning och vätning hos vippkärletoch manuella mätningar kan ge mindre nederbörd. En annan orsak kan varafelkalibrering av datan från distrometern. Inga samband hittades för vindhastighet,vindriktning och typ av nederbörd mellan de tre instrumenten. En vidare undersökning gjordes för droppstorleksfördelningen för att ge exempelpå fördelar med en distrometer. Droppstorleksfördelningen från distrometernjämfördes med exponentialfördelningen framtagen av Marshall & Palmer (1948).Resultatet visade sig stämma överens med tidigare studier, fördelningen stämmerbra överens för stratiforma väder, men sämre för konvektiva och snö. / Measuring precipitation is important in many areas of research. A relatively newtechnology for measuring precipitation is the optical disdrometer, which measures thefalling velocity and drop size of particles by using lasers. The purpose of this workwas to compare data from a disdrometer with data from a tipping bucket and amanual measurement series from the Department of Earth Sciences at UppsalaUniversity. The comparison between the instruments showed that the disdrometermeasured more precipitation than the tipping bucket and the manual measurements.A reason for this can be due to evaporation and wetting from the tipping bucket andmanual measurement. Errors in calibration of data from the disdrometer may alsohave influence. Furthermore, an analysis of the drop size distribution was done in order todetermine areas of special use for the device. The drop size distribution calculatedfrom the distrometer was compared with the Marshall and Palmer (1948) distribution.The results showed that the MP-distribution was a good fit for stratiform weather;however, for convective clouds and snow the fit was not satisfactory and some otherrelationship should be used instead.

Superhydrophobic surfaces have gained attention as a potential mechanism for increasing condensation heat transfer rates. Various aspects related to condensation heat transfer are explored. Adiabatic, air-water mixtures are used to explore the influence of hydrophobicity on two-phase flows and the hydrodynamics which might be present in flow condensation environments. Pressure drop measurements in a rectangular channel with one superhydrophobic wall (cross-section approximately 0.37 X 10 mm) are obtained, revealing a reduction in the pressure drop for two-phase flow compared to a control scenario. The observed reduction is approximately 10% greater than the reduction that is observed for single-phase flow (relative to a classical channel). Carbon nanotubes have been used to create superhydrophobic coatings due to their ability to offer a relatively uniform nanostructure. However, as-grown carbon nanotubes often require the addition of a thin-film hydrophobic coating to render them superhydrophobic, and fine control of the overall nanostructure is difficult. This work demonstrates the utility of using carbon infiltration to layer amorphous carbon on multi-walled nanotubes to achieve superhydrophobic behavior with tunable geometry. The native surface can be rendered superhydrophobic with a vacuum pyrolysis treatment, with contact angles as high as 160 degrees and contact angle hysteresis less than 2-3 degrees. Drop-size distribution is an important aspect of heat transfer modeling that is difficult to measure for small drop sizes. The present work uses a numerical simulation of condensation to explore the influence of nucleation site distribution approach, nucleation site density, contact angle, maximum drop size, heat transfer modeling to individual drops, and minimum jumping size on the distribution function and overall heat transfer rate. The simulation incorporates the possibility of coalescence-induced jumping over a range of sizes. Results of the simulation are compared with previous theoretical models and the impact of the assumptions used in those models is explored. Results from the simulation suggest that when the contact angle is large, as on superhydrophobic surfaces, the heat transfer may not be as sensitive to the maximum drop-size as previously supposed. Furthermore, previous drop-size distribution models may under-predict the heat transfer rate at high contact angles. Condensate drop behavior (jumping, non-jumping, and flooding) and size distribution are shown to be dependent on the degree of subcooling and nanostructure size. Drop-size distributions for surfaces experiencing coalescence-induced jumping are obtained experimentally. Understanding the drop-size distribution in the departure region is important since drops in this size are expected to contribute significantly to the overall heat transfer rate.

