Cette thèse traite de la manipulation de l'énergie dans trois systèmes quantiques ouverts différents dans la limite de couplage faible système-environnement, et leurs dynamiques respectives sont décrites par une équation maîtresse quantique markovienne. Dans le premier chapitre, le calcul d'une telle équation est réalisé pour un système particulier, et diverses notions de thermodynamique quantique sont introduites. Pour le premier système physique, on analyse le transport d'énergie le long de chaînes atomiques (entre 2 et 7 atomes) soumises à un rayonnement de corps noir proche de la température ambiante. Il est montré que l'efficacité du transport peut atteindre des valeurs remarquables, surpassant 100% et atteignant jusqu'à 1400% dans certaines configurations. De plus, lorsque l'efficacité est amplifiée, la portée du transport est également considérablement augmentée. Le chapitre suivante traite aussi du transport d'énergie dans des chaînes atomiques. Le système quantique est placé à l'interface d'un isolant topologique photonique (ITP), qui supporte un plasmon polariton de surface (PPS) insensible à la réflexion. Le PPS se propage le long de la chaîne atomique et assiste le transport d'énergie. La comparaison est faite entre PPSs réciproque et unidirectionnel en termes d'efficacité du transport, et il est démontré que ce dernier produit une meilleure efficacité, de plus d'un ordre de grandeur. De surcroît, divers aspects pratiques dus aux propriétés des ITPs sont mis en avant, notamment la robustesse du transport d'énergie en présence de défauts sur le parcours du PPS. Enfin, un système quantique immergé dans un champ électromagnétique hors équilibre thermique est étudié. Il est composé d'un système à trois niveaux d'énergie, jouant le rôle de machine thermique quantique à absorption, ainsi que de N atomes à deux niveaux ("qubits") qui sont affectés par l'action de la machine. Il est montré que la machine est capable de délivrer des tâches thermiques d'intensité significative sur les qubits, y compris lorsque leur nombre augmente. De plus, il est mis en évidence qu'en raison d'interactions qubit-qubit, les tâches réalisées par la machine sont distribuées parmi l'ensemble du système des qubits en interaction, de sorte que dans certains cas, même les qubits complètement découplés de la machine subissent une modification de température considérable. Ce mécanisme de distribution des tâches est analysé à travers les corrélations entre différentes partitions du système quantique. Par ailleurs, le contrôle des tâches thermiques est également discuté. / This thesis deals with energy management in open quantum systems. Three different systems are under study in the limit of weak system-environment coupling, and their dynamics is described by Markovian quantum master equations. In the first chapter, the complete derivation of such equation is performed in a specific case, and several notions of quantum thermodynamics are introduced. In the first system, energy transport is investigated along atomic chains (between 2 and 7 atoms) embedded in blackbody radiation around room temperature. It is shown that the transport efficiency can reach remarkable values, exceeding 100% and reaching 1400% in some configurations. Moreover, when the efficiency is amplified, the transport range is also considerably increased. The following chapter also deals with energy transport in atomic chains. The quantum system is located at the interface of a photonic topological insulator (PTI), supporting a unidirectional surface-plasmon-polariton (SPP) immune to backscattering. The SPP propagates along the chain and assists energy transport. Comparison is made between reciprocal and unidirectional SPPs in terms of transport efficiency, and it is shown that the latter can yield an efficiency larger by one order of magnitude. In addition, several practical aspects stemming from PTIs are highlighted, including the robustness of energy transport in the presence of defects on the SPP path. In the last chapter, a quantum system embedded in an out-of-thermal-equilibrium electromagnetic field is investigated. It is composed of a three-level atom playing the role of an absorption quantum thermal machine, as well as N two-level atoms ('qubits'), with N=1,...,6, which are the target bodies. It is demonstrated that the machine is able to perform significant thermal tasks on the qubits, even when their number is increased. Moreover, it is pointed out that due to qubit-qubit interactions, the tasks delivered by the machine are distributed throughout the system of interacting qubits, such that in some cases the temperature of the qubits which are completely decoupled from the machine can still be considerably affected by it. This task-distribution mechanism is investigated by means of the correlations between different subparts of the system. In addition, the tuning of thermal tasks is discussed.

No description available.

Following established traditions in anthropology and sociology, where cross-border research helps to identify important themes which benefit from comparative study, this dissertation introduces cross-sector policy research as a new methodology for generating useful insights about public policy. The cross-sector method is applied to the study of the UK energy and transport sectors. A range of generic policy developments in the energy sector are identified including: the development of efficiency indicators, scenario analysis, and the establishment of energy efficiency programmes. Such developments have not, as yet, occurred in the transport sector. A structural analogy between energy and transport is developed which is used to generate a range of innovations for transport policy including: gross mass movements and intensities as indicators of the efficiency with which the economy uses transport; the projection of a quantitative scenario of sustainable mobility; and the outline of a transport efficiency programme. The insights from the analogy are generalised to consider the benefits of a wider application of cross-sector policy research to other policy areas.

Do changes in how cross-equatorial energy transport is partitioned between the ocean and atmosphere impact the hemispheric climate response to forcing? To find out, we alter the cross-equatorial ocean heat transport in a state-of-the-art GCM and ascertain how changes in energy transport and its partitioning impact hemispheric climate and precipitation sensitivity following abrupt CO2-doubling. We further evaluate the applicability our results in CMIP6-class ESMs, where AMOC facilitates the northward cross-equatorial ocean heat transport. In our experiments, changes in ocean cross-equatorial energy transport trigger compensating changes in atmospheric energy transport through changes in the Hadley cells and a shift in the Intertropical Convergence Zone. However, the climate sensitivity in each hemisphere is linearly related to the ocean heat transport convergence, not atmospheric energy transport convergence, due to the impact of ocean heating on evaporation and atmospheric specific humidity. Similarly, we also find that ocean heat transport convergence controls the hemispheric precipitation sensitivity through the impact of ocean heating on surface evaporation. This relationship is also evident in CMIP6 models, where we find differences in hemispheric precipitation sensitivity to be related to the Atlantic Meridional Overturning Circulation (AMOC). Changes in the AMOC control hemispheric differences in upper ocean heat content, which then affect how the hydrologic cycle responds to CO2 forcing in each hemisphere. These results suggest that ocean dynamics impact the hemispheric climate response to CO2 forcing, particularly how much regional precipitation changes with warming. / Graduate

O espalhamento eletromagnético por uma esfera com propriedades ópticas e raio arbitrários, conhecido como espalhamento de Lorenz-Mie, ou por um cilindro circular infinito, pode ser resolvido analiticamente e é comumente tratado dentro da abordagem de espalhadores dielétricos. Na região óptica, tanto meio circundante quanto partícula espalhadora possuem o mesmo valor de permeabilidade magnética. A ausência do magnetismo nessa região do espectro torna o índice de refração relativo entre os meios interno e externo ao espalhador homogêneo equivalente ao respectivo índice de impedância óptica. Em regiões espectrais de micro-ondas ou radiofrequências, entretanto, materiais ferro- e ferrimagnéticos podem exibir valores absolutos de permeabilidade magnética extremamente elevados, reduzindo então a impedância óptica em comparação ao valor correspondente de índice de refração relativo. Uma característica marcante vinculada ao magnetismo no centro espalhador é que pequenas partículas comparadas com o comprimento de onda (parâmetros de tamanho na região de Rayleigh) podem apresentar grandes seções de choque de extinção a despeito de suas pequenas seções de choque geométricas. Isso torna possível, fisicamente, a presença de picos de ressonância morfológica na energia eletromagnética interna ao centro espalhador mesmo na região de parâmetros de tamanho inferiores à unidade. Em especial, mostramos que essa energia eletromagnética possui, no regime de fraca absorção, uma relação funcional simples com o comprimento de onda incidente e a seção de choque de absorção da partícula espalhadora, independentemente do formato geométrico da mesma. No espalhamento por uma coleção de partículas magnéticas, a velocidade de transporte de energia pode ser estimada a partir da energia eletromagnética média que é armazenada no interior de um centro espalhador isolado. Dessa maneira, a validade da relação universal que encontramos entre o fator de aumento da energia eletromagnética interna ao centro espalhador e sua correspondente seção de choque de absorção (no regime de baixa absorção óptica) implica na possibilidade de estimarmos de maneira simples a velocidade de transporte de energia em um meio desordenado. Um resultado decorrente dessa aproximação é que mesmo na região de Rayleigh a velocidade de transporte de energia em um meio magnético desordenado é drasticamente reduzida, levando, por conseguinte, à redução