Emulsions constitute a wide range of natural as well as processed products. Pharmaceutical applications of emulsions include oral administration, parenteral delivery, ophthalmic medicine, topical and transdermal creams, and fluorocarbon-in-water emulsions for blood oxygenation. In the foods area many of the products like mayonnaise, margarine, ice-creams are emulsions by nature and some products can also be used for delivery of active ingredients (e.g. nutraceuticals) with potential health benefits. Emulsions are also encountered at many stages of petroleum recovery, transportation, and processing. Typically, emulsions are manufactured in a two-step process. First a coarse emulsion called a premix is made which is passed through a high-pressure homogenizer. Intense energy supplied in the high pressure homogenizer causes breakage of the coarse emulsion to a fine one with a tighter distribution. Population balance equation (PBE) models are useful for emulsions since they allow prediction of the evolution of the drop size distribution on specification of the two rate processes i.e., breakage of drops due to the flow field and coalescence of colliding drops. In our work, we developed a PBE model to describe emulsion breakage in a high pressure homogenizer. The focus of the work was breakage and conditions to keep coalescence to minimum were implemented. Two breakage rates representing two mechanisms i.e., turbulent inertial and turbulent viscous breakage were necessary for reproducing the bimodal nature of the distributions. We used mechanistic functions in the PBE model to develop a predictive model which could be extended to changes in formulation variables as well as process variables. Starting with the assumption of binary breakage, the model was refined to include multiple drop breakage. The developed model was found to be extensible to reasonable changes in oil concentration, surfactant concentration, continuous phase viscosity and constant ratio of oil to surfactant. Anomalies in pressure prediction encountered earlier were also corrected for by including some additional features like heating, maximum stable diameter, and number of daughter drops. A preliminary attempt was also made to use the developed model for designing experiments for making target emulsions with pre-specified properties.

The interception and redirection of rainfall by vegetation has implications for many fields such as remote sensing of soil moisture, satellite observation of rainfall, and the modeling of runoff, climate, and soil erosion. Although the modeling of rainfall partitioning by forests has received attention in the past, partitioning caused by crops has been overlooked. The present work proposes a two front experimental and computational methodology to comprehensively study rainfall interception and partitioning by the maize canopy. In the experimental stage, we deployed two compact weather stations, two optical disdrometers, and five tipping bucket rain gauges. Two of the tipping bucket rain gauges were modified to measure throughfall while two were adapted to measure stemflow. The first optical disdrometer allowed for inspection of the unmodified drop-size and velocity distributions, whereas the second disdrometer measured the corresponding distributions under the canopy. This indicates that the outcome of the interaction between the hydrometeors and the canopy depends on the drop diameter. In the computational stage, we created a model that uses drop-size and velocity distributions as well as a three-dimensional digital canopy to simulate the movement of raindrops on the surfaces of leaves. Our model considers interception, redirection, retention, coalescence, breakup, and re-interception of drops to calculate the stemflow, throughfall, and equivalent height of precipitation stored on plants for a given storm. Moreover, the throughfall results are presented as two-dimensional matrices, where each term corresponds to the accumulated volume of drops that dripped at a given location. This allows insight into the spatial distribution of throughfall beneath the foliage. Finally, we examine the way in which the maize canopy modifies the drop-size distribution by recalculating the drop velocity based on the raindrop's size and detachment height and by storing the counts of drops in diameter-velocity classes that are consistent with the classes used by disdrometers in the experimental study.

Vindtunneln som drivs av Sports Tech Research Centres   är en unik anläggning för att bedriva forskning på både atletiska utövare och   utrustning. Vindtunnelns avancerade system möjliggör för forskning och tester   på material och produkter kan utföras i en verklighetstrogen miljö. Det finns   även sedan byggnationen ett regnsystem installerat i vindtunneln. Detta   system är inte uppmätt efter viktiga faktorer och ingen vetskap om det   simulerade regnets egenskaper eller likhet med naturligt förekommande regn   finns. Syftet med arbetet var att utföra mätningar på det   befintliga regnsystemet med avseende på storlek och fallhastighet för   dropparna. Arbetets syfte var även att jämföra de uppmätta regn egenskaperna   mot vetenskapliga modeller som beskriver ett naturligt regn. Där målet med   arbetet var att ta fram ett underlag på det befintliga regnet i vindtunneln. Testerna utfördes med en optisk distrometer