do coeficiente de difusividade dos fótons no meio. O estudo analítico e numérico da energia eletromagnética armazenada por uma esfera e por um cilindro magnéticos irradiados por ondas planas homogêneas são os temas em foco nesta dissertação de Mestrado. / Electromagnetic scattering by a sphere with arbitrary optical properties and radius, known as the Lorenz-Mie scattering, or by an infinite right circular cylinder can be solved analytically and is widely treated in the approach of dielectric scatterers. In the optical range, both embedding medium and scattering particle have the same magnetic permeability. The absence of magnetism in this spectral range leads to the equivalence between the relative refraction and impedance indices associated with the scatterers. However, in microwave or radio-frequency ranges, ferro- and ferrimagnetic materials can exhibit extremely huge values of magnetic permeability, which reduce the optical impedance in comparison to the corresponding value of relative refraction index. One striking feature associated with the magnetism in the scatterer is that particles smaller than the wavelength (Rayleigh size region) can present large extinction cross sections in despite of their small geometric cross sections. This becomes physically possible the presence of morphology-dependent resonances in the electromagnetic energy within the scatterer even in size parameters region smaller than unity. In particular, we show that this time-averaged electromagnetic energy has, in the weak absorption regime, a simple functional relation with the incident wavelength and the scatterer absorption cross section which does not depend on the shape of the scatterer. In the multiple scattering regime, the energy-transport velocity can be estimated from the time-averaged electromagnetic energy stored in a single scatterer. Thereby, the validity of the universal relation between the internal energy-enhancement factor and the absorption cross section respective to an arbitrary scattering center (in the weak absorption regime) implies that the energy-transport velocity in disordered media can be evaluated in a simple way. From this approximation, we obtain that even in the Rayleigh size region the energy-transport velocity in disordered magnetic media is dramatically reduced, which consequently leads to a reduction of the diffusion coefficient of the photons. The analytical and numerical studies of the time-averaged electromagnetic energy within magnetic isotropic spheres and cylinders irradiated by plane waves are our aim in this Master\'s degree dissertation.

O espalhamento eletromagnético por uma esfera com propriedades ópticas e raio arbitrários, conhecido como espalhamento de Lorenz-Mie, ou por um cilindro circular infinito, pode ser resolvido analiticamente e é comumente tratado dentro da abordagem de espalhadores dielétricos. Na região óptica, tanto meio circundante quanto partícula espalhadora possuem o mesmo valor de permeabilidade magnética. A ausência do magnetismo nessa região do espectro torna o índice de refração relativo entre os meios interno e externo ao espalhador homogêneo equivalente ao respectivo índice de impedância óptica. Em regiões espectrais de micro-ondas ou radiofrequências, entretanto, materiais ferro- e ferrimagnéticos podem exibir valores absolutos de permeabilidade magnética extremamente elevados, reduzindo então a impedância óptica em comparação ao valor correspondente de índice de refração relativo. Uma característica marcante vinculada ao magnetismo no centro espalhador é que pequenas partículas comparadas com o comprimento de onda (parâmetros de tamanho na região de Rayleigh) podem apresentar grandes seções de choque de extinção a despeito de suas pequenas seções de choque geométricas. Isso torna possível, fisicamente, a presença de picos de ressonância morfológica na energia eletromagnética interna ao centro espalhador mesmo na região de parâmetros de tamanho inferiores à unidade. Em especial, mostramos que essa energia eletromagnética possui, no regime de fraca absorção, uma relação funcional simples com o comprimento de onda incidente e a seção de choque de absorção da partícula espalhadora, independentemente do formato geométrico da mesma. No espalhamento por uma coleção de partículas magnéticas, a velocidade de transporte de energia pode ser estimada a partir da energia eletromagnética média que é armazenada no interior de um centro espalhador isolado. Dessa maneira, a validade da relação universal que encontramos entre o fator de aumento da energia eletromagnética interna ao centro espalhador e sua correspondente seção de choque de absorção (no regime de baixa absorção óptica) implica na possibilidade de estimarmos de maneira simples a velocidade de transporte de energia em um meio desordenado. Um resultado decorrente dessa aproximação é que mesmo na região de Rayleigh a velocidade de transporte de energia em um meio magnético desordenado é drasticamente reduzida, levando, por conseguinte, à redução do coeficiente de difusividade dos fótons no meio. O estudo analítico e numérico da energia eletromagnética armazenada por uma esfera e por um cilindro magnéticos irradiados por ondas planas homogêneas são os temas em foco nesta dissertação de Mestrado. / Electromagnetic scattering by a sphere with arbitrary optical properties and radius, known as the Lorenz-Mie scattering, or by an infinite right circular cylinder can be solved analytically and is widely treated in the approach of dielectric scatterers. In the optical range, both embedding medium and scattering particle have the same magnetic permeability. The absence of magnetism in this spectral range leads to the equivalence between the relative refraction and impedance indices associated with the scatterers. However, in microwave or radio-frequency ranges, ferro- and ferrimagnetic materials can exhibit extremely huge values of magnetic permeability, which reduce the optical impedance in comparison to the corresponding value of relative refraction index. One striking feature associated with the magnetism in the scatterer is that particles smaller than the wavelength (Rayleigh size region) can present large extinction cross sections in despite of their small geometric cross sections. This becomes physically possible the presence of morphology-dependent resonances in the electromagnetic energy within the scatterer even in size parameters region smaller than unity. In particular, we show that this time-averaged electromagnetic energy has, in the weak absorption regime, a simple functional relation with the incident wavelength and the scatterer absorption cross section which does not depend on the shape of the scatterer. In the multiple scattering regime, the energy-transport velocity can be estimated from the time-averaged electromagnetic energy stored in a single scatterer. Thereby, the validity of the universal relation between the internal energy-enhancement factor and the absorption cross section respective to an arbitrary scattering center (in the weak absorption regime) implies that the energy-transport velocity in disordered media can be evaluated in a simple way. From this approximation, we obtain that even in the Rayleigh size region the energy-transport velocity in disordered magnetic media is dramatically reduced, which consequently leads to a reduction of the diffusion coefficient of the photons. The analytical and numerical studies of the time-averaged electromagnetic energy within magnetic isotropic spheres and cylinders irradiated by plane waves are our aim in this Master\'s degree dissertation.

No description available.

<p dir="ltr">Photovoltaics are leading devices in green energy production. Understanding the fundamental physics behind energy transport in candidate materials for future photovoltaic and optoelectronic devices is necessary to both realize material limitations and improve efficiency. Excitons, which are bound electron-hole pairs, are central to determining how energy propagates throughout semiconductors. Exciton transport is greatly influenced by material dimensionality. In highly ordered quantum dot (QD) systems, electronic coupling between individual QDs can lead to coherent exciton transport, whereas in two-dimensional heterostructures, excitons can form at the interface of a heterojunction, creating charge-transfer excitons.</p><p dir="ltr">This dissertation is dedicated to summarizing the studies of exciton transport and behavior in two systems: perovskite QD superlattices and transition metal dichalcogenide (TMDC)/polyacene heterostructures. Chapter 1 provides readers with details on these materials in addition to information on the fundamental concepts (i.e., excitons, phonons, energy transfer) needed to best appreciate further chapters. Chapter 2 summarizes the spectroscopic techniques (photoluminescence and transient absorption spectroscopy and microscopy) used to examine exciton behavior. Next, the effects of disorder and dephasing pathways on the ability of perovskite QDs to coherently couple is investigated through the lens of superradiance in Chapter 3. After this, the temperature-dependent exciton transport within perovskite QD superlattices is imaged with high spatial and temporal resolutions in Chapter 4. The experimental transport data on these superlattices provides evidence for environment-assisted quantum transport, which, until this study, had yet to be realized in solid-state systems. In Chapter 5, attention is switched to verifying the existence and deepening the understanding of the behavior of several spatially separated interlayer excitons in a tungsten disulfide/tetracene heterostructure. Finally, Chapter 6 summarizes the preliminary results obtained through transient absorption spectroscopy on other TMDC/polyacene heterostructures where separation of the triplet pair state is attempted. </p><p dir="ltr">It is this author’s hope that this dissertation will not only summarize their graduate work but will also serve as inspiration for others to continue learning and contribute to the advancement of the energy research field.</p>