som   mätte de fallande vattendropparna med en laser. Distrometern användes för att   mäta storlek samt fallhastighet på vattendropparna. Distrometer placerades   vid tester på olika höjder i vindtunneln, regnet undersöktes även vid   varierande vattenflöde och vindhastigheter. Resultatet visade på att simulerade regnet hade en   lägre hastighet i förhållande till den uppmätta droppstorleken högt i   tunneln. Hastigheten på dropparna lågt i tunneln visade mer följa modellernas   beskrivning av en naturligfallhastighet. Droppstorleksfördelningen visades   inte överstämma mot naturligt regn utan visar på en högre mängd stora droppar   än vad som är naturligt förekommande. Intensiteten i vindtunneln var som   lägst 62 mm/h vilket väldigt högt sett från naturligt regn. Utifrån dessa   parametrar följer inte det simulerade regnet ett naturligt förekommande regn. / The wind tunnel operated by Sport Tech Research Centres,   are a unique facility to conduct research on athletic practitioners and their   equipment. The advanced systems in the wind tunnel allows for research and   testing of materials and product in a realistic environment. Since the   construction of the wind tunnel a rain system was fitted. This system is not   measured for important factors and no knowledge of the simulated rainfall   properties or similarities to naturally occurring rain exists. The aim of this work was to perform measurements of   the existing rainfall system with regards to size and falls speed of the   droplets. The purpose was also to compare the measure rain properties to   scientific models describing natural rainfall. The goal of the work was to   get a foundation of the existing rain in the wind tunnel. The tests were performed with an optic disdrometer   that measured the falling water particles with a laser. The disdrometer   measured size and fall speed of the droplets. The tests were carried out on   different heights in the wind tunnel, the rain was also investigated at   varying water pressure and wind speeds. The result shows that the simulated rainfall had   lower speed relative to the measured drop size high in the tunnel. Fall speed   of droplets low in the tunnel showed more according to the model’s   description of a natural rain fall speed. Drop size distribution was shown   not to be consistent with natural rainfall. The distribution shows a higher   amount of large drops than is naturally occurring. Rainfall intensity was   measured to 62 mm/h as lowest which is very high compared to natural rain.   Based on these parameters the simulated rain is not a naturally occurring   rainfall. / <p>Betyg: 180803</p>

Orientador: Liliane Maria Ferrareso Lona / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química / Made available in DSpace on 2018-08-07T08:12:19Z (GMT). No. of bitstreams: 1 Bufo_MoacirJose_D.pdf: 987875 bytes, checksum: 8fa242d4879a20b9592f76cbbb4e5681 (MD5) Previous issue date: 2006 / Resumo: Águas residuárias urbanas e industriais, cujo destino final em nível mundial é o rio, sempre apresentam imiscíveis na forma de película e gotas, sejam de óleos comestíveis ou óleos lubrificantes ou solventes petroquímicos. A grande dificuldade em separar estes imiscíveis está no diâmetro de gotas inferior a 40 microns. A melhor tecnologia, hoje, produz água tratada ainda com gotas de 20 microns e com teor de imiscível igual a 10 mg/litro. O autor do presente trabalho, em 1984, acidentalmente criou um coalescedor a filme, e realizou ensaios numa instalação em escala piloto, para encontrar uma solução para um problema de imiscível em água, de uma indústria petroquímica. Os ensaios qualitativos realizados mostraram que a tecnologia é eficiente para separar imiscíveis em água. Os estudos, naquela época, não tiveram continuidade. O regime de operação da instalação piloto era contínuo. A aparelhagem da piloto era totalmente em vidro. O controle destes ensaios foi por meio visual que é bastante significativo pelo fato de ser um controle simnão, isto é, ou tem turbidez ou não tem turbidez. A água residuária entrando no coalescedor era homogênea e na saída do coalescedor havia a formação de duas camadas distintas com uma interface de separação. A camada inferior apresentava uma turvação e a camada superior não apresentava turvação. Este fato mostra de forma inquestionável de que ocorreu um processo de aglutinação de partículas ou coalescência. Desta forma, o objetivo deste trabalho é dar continuidade ao trabalho iniciado em 1984, visando desenvolver uma metodologia para explicar o fenômeno da coalescência neste tipo de coalescedor e também desenvolver um modelo para o seu dimensionamento, visto que o fluxograma do processo já está estabelecido. Este trabalho é assim definido como teórico, uma vez que já existe o trabalho experimental realizado em 1984. A consulta em literatura tem três enfoques: O primeiro é conhecer o fenômeno da coalescência em termos científico. O segundo enfoque foi conhecer o estado da arte da tecnologia de coalescedor. O terceiro foi uma compilação de todos aqueles conhecimentos científicos e tecnológicos julgados pertinentes para a condução deste estudo. Adotouse, neste trabalho, o método de dedução indutiva e a antiga técnica da equação da proporcionalidade para propor um mecanismo e uma equação cinética da coalescência em filme de líquido. Também foi usada a equação da continuidade de NavierStokes para determinar o perfil de concentração das gotas ao longo do filme, visando gerar um modelo de dimensionamento para o coalescedor proposto. Foi constatado que o comportamento de imiscível em água é específico para cada espécie química e também depende da intensidade de energia aplicada ao meio. Por este motivo, a consolidação da tecnologia de separação de gotas de imiscível proposta só poderá ser realizada mediante um estudo numa instalação em escala industrial. Qualquer estudo em escala piloto vem somente confirmar o que já foi realizado e no máximo fornecer valores isolados de concentração de gotas de imiscível / Abstract: Urban and industrial wastewaters always have immiscible chemicals. These immiscibles are chemicals such as edible oils, lubricant oil and petrochemical solvents. The final destinations of these wastewaters is the river. It is very difficult to separate immiscibles with diameter drop less than 40 µm from the wastewater. The best separation technology available today still produces clean water with drops below 20 microns and with immiscible content of 10 mg/l. In 1984 the author of this work accidentally created one coalescence film equipment. The pilot scale test results were successful in separating immiscibles from wastewater in a petrochemical plant. The glass pilot plant operated continuously. The kind of control plant it is visual to detect the turbidity. The homogenous liquid wastewater is fed to the top of the coalescence equipment. The liquid issue. the bottom of equipment had two phases. The lower phase was turbid and the upper phase was not. Unfortunately the investigation was stopped at the time. Based on the research developed in 1984, the objective of this work is to study the phenomena of coalescence of the liquid film and to develop a kinetic coalescence model and a design model for a coalescence equipment. This present work is theoretical based on the experimental date (process flowsheet and design equipment) obtained in 1984. There are three main objectives: the first objective is to understand the coalescence phenomena; the second is to understand the development of coalescer technology; the third is to compile all relevant scientific and technological knowledge for this research. The investigation used the inductive deduction method and the old proportional equation technique to suggest a mechanism and kinetic equation to describe the film coalescence phenomenon. The NavierStokes equation was used to determine the drop concentration profile in the film, in order to produce a way to design the equipment. One conclusion is that each immiscible chemical behave differently in water. The applied energy also plays a role. Another pilot plant will only confirm what has been done and give isolated immiscible products drop concentration / Doutorado / Desenvolvimento de Processos Químicos / Mestre em Engenharia Química

<div>Rain drop size distributions (DSDs) in severe convective storms are highly variable in time and space. DSDs can be derived from polarimetric radar observations at high spatiotemporal resolution but these observations are often lacking near the surface owing to radar horizon issues. Disdrometers provide “ground-truth” measurements and validation of radar-derived DSDs but are by nature limited point measurements. Moreover, substantial evolution of the DSD can occur between the lowest radar elevation angle and the surface. Recent studies have shown that hydrometeor size sorting (HSS) is an important and even dominant process contributing to DSD evolution in severe storms; many physical processes such as the strength of the updraft, transient effects, and storm-relative mean winds are contributing factors to continued size sorting. In this study, we focus on strong storm-relative mean winds that induce sustained size sorting owing to the different residence times of hydrometeors of different sizes as they fall in severe storms. The resulting differential advection leads to a distinct horizontal spread of hydrometeors of different sizes at the bottom of a given layer. The goal of this study is to evaluate the impact of size sorting on DSD evolution from the radar level to the surface. To accomplish this, we develop and apply a raindrop trajectory model to compute the evolution of DSDs between radar observations aloft and the surface. For simplicity and to isolate the effects of size sorting, we neglect processes such as breakup, collection, and evaporation, and assume a horizontally homogeneous wind profile. We use disdrometer and radar data, which measure DSDs at the surface and provide the observed quantities aloft, respectively. The disdrometer data was collected from portable disdrometers as a collaboration between Purdue University, University of Oklahoma, University of Massachusetts, and the National Severe Storms Laboratory during the VORTEX-SE 2017 field campaign. NEXRAD data from KHTX Huntsville, AL and KGWX Columbus Air Force Base, MS was retrieved from the National Centers for Environmental Information (NCEI).</div><div><br></div><div>We evaluate three separate cases, a tornadic QLCS on 30 April 2017, a cluster storm on 27 March 2017, and a squall line on 25 March 2017. After the radar data is pre-processed, we retrieve the DSDs from the radar by assuming a gamma distribution and discretize them into PARSIVEL bins to produce a gridded dataset of DSDs. We then apply the raindrop trajectory model to compute the DSDs at the surface which are then compared directly with disdrometer observations. Analysis and comparisons from all cases yield similar results in that-the sorted radar DSDs at the surface are overall closer to the disdrometer observations than the original radar DSDs aloft. Results also show that the spatial variation of DSDs is higher at the surface due to size sorting by the storm-relative mean winds.</div><div><br></div>

<p> The separation of a mixture of carbon tetrachloride in water was studied in a 2 inch diameter glass hydrocyclone. First, the effect of a mixing valve and of oil/water ratio on the volume/surface diameter of the dispersion in the feed to the hydrocyclone was studied using a statistical experiment design. Secondly, the effect of feed drop size distribution, oil/water ratio, and overflow/underflow split on the separation in the hydrocyclone was determined, again using a statistical experiment design. In both designs, five levels of each variable were studied. Flow rate, design shape, and temperature were kept constant. The range of variables was: </p> <p> 1. Mixing Value Pressure Drop 17.95 to 88.25 mm. Hg </p> <p> 2. Oil/Water Ratio 0.132 to 0.211 </p> <p> 3. Overflow/Underflow Split 4/1 to 8/1 </p> <p> From the first part of the work it was found that oil/water ratio had no significant effect on the volume/surface diameter, and that there was a linear relationship between the volume/surface diameter and mixing valve pressure drop. </p> <p> From the second part of the work it was found that volume split had most significant effect on hydrocyclone separation for the range of variables studied. The oil/water ratio had the next most significant effect on separation, and finally, drop size distribution was also found to be significant, but was the least important of the three variables. The interactions of the variables were no significant. The hydrocyclone separation could be predicted. The prediction of the overflow drop-size distribution agreed very well with the distribution observed photographically. Both predictions required assumptions that short-circuit flow and drop-drop coalescence was negligible. </p> / Thesis / Master of Engineering (ME)

Emulsion explosives have become the preferred choice as blasting agents for numerous industries including mining, agriculture, and construction. One of the most important components in such an emulsion is an emulsifier, which controls the emulsification properties of the explosive. The present study involves the production of one such emulsifier, which is produced by reacting two immiscible liquids, PIBSA (polyisobutylene succinic anhydride) and MEA (monoethanolamine). The study examines the effect of design variable such as the impeller speed, impeller type and the dispersed phase volume fraction on interfacial area. Experiments were carried out in a 0.15 m diameter fully baffled stirred tank using a 6-bladed Rushton turbine impeller and a marine propeller. Drop size was determined using a microscope with a video camera and image processing system. The transient concentration of PIBSA was determined using FTIR analysis and used to estimate the volume fraction of the dispersed phase (ƒÖ). The effective interfacial area was calculated using the Sauter mean drop diameter, d32 and ƒÖ. Impeller speeds ranging from 150 to 600 rpm and dispersed phase volume fractions, ƒÖ ranging from 0.01 to 0.028 were examined in the experimental study. It was found that that the evolution of Sauter mean drop diameter, d32 has four different trends depending on ƒÖ and impeller speed. At high impeller speeds and high ƒÖ, d32 values decrease initially and reach constant values after a long period of time. This trend is consistent with the findings in previous investigations. Under certain operating conditions, d32 values increase initially with stirring time to reach a maximum value and then decrease to reach a steady state value. The presence of these trends has been attributed to the effect of changing physical properties of the system as a result of chemical reaction. Results indicate that, in general, Sauter mean drop diameter d32 decreases with an increase in agitation intensity. However a decrease in the dispersed phase volume fraction is found to increase d32. These trends are found to be the same for both impeller types studied. Comparing the drop size results produced by the two impellers, it appears that low-power number propeller produces s ignificantly smaller drops than the Rushton turbine. It was found that the concentrations of reactants decrease with time for all impeller speeds thereby leading to a decrease in interfacial area with the progress of the reaction. Interfacial area values obtained at higher impeller speeds are found to be lower in spite of lower d32 values at these speeds. Also, these values decrease with time and become zero in a shorter duration indicating the rapid depletion of MEA. The interfacial area values obtained with the propeller at a given impeller speed are lower as compared to those for Rushton turbine. They also decrease and become zero in a shorter duration as compared to those for Rushton turbine suggesting propeller¡¦s performance is better in enhancing the reaction rate.