Cooking is an integral part of each and every human being as food is one of the basic necessities for living. Commonly used sources of energy for cooking are firewood, crop residue, cow dung, kerosene, electricity, liquefied petroleum gas(LPG), biogas etc. Half of the world’s population is exposed to indoor air pollution, mainly the result of burning solid fuels for cooking and heating. Wood cut for cooking purpose contributes tothe16 million hectares(above4% of total area of India) of forest destroyed annually. The World Health Organization(WHO) reports that in 23 countries 10% of deaths are due to just two environmental risk factors: unsafe water, including poor sanitation and hygiene; and indoor air pollution due to solid fuel usage for cooking. In under-developed countries, women have to walk 2kms on average and spend significant amount of time for collecting the firewood for cooking. The cooking energy demand in rural areas of developing countries is largely met with bio-fuels such as fuel wood, charcoal, agricultural residues and dung cakes, whereas LPG or electricity is predominantly used in urban areas. India has abandon amount of solar energy in most of the regions making it most ideal place for harvesting solar energy. With almost 300 sunny days each year, one can confidently relay on this source of energy. India’s geographical location is in such a way that theoretically it receives 5x1015 kWh/ year of solar energy. Solar cooking is the simplest, safest, environmental friendly and most convenient way to cook. It is a blessing for those who cook using firewood or cow dung, who walk for miles to collect wood, who suffer from indoor air pollution. Hence solar cooking is going to play major role in solving future energy problem. Solar based cooking has never been a strong contender in the commercial market or even close to being a preferred method of cooking. They have been relegated to demonstration appliances to show case the solar based concepts. In this mode, cooking is no longer a time independent activity that can be performed at any time of day. One is forced to cook only at certain times when there is sufficient insolation. The geography of the cooking activity also shifts away from the kitchen. The kitchen is no longer the hearth of the home as the actual cooking activity shifts to the roof tops or high insolation platforms. This further adds to the inconvenience apart from being unable to cook at night or during cloudy conditions or during most of the winter days. Another issue of significant inconvenience is the general social structure in most families of the developing countries wherein the cooking activity is carried out by the senior ladies of the home. They are generally not athletic enough to be moving to and from the kitchen and the roof top to carry out the cooking exercise. As the solar cookers are enclosed spaces, interactive cooking is not possible let alone having any control on the rate of cooking. These are some of the more significant issues in the social psyche that has abundantly impeded the acceptance of solar thermal based cooking appliances. These issues and problems are in fact the motivating factors for this thesis. Based on these motivating factors, this thesis aims to propose solutions keeping the following points as the major constraints. cooking should be performed in the kitchen. one should be able to perform the cooking activity independent of the time of day or insolation. the cooking activity should be interactive the time taken for cooking should be comparable with the conventional methods in vogue. there should be a reduction in the use of conventional energy. Using the constraints and the motivating factors discussed above as the central theme, this thesis proposes a method to transfer solar thermal energy to the kitchen and act as a supplement to the conventional source of energy like the LPG or other sources that are traditionally being used in the households. The method proposed is in fact a hybrid scenario wherein the solar thermal is used to supplement the traditional source. Solar photovoltaic cells are also used to power the electronics and apparatus proposed in this thesis. This thesis addresses in detail the issues in analysis, modeling, designing and fabrication of the proposed hybrid solar cooking topology. The main goal of the proposed system is to transfer heat from sun to the cooking load that is located in the kitchen. The topology includes an additional feature for storing the energy in a buffer. The heat is first transferred from the solar thermal collector to a heat storage tank(that acts as the buffer) by circulating the heat transfer fluid at a specific flow rate that is controlled by a pump. The stored heat energy that is collected in the buffer is directed into the kitchen by circulating the heat transfer fluid into the heat exchanger, located in the kitchen. This is accomplished by controlling the flow rate using another pump. The solar thermal collector raises the temperature of the thermic fluid. The collector can be of a concentrating type in order to attain high temperatures for cooking. Concentrating collector like linear parabolic collector or parabolic dish collector is used to convert solar energy into heat energy. Absorption of energy from the incident solar insolation is optimized by varying the flow rate of circulating thermic fluid using a pump. This pump is energized from a set of photovoltaic panels(PV cell) which convert solar energy into electrical energy. The energy absorbed from the solar thermal collector is stored in a buffer tank which is thermally insulated. Whenever cooking has to be carried out, the high temperature fluid from the buffer tank is circulated through a heat exchanger that is located in the kitchen. The rate of cooking can be varied by controlling both the flow rate of fluid from the buffer tank to heat exchanger and also by controlling the amount of energy drawn from the auxiliary source. If the available stored energy is not sufficient, the auxiliary source of energy is used for cooking in order to ensure that cooking is in-dependent of time and solar insolation. In the proposed hybrid solar cooking system, the thesis addresses the issues involved in optimization of energy extracted from sun to storage tank and its subsequent transfer from the storage tank to the load. The flow rate at which maximum energy is extracted from sun depends on many parameters. Solar insolation is one of the predominant parameters that affect the optimum flow rate. Insolation at any location varies with time on a daily basis (diurnal variations) and also with day on a yearly basis(seasonal variation). This implies that the flow rate of the fluid has to be varied appropriately to maximize the energy absorbed from sun. In the proposed system, flow rate control plays a very significant role in maximizing the energy transfer from the collector to the load. The flow rate of the thermic fluid in the proposed system is very small on the order of 0.02kg/s. It is very difficult to sense such low flows without disrupting the operating point of the system. Though there are many techniques to measure very low flow rates, they invariably disrupt the system in which flow rate has to be measured. Further, the low flow sensors are far too expensive to be included in the system. A reliable, accurate and inexpensive flow measuring technique has been proposed in this thesis which is non-disruptive and uses a null-deflection technique. The proposed measuring method compensates the pressure drop across the flow meter using a compensating pump. The analysis, modeling, design and fabrication of this novel flow meter are addressed. The design and implementation of different subsystems that involves the selection and design of solar concentrating collector and tracking are explained. Finally, it is essential to know the economic viability of the proposed system that is designed and implemented. To understand the economics, the life cycle cost analysis of the proposed system is presented in this thesis. The major contributions of this thesis are: Energy transport: Major challenge in energy transport is to bring heat energy obtained from the sun to the kitchen for cooking. Energy transferred from solar insolation to the cooking load has to be optimized to maximize the overall efficiency. This can be split in to two parts,(a) optimizing efficiency of energy transferred from the collect or to the energy buffer tank,(b) optimizing efficiency of energy transferred from the buffer tank to the load. The optimization is performed by means of a maximum power point tracking(MPPT) algorithm for a specific performance index. Modeling of the cooking system: There are several domains that exist in the solar cooking system such as electrical domain, thermal domain, and hydraulic domain. The analysis of power/energy flow across all these domains presents a challenging task in developing a model of the hybrid cooking system. A bond graph modeling approach is used for developing the mathematical model of the proposed hybrid cooking system. The power/energy flow across different domains can be seamlessly integrated using the bond graph modeling approach. In this approach, the various physical variables in the multi-domain environment are uniformly de-fined as generalized power variables such as effort and flow. The fundamental principle of conservation of power/energy issued in describing the flow of power/energy across different domains and thus constructing the dynamic model of the cooking system. This model is validated through experimentation and simulation. Flow measurement: A novel method of low fluid mass flow measurement by compensating the pressure drop across the ends of measuring unit using a compensating pump has been proposed. The pressure drop due to flow is balanced by feedback control loop. This is a null-deflection type of measurement. As insertion of such a measuring unit does not affect the functioning of the systems, this is also a non-disruptive flow measurement method. This allows the measurement of very low flow rate at very low resolution. Implementation and design of such a unit are discussed. The system is modeled using bond graph technique and then simulated. The flow meter is fabricated and the model is experimentally validated. Design Toolbox: Design of hybrid cooking system involves design of multi domain systems. The design becomes much more complex if the energy source to operate the system is hybrid solar based. The energy budget has to be evaluated considering the worst case conditions for the availability of the solar energy. The design toolbox helps in assessing the user requirement and help designing the cooking system to fulfill the user requirement. A detailed toolbox is proposed to be developed that can be used in designing/selecting sub-systems like collector, concentrator, tracking system, buffer tank, heat exchanger, PV panel, batteries etc. The toolbox can also be used for performing life cycle costing.

Le présent mémoire de maîtrise est consacré à une étude spectroscopique de la température du gaz dans les plasmas hors équilibre thermodynamique d’argon à la pression atmosphérique. Nous avons notamment pu extraire, à l’aide de mesures par spectroscopie optique d’émission de structures rotationnelles des systèmes OH (A2Σ+- X2Πi) et N2+ (B2Σu+- X2Σg+), la température rotationnelle d’un plasma radiofréquence en régime capacitif et d’un plasma micro-onde produit par une onde électromagnétique de surface. En comparant ces mesures à celles obtenues par l’analyse de l’élargissement des raies 2p2-1s2 et 2p3-1s2 de l’argon avec un spectromètre à très haute résolution spectrale, nous avons pu démontrer que l’équilibre rotation-translation (Trot=Tg) n’est jamais atteint dans les configurations de plasmas étudiées. Cet écart entre les deux températures est attribué à l’influence des électrons, en compétition avec les atomes neutres, imposant leurs propres températures sur la distribution des niveaux rotationnels. De plus, l’effet du flux de gaz et de l’ajout de CO2 sur le chauffage du gaz a été étudié dans un plasma micro-onde d’argon à la pression atmosphérique. Nous avons noté des changements importants dans les profils axiaux de Tg en amont et en aval de l’excitateur à onde de surface selon les conditions opératoires. Pour séparer les facteurs gouvernant le chauffage du gaz à ceux associés au dépôt de puissance par l’onde électromagnétique, nous avons normalisé nos valeurs de Tg aux intensités des émissions de l’argon liées aux transitions 2p-1s entre 700 et 900 nm. Pour des temps de résidence dans le plasma d’argon suffisamment longs (et donc de faibles débits de gaz), les valeurs de Tg normalisées montrent un comportement assez constant, ce qui indique que le chauffage s’effectue principalement de manière locale. Au contraire, pour des temps plus longs (et donc des débits de gaz plus importants), les valeurs de Tg normalisées augmentent le long de la colonne à plasma, ce qui révèle que les phénomènes de transport commencent à jouer un rôle important. On note aussi un changement de comportement à plus hauts débits de gaz dû au passage d’un régime d’écoulement laminaire à un régime turbulent. En présence de CO2, dû aux mécanismes de chauffage additionnels, les valeurs de Tg normalisées sont systématiquement plus élevées. / The present master thesis is devoted to a spectroscopic study of the gas temperature in non-thermodynamic equilibrium argon plasmas at atmospheric pressure. In particular, we were able to extract, by means of optical emission spectroscopy measurements of rotational structures of the systems OH (A2Σ+- X2Πi) and N2+ (B2Σu+- X2Σg+), the rotational temperature of a radiofrequency plasma in capacitive mode and of a microwave plasma produced by an electromagnetic surface wave. By comparing these measurements with those obtained by the analysis of line broadening from 2p2-1s2 et 2p3-1s2 of argon with an ultrahigh spectral resolution spectrometer, we were able to demonstrate that the rotational-translational equilibrium (Trot=Tg) is never achieved in the plasma configurations studied. The departure from both temperatures is ascribed to the influence of electrons competing with neutrals to impose their own temperature on the distribution of rotational levels. In addition, the effect of gas flow and addition of CO2 admixtures on the gas heating has been studied in a microwave argon plasma at atmospheric pressure. We noted significant changes in the axial profiles of Tg on the upstream and downstream plasma column according to operating conditions. To separate the factors governing the heating of gas from those associated with the deposition of power by the electromagnetic wave, we have normalized our Tg values to the intensities of the argon emissions linked to the transitions 2p-1s between 700 and 900 nm. For long enough gas residence times in the argon plasma (and therefore low gas flow rates), normalized Tg values show a fairly constant behaviour, which indicates that the heating takes place mainly locally. On the contrary, for longer times (and therefore higher gas flow rates), normalized Tg values increases along the plasma column, which reveals that transport phenomena are starting to play an important role. There is also a change in behaviour at higher gas flow rates due to the change from a laminar flow regime to a turbulent regime. In the presence of CO2 admixtures, due to additional heating mechanisms, normalized Tg values are consistently